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1. 发明授权

US09580526B2 Partially fluorinated polysulfinic acids and their salts 有权
标题翻译：部分氟化聚亚磺酸及其盐
公开(公告)号：US09580526B2
公开(公告)日：2017-02-28
申请号：US13885185
申请日：2011-12-09
申请人： Zai-Ming Qiu , Gregg D. Dahlke , Tatsuo Fukushi , Werner M. Grootaert , Miguel A. Guerra
发明人： Zai-Ming Qiu , Gregg D. Dahlke , Tatsuo Fukushi , Werner M. Grootaert , Miguel A. Guerra
IPC分类号： C08F14/16 , C08F8/34 , C08F114/16 , C08F8/44 , C08F28/02
CPC分类号： C08F114/16 , C08F8/12 , C08F8/26 , C08F8/34 , C08F8/44 , C08F14/16 , C08F28/02 , C08F114/185 , C08F214/182 , C08F2800/20 , C08F2810/50 , C08F214/184 , C08F228/02
摘要： Described herein is a composition comprising a fluorinated polysulfinic acid or a salt thereof having the following formula (I): wherein X1, X2, and X3 are independently selected from H, F, Cl, Br, I, CF3, and CH3 and wherein at least one of X1, X2, or X3 is H; R1 is a linking group; Z1 and Z2 are independently selected from Br, Cl, I, F, CF3, and a perfluorinated alkyl group; M is a cation; p is 0 or 1; and n is at least 2. Also described is a method of making the partially fluorinated polysulfinic acid or salt thereof.
摘要翻译：本文描述的是包含具有下式（I）的氟化聚亚磺酸或其盐的组合物：其中X 1，X 2和X 3独立地选自H，F，Cl，Br，I，CF 3和CH 3，并且其中 X 1，X 2或X 3中的至少一个为H; R1是连接基团; Z 1和Z 2独立地选自Br，Cl，I，F，CF 3和全氟化烷基; M是阳离子; p为0或1; 并且n至少为2.还描述了制备部分氟化聚亚磺酸或其盐的方法。

2. 发明授权

US08946465B2 Preparation of oligomers and co-oligomers of highly fluorinated sulfinic acids and salts thereof 有权
标题翻译：制备高度氟化亚磺酸的低聚物和共低聚物及其盐
公开(公告)号：US08946465B2
公开(公告)日：2015-02-03
申请号：US13994819
申请日：2011-12-13
申请人： Miquel A. Guerra , Gregg D. Dahlke , Denis Duchesne , Tatsuo Fukushi , Werner M. A. Grootaert , Zai-Ming Qiu
发明人： Miquel A. Guerra , Gregg D. Dahlke , Denis Duchesne , Tatsuo Fukushi , Werner M. A. Grootaert , Zai-Ming Qiu
IPC分类号： C07C313/04 , C08G75/00 , C07C303/22 , C08F214/18
CPC分类号： C08G75/00 , C07C303/22 , C07C313/04 , C08F214/18 , C07C309/82
摘要： There is provided a method for preparing oligomers and co-oligomers of highly fluorinated sulfuric acids and salts thereof.
摘要翻译：提供了制备高度氟化亚磺酸及其盐的低聚物和共低聚物的方法。

3. 发明申请

US20060148971A1 Fluoropolymer nanoparticle coating composition 有权
公开(公告)号：US20060148971A1
公开(公告)日：2006-07-06
申请号：US11305978
申请日：2005-12-19
申请人： Naiyong Jing , Tatsuo Fukushi , Chuntao Cao , Lan Liu , Thomas Klun , William Coggio , Vivian Jones
发明人： Naiyong Jing , Tatsuo Fukushi , Chuntao Cao , Lan Liu , Thomas Klun , William Coggio , Vivian Jones
IPC分类号： C08G75/02
CPC分类号： C08J3/005 , C08J7/047 , C08J2327/12 , C08J2427/00 , C08L27/12 , C08L27/16 , C08L27/18 , C08L2205/02 , C09D127/12 , C09D127/16 , C09D127/18 , C08L2666/04
摘要： A fluoropolymer coating composition contains a homogeneous mixture of crystalline submicron fluoropolymer particles dispersed in a solvent-borne solution of less crystalline or amorphous fluororesin. The composition may be prepared by blending a latex containing crystalline submicron fluoropolymer particles with a latex containing less crystalline or amorphous fluororesin particles, coagulating and drying the blended latices, and dissolving the dried blend in a solvent for the fluororesin particles. Quasi-homogenous compositions may be prepared by blending dry crystalline submicron fluoropolymer particles with a) dry less crystalline or amorphous fluororesin particles and a solvent for the fluororesin particles, or b) a solvent-borne solution of less crystalline or amorphous fluororesin. Rubbing the disclosed coatings can provide a thin, continuous or nearly continuous fluoropolymer surface layer atop a less crystalline or amorphous fluororesin binder containing crystalline submicron fluoropolymer particles.

