专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US4294621A Production of an anticorrosive pigment on phosphate basis 失效
标题翻译：以磷酸盐为基础生产防腐颜料
公开(公告)号：US4294621A
公开(公告)日：1981-10-13
申请号：US141135
申请日：1980-04-16
申请人： Alexander Maurer , Renate Adrian , Klaus Hestermann , Gero Heymer
发明人： Alexander Maurer , Renate Adrian , Klaus Hestermann , Gero Heymer
IPC分类号： C09D5/08 , C01B25/32 , C09C1/00 , C09C1/02 , C08K3/10
CPC分类号： C01B25/322 , C01B25/325 , C09C1/02 , C01P2004/61 , C01P2006/12
摘要： The invention relates to the production of phosphorus-containing anticorrosive pigments with a particle size of at most 20 microns by reacting one or more calcium or magnesium compounds with phosphoric acid or acid alkali metal or ammonium phosphates by intimately mixing an aqueous suspension or solution of the reactants inside a dispersing means rotating at a speed of 3000 to 10,000 rpm. More particularly, fine pulverulent calcium and magnesium compounds are converted, with agitation, together with water and, if desired, a water-soluble alkanol to a homogeneous suspension or solution. The suspension or solution is intimately mixed, inside the dispersing means at 0.degree. to 40.degree. C. and in an approximately stoichiometric ratio, with the phosphoric acid or acid phosphate solution. Resulting and precipitated pigment is separated and dried under mild conditions while maintaining its content of water of crystallization. The anticorrosive pigment is comprised of a homogeneous mixture and/or mixed crystals of which 10 to 95 mol % is calcium hydrogen phosphate dihydrate, the balance being magnesium hydrogen phosphate trihydrate. An at least 55 weight % proportion consists of particles with a size of up to 5 microns with a BET-surface of at least 1 m.sup.2 /g.
摘要翻译：本发明涉及通过使一种或多种钙或镁化合物与磷酸或酸性碱金属或铵磷酸盐反应，通过将下列物质的水性悬浮液或溶液紧密混合，从而生产粒径至多为20微米的含磷防腐颜料分散装置内的反应物以3000至10,000rpm的速度旋转。更具体地，精细的粉末状钙和镁化合物在搅拌下与水一起转化，如果需要，将水溶性链烷醇转化成均匀的悬浮液或溶液。悬浮液或溶液在分散装置内在0℃至40℃下以大约化学计量比与磷酸或酸式磷酸盐溶液紧密混合。将所得沉淀的颜料分离并在温和条件下干燥，同时保持其结晶水含量。防腐颜料由均匀的混合物和/或其中10〜95摩尔％为磷酸氢钙二水合物的混合晶体组成，余量为磷酸氢二氢钙三水合物。至少55重量％的比例由尺寸高达5微米，BET表面至少为1m 2 / g的颗粒组成。

2. 发明授权

US4080384A Production of (hydroxymethyl)-alkyl, cycloalkyl and aralkylphosphines 失效
标题翻译：（羟甲基） - 烷基，环烷基和芳烷基膦的制备
公开(公告)号：US4080384A
公开(公告)日：1978-03-21
申请号：US559529
申请日：1975-03-18
申请人： Bernd Lippsmeier , Klaus Hestermann , Gero Heymer
发明人： Bernd Lippsmeier , Klaus Hestermann , Gero Heymer
IPC分类号： B01J31/24 , C07F9/50
CPC分类号： B01J31/0268 , B01J31/0258 , B01J31/0259 , B01J31/1845 , B01J31/24 , C07F9/5004 , B01J2231/4277 , B01J2531/822 , B01J2531/828 , B01J2531/847 , B01J27/10 , B01J27/128
摘要： Production of (hydroxymethyl)-alkyl, cycloalkyl or aralkylphosphines of the general formula:R.sub.n P(CH.sub.2 OH).sub.3-nin which n stands for 1 or 2 and R stands for identical or different, substituted or unsubstituted alkyl, cycloalkyl or aralkyl radicals having from 1 to 18 carbon atoms. The compounds are made by reacting suitable mono- or di-alkyl, cycloalkyl or aralkylphosphines at atmospheric pressure and at temperatures lower than 40.degree. C with formaldehyde, paraformaldehyde or trioxane in the presence of polar organic solvents being inert with respect to the resulting reaction product, and separating the solvent from the reaction product.
摘要翻译：（羟甲基） - 烷基，环烷基或芳烷基膦的制备：

