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1. 发明申请

US20030024435A1 Black-dyeing inks and their use 失效
标题翻译：黑染油墨及其用途
公开(公告)号：US20030024435A1
公开(公告)日：2003-02-06
申请号：US10060833
申请日：2002-01-29
发明人： Urs Lehmann , Athanassios Tzikas , Marcel Frick
IPC分类号： C09D011/00
CPC分类号： C09D11/32 , C09B43/16 , C09B62/04 , C09B62/4403 , C09B67/0041 , C09B67/0046 , C09D11/17 , C09D11/18 , C09D11/328 , D06P5/30
摘要： Black-dyeing aqueous inks comprising 20 to 95% by weight of at least one dye (A), together with 5 to 80% by weight of at least one dye chosen from the group consisting of (B) and (C), based on the total weight of the dyes (A), (B) and (C) in the ink, and 1 to 40% by weight of a water-miscible organic solvent, based on the total weight of the ink, the dye (A) containing, as the colouring part of the molecule, one or more radicals of the formula (I), (II), (III) or (IV) 1 the dye (B) containing, as the coloring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the formula (V), (VI), (VII) or (VIII) 2 and the dye (C) containing, as the coloring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the abovementioned formula (V), (VI), (VII) or (VIII) and one or more radicals of the abovementioned formula (I), (II), (III) or (IV), in which (G)0-2 is 0 to 2 identical or different substituents from the group consisting of substituted or unsubstituted amino, hydroxyl and nitro, L is substituted or unsubstituted amino, R is halogen, C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, nitro or cyano, (V)0-2 is 0 to 2 identical or different substituents from the group consisting of halogen, C1-C4alkyl, C1-C4alkoxy, null-sulfatoethylsulfonyl and sulfo, (W)0-1 is an N-acyl radical, if any, n is the number 0, 1, 2 or 3, m is the number 1, 2 or 3 and r and q are the number 0 or 1. The inks according to the invention are distinguished by good black shades without a change in shade in artificial light (metamerism) and an outstanding fastness to light.
摘要翻译：包含20至95重量％的至少一种染料（A）和5-80重量％的至少一种选自（B）和（C）的染料的黑染水性油墨基于染料（A）中的染料（A），（B）和（C）的总重量，以及1至40重量％的与水可混溶的有机溶剂，作为分子的着色部分，含有一个或多个式（I），（II），（III）或（IV）的基团含有作为分子着色部分的染料（B）一个或多个含有磺基或一或多个式（Ⅴ），（Ⅵ），（Ⅶ）或（Ⅷ）的基团的单或双偶氮基团和含有分子着色部分的染料（C）含有上述式（V），（VI），（VII）或（VIII）的一个或多个上述式（I），（II），（II）， III）或（IV），其中（G）0-2为0至2相同或不同取代或未取代的氨基，羟基和硝基取代基，L为取代或未取代的氨基，R为卤素，C1-C4烷基，C1-C4烷氧基，C2-C4烷酰基氨基，羟基，羧基，硝基或氰基，（Ⅴ） -2是0至2个与卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，β-硫酸基乙基磺酰基和磺基相同或不同的取代基，（W）0-1是N-酰基，如果有的话，n是数字0,1,2或3，m是数字1,2或3，r和q是数字0或1.根据本发明的油墨的特征在于良好的黑色阴影，而人造光下的色调不变同色异谱）和出色的耐光牢度。

2. 发明授权

US5646274A Phthalocyanine monoazo compounds and a process for producing the same 失效
标题翻译：酞菁单偶氮化合物及其制造方法
公开(公告)号：US5646274A
公开(公告)日：1997-07-08
申请号：US550370
申请日：1995-10-30
申请人： Toshiyuki Araki , Takemi Tokieda , Shin-ichi Yabushita , Yasuyoshi Ueda , Bunzi Tsukise
发明人： Toshiyuki Araki , Takemi Tokieda , Shin-ichi Yabushita , Yasuyoshi Ueda , Bunzi Tsukise
IPC分类号： C07D487/22 , C09B56/14 , C09B62/10 , C09B62/44 , C09B62/503 , C09B47/24 , C07D403/10
CPC分类号： C09B62/4403 , C09B62/503
摘要： A phthalocyanine monoazo compound which is represented by the following formula (I): ##STR1## wherein the variable radicals have the meaning given in the description, and the phthalocyanine monoazo compound has green color.
摘要翻译：由下式（I）表示的酞菁单偶氮化合物：描述中给出的含义，酞菁单偶氮化合物具有绿色。