4. 发明申请

US20050182199A1 Fluoropolymer coating compositions with multifunctional fluoroalkyl crosslinkers for anti-reflective polymer films 失效
标题翻译：具有用于抗反射聚合物膜的多功能氟代烷基交联剂的含氟聚合物涂料组合物
公开(公告)号：US20050182199A1
公开(公告)日：2005-08-18
申请号：US11026754
申请日：2004-12-30
申请人： Naiyong Jing , Chuntao Cao , Tatsuo Fukushi , Timothy Tatge , Christopher Walker , Thomas Klun , William Schultz , Zai-Ming Qiu
发明人： Naiyong Jing , Chuntao Cao , Tatsuo Fukushi , Timothy Tatge , Christopher Walker , Thomas Klun , William Schultz , Zai-Ming Qiu
IPC分类号： A63B37/00 , C08F8/00
CPC分类号： G02B1/111 , A63B37/0004 , Y10T428/269
摘要： An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer and a fluoroalkyl containing multi-olefinic crosslinker. In another aspect of the invention, the composition further includes surface modified inorganic nanoparticles.
摘要翻译：用于抗反射膜或耦合到光学显示器的经济，光学透射，防污和防油墨，耐用的低折射率含氟聚合物组合物。在本发明的一个方面，组合物是由含氟聚合物和含氟烷基的多烯烃交联剂的反应产物形成的。在本发明的另一方面，组合物还包括表面改性的无机纳米颗粒。

5. 发明申请

US20050159557A1 Fluoroelastomers with improved low temperature property and method for making the same 失效
标题翻译：具有改善的低温性能的氟弹性体及其制备方法
公开(公告)号：US20050159557A1
公开(公告)日：2005-07-21
申请号：US10759497
申请日：2004-01-16
申请人： Tatsuo Fukushi , Nena Serios , Steven Wellner
发明人： Tatsuo Fukushi , Nena Serios , Steven Wellner
IPC分类号： C08F214/22 , C08K3/00 , C08L27/12 , C08L27/16 , C08F16/24
CPC分类号： C08L27/16 , C08F214/22 , C08L2205/02 , C08L2666/04 , C08L27/00
摘要： A compound is prepared, suitable for forming fluoroelastomers, having the unique features of a low glass transition temperature and desirable physical properties. The compound generally comprises a elastomeric copolymer, a curable component, and at least one mineral filler. The elastomeric copolymer includes interpolymerized monomeric units derived from vinylidene fluoride. Upon vulcanization the resulting elastomeric compound has desirable physical characteristics as indicated by the tensile strength, elongation and the retraction at lower temperatures (TR-10).
摘要翻译：制备适于形成含氟弹性体的化合物，其具有低玻璃化转变温度和所需物理性质的独特特征。化合物通常包含弹性体共聚物，可固化组分和至少一种矿物填料。弹性体共聚物包括衍生自偏二氟乙烯的共聚单体单元。硫化后，得到的弹性体化合物具有所需的物理特性，如拉伸强度，伸长率和在较低温度下的回缩（TR-10）所示。