3. 发明授权

US4136155A Production of phosphine 失效
标题翻译：生产磷酸盐
公开(公告)号：US4136155A
公开(公告)日：1979-01-23
申请号：US904026
申请日：1978-05-08
申请人： Klaus Hestermann , Gero Heymer
发明人： Klaus Hestermann , Gero Heymer
IPC分类号： C01B25/06 , C01B25/00
CPC分类号： C01B25/06
摘要： Phosphine (hydrogen phosphide) is made by reacting gaseous yellow phosphorus with steam at temperatures of 280 to 400.degree. C in the presence of ammonia in contact with a carbon catalyst.

4. 发明授权

US3980711A Production of methylphosphine oxides 失效
标题翻译：生产甲基膦氧化物
公开(公告)号：US3980711A
公开(公告)日：1976-09-14
申请号：US549174
申请日：1975-02-12
申请人： Bernd Lippsmeier , Klaus Hestermann , Gero Heymer
发明人： Bernd Lippsmeier , Klaus Hestermann , Gero Heymer
IPC分类号： B01J31/00 , C07F9/53 , C07F9/02
CPC分类号： C07F9/53
摘要： Methylphosphine oxides of the general formula (I) ##EQU1## are produced from hydroxymethylphosphines of the general formula (II) ##EQU2## in which formulae R and R' each stand for identical or different alkyl-, cycloalkyl-, aralkyl- or aryl groups having from 1 to 18 carbon atoms, or carrying substituents being inert under the reaction conditions.The methylphosphine oxides are more particularly produced by subjecting the hydroxymethylphosphines to a rearrangement reaction with the aid of radical-yielding compounds.
摘要翻译：由通式（I）R HOCH2-P ANGLE（II）R'的羟甲基膦制备通式（I）的二甲基膦氧化物。其中式R和R'各自为代表具有1至18个碳原子的相同或不同的烷基 - ，环烷基 - ，芳烷基 - 或芳基，或在反应条件下携带取代基是惰性的。

5. 发明授权

US4156697A Production of alkylphosphines 失效
标题翻译：生产烷基膦
公开(公告)号：US4156697A
公开(公告)日：1979-05-29
申请号：US823140
申请日：1977-08-09
申请人： Klaus Hestermann , Hartfrid Vollmer , Gero Heymer , Ernst-Gunther Schlosser
发明人： Klaus Hestermann , Hartfrid Vollmer , Gero Heymer , Ernst-Gunther Schlosser
IPC分类号： C07F9/50
CPC分类号： C07F9/5004 , Y02P20/582
摘要： Alkyl phosphines of the general formula:R.sub.n PH.sub.3-n (I)are made. To this end hydrogen phosphide, a primary or a secondary phosphine is reacted with an alkylamine of the general formula:R.sub.n NH.sub.3-n (II)in a molar ratio of 0.1 to 10 mols of the alkylamine of formula II per mol of hydrogen phosphide or primary or secondary phosphine. The reaction is effected at a 150.degree. to 400.degree. C., at atmospheric pressure or a superatmospheric pressure up to 1 atmosphere gauge, and in contact with a catalyst comprising active carbon, copper (II) chromite, or one or more metals of Group Ib or VIII of the Periodic System of the elements. The starting materials are passed through a reaction zone at a rate which permits a contact time between them and the catalyst of 0.1 to 400 seconds.
摘要翻译：具有以下通式的烷基膦：