3. 发明授权

US5484458A Triphendioxazine compounds, processes for their preparation and their use as dyestuffs 失效
标题翻译：三苯并二恶嗪化合物，其制备方法及其作为染料的用途
公开(公告)号：US5484458A
公开(公告)日：1996-01-16
申请号：US243111
申请日：1994-05-16
申请人： Werner H. Russ , Horst Tappe , Christian Schumacher
发明人： Werner H. Russ , Horst Tappe , Christian Schumacher
IPC分类号： C07C317/28 , C09B62/44 , C09B62/503 , C09B67/22 , D06P3/24 , D06P3/66 , C09B62/002 , D06P1/38
CPC分类号： C09B62/503 , C07C317/28 , C09B62/4403 , C09B67/0033 , Y10S8/917 , Y10S8/918 , Y10S8/924
摘要： Triphendioxazine compounds corresponding to the formula ##STR1## which are suitable as fiber-reactive dyestuffs for dyeing and printing material, in particular fiber material, containing hydroxy and/or carboxamide groups, such as wool and synthetic polyamide fibers, and especially cellulose fibers, such as cotton, are described. In formula (1), M is hydrogen or an alkali metal and Z is a radical of the formula (2) ##STR2## in which R is hydrogen, sulfo, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, nitro or cyano, W is alkylene having 3 to 6 carbon atoms and the group --SO.sub.2 --Y is a fiber-reactive group of the vinyl sulfone series.
摘要翻译：对应于式（1）的三苯并二恶嗪化合物适合用作染色和印刷材料的纤维反应性染料，特别是含有羟基和/或羧酰胺基团的纤维材料，例如羊毛和合成聚酰胺纤维，特别是纤维素描述了诸如棉花之类的纤维。在式（1）中，M是氢或碱金属，Z是式（2）的基团，其中R是氢，磺基，具有1至4个碳原子的烷基，具有1至 4个碳原子，硝基或氰基，W是具有3至6个碳原子的亚烷基，基团-SO 2 -Y是乙烯基砜系列的纤维反应性基团。

4. 发明授权

US5334709A Reactive dyestuffs containing a triazinylamino group and one or two groups of the vinylsulfone series 失效
标题翻译：含有三嗪基氨基和一个或两个乙烯基砜系列的反应性染料
公开(公告)号：US5334709A
公开(公告)日：1994-08-02
申请号：US993360
申请日：1992-12-18
申请人： Jorg Dannheim , Werner H. Russ
发明人： Jorg Dannheim , Werner H. Russ
IPC分类号： C09B62/505 , C09B62/44 , C09B62/503 , C09B62/515 , D06P1/38 , D06P1/384
CPC分类号： C09B62/503 , C09B62/4403
摘要： Fiber-reactive dyestuffs, such as, for example, azo dyestuffs and heavy metal complex derivatives thereof, anthraquinone dyestuffs, phthalocyanine dyestuffs and formazan dyestuffs, which contain a fiber-reactive group of the vinylsulfone series and furthermore a group of the general formula ##STR1## in which R.sup.x is hydrogen or lower alkyl, which can be substituted by substituents customary in dyestuffs, and Q.sup.1 and Q.sup.2 both independently of one another are each lower alkyl, which is substituted by 1 or 2 lower alkanoyl groups or 1 or 2 lower alkoxycarbonyl groups or by one such alkoxycarbonyl and alkanoyl group, or an amino group, which is substituted by optionally substituted aryl and/or alkyl radicals, or an optionally substituted alkoxy, aryloxy, alkylthio or arylthio radical or a cyanamido radical, are described. The novel dyestuffs dye material containing hydroxy and/or carboxamide groups, such as cellulose fiber materials, wool and polyamides, in deep shades, and moreover are suitable for discharge and resist printing.
摘要翻译：纤维反应性染料，例如偶氮染料和其重金属络合物衍生物，蒽醌染料，酞菁染料和甲an染料，其含有乙烯基砜系列的纤维反应性基团，此外还有通式（3）其中Rx是氢或可以被染料中常规取代的低级烷基，并且Q1和Q2彼此独立地是低级烷基，其被1或2个低级烷酰基取代，或1或2个 2个低级烷氧基羰基或一个这样的烷氧基羰基和烷酰基，或被任选取代的芳基和/或烷基或任选取代的烷氧基，芳氧基，烷硫基或芳硫基或氰酰氨基取代的氨基。。含有羟基和/或羧酰胺基团的新型染料染料，例如纤维素纤维材料，羊毛和聚酰胺，深色调，并且还适用于放电和抗蚀印刷。

