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    • 21. 发明授权
    • Fiber-reactive dyes containing chromophoric system bound to a bridging
member consisting of two or three triazinyl radicals
    • US4963659A
    • 1990-10-16
    • US323455
    • 1989-03-14
    • Athanassios Tzikas
    • Athanassios Tzikas
    • C09B62/503C09B62/44C09B62/505C09B62/51C09B62/513C09B62/515C09B62/517D06P3/66
    • C09B62/4403
    • Reactive dyes which are particularly suitable for the dyeing or printing of cellulose-containing fiber materials by the exhaust process or by the continuous process and give, at a high color yield, dyeings and prints having good fastness properties, having the formula ##STR1## in which D.sub.1 and D.sub.2, independently of one another, are each a radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye; R.sub.1, R.sub.2, B.sub.1 and B.sub.2, independently of one another, are hydrogen or alkyl having 1 to 4 carbon atoms, which is unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato; X is fluorine, chlorine, bromine, sulfo, C.sub.1 -C.sub.4 alkylsulfonyl, phenylsulfonyl or carboxypyridinium, and E is a radical of the formula ##STR2## in which A.sub.1 and A.sub.2, independently of one another, are each a radical of the formula ##STR3## or X is a radical of the formula ##STR4## and E is a radical of the formula (3a), (3b), (3c) or (3d); and R.sub.3 is hydrogen or alkyl having 1 to 4 carbon atoms, which is unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato; R.sub.4 and R.sub.5, independently of one another, are 0 to 3 substituents from the group consisting of C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo; B is a direct bond or --(CH.sub.2).sub.n --or --O--(CH2).sub.n --, n is 1 to 6; R is a radical of the formula ##STR5## Z is a .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-acyloxyethyl, .beta.-halogenoethyl or vinyl; alk is alkylene having 1 to 6 carbon atoms or branced isomers thereof; T is hydrogen, chlorine, bromine, fluorine, hydroxyl, sulfato, alkanoyloxy having 2 to 4 carbon atoms, cyano, carboxyl, alkoxycarbonyl having 1 to 5 carbon atoms, carbamoyl, or --SO.sub.2 --Z in which Z is as defined above;V is hydrogen or alkyl having 1 to 4 carbon atoms, which is unsubstituted or substituted by carboxyl, sulfo, carbamoyl, N-methylcarbamoyl, N-ethylcarbamoyl, N,N-dimethylcarbamoyl, N,N-diethylcarbamoyl, cyano, acetyl, propionyl, butyryl, methoxycarbonyl, ethoxycarbonyl, propyloxycarbonyl, sulfamoyl, N-methylsulfamoyl, N-ethylsulfamoyl, N,N-dimethylsulfamoyl, N,N-diethylsulfamoyl, methylsulfonyl, ethylsulfonyl, propylsulfonyl, alkoxy having 1 or 2 carbon atoms, halogen or hydroxyl; or is ##STR6## in which Z, alk and T are as defined above; R' is hydrogen or C.sub.1 -C.sub.6 alkyl; alk', independently of one another, is polymethylene having 2 to 6 carbon atoms or branched isomers thereof; and m is 1 to 6, p is 1 to 6 and q is 1 to 6.
    • 22. 发明授权
    • Fiber-reactive dyes containing an aniline radical which carries two
different vinylsulfonyl moieties
    • 含有带有两个不同乙烯基磺酰基部分的苯胺基团的纤维反应性染料
    • US4929719A
    • 1990-05-29
    • US394302
    • 1989-08-10
    • Hansrudolf SchwanderAthanassios TzikasPeter Aeschlimann
    • Hansrudolf SchwanderAthanassios TzikasPeter Aeschlimann
    • C09B62/513C09B62/44C09B62/503C09B62/51
    • C09B62/503C09B62/4401
    • Reactive dyes which are particularly suitable for dyeing and printing cellulose containing fiber materials by the cold padbatch process and which produce, in high dye yield, dyeings and prints having good fastness properties containing the radical of an amine of the formula ##STR1## in which R is hydrogen, halogen, hydroxyl or sulfo, Z is a radical of the formula --CH.dbd.CH.sub.2 or --CH.sub.2 --CH.sub.2 --Y, Y is a detachable group, R' is hydrogen or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by --COOH, --CN, --OH or --SO.sub.3 H, and E is a radical of the formula ##STR2## in which R' and Z are as defined above, alk, alk' and alk" independently of one another are a C.sub.1 -C.sub.6 alkylene radical, U is hydrogen, halogen, hydroxyl, sulfato, C.sub.1 -C.sub.4 alkanoyloxy, cyano, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, carbamoyl or a radical --SO.sub.2 --Z in which Z is as defined above, V is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or a radical of the formula ##STR3## in which Z, alk and U are as defined above, and q, r and s independently of one another are an integer from 1 to 6.