6. 发明授权

US06906145B2 Bonding of a fluoropolymer layer to a substrate 失效
标题翻译：将氟聚合物层粘合到基材上
公开(公告)号：US06906145B2
公开(公告)日：2005-06-14
申请号：US10282677
申请日：2002-10-29
申请人： Ludo Govaerts , Dirk H. Arren , Tatsuo Fukushi , William D. Coggio , Klaus Hintzer , Harald Kaspar
发明人： Ludo Govaerts , Dirk H. Arren , Tatsuo Fukushi , William D. Coggio , Klaus Hintzer , Harald Kaspar
IPC分类号： F16L11/04 , B32B1/08 , B32B7/10 , B32B25/08 , B32B27/28 , B32B27/30 , C08K5/00 , C08K5/54 , C08L27/12 , C08L27/22 , C08F8/06 , C08F8/12 , C08F8/42
CPC分类号： B32B27/28 , B32B1/08 , B32B7/10 , B32B25/08 , C08K5/54 , Y10T428/1393 , C08L27/12
摘要： The present invention comprises a substrate having a fluoropolymer on at least one of its surfaces wherein one of the substrates or the fluoropolymer comprises a hydride function MH wherein M is Si, Ge, Sn or Pb. The invention further comprises articles comprising the substrate and fluoropolymer; a method of bonding the fluoropolymer to the substrate; a fluoropolymer composition that contains the fluoropolymer, a polyhydroxy cure composition, and an organic composition comprising the hydride function MH; a premix that contains the fluoropolymer and the hydride function MH; and a fluoropolymer composition that comprises (a) a thermoplastic fluoropolymer comprising Cl, Brand/or I atoms and (b) an organic compound that comprises the hydride function MH.
摘要翻译：本发明包括在其至少一个表面上具有含氟聚合物的基材，其中一个基材或含氟聚合物包含氢化物功能MH，其中M是Si，Ge，Sn或Pb。本发明还包括包含基材和含氟聚合物的制品; 将含氟聚合物粘合到基材上的方法; 含氟聚合物的含氟聚合物组合物，多羟基固化组合物和包含氢化物功能MH的有机组合物; 含氟聚合物和氢化物功能MH的预混物; 和含氟聚合物组合物，其包含（a）包含Cl，Brand /或I原子的热塑性含氟聚合物和（b）包含氢化物功能MH的有机化合物。

7. 发明授权

US06759129B2 Adhesion and bonding of multi-layer articles including a fluoropolymer layer 失效
标题翻译：包含含氟聚合物层的多层制品的粘附和结合
公开(公告)号：US06759129B2
公开(公告)日：2004-07-06
申请号：US10126117
申请日：2002-04-18
申请人： Tatsuo Fukushi
发明人： Tatsuo Fukushi
IPC分类号： B32B2736
CPC分类号： B32B7/12 , B32B27/06 , Y10T428/31507 , Y10T428/3154 , Y10T428/31551 , Y10T428/31678 , Y10T428/31725 , Y10T428/31891 , Y10T428/31931 , Y10T428/31935 , Y10T428/31938
摘要： A multi-layer article includes a first polymer layer, a substrate, and a bonding layer on a surface of the first polymer layer and in contact with the substrate.
摘要翻译：多层制品包括第一聚合物层，基底和在第一聚合物层的表面上并与基底接触的结合层。

8. 发明授权

US6080487A Method of improving adhesion between a fluoropolymer and a substrate 失效
标题翻译：提高含氟聚合物与基材之间粘合性的方法
公开(公告)号：US6080487A
公开(公告)日：2000-06-27
申请号：US703810
申请日：1996-08-26
申请人： William D. Coggio , Timothy M. Dietz , Daniel R. Fronek , Tatsuo Fukushi , Constance J. Nelson , Douglas S. Parker , Trang D. Pham , Keizo Yamanaka
发明人： William D. Coggio , Timothy M. Dietz , Daniel R. Fronek , Tatsuo Fukushi , Constance J. Nelson , Douglas S. Parker , Trang D. Pham , Keizo Yamanaka
IPC分类号： C08J5/12 , B32B27/08 , B32B27/30 , C08F8/26 , C08F14/18 , C08J5/18 , C08J7/12 , B32B27/16 , B32B27/32 , B32B31/30
CPC分类号： C08J5/18 , B32B27/08 , C08F8/26 , C08J2327/12 , Y10T156/1089 , Y10T428/3154 , Y10T428/31544 , Y10T428/31551 , Y10T428/31721 , Y10T428/3175 , Y10T428/31909 , Y10T428/31928
摘要： A multi-layer article comprising a substrate and a dehydrofluorinated fluoropolymer, wherein the dehydrofluorinated polymer contains substantially no grafted adhesion-promoting groups, and the dehydrofluorinated fluoropolymer contains sufficient carbon-carbon unsaturation to increase the adhesion between the dehydrofluorinated fluoropolymer and the substrate.
摘要翻译：一种包含底物和脱氟化氢氟聚合物的多层制品，其中脱氟化氢聚合物基本上不含接枝粘合促进基团，脱氟氟化氟聚合物含有足够的碳 - 碳不饱和度以增加脱氟化氢氟聚合物与基材之间的粘合性。

