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31. 发明授权

US4073810A Production of organophosphines 失效
标题翻译：生产有机膦
公开(公告)号：US4073810A
公开(公告)日：1978-02-14
申请号：US549172
申请日：1975-02-12
申请人： Klaus Hestermann , Bernd Lippsmeier , Gero Heymer
发明人： Klaus Hestermann , Bernd Lippsmeier , Gero Heymer
IPC分类号： B01J21/00 , C07B61/00 , C07F9/50 , C07F9/53 , C07F9/54
CPC分类号： C07F9/5086 , C07F9/54
摘要： Production of organophosphines of the general formula R.sub.n PH.sub.3-n, in which R stands for identical or different, substituted or unsubstituted alkyl, cycloalkyl or aralkyl groups having from 1 to 18 carbon atoms, preferably from 1 to 4 carbon atoms, more preferably from 1 to 2 carbon atoms, and n stands for a whole number within the range 1 and 3. The compounds are more particularly produced by continuously reacting hydrocarbon halides of the general formula RX, in which R has the meaning given hereinabove and X stands for halogen, especially for chlorine or bromine, with hydrogen phosphide, and primary or secondary organophosphines at temperatures within the range 100.degree. and 600.degree. C. and under pressures of up to 20 atmospheres in contact with a catalyst being placed in a reactor. Gaseous matter issuing from the reactor is cooled and the resulting organophosphonium halides (R.sub.n PH.sub.4-n)X are hydrolyzed in conventional manner to the corresponding organophosphines.
摘要翻译：制备通式RnPH3-n的有机膦，其中R代表相同或不同的取代或未取代的具有1至18个碳原子，优选1至4个碳原子的烷基，环烷基或芳烷基，更优选1至 2个碳原子，n表示1和3范围内的整数。化合物更特别地通过连续反应通式RX的卤代烃，其中R具有上文给出的含义，X代表卤素，特别是对于氯或溴，与磷化氢以及初级或次级有机膦在100℃和600℃的温度范围内以及在与置于反应器中的催化剂接触的情况下在高达20个大气压的压力下进行。将从反应器排出的气态物质冷却，并将所得的有机鏻卤化物（RnPH4-n）X以常规方式水解成相应的有机膦。

32. 发明授权

US4042324A Process for inhibiting the corrosions and deposition of boiler scale in water-conveying systems 失效
标题翻译：防止锅炉水垢在水输送系统中的腐蚀和沉积的过程
公开(公告)号：US4042324A
公开(公告)日：1977-08-16
申请号：US654885
申请日：1976-02-03
申请人： Theodor Auel , Hannsjorg Ulrich , Horst-Dieter Wasel-Nielen , Gero Heymer
发明人： Theodor Auel , Hannsjorg Ulrich , Horst-Dieter Wasel-Nielen , Gero Heymer
IPC分类号： C02F5/14 , C07F9/38 , C23F11/167 , C02B5/06 , C23F11/16
CPC分类号： C23F11/1676 , C02F5/14 , C07F9/3808 , C23F11/167
摘要： Corrosion and deposition of boiler scale in water-conveying systems are inhibited. To this end the water is admixed with at least one carboxy-alkane compound of phosphorus of the general formula: ##STR1## in which each of the substituents R.sup.1, R.sup.2, R.sup.3, and R.sup.4 stands for hydrogen or an alkyl group having from 1 to 4 carbon atoms, R.sup.5 stands for hydrogen, an OH-group or an alkyl group having from 1 to 3 carbon atoms, and n stands for 0 or 1, or with at least one water-soluble salt thereof.
摘要翻译：锅炉秤在输水系统中的腐蚀和沉积受到抑制。为此，将水与至少一种以下通式的磷的羧基烷烃化合物混合：其中每个取代基R 1，R 2，R 3和R 4代表氢或具有1至 4个碳原子，R5代表氢，OH-基团或具有1至3个碳原子的烷基，n代表0或1，或其至少一种水溶性盐。