5. 发明授权

US5241055A Reactive dyes with a reactive system based on alkenylsulfonyl and benzyl compounds as intermediates therefor 失效
标题翻译：具有基于烯基磺酰基和苄基化合物的反应体系的活性染料作为其中间体
公开(公告)号：US5241055A
公开(公告)日：1993-08-31
申请号：US899943
申请日：1992-06-17
申请人： Claus Marschner , Joerg L. Jessen , Klaus Pandl , Manfred Patsch
发明人： Claus Marschner , Joerg L. Jessen , Klaus Pandl , Manfred Patsch
IPC分类号： C07C317/14 , C07C317/36 , C09B62/44
CPC分类号： C09B62/4403 , C07C317/14 , C07C317/36
摘要： Reactive dyes useful for dyeing or printing hydroxyl- or nitrogen-containing substrates have the formula ##STR1## where U is vinyl, propenyl or the radical of the formula ##STR2## in which Z.sup.1 is hydrogen or methyl and Z.sup.2 is a group which is detachable under alkaline reaction conditions,X isa) the radical of a chromophore orb) the radical of a coupling component to which may be additionally attached the radical of a diazo component via an azo linkage and which may contain an additional reactive group, andL isa) a bridge member of the formula ##STR3## where Q.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl, Q.sup.2 and Q.sup.3 are each independently of the other hydrogen or C.sub.1 -C.sub.4 -alkyl, and Q.sup.4 is a leaving group, orb) an azo linkage,the radical X-L being bonded to the benzene ring meta or para to the CH.sub.2 -SO.sub.3 H group,and their preparation may involve novel benzyl compounds as intermediates.
摘要翻译：可用于染色或印刷含羟基或含氮底物的活性染料具有式“IMAGE”，其中U是乙烯基，丙烯基或式（IMAGE）基团，其中Z1是氢或甲基，Z2是可分离的基团在碱性反应条件下，X是a）发色团的基团或b）偶联组分的基团，其可以另外通过偶氮键连接重氮组分的基团，并且可以含有另外的反应性基团，并且L 是a）式为“IMAGE”的桥式成员，其中Q1为氢或C1-C4-烷基，Q2和Q3各自独立于另一个氢或C 1 -C 4 - 烷基，Q 4为离去基团，或b）偶氮键，基团XL键合到CH2-SO3H基团的间位或对位的苯环上，它们的制备可以包括新的苄基化合物作为中间体。