    • 特别适用于通过冷拼接方法对含纤维素纤维材料进行染色和印花的活性染料,其以高染料产率,染色和印刷品具有良好的牢固性能,其含有式(1)的胺基团, 其中R是氢,卤素,羟基或磺基,Z是式-CH = CH 2或-CH 2 -CH 2 -Y的基团,Y是可分离的基团,R'是氢或被未取代或取代的C 1 -C 4烷基 通过-COOH,-CN,-OH或-SO 3 H,并且E是下式的基团:其中R'是(R 1) 和Z如上所定义,烷基,烷基和烷基彼此独立地是C 1 -C 6亚烷基,U是氢,卤素,羟基,硫酸根,C 1 -C 4烷酰氧基,氰基,羧基,C 1 -C 4烷氧基羰基, 氨基甲酰基或其中Z如上定义的基团-SO 2-Z,V是氢,取代或未取代的C 1 -C 4烷基或其中Z,alk和U为 并且q,r和s彼此独立地是1至6的整数。
    • 27. 发明授权
    • Water-soluble azo compounds containing fiber-reactive groups and having
a sulfo-naphthal coupling component with a triazinylamino substituent
suitable as dyestuffs
    • 含有纤维反应性基团并具有磺基 - 萘偶合组分的适用作为染料的三嗪基氨基取代基的水溶性偶氮化合物
    • US4740592A
    • 1988-04-26
    • US913485
    • 1986-09-30
    • Hartmut SpringerMichael KunzeMarcos SegalWerner H. Russ
    • Hartmut SpringerMichael KunzeMarcos SegalWerner H. Russ
    • C07D251/52C07D251/70C09B62/51D06P1/384D06P3/10D06P3/66C09B62/507
    • C09B62/51
    • Water soluble azo compounds having fiber-reactive dye properties conforming to the formula ##STR1## in which D denotes a benzene or naphthalene ring;R.sup.1 denotes hydrogen, alkyl, alkoxy, sulfo or carboxy;R.sup.2 denotes hydrogen, alkyl, alkoxy, sulfo, carboxy, substituted or unsubstituted aryl, hydroxy, nitro or halogen;R denotes hydrogen or substituted or unsubstituted alkyl;A denotes hydroxy, substituted or unsubstituted alkoxy or aryloxy, thio, substituted or unsubstituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;B hydroxy, optionally substituted alkoxy or aryloxy, thio, optionally substituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;M denotes hydrogen, alkali or alkaline earth;m denotes the number 1 or 2;n denotes the number 0 or 1;p denotes the number 0, 1 or 2;Y denotes .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl, vinyl or .beta.-sulfatoethyl; the group --SO.sub.2 --Y is bonded to A or D or to both; or in which:A is chlorine or bromine,B is an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series,m denotes the number 1 and the group --SO.sub.2 Y is bonded to D andD, R.sup.1, R.sup.2, R, M, n, p and Y have the above meanings.The new azo compounds dye fiber materials, such as wool and in particular cellulose, in strong and fast shades.
    • 具有符合式(1)< IMAGE>的式(1)的具有纤维反应性染料性质的水溶性偶氮化合物,其中D表示苯或萘环; R1表示氢,烷基,烷氧基,磺基或羧基; R 2表示氢,烷基,烷氧基,磺基,羧基,取代或未取代的芳基,羟基,硝基或卤素; R表示氢或取代或未取代的烷基; A表示羟基,取代或未取代的烷氧基或芳氧基,硫代,取代或未取代的烷基硫醚或芳基硫醚或任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基; B羟基,任选取代的烷氧基或芳氧基,硫代,任选取代的烷基硫醚或芳硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; M表示氢,碱或碱土; m表示数字1或2; n表示数字0或1; p表示数字0,1或2; Y表示β-硫代硫代乙基,β-磷酰乙基,β-氯乙基,乙烯基或β-磺基乙基; 基团-SO 2 -Y键合到A或D或两者; 或其中:A为氯或溴,B为任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基,m表示数1,基团-SO 2 Y与D键合,D, R2,R,M,n,p和Y具有上述含义。 新的偶氮化合物染料纤维材料,如羊毛,特别是纤维素,具有强烈和快速的色调。
    • 28. 发明授权
    • Water-soluble pyridone monoazo compounds suitable as fiber reactive
dyestuffs
    • US4659807A
    • 1987-04-21
    • US757687
    • 1985-07-22
    • Marcos Segal
    • Marcos Segal
    • C09B62/51D06P1/384D06P3/10D06P3/66C09B62/527C09B62/53
    • D06P1/384C09B62/51