33. 发明授权

US4923691A Aluminum nitride powder and a process for the preparation thereof 失效
标题翻译：氮化铝粉末及其制备方法
公开(公告)号：US4923691A
公开(公告)日：1990-05-08
申请号：US364013
申请日：1989-06-09
申请人： Dieter Peters , Gero Heymer , Christian May
发明人： Dieter Peters , Gero Heymer , Christian May
IPC分类号： C01B21/072
CPC分类号： C01B21/072 , C01P2002/60 , C01P2004/62 , C01P2006/12 , C01P2006/60
摘要： An aluminum nitride powder has a crystallite size of 40 to 150 nm, measured by powder diffractometry and evaluated by the method of Scherrer, a primary particle size of 0.1 to 0.5 .mu.m, a specific surface according to BET of 5 to 50 m.sup.2 /g and a degree of whiteness of more than 91%, measured using light of a 400 to 700 nm wavelength against barium sulfate analytical reagent as standard of whitness.To prepare this aluminum nitride powder, metallic aluminum and monoamminealuminum chloride [AlCl.sub.3 (NH.sub.3)] are first molten together in an inert gas atmosphere at temperatures above 125.degree. C. and allowed to react with one another with evolution of hydrogen. 8 to 20 g of ammonia are then introduced per hour per mol of monoamminealuminum chloride into the aluminum-containing monoamminealuminum chloride melt at temperatures between 250.degree. and 400.degree. C., aluminum nitride being precipitated as a solid until the conversion of the aluminum is complete. The temperature of the melt is finally raised to more than 400.degree. C.
摘要翻译：氮化铝粉末的微晶尺寸为40〜150nm，用粉末衍射法测定，用Scherrer法评价，一次粒径为0.1〜0.5μm，BET比表面积为5〜50m 2 / g 白度为91％以上，采用400〜700nm波长的光作为白度标准测定硫酸钡分析试剂。为了制备这种氮化铝粉末，首先在惰性气体气氛中，在高于125℃的温度下将金属铝和一氯化铝[AlCl 3（NH 3）]熔融在一起，并使其彼此发生氢气反应。然后在250-400℃的温度下将8至20g的氨每小时每摩尔氯化单铝酸铵引入含铝单胺氯化铝熔体中，将氮化铝作为固体沉淀直到铝的转化完全。熔体的温度最终升至400℃以上。

34. 发明授权

US4600565A Process for making manganese (II) salt solutions containing ammonium salt 失效
标题翻译：制备含有铵盐的锰（II）盐溶液的方法
公开(公告)号：US4600565A
公开(公告)日：1986-07-15
申请号：US708299
申请日：1985-03-05
申请人： Klaus Lehr , Bernhard Hofmann , Gero Heymer
发明人： Klaus Lehr , Bernhard Hofmann , Gero Heymer
IPC分类号： C01G45/00 , C22B47/00
CPC分类号： C01G45/00 , C22B47/00
摘要： Manganese(II)salt solutions containing ammonium salt are made by subjecting a manganese-containing compound to processing treatment with an ammonium salt solution. A boiling temperature of 57.degree.-68.degree. C. is established in the suspension to be subjected to the processing treatment, by application of a vacuum. The ammonium salt solution used contains 0.5-2.5 mol/l diammonium sulfate or 1.0-5.0 mol/l ammonium nitrate.
摘要翻译：含有铵盐的锰（II）盐溶液通过使含锰化合物用铵盐溶液进行处理来制备。通过施加真空在待处理处理的悬浮液中建立沸点为57-68℃的温度。使用的铵盐溶液含有0.5-2.5mol / l硫酸二铵或1.0-5.0mol / l硝酸铵。