6. 发明授权

US5225544A Fiber reactive dyes which contain a cyanoaminotriazinyl group and one or two groups of the vinyl sulfone series 失效
标题翻译：含有氰基氨基亚氨基的纤维反应性染料和一种或两种乙烯基磺酸酯系列
公开(公告)号：US5225544A
公开(公告)日：1993-07-06
申请号：US975429
申请日：1992-11-12
申请人： Jorg Dannheim , Werner H. Russ
发明人： Jorg Dannheim , Werner H. Russ
IPC分类号： C09B62/503 , C09B62/44 , D06P3/24 , D06P3/66
CPC分类号： C09B62/4403
摘要： Water-soluble dyes are described, such as azo dyes, metal complex dyes, anthraquinone, phthalocyanine and formazan dyes, which contain a fiber-reactive group of the vinyl sulfone series which, if desired, is bound via a bridging member, and furthermore contain a 4-cyanamido-1,3,5-triazin-6-ylamino radical which is substituted in the 2 position by a group of the formula (2) ##STR1## in which R.sup.z is hydrogen or a lower alkyl group which is unsubstituted or substituted by alkyl, hydroxy, cyano, lower alkoxy, carboxyl, sulfamoyl, sulfo or sulfato or by a substituted or unsubstituted phenyl radical or is a cyclohexyl radical or a substituted or unsubstituted phenyl radical, W is an aryl, alkylenearyl, arylenealkyl, alkylenearylenealkyl or arylenealkylenearyl radical substituted by 1 to 4 water-solubilizing substituents, it being possible for these aryl, arylene, alkyl and alkylene radicals to be additionally substituted and/or interrupted by hetero groups, A is the number zero or 1, and B is the number 1 or 2, the sum of (A+B) being the number 2. The dyes are fiber-reactive and are suitable for the dyeing of hydroxy- and/or carboxamido-containing material, in particular fiber material, such as cotton, wool, silk and synthetic polyamide, by the procedures known for fiber-reactive dyes.
摘要翻译：描述了水溶性染料，例如偶氮染料，金属络合物染料，蒽醌，酞菁和甲an染料，其含有乙烯基砜系列的纤维反应性基团，如果需要，其通过桥连构件结合，并且还含有在2位被式（2）的基团取代的4-氰氨基-1,3,5-三嗪-6-基氨基，其中R z是氢或低级烷基，被烷基，羟基，氰基，低级烷氧基，羧基，氨磺酰基，磺基或硫酸根取代或被取代或未取代的苯基取代，或者是环己基或取代或未取代的苯基，W是芳基，亚烷基硬脂基，亚芳基，被1至4个水溶性取代基取代的亚烷基亚烷基烷基或亚芳基亚烷基烯基，这些芳基，亚芳基，烷基和亚烷基可以另外被杂原子取代和/或中断，A是数字0或1，B 是数字1或2，（A + B）的数量为数字2.染料是纤维反应性的，适用于染色含羟基和/或含羧酰氨基的材料，特别是纤维材料，例如棉，羊毛，丝绸和合成聚酰胺，通过纤维活性染料已知的程序。

7. 发明授权

US5021558A Water-soluble fiber reactive dyes 失效
标题翻译：水溶性纤维活性染料
公开(公告)号：US5021558A
公开(公告)日：1991-06-04
申请号：US496534
申请日：1990-03-20
申请人： Holger M. Buch
发明人： Holger M. Buch
IPC分类号： C09B62/002 , C09B62/44
CPC分类号： C09B62/4403
摘要： Water-soluble fiber-reactive azo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylemthane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dyes which contain once or twice the group of the general formula ##STR1## in which: R.sup.x and R.sup.z are, independently of one another, hydrogen or lower alkyl, which can be substituted by halogen, hydroxyl, cyano, lower alkoxy, lower alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato;W is fluorine, chlorine, bromine, sulfo, phenylsulfonyl or alkylsulfonyl of 1 to 4 carbon atoms;Y is vinyl, .beta.-substituted, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-alkanoyloxyethyl of 2 to 5 carbon atoms in the alkanoyl radical, .beta.-benozoyloxyethyl, .beta.-(sulfobenzoyloxy)ethyl, .beta.-(p-toluenesulfonyloxy)ethyl or .beta.-halogenoethyl.The fiber-reactive dyes are highly suitable for the dyeing of carboxamido-containing and/or hydroxyl-containing materials, such as, for example, synthetic polyamide fiber materials, wool and in particular cellulose fiber materials with a high degree of fixation in hues which have a high color strength and good fastness properties.
摘要翻译：金属络合物偶氮，蒽醌，酞菁，甲an，偶氮甲碱，二恶嗪，吩嗪，芪，三苯酚，呫吨，噻吨酮，硝基芳基，萘醌，芘醌或苝四亚甲基亚胺染料，其含有一般或一般为羟基，氰基，低级烷氧基，低级烷氧基羰基，羧基，氨磺酰基，磺基或硫酸根取代的氢或低级烷基;其中：R 1和R 3彼此独立地为氢或低级烷基。 W是1至4个碳原子的氟，氯，溴，磺基，苯基磺酰基或烷基磺酰基; Y是乙酰基，β-取代的，β-硫代硫代乙基，β-磷酰乙基，在链烷酰基中具有2至5个碳原子的β-烷酰氧基乙基，β-苯并氧乙基，β-（磺基苯甲酰氧基）乙基，β-（对甲苯磺酰氧基）乙基或 β-卤代乙基。纤维反应性染料非常适合于含有羧酰胺的和/或含羟基材料的染色，例如合成聚酰胺纤维材料，羊毛，特别是具有高度固色度的纤维素纤维材料具有高的色强度和良好的牢度性能。