6. 发明授权

US4150058A Production of alkyl phosphines 失效
标题翻译：烷基膦的生产
公开(公告)号：US4150058A
公开(公告)日：1979-04-17
申请号：US904027
申请日：1978-05-08
申请人： Klaus Hestermann , Gero Heymer
发明人： Klaus Hestermann , Gero Heymer
IPC分类号： C07F9/50
CPC分类号： C07F9/5004 , Y02P20/582
摘要： Alkyl phosphines are made. To this end, phosphorus in vapor form is reacted with steam and an alkyl amine at elevated temperature in contact with a carbon catalyst placed in a reactor, the reactants being used individually or in admixture with one another.
摘要翻译：制备烷基膦。为此，蒸气形式的磷与蒸汽和烷基胺在升高的温度下与放置在反应器中的碳催化剂接触，反应物单独使用或彼此混合使用。

7. 发明授权

US4091078A Production of phosphine 失效
标题翻译：生产磷化氢
公开(公告)号：US4091078A
公开(公告)日：1978-05-23
申请号：US736556
申请日：1976-10-28
申请人： Klaus Hestermann , Jurgen Stengel , Gero Heymer , Christian May
发明人： Klaus Hestermann , Jurgen Stengel , Gero Heymer , Christian May
IPC分类号： C01B25/06 , C01B25/00
CPC分类号： C01B25/06
摘要： Phosphine is produced from elementary yellow phosphorus and an aqueous alkali metal hydroxide solution in the presence of an alcohol. The phosphine is more particularly made by using an alcohol having from 5 to 10 carbon atoms and a dissolving power for yellow phosphorus of more than 5 g/l; suspending the phosphorus with agitation in the said alcohol in a reaction zone; reacting the resulting suspension with the alkali metal hydroxide solution at temperatures lower than the boiling point of the alcohol; and collecting the resulting issuing gaseous phosphine.
摘要翻译：在醇的存在下，由元素黄磷和碱金属氢氧化物水溶液生产磷化氢。膦更特别地通过使用具有5至10个碳原子的醇和大于5g / l的黄磷的溶解力来制备; 在反应区内搅拌将磷悬浮在所述醇中; 在低于醇的沸点的温度下使得到的悬浮液与碱金属氢氧化物溶液反应; 并收集产生的发出的气态膦。

8. 发明授权

US4073810A Production of organophosphines 失效
标题翻译：生产有机膦
公开(公告)号：US4073810A
公开(公告)日：1978-02-14
申请号：US549172
申请日：1975-02-12
申请人： Klaus Hestermann , Bernd Lippsmeier , Gero Heymer
发明人： Klaus Hestermann , Bernd Lippsmeier , Gero Heymer
IPC分类号： B01J21/00 , C07B61/00 , C07F9/50 , C07F9/53 , C07F9/54
CPC分类号： C07F9/5086 , C07F9/54
摘要： Production of organophosphines of the general formula R.sub.n PH.sub.3-n, in which R stands for identical or different, substituted or unsubstituted alkyl, cycloalkyl or aralkyl groups having from 1 to 18 carbon atoms, preferably from 1 to 4 carbon atoms, more preferably from 1 to 2 carbon atoms, and n stands for a whole number within the range 1 and 3. The compounds are more particularly produced by continuously reacting hydrocarbon halides of the general formula RX, in which R has the meaning given hereinabove and X stands for halogen, especially for chlorine or bromine, with hydrogen phosphide, and primary or secondary organophosphines at temperatures within the range 100.degree. and 600.degree. C. and under pressures of up to 20 atmospheres in contact with a catalyst being placed in a reactor. Gaseous matter issuing from the reactor is cooled and the resulting organophosphonium halides (R.sub.n PH.sub.4-n)X are hydrolyzed in conventional manner to the corresponding organophosphines.
摘要翻译：制备通式RnPH3-n的有机膦，其中R代表相同或不同的取代或未取代的具有1至18个碳原子，优选1至4个碳原子的烷基，环烷基或芳烷基，更优选1至 2个碳原子，n表示1和3范围内的整数。化合物更特别地通过连续反应通式RX的卤代烃，其中R具有上文给出的含义，X代表卤素，特别是对于氯或溴，与磷化氢以及初级或次级有机膦在100℃和600℃的温度范围内以及在与置于反应器中的催化剂接触的情况下在高达20个大气压的压力下进行。将从反应器排出的气态物质冷却，并将所得的有机鏻卤化物（RnPH4-n）X以常规方式水解成相应的有机膦。