35. 发明授权

US4530769A Process for separating carbon black from an aqueous suspension 失效
标题翻译：从水性悬浮液中分离炭黑的方法
公开(公告)号：US4530769A
公开(公告)日：1985-07-23
申请号：US479965
申请日：1983-03-29
申请人： Manfred Wolter , Friedrich-Wilhelm Dorn , Gero Heymer , Hans-Werner Stephan
发明人： Manfred Wolter , Friedrich-Wilhelm Dorn , Gero Heymer , Hans-Werner Stephan
IPC分类号： B01D25/12 , C09C1/48 , C10G31/09 , B01D29/10
CPC分类号： C09C1/487 , C01P2006/12
摘要： The disclosure relates to a process for the discontinuous separation of a solid consisting predominantly of carbon black from its aqueous suspension by filtration. To this end, the disclosure provides for use to be made of a tube pressure filter which is operated under a final pressure of 30 to 100 bars.
摘要翻译：本公开涉及通过过滤从其水悬浮液中主要由炭黑组成的固体的不连续分离的方法。为此，本公开提供了用于在30至100巴的最终压力下操作的管式压力过滤器的使用。

36. 发明授权

US4399114A Process for the dearsenification of polyphosphoric acid 失效
标题翻译：多磷酸脱砷方法
公开(公告)号：US4399114A
公开(公告)日：1983-08-16
申请号：US402941
申请日：1982-07-29
申请人： Alexander Maurer , Gero Heymer , Markus Erpenbach
发明人： Alexander Maurer , Gero Heymer , Markus Erpenbach
IPC分类号： C01B25/24 , C01B25/16
CPC分类号： C01B25/24
摘要： The disclosure relates to a process for the continuous dearsenification of polyphosphoric acid with the aid of hydrogen sulfide in a gas admission zone. To this end, the disclosure provides for the acid to be dearsenified in a gas admission zone subdivided so as to comprise at least two separate liquid matter-receiving zones, each zone being separated from the other by means of a separate gas zone; for the liquid in each of the liquid matter-receiving zones to be maintained at a level 0.1 up to 10 cm high, without admission of gas; for hydrogen sulfide which remained unreacted in the individual liquid matter-receiving zones to be collected in the respective gas zone and for it to be finely redispersed in the liquid matter-receiving zone directly upstream of the respective gas zone by allowing the hydrogen sulfide to flow through a plurality of openings into the acid, the latter being delivered from the respective liquid-matter-receiving zone into the next downstream liquid-matter-receiving zone, and introduced thereinto directly below the liquid matter level therein; for precipitated arsenic sulfide to be separated from the acid coming from the lower end of the gas admission zone, and for the filtrate obtained to be freed from gaseous hydrogen sulfide in excess.
摘要翻译：本公开涉及在气体入口区借助硫化氢连续脱砷多磷酸的方法。为此，本公开内容提供了在气体进入区域中进行脱砷的酸，其被细分为包括至少两个分离的液体物质接收区域，每个区域通过单独的气体区域与另一个区域分离; 使每个液体物质接收区域中的液体保持在0.1至10厘米高的水平，而不允许气体; 对于在各个液体物质接收区中保持未反应的硫化氢，其被收集在各个气体区中，并且通过允许硫化氢流动直接在各个气体区的上游被精细地再分散在液体物质接收区中通过多个开口进入酸，后者从相应的液体接收区输送到下一个下游液体接收区，并直接在其中引入液体物质的下方; 使沉淀的硫化砷与气体入口区的下端的酸分离，得到的过滤得到的无水硫化氢的滤液。