8. 发明授权

US4879372A Fiber reactive compound having sym-triazine and aminobenzoylamine moieties 失效
标题翻译：具有对 - 三嗪和氨基苯甲酰胺部分的纤维反应性化合物
公开(公告)号：US4879372A
公开(公告)日：1989-11-07
申请号：US117552
申请日：1987-11-06
申请人： Toshihiko Morimitsu , Naoki Harada , Takashi Omura
发明人： Toshihiko Morimitsu , Naoki Harada , Takashi Omura
IPC分类号： C09B62/503 , C09B62/44 , D06P1/38
CPC分类号： C09B62/4403 , D06P1/38
摘要： A triazine compound having a dye moiety, a sym-monohalotriazine moiety and an aminobenzoylamine moiety, which is represented, for example, by the following formula, ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently hydrogen or alkyl, A is phenylene or naphthylene, D is a dye moiety, X is chloro or fluoro, Z is --SO.sub.2 CH.dbd.CH.sub.2, --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H or the like, and n is 0, 1 or 2, and which is useful for dyeing or printing fiber materials such as cellulose fiber materials with superior dye performance such as build-up property to give dyed or printed products excellent is fastness properties.
摘要翻译：具有染料部分，对称单卤代三嗪部分和氨基苯甲酰胺部分的三嗪化合物，其例如由下式表示，其中R 1，R 2和R 3独立地为氢或烷基，A为亚苯基或亚萘基，D为染料部分，X为氯或氟，Z为-SO2CH = CH2，-SO2CH2CH2OSO3H等，n为0,1或2，可用于染色或印刷纤维素纤维材料具有优异的染色性能，如堆积性能，赋予染色或印刷产品优异的耐牢度性能。

9. 发明授权

US4649193A Water-soluble dyestuffs containing fibre-reactive groups of the vinylsulfone series and the fluoro-s-triazinyl-amino series 失效
标题翻译：含有乙烯基砜系列的纤维反应性基团和氟代-s-三嗪基 - 氨基系列的水溶性染料
公开(公告)号：US4649193A
公开(公告)日：1987-03-10
申请号：US519211
申请日：1983-08-01
申请人： Fritz Meininger , Joachim W. Otten, deceased , by Ursula Otten, heir , by Anna G. Rudolph nee Otten, heir
发明人： Fritz Meininger , Joachim W. Otten, deceased , by Ursula Otten, heir , by Anna G. Rudolph nee Otten, heir
IPC分类号： C09B62/503 , C09B62/44 , D06P1/384 , C09B62/06 , C09B62/085 , C09B62/095 , C09B62/10
CPC分类号： C09B62/4403
摘要： Water-soluble fibre-reactive dyestuffs containing one or two fibre-reactive groups of the vinylsulfone series and one or two fibre-reactive groups of the fluoro-s-triazinyl-amino series. These dyestuffs can be applied on fibre materials containing hydroxy and/or carbonamide groups by known application and fixation techniques for fibre-reactive dyes to yield deep and fast dyeings on these materials.
摘要翻译：含有一个或两个乙烯基砜系列的纤维反应性基团和氟代-s-三嗪基 - 氨基系列的一个或两个纤维反应性基团的水溶性纤维活性染料。这些染料可以通过纤维活性染料的已知应用和固色技术应用于含有羟基和/或碳酰胺基团的纤维材料上，以在这些材料上产生深色和快速的染色。

10. 发明授权

US3440240A Reactive azo-dyestuffs 失效
标题翻译：反应性AZO-DYESTUFFS
公开(公告)号：US3440240A
公开(公告)日：1969-04-22
申请号：US3440240D
申请日：1964-06-09
申请人： HOECHST AG
发明人： KUHNE RUDOLF , MEININGER FRITZ , FROLICH HEINRICH
IPC分类号： C09B62/006 , C09B62/44 , C09B62/523 , C09B62/527 , D06P1/384 , C09B62/00 , C09B29/24 , C09B31/02
CPC分类号： C09B62/006 , C09B62/4403 , C09B62/523 , C09B62/527 , D06P1/384 , Y10S534/01

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