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    • 23. 发明授权
    • Method and apparatus for the production of alkylene carbonate
    • 用于生产碳酸亚烷基酯的方法和装置
    • US5440004A
    • 1995-08-08
    • US238743
    • 1994-05-05
    • Masaharu DoyaYutaka KanbaraKen-ichi KimizukaTakashi Okawa
    • Masaharu DoyaYutaka KanbaraKen-ichi KimizukaTakashi Okawa
    • C07D317/36C08G64/00
    • C07D317/36
    • A method for the production of an alkylene carbonate at high yields and high selectivity by a reaction between an alkylene glycol and urea, the method being capable to preventing the deposition of a white crystal in the reflux condenser used in a conventional method for the production of alkylene carbonate and the subsequent decrease in the yield, wherein:a gas washing member and a cooling member are disposed above a reaction portion where alkylene glycol and urea are allowed to react,ammonia-containing steam exhausted from the reaction portion is downwardly introduced into the cooling member through the gas washing member,condensate and ammonia gas exhausted from a bottom of the cooling member are gas-liquid separated,the condensate is introduced into the gas washing member, andthe ammonia gas is removed from the reaction system.
    • 一种通过亚烷基二醇和尿素之间的反应以高产率和高选择性生产碳酸亚烷基酯的方法,该方法能够防止白色结晶沉积在用于生产 碳酸亚烷基酯和随后的产率降低,其中:气体洗涤部件和冷却部件设置在使亚烷基二醇和尿素反应的反应部分上方,从反应部分排出的含氨蒸气被向下引入 通过气体洗涤部件的冷却部件,从冷却部件的底部排出的冷凝物和氨气体被气液分离,将冷凝物引入到气体洗涤部件中,从反应体系中除去氨气。
    • 29. 发明授权
    • Process for producing methyl p-toluate
    • 制备对甲苯甲酸甲酯的方法
    • US4010195A
    • 1977-03-01
    • US648027
    • 1976-01-12
    • Nobuo IsogaiTakashi OkawaTakako Takeda
    • Nobuo IsogaiTakashi OkawaTakako Takeda
    • C01B15/022C07C51/00C07C51/255C07C409/30C07C69/76
    • C07C45/80C01B15/022C07C407/00C07C45/81C07C51/00C07C51/255C07C67/08
    • P-Tolualdehyde freed from reaction-inhibiting substances is autooxidized by a gas containing molecular oxygen in an aliphatic ketone or fatty acid ester solvent under pressure in the absence of catalyst to produce per-p-toluic acid. The resulting per-p-toluic acid is brought into contact with a lower olefin in the absence of catalyst to produce p-toluic acid and an alkylene oxide at the same time, or said per-p-toluic acid is reacted with allyl alcohol to produce glycidol and p-toluic acid at the same time, and further the resulting glycidol is hydrolyzed to produce glycerin, or said per-p-toluic acid is reacted with methanol in the presence of an esterification catalyst to produce hydrogen peroxide and methyl p-toluate at the same time. The foregoing reactions can be carried out easily and safely in simple processes in high yields.
    • 在不存在催化剂的情况下,在脂肪族酮或脂肪酸酯溶剂中,通过含有分子氧的气体,将从反应抑制物质中除去的P-甲醛自动氧化,生成对 - 对甲苯甲酸。 在不存在催化剂的情况下,使所得的对 - 对甲苯甲酸与低级烯烃接触,同时产生对甲苯甲酸和环氧烷烃,或将所述每对甲苯甲酸与烯丙醇反应, 同时产生缩水甘油和对甲苯甲酸,进一步将所得缩水甘油酯水解制备甘油,或者在酯化催化剂存在下使所述每对甲苯甲酸与甲醇反应生成过氧化氢和对甲苯磺酸甲酯, 同时甲苯甲酸。 上述反应可以在高产率的简单方法中容易且安全地进行。