9. 发明授权

US4337092A Corrosion-inhibiting pigment and paint composition 失效
标题翻译：防腐蚀颜料和涂料组成
公开(公告)号：US4337092A
公开(公告)日：1982-06-29
申请号：US193550
申请日：1980-10-03
申请人： Klaus Hestermann , Alexander Maurer , Joachim Kandler , Gerhard Mietens , Herbert Beumling
发明人： Klaus Hestermann , Alexander Maurer , Joachim Kandler , Gerhard Mietens , Herbert Beumling
IPC分类号： C09C1/00 , C09C1/04 , C09D5/08
CPC分类号： C09D5/084
摘要： The invention relates to a corrosion-inhibiting active pigment for use in the surface protection of iron and iron alloys. The pigment consists of a mixture of calcium hydrogen phosphate dihydrate, magnesium hydrogen phosphate trihydrate and zinc oxide. More specifically, the mixture contains 2 to 98 weight % of ZnO and 98 to 2 weight % of phosphate components. These in turn contain 3 to 97 weight % of CaHPO.sub.4 .multidot.2 H.sub.2 O and 97 to 3 weight % of MgHPO.sub.4 .multidot.3 H.sub.2 O. The active pigment is suitable for use in painting compositions or lacquers.
摘要翻译：本发明涉及用于铁和铁合金表面保护的腐蚀抑制活性颜料。颜料由磷酸氢二钙二水合物，磷酸氢钙三水合物和氧化锌的混合物组成。更具体地，该混合物含有2至98重量％的ZnO和98至2重量％的磷酸盐组分。这些又包含3至97重量％的CaHPO 4/2 H 2 O和97至3重量％的MgHPO 4 x 3 H 2 O. 活性颜料适用于涂漆组合物或漆。

10. 发明授权

US4076755A Production of hydroxyalkylphosphine oxides 失效
标题翻译：生产羟烷基膦氧化物
公开(公告)号：US4076755A
公开(公告)日：1978-02-28
申请号：US666699
申请日：1976-03-15
申请人： Bernd Lippsmeier , Klaus Hestermann
发明人： Bernd Lippsmeier , Klaus Hestermann
IPC分类号： C07F9/53 , C09K21/12
CPC分类号： C09K21/12 , C07F9/5304
摘要： Production of tertiary hydroxyalkylphosphine oxides of general formula (I) ##STR1## in which R.sup.1 and R.sup.2 each stand for organic groups having from 1 to 18 carbon atoms, where R.sup.1 may be identical with R.sup.2 and R.sup.2 may be identical with R which stands for a radical of general formula (II) ##STR2## in which R.sup.3 and R.sup.4 equally stand for organic groups having from 1 to 18 carbon atoms and/or more preferably for hydrogen. The compounds are made from phosphines of general formula (III) ##STR3## in which R.sup.3 and R.sup.4 have the meanings given above, which are reacted in a single step operation with carbonyl compounds of general formula (IV) ##STR4## in which R.sup.3 and R.sup.4 equally have the meanings given above. The reaction is effected while adding at least one substance yielding hydroxyl ions and in the presence of water, and the resulting hydroxyalkylphosphine oxides are separated from the reaction product.
摘要翻译：其中R 1和R 2各自代表具有1至18个碳原子的有机基团，其中R 1可以与R 2和R 2相同，通式（Ⅰ）的叔羟烷基膦氧化物的制备可以与R相同，代表通式（II）的基团（II），其中R 3和R 4均等于具有1至18个碳原子和/或更优选氢的有机基团。化合物由通式（III）的膦制备，其中R 3和R 4具有上述含义，其在单步操作中与通式（IV）的羰基化合物（IMA）反应 IV），其中R3和R4同样具有上述含义。在加入至少一种产生羟基离子的物质和水的存在下进行反应，并将所得羟烷基氧化膦与反应产物分离。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式