9. 发明授权

US5855977A Multi-layer compositions comprising a fluoropolymer 失效
标题翻译：包含含氟聚合物的多层组合物
公开(公告)号：US5855977A
公开(公告)日：1999-01-05
申请号：US703311
申请日：1996-08-26
申请人： Tatsuo Fukushi , Keizo Yamanaka , Paul F. Tuckner
发明人： Tatsuo Fukushi , Keizo Yamanaka , Paul F. Tuckner
IPC分类号： B32B27/30 , B32B27/08 , B32B1/02 , B32B1/08 , B32B27/10 , B32B31/00
CPC分类号： B32B27/08 , Y10T428/1379 , Y10T428/3154 , Y10T428/31544
摘要： A multi-layer article comprises a substantially non-fluorinated layer, and a fluorinated layer of fluoropolymer comprising interpolymerized monomeric units derived from one or more of hexafluoropropylene and tetrafluoroethylene monomers, one or more non-fluorinated olefinically unsaturated monomer, and substantially no vinylidene fluoride monomer. The multi-layer article further comprises an aliphatic di-, or polyamine which provides increased adhesion between the layers as compared to a multi-layer article not containing the aliphatic di-, or polyamine. The multi-layer article can be prepared by mixing the aliphatic di-, or polyamine into the substantially non-fluorinated polymeric material, or by applying the aliphatic di-, or polyamine to a surface of one or more of the substantially non-fluorinated polymeric material or the fluoropolymer, and thereafter preparing a multi-layer article.
摘要翻译：多层制品包括基本上非氟化层和含氟聚合物的氟化层，其包含衍生自六氟丙烯和四氟乙烯单体中的一种或多种的共聚单体单元，一种或多种非氟化烯属不饱和单体，基本上不含偏二氟乙烯单体。与不含脂肪族二胺或多胺的多层制品相比，多层制品还包含脂族二胺或多胺，其提供层之间增加的粘合性。多层制品可以通过将脂族二胺或多胺混合到基本上非氟化的聚合物材料中，或通过将脂族二胺或多胺施用到一种或多种基本上非氟化的聚合物材料或含氟聚合物，然后制备多层制品。

10. 发明授权

US09234058B2 Partially fluorinated polysulfinic acids and their salts 有权
公开(公告)号：US09234058B2
公开(公告)日：2016-01-12
申请号：US13885185
申请日：2011-12-09
申请人： Zai-Ming Qiu , Gregg D. Dahlke , Tatsuo Fukushi , Werner M. Grootaert , Miguel A. Guerra
发明人： Zai-Ming Qiu , Gregg D. Dahlke , Tatsuo Fukushi , Werner M. Grootaert , Miguel A. Guerra
IPC分类号： C08F14/16 , C08F8/34 , C08F114/16 , C08F8/44 , C08F28/02
摘要： Described herein is a composition comprising a fluorinated polysulfinic acid or a salt thereof having the following formula (I): wherein X1, X2, and X3 are independently selected from H, F, Cl, Br, I, CF3, and CH3 and wherein at least one of X1, X2, or X3 is H; R1 is a linking group; Z1 and Z2 are independently selected from Br, Cl, I, F, CF3, and a perfluorinated alkyl group; M is a cation; p is 0 or 1; and n is at least 2. Also described is a method of making the partially fluorinated polysulfinic acid or salt thereof.

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