    • Monoazo compounds which are suitable as fiber-reactive dyestuffs have the general formula (1) ##STR1## in which: D is a benzene or naphthalene ring or a radical of the formula (2) or (3) ##STR2## R.sup.1 is hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, hydroxy, nitro or halogen, if D stands for a benzene ring, andR.sup.2 is hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen, carboxy or sulfo, if D stands for a benzene ring, orR.sup.1 is hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, carboxy, halogen, sulfo or a group of the formula --SO.sub.2 --Y (where Y has the meaning mentioned hereinafter), if D stands for a naphthalene ring, andR.sup.2 is hydrogen or sulfo, if D is a naphthalene ring, orR.sup.1 is, if D is a radical of the formula (2), hydrogen, nitro, chlorine or alkoxy of 1 to 4 carbon atoms, R.sup.1 being bonded to the benzene nucleus V, andR.sup.2 is, if D is a radical of the formula (2), chlorine, sulfo, nitro or hydrogen, R.sup.2 being bonded to the benzene nucleus W, orR.sup.1 is, if D is a radical of the formula (3), hydrogen, nitro or sulfo, R.sup.1 being bonded to the benzene nucleus V, andR.sup.2 is, if D is a radical of the formula (3), chlorine, sulfo or hydrogen, R.sup.2 being bonded to the benzene nucleus W;the group --SO.sub.2 --Y in the formulae (2) and (3) is bonded to V or W, preferably to V;Y is vinyl or ethyl which contains bonded in the .beta.-position a substituent which is eliminatable as an anion under alkaline conditions;R is hydrogen or carbamoyl,B is alkyl of 1 to 4 carbon atoms which is substituted by sulfato, phosphato, carboxy or sulfo;M is hydrogen or one equivalent of a monovalent, divalent or trivalent metal;the moieties B, R.sup.1, R.sup.2 and R can have meanings which are identical to or different from one another.The new monoazo compounds produce on hydroxy- and/or carboxamido-containing materials, in particular fiber materials, such as cellulose fibers and wool, useful dyeings and prints having good end-use and manufacturing fastness properties.
    • 30. 发明授权
    • Process for dyeing silk or fibre blends containing silk
    • 染色丝绸或含有丝的纤维混合物的方法
    • US4560388A
    • 1985-12-24
    • US598951
    • 1984-04-11
    • Rudolf Rohrer
    • Rudolf Rohrer
    • C09B62/085C09B62/20C09B62/44C09B62/443C09B62/47C09B62/51D06P3/10D06P3/14C09B62/00
    • C09B62/443C09B62/4401D06P3/10Y10S534/01Y10S8/917
    • A process for dyeing or printing silk or silk-containing fibre blends with reactive dyes, which comprises the use of a reactive dye of the formulaD--Y].sub.n (1),wherein D is the radical of a sulfo group containing dye of the mono- or polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, [Y].sub.n, where n is 1 to 4, denotes identical or different reactive radicals Y, except reactive dyes of the formula (1), wherein n is 1 and Y is a chloroacetyl, .alpha.-bromoacryloyl, .alpha.,.beta.-dibromopropionyl, aminochloro-s-triazinyl, C.sub.1 -C.sub.4 alkoxychloro-s-triazinyl or C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkoxychloro-s-triazinyl radical, and [Y].sub.2 denotes two identical chloroacetyl, .alpha.-bromoacryloyl or .alpha.,.beta.-dibromopropionyl radicals, in aqueous medium at a temperature in the range from 50.degree. to 130.degree. C., and subsequently effecting dye fixation at pH 8 to 11. Dyeings or prints with good fastness properties are obtained.
    • 一种用活性染料染色或印刷丝绸或含丝的纤维共混物的方法,其包括使用式DY] n(1)的活性染料,其中D是含单磺酸基团的染料的基团, 或多偶氮,金属络合物偶氮,蒽醌,酞菁,甲an,偶氮甲碱,二恶嗪,吩嗪,二苯乙烯,三苯基甲烷,呫吨,噻吨酮,硝基芳基,萘醌,芘醌或苝四亚甲基酰亚胺系列,[Y] n,其中n为1〜4, 或不同的反应性基团Y,除了式(1)的活性染料,其中n是1,Y是氯乙酰基,α-溴丙烯酰,α,β-二溴丙酰基,氨基氯代三嗪基,C 1 -C 4烷氧基氯代三嗪基或 C 1 -C 4烷氧基-C 1 -C 4烷氧基氯代三嗪基,和[Y] 2表示两种相同的氯代乙酰基,α-溴丙酰基或α,β-二溴丙酰基,在水介质中,温度为50-130℃ 然后进行染料染色 pH为8〜11。得到具有良好牢度特性的染色或印花。