37. 发明授权

US4394358A Production of granular alkali metal diphosphates or triphosphates 失效
标题翻译：生产颗粒状碱金属二磷酸盐或三磷酸盐
公开(公告)号：US4394358A
公开(公告)日：1983-07-19
申请号：US303100
申请日：1981-09-17
申请人： Alexander Maurer , Renate Adrian , Herbert Panter , Gero Heymer , Dieter Nolker
发明人： Alexander Maurer , Renate Adrian , Herbert Panter , Gero Heymer , Dieter Nolker
IPC分类号： C01B25/41 , C01B25/42 , C11D3/06 , C01B25/30
CPC分类号： C01B25/418 , C01B25/425 , C11D3/062
摘要： The invention relates to a process for making granulated, partially or completely hydrated alkali metal diphosphates or triphosphates. To this end, the invention provides for alkali metal diphosphates or triphosphates which consist to an extent of at least 20% of particles with a size of less than 0.045 mm and are hydrated to an extent of less than 90%, based on the phosphates' theoretical content of water of hydration, to be intensively mixed and granulated in the presence of water and an ammonium polyphosphate, this latter being used in a proportion of about 0.5 to 50 weight %, based on the quantity of water used.
摘要翻译：本发明涉及制备颗粒状，部分或完全水合的碱金属二磷酸盐或三磷酸盐的方法。为此，本发明提供碱金属二磷酸盐或三磷酸盐，其碱度至少为20％，其尺寸小于0.045mm，并且基于磷酸盐的水合物水合至小于90％的程度，在水和多磷酸铵的存在下，水合的水的理论含量将被浓缩混合和造粒，后者基于所用的水量以约0.5至50重量％的比例使用。

38. 发明授权

US4385041A Process for making aqueous alkali metal phosphate solutions 失效
标题翻译：制备碱金属磷酸盐水溶液的方法
公开(公告)号：US4385041A
公开(公告)日：1983-05-24
申请号：US326078
申请日：1981-11-30
申请人： Klaus Jodden , Gero Heymer
发明人： Klaus Jodden , Gero Heymer
IPC分类号： C01B25/30 , C01B15/16 , C01B25/26
CPC分类号： C01B25/30
摘要： The invention relates to a process for making aqueous alkali metal phosphate solutions by subjecting aqueous alkali metal phosphite solutions to catalytic oxidation with oxygen or air. More particularly, oxygen or air in stoichiometric excess proportions is introduced into the aqueous alkali metal phosphite solution at about 30.degree. to 110.degree. C., at a pH-value of 0 to about 8, and in the presence of SiO.sub.2 or aluminum silicate containing at most 10 weight % Al.sub.2 O.sub.3, for as long as necessary to achieve conversion of the alkali metal phosphite to alkai metal phosphate. After completion of the oxidation, the aqueous solution is separated from the catalyst.
摘要翻译：本发明涉及通过使碱金属亚磷酸盐水溶液用氧气或空气进行催化氧化来制备碱金属磷酸盐水溶液的方法。更具体地说，在约30℃至110℃，pH值为0至约8的条件下，在含碱金属亚磷酸盐水溶液中的化学计量过量的氧气或空气中，在含有至多10重量％的Al 2 O 3，只要需要实现碱金属亚磷酸盐转化为磷酸金属。氧化完成后，将水溶液与催化剂分离。

39. 发明授权

US4294808A Production of anticorrosive pigments containing phosphorus 失效
标题翻译：生产含磷的防锈颜料
公开(公告)号：US4294808A
公开(公告)日：1981-10-13
申请号：US76307
申请日：1979-09-17
申请人： Horst-Dieter Wasel-Nielen , Renate Adrian , Herbert Panter , Gero Heymer , Alexander Maurer , Raban von Schenck
发明人： Horst-Dieter Wasel-Nielen , Renate Adrian , Herbert Panter , Gero Heymer , Alexander Maurer , Raban von Schenck
IPC分类号： C23C22/08 , C01B25/163 , C01B25/165 , C01B25/26 , C01B25/32 , C01B25/34 , C01B25/37 , C09D5/08 , C01B25/36
CPC分类号： C09D5/084 , C01B25/163 , C01B25/165 , C01B25/265 , C01B25/325 , C01B25/34 , C01B25/37
摘要： The invention relates to a process for making phosphorus-containing anticorrosive pigments having a size of at most 20 microns by reacting one or more compounds of magnesium, calcium, strontium, barium, zinc, aluminum, iron, chromium or manganese with an oxygen acid of phosphorus or its alkali metal or ammonium salts at temperatures within the range 10.degree. to 100.degree. C. More particularly pigments consisting to an extent of at least 90% of particles with a size between 0.05 and 8 microns are produced by introducing an aqueous suspension or solution of the reactants into a dispersing means rotating at a speed of 3000 to 10,000 rpm, reacting the reactants by intimately mixing them, and separating and drying precipitated pigment.
摘要翻译：本发明涉及一种通过使一种或多种镁，钙，锶，钡，锌，铝，铁，铬或锰的化合物与氧酸的氧酸反应制备尺寸至多为20微米的含磷防腐颜料的方法磷或其碱金属或铵盐。更具体地说，通过将水性悬浮液或水溶性悬浮液引入至少90％的尺寸为0.05至8微米的颗粒的程度，将反应物溶解在以3000至10,000rpm的速度旋转的分散装置中，通过将它们紧密混合使反应物反应，并分离和干燥沉淀的颜料。

40. 发明授权

US4294621A Production of an anticorrosive pigment on phosphate basis 失效
标题翻译：以磷酸盐为基础生产防腐颜料
公开(公告)号：US4294621A
公开(公告)日：1981-10-13
申请号：US141135
申请日：1980-04-16
申请人： Alexander Maurer , Renate Adrian , Klaus Hestermann , Gero Heymer
发明人： Alexander Maurer , Renate Adrian , Klaus Hestermann , Gero Heymer
IPC分类号： C09D5/08 , C01B25/32 , C09C1/00 , C09C1/02 , C08K3/10
CPC分类号： C01B25/322 , C01B25/325 , C09C1/02 , C01P2004/61 , C01P2006/12
摘要： The invention relates to the production of phosphorus-containing anticorrosive pigments with a particle size of at most 20 microns by reacting one or more calcium or magnesium compounds with phosphoric acid or acid alkali metal or ammonium phosphates by intimately mixing an aqueous suspension or solution of the reactants inside a dispersing means rotating at a speed of 3000 to 10,000 rpm. More particularly, fine pulverulent calcium and magnesium compounds are converted, with agitation, together with water and, if desired, a water-soluble alkanol to a homogeneous suspension or solution. The suspension or solution is intimately mixed, inside the dispersing means at 0.degree. to 40.degree. C. and in an approximately stoichiometric ratio, with the phosphoric acid or acid phosphate solution. Resulting and precipitated pigment is separated and dried under mild conditions while maintaining its content of water of crystallization. The anticorrosive pigment is comprised of a homogeneous mixture and/or mixed crystals of which 10 to 95 mol % is calcium hydrogen phosphate dihydrate, the balance being magnesium hydrogen phosphate trihydrate. An at least 55 weight % proportion consists of particles with a size of up to 5 microns with a BET-surface of at least 1 m.sup.2 /g.
摘要翻译：本发明涉及通过使一种或多种钙或镁化合物与磷酸或酸性碱金属或铵磷酸盐反应，通过将下列物质的水性悬浮液或溶液紧密混合，从而生产粒径至多为20微米的含磷防腐颜料分散装置内的反应物以3000至10,000rpm的速度旋转。更具体地，精细的粉末状钙和镁化合物在搅拌下与水一起转化，如果需要，将水溶性链烷醇转化成均匀的悬浮液或溶液。悬浮液或溶液在分散装置内在0℃至40℃下以大约化学计量比与磷酸或酸式磷酸盐溶液紧密混合。将所得沉淀的颜料分离并在温和条件下干燥，同时保持其结晶水含量。防腐颜料由均匀的混合物和/或其中10〜95摩尔％为磷酸氢钙二水合物的混合晶体组成，余量为磷酸氢二氢钙三水合物。至少55重量％的比例由尺寸高达5微米，BET表面至少为1m 2 / g的颗粒组成。

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