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    • 3. 发明授权
    • Process for purifying phosphorous acid
    • 纯化亚磷酸的方法
    • US4834960A
    • 1989-05-30
    • US182871
    • 1988-04-18
    • Jurgen GrosseGunther SchimmelBernhard Hofmann
    • Jurgen GrosseGunther SchimmelBernhard Hofmann
    • C01B25/163
    • C01B25/163
    • The purification of phosphorous acid which is formed in halogenations of hydrocarbon derivatives using phosphorus trihalides is carried out in the context of preparing phosphorous acid in a reaction zone by reacting a mixture of phosphorus trichloride and water which has been finely divided by means of steam at temperatures between 150.degree. and 200.degree. C. in the gas phase. In this process, the liquid reaction product drains into a concentrating evaporation zone which has a downstream first separation zone. Inert gas is introduced to the lower part of the first separation zone. A melt is withdrawn from the first separation zone into a crystallizing zone. The waste gases from the reaction zone are treated with a washing liquid in a second separation zone before being passed into the atmosphere. The washing liquid used is an aqueous solution of never-purified phosphorous acid, which can have been prepurified by hydrolysis and stripping.
    • 通过使用三卤化磷在烃衍生物的卤化中形成的亚磷酸的纯化是在反应区中通过使三氯化磷和水分混合物在蒸气中分解的温度反应在反应区中进行的 在气相中为150〜200℃。 在该方法中,液体反应产物排入具有下游第一分离区的浓缩蒸发区。 惰性气体被引入第一分离区的下部。 将熔体从第一分离区取出成结晶区。 来自反应区的废气在通入大气中之前用洗涤液在第二分离区中处理。 所使用的洗涤液是未经纯化的亚磷酸的水溶液,其可以通过水解和汽提进行预净化。