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11. 发明申请

US20070037999A1 Method for isolating a homogeneous catalyst containing rhodium 审中-公开
标题翻译：用于分离含铑的均相催化剂的方法
公开(公告)号：US20070037999A1
公开(公告)日：2007-02-15
申请号：US10561611
申请日：2004-06-19
申请人： Wolfram Stuer , Jens Scheidel , Peter Bassler , Michael Roper
发明人： Wolfram Stuer , Jens Scheidel , Peter Bassler , Michael Roper
IPC分类号： C07C69/52 , C07C69/34 , C07C253/30 , C07C231/14
CPC分类号： C07C67/54 , C07C51/44 , C07C231/24 , C07C253/32 , C07C253/34 , C07C255/08 , C07C255/03 , C07C255/20
摘要： A process for removing a compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group and carboxamide group, from a mixture which comprises a compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group and carboxamide group, and a compound which is homogeneous with respect to the mixture and contains rhodium, by distillation.
摘要翻译：从包含至少两个官能团的化合物的混合物的混合物中除去至少两个各自独立地选自腈基，羧酸基，羧酸酯基和羧酰胺基的官能团的化合物的方法，各自独立地选自腈基，羧酸基，羧酸酯基和羧酰胺基的基团，和通过蒸馏相对于混合物均匀并含有铑的化合物。

12. 发明授权

US6048997A Manufacturing process for 6-aminocapronitrile 有权
标题翻译： 6-氨基己腈的制备方法
公开(公告)号：US6048997A
公开(公告)日：2000-04-11
申请号：US230742
申请日：1999-02-01
申请人： Rolf Fischer , Rocco Paciello , Michael Roper , Werner Schnurr
发明人： Rolf Fischer , Rocco Paciello , Michael Roper , Werner Schnurr
IPC分类号： B01J31/18 , B01J31/24 , C07C209/26 , C07C253/30 , C07C255/24 , C07F9/6574 , C07C255/00
CPC分类号： C07F9/65746 , B01J31/185 , B01J31/2409 , C07C209/26 , C07C253/30 , C07C255/24 , B01J2531/822 , B01J2531/828 , B01J2531/845
摘要： Manufacture of 6-aminocapronitrile or 6-aminocapronitrile/hexamethylene diamine mixtures, involving a) the reaction of at least one pentennitrile, selected from the group consisting of 2,3 and 4-pentennitrile with carbon monoxide and hydrogen in the presence of catalysts, which contain at least one element of the eighth subgroup as active components, obtaining a hydrogenation formylating discharge (I), b) the optional separation of carbon monoxide, hydrogen and the catalyst from the hydrogenation formylating discharge (I), obtaining a hydrogenation formylating discharge (II), c) the separation of 5-formyl valeronitrile from the hydrogenation formylating discharge (I) or (II), d) the reaction of separated 5-formyl valeronitrile with ammonia and hydrogen in the presence of hydrogenating catalysts, selected from the group consisting of rhenium, copper and its compounds as well as metals and metallic compounds of the eighth group, obtaining a hydrogenation discharge, and e) obtaining 6-aminocapronitrile and if necessary hexamethylene diamine.
摘要翻译： PCT No.PCT / EP97 / 03988 Sec。 371日期1999年2月1日 102（e）1999年2月1日PCT 1997年7月23日PCT公布。第WO98 / 05632号公报日期1998年2月12日6-氨基己腈或6-氨基己腈/六亚甲基二胺混合物的制造，涉及a）选自2,3和4-戊腈中的至少一种戊腈与一氧化碳和氢的反应存在含有第八亚组中的至少一种元素作为活性组分的催化剂，获得加氢甲酰化放电（I），b）任选从氢化甲酰化放电（I）中分离一氧化碳，氢和催化剂，获得加氢甲酰化放电（II），c）从加氢甲酰化放电（I）或（II）中分离5-甲酰基戊腈; d）在氢化催化剂存在下，分离的5-甲酰基戊腈与氨和氢的反应，选自铼，铜及其化合物以及第八组的金属和金属化合物，获得氢化放电，以及 e）获得6-氨基己腈，如果需要的话，得到六亚甲基二胺。

13. 发明授权

US6030505A Process for the continuous preparation of pure 5-formyl valeric acid esters 失效
标题翻译：连续制备纯5-甲酰戊酸酯的方法
公开(公告)号：US6030505A
公开(公告)日：2000-02-29
申请号：US11096
申请日：1998-01-27
申请人： Gunther Achhammer , Michael Roper
发明人： Gunther Achhammer , Michael Roper
IPC分类号： C07C67/54 , C07C69/716 , B01D3/34
CPC分类号： C07C67/54
摘要： 5-Formylvaleric esters are prepared in a yield of not less than 90% by distillation of a formylvaleric ester mixture of 5-formylvaleric ester and either 3- or 4-formylvaleric ester or a mixture of 3- and 4-formylvaleric esters, where the ester radicals of the respective formylvaleric esters are identical, wherein the 3- or 4-formylvaleric ester or a mixture thereof is separated from the 5-formylvaleric ester in a distillation column at a pressure in the range from 2 to 100 mbar and a temperature of not above 150.degree. C. (measured as the temperature at the bottom of the column) and the esters used are the corresponding methyl or ethyl esters, where the purity of the 5-formylvaleric ester is not less than 98% and, as impurity, 4-formylvaleric ester is present in an amount of not more than 100 ppm.
摘要翻译： PCT No.PCT / EP96 / 03290 Sec。 371日期：1998年1月27日 102（e）日期1998年1月27日PCT提交1996年7月26日PCT公布。出版物WO97 / 06126 日本19975年2月20日 - 通过蒸馏5-甲酰戊酸酯和3-甲酰基戊酸酯或3-和4-甲酰基戊酸酯的混合物的甲酰戊酸酯混合物，以不低于90％的产率制备甲酰基戊酸酯，甲酰基戊酸酯，其中各自甲酰基戊酸酯的酯基是相同的，其中在蒸馏塔中将3-或4-甲酰基戊酸酯或其混合物与5-甲酰基戊酸酯在2至100的压力下分离 mbar，温度不高于150℃（以塔底温度测量），所用酯为相应的甲基或乙酯，其中5-甲酰基戊酸酯的纯度不低于98％作为杂质，4-甲酰基戊酸酯的含量不超过100ppm。

14. 发明授权

US6020441A Hydroformylation of ethylenically unsaturated polymers in aqueous dispersion 失效
标题翻译：乙烯基不饱和聚合物在水分散体中的加氢甲酰化
公开(公告)号：US6020441A
公开(公告)日：2000-02-01
申请号：US854661
申请日：1997-05-12
申请人： Edgar Zeller , Hartmann F. Leube , Bernhard Schlarb , Heinz-Josef Kneuper , Michael Roper
发明人： Edgar Zeller , Hartmann F. Leube , Bernhard Schlarb , Heinz-Josef Kneuper , Michael Roper
IPC分类号： C08C19/00 , C08F8/00
CPC分类号： C08C19/00 , C08F8/00 , C08F2/38 , C08F2800/20
摘要： Polymers containing ethylenically unsaturated double bonds are hydroformylated by reacting aqueous dispersions of the polymers with hydrogen and carbon monoxide in the presence of suitable hydroformylation catalysts.Also provided are the polymer dispersions obtainable by this process and the hydroformylated polymers themselves.
摘要翻译：含有烯属不饱和双键的聚合物在合适的加氢甲酰化催化剂存在下，通过使聚合物的水分散体与氢气和一氧化碳反应而加氢甲酰化。还提供了可通过该方法获得的聚合物分散体和加氢甲酰化聚合物本身。

15. 发明授权

US5705707A Preparation of n-butyraldehyde and/or n-butanol 失效
标题翻译：正丁醛和/或正丁醇的制备
公开(公告)号：US5705707A
公开(公告)日：1998-01-06
申请号：US676185
申请日：1996-07-12
申请人： Jurgen Kanand , Michael Roper , Rolf Pinkos , Rocco Paciello , Alfred Thome
发明人： Jurgen Kanand , Michael Roper , Rolf Pinkos , Rocco Paciello , Alfred Thome
IPC分类号： B01J21/16 , B01J27/18 , B01J29/06 , C07B61/00 , C07C27/00 , C07C29/17 , C07C31/12 , C07C41/06 , C07C41/32 , C07C43/15 , C07C45/51 , C07C47/02 , C07C47/52
CPC分类号： C07C41/32 , C07C29/172 , C07C41/06 , C07C45/513
摘要： A process for the preparation of n-butyraldehyde and/or n-butanol, wherein a) 1,3-butadiene is caused to react with an alcohol of the formula I ROH I, to form a mixture of adducts of the formulas II ##STR1## and III ##STR2## b) the adduct III is isomerized to the adduct II, c) the adduct II is isomerized in the presence of a homogeneous or heterogeneous transition metal element catalyst to form the enol ether of the formula IV ##STR3## and d) n-butyraldehyde and/or n-butanol is/are produced from this ether IV by the reaction thereof with hydrogen and water or water only in the presence of a homogeneous or heterogeneous catalyst.
摘要翻译： PCT No.PCT / EP94 / 00114 Sec。 371日期：1996年7月12日 102（e）日期1996年7月12日PCT提交1995年1月12日PCT公布。公开号WO95 / 19334 日期1995年7月20日一种用于制备正丁醛和/或正丁醇的方法，其中使a）1,3-丁二烯与式IROHI的醇反应，形成下式的加合物的混合物 II）III和III IIIa）b）加合物III异构化为加合物II，c）加合物II在均相或不均匀的过渡金属元素催化剂的存在下异构化以形成式 IV和d）只有在均相或多相催化剂的存在下，通过与氢和水或水的反应，由该醚IV产生正丁醛和/或正丁醇。

16. 发明申请

US20070034576A1 Method for separating a homogeneous catalyst 审中-公开
标题翻译：分离均相催化剂的方法
公开(公告)号：US20070034576A1
公开(公告)日：2007-02-15
申请号：US10561613
申请日：2004-06-11
申请人： Wolfram Stuer , Jens Scheidel , Hartwig Voss , Peter Bassler , Michael Roper
发明人： Wolfram Stuer , Jens Scheidel , Hartwig Voss , Peter Bassler , Michael Roper
IPC分类号： B01D61/00
CPC分类号： C07F15/0073 , C07F15/008
摘要： A process for separating a mixture comprising a) a monoolefinically unsaturated compound which is obtainable by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, or a saturated compound obtained by hydrogenating such a compound, b) a compound which is obtainable by adding more than two of the terminal olefins mentioned in a) or a compound obtained by hydrogenating such a compound, and c) a compound which contains a transition metal, is homogeneous with respect to the mixture and is suitable as a catalyst for preparing a monoolefinically unsaturated compound by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, by means of a semipermeable membrane to obtain a permeate and a retentate in such a way that the weight ratio of component b) to component c) in the mixture fed to the semipermeable membrane is smaller than in the retentate.
摘要翻译：一种分离混合物的方法，该混合物包含a）单烯属不饱和化合物，其可以通过加入含有制备含有至少两个官能团的单烯属不饱和化合物所需的官能团的二末端烯烃，或通过氢化这种化合物获得的饱和化合物 b）通过添加a）中所述的两种以上的末端烯烃或通过氢化这种化合物得到的化合物得到的化合物，和c）含有过渡金属的化合物相对于混合物是均匀的，通过加入具有制备含有至少两个官能团的单烯属不饱和化合物所需的官能团的二末端烯烃，通过半透膜以制备单烯属不饱和化合物，以获得渗透物和渗余物组分b）与组分c）的重量比在mi中的方式进料到半透膜的切口小于滞留物中的孔。

17. 发明申请

US20060167308A1 Process for the preparation of alkylarylsulfonates 审中-公开
标题翻译：烷基芳基磺酸盐的制备方法
公开(公告)号：US20060167308A1
公开(公告)日：2006-07-27
申请号：US11385773
申请日：2006-03-22
申请人： Heiko Maas , Thomas Narbeshuber , Michael Roper
发明人： Heiko Maas , Thomas Narbeshuber , Michael Roper
IPC分类号： C07C309/00
CPC分类号： C07C303/32 , C07C2/08 , C07C2/66 , C07C6/04 , C07C303/06 , C11D1/22 , C11D11/04 , C07C309/31 , C07C11/02 , C07C11/10 , C07C11/107 , C07C15/107
摘要： The invention relates to a process for the preparation of alkylarylsulfonates by a) reaction of a C4-olefin mixture over a metathesis catalyst for the preparation of an olefin mixture comprising 2-pentene and/or 3-hexene, and optional removal of 2-pentene and/or 3-hexene, b) dimerization of the 2-pentene and/or 3-hexene obtained in stage a) over a dimerization catalyst to give a mixture containing C10-12-olefins, and optional removal of the C10-12-olefins, c) reaction of the C10-12-olefin mixtures obtained in stage b) with an aromatic hydrocarbon in the presence of an alkylating catalyst to form alkylaromatic compounds, where, prior to the reaction, additional linear olefins may be added, d) sulfonation of the alkylaromatic compounds obtained in stage c), and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, linear alkylbenzenes may additionally be added, e) optional mixing of the alkylarylsulfonates obtained in stage d) with linear alkylarylsulfonates.
摘要翻译：本发明涉及一种通过以下步骤制备烷基芳基磺酸盐的方法：a）在复分解催化剂上反应C 4/4烯烃混合物，用于制备包含2-戊烯和/或3-己烯的烯烃混合物并且任选地除去2-戊烯和/或3-己烯，b）在二级催化剂中在阶段a）中获得的2-戊烯和/或3-己烯的二聚化，得到含有C 10-12 并且任选地除去C 10-12 - 烯烃，c）在步骤b）中获得的C 10-12α-烯烃混合物的反应，在烷基化催化剂存在下用芳族烃形成烷基芳族化合物，其中在反应之前可以加入另外的直链烯烃，d）在步骤c）中获得的烷基芳族化合物的磺化，并中和得到烷基芳基磺酸盐，其中在磺化之前，可以另外加入直链烷基苯，e）任选地将在sta中获得的烷基芳基磺酸盐 ge d）与直链烷基芳基磺酸盐。

18. 发明申请

US20060014988A1 Method for the production of 1,6-hexanediol 失效
标题翻译： 1,6-己二醇生产方法
公开(公告)号：US20060014988A1
公开(公告)日：2006-01-19
申请号：US10537829
申请日：2003-12-03
申请人： Rolf-Hartmuth Fischer , Thomas Krug , Andrea Haunert , Michael Roper , Tilman Sirch , Wolfram Stuer
发明人： Rolf-Hartmuth Fischer , Thomas Krug , Andrea Haunert , Michael Roper , Tilman Sirch , Wolfram Stuer
IPC分类号： C07C35/08
CPC分类号： C07C29/177 , C07C31/20
摘要： The present invention provides a process for preparing 1,6-hexanediol having a purity of ≧99.5% by weight by catalytically dimerizing acrylic esters and catalytically hydrogenating the hexenedioic diesters obtained in this way to 1,6-hexanediol by a) dimerizing C1- to C8-acrylic esters in the presence of at least one rhodium compound to give mixtures of predominantly 2- and 3-hexenedioic diesters, b) hydrogenating the resulting dimerizing effluent in the presence of chromium-free catalysts comprising predominantly copper as the hydrogenation component and c) purifying the crude 1,6-hexanediol obtained in this way by fractional distillation.
摘要翻译：本发明提供了一种通过催化二聚丙烯酸酯制备纯度> 99.5％（重量）的1,6-己二醇的方法，并将以这种方式获得的己二酸二酯催化氢化，在至少一种铑化合物的存在下加入到C 8 - 丙烯酸酯中，得到主要为2-和3-己烯二酸二酯的混合物，b）将得到的二聚流出物在主要含有铜作为氢化组分的无铬催化剂的存在下，和c）通过分馏纯化以这种方式得到的粗制1,6-己二醇。

19. 发明授权

US6166265A Processes for the preparation of n-butyraldehyde, n-butanol and mixtures thereof 失效
标题翻译：制备正丁醛，正丁醇及其混合物的方法
公开(公告)号：US6166265A
公开(公告)日：2000-12-26
申请号：US381452
申请日：1999-09-15
申请人： Jurgen Kanand , Rocco Paciello , Michael Roper
发明人： Jurgen Kanand , Rocco Paciello , Michael Roper
IPC分类号： C07C27/06 , C07B61/00 , C07C29/132 , C07C31/12 , C07C41/06 , C07C41/32 , C07C41/54 , C07C45/51 , C07C47/02
CPC分类号： C07C29/132 , C07C41/06 , C07C41/32 , C07C41/54 , C07C45/515 , C07C31/12 , C07C47/02 , C07C43/15 , C07C43/303
摘要： Process for the preparation of n-butyraldehyde and/or n-butanol, whereina) 1,3-Butadiene or a butadiene-containing hydrocarbon mixture is reacted with an alcohol of the formula IROH I, where R is C.sub.2 -C.sub.20 -alkyl or alkenyl which is unsubstituted or substituted by 1 or 2 C.sub.1 -C.sub.10 -alkoxy or hydroxyl groups, or is C.sub.6 -C.sub.10 -aryl, C.sub.7 -C.sub.11 -aralkyl or methyl, at elevated temperatures and superatmospheric pressure in the presence of a Bronsted acid or in the presence of a complex of an element of Group Ia, VIIA or VIIIA of the Periodic Table of Elements with phosphorus- or nitrogen-containing ligands to give a mixture of the adducts of the formulae II ##STR1## and III ##STR2## b) the adduct III is isomerized to the adduct II, c) the adduct II is converted into the acetal of the formula IV ##STR3## d) n-butyraldehyde and/or n-butanol are then produced from this acetal IV by reacting it, in the liquid phase, with hydrogen and water or water in the presence of a homogeneous or heterogeneous transition metal catalyst which differs from dicobaltoctacarbonyl or hydridocobalttetracarbonyl.
摘要翻译： PCT No.PCT / EP98 / 01324 Sec。 371日期1999年9月15日 102（e）1999年9月15日PCT 1998年3月6日PCT PCT。第WO98 / 41494号公报日期1998年9月24日制备正丁醛和/或正丁醇的方法，其中a）1,3-丁二烯或含丁二烯的烃混合物与式IROHI的醇反应，其中R是C2- C 1 -C 10 - 芳基，C 7 -C 11 - 芳烷基或甲基未被取代或被1或2个C 1 -C 10 - 烷氧基或羟基取代的C 1 -C 20 - 烷基或烯基，在高温和超大气压的存在下， Br + E，uml + EE ed ed ed ed ed acid acid the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the 式II和III b）加合物III异构化为加合物II，c）加合物II转化为式IV的缩醛d）然后由该缩醛IV由该缩醛IV制备正丁醛和/或正丁醇，通过使在液相中，在均相或不均匀转变的存在下，用氢和水或水进行反应金属催化剂不同于二羰基羰基或氢化钴四羰基。

20. 发明授权

US5919987A Preparation of alcohols and/or aldehydes 失效
标题翻译：醇和/或醛的制备
公开(公告)号：US5919987A
公开(公告)日：1999-07-06
申请号：US716216
申请日：1996-09-13
申请人： Heinz-Josef Kneuper , Maik Aron , Frank-Michael Korgitzsch , Michael Nilles , Wolfgang Harder , Michael Roper , Rocco Paciello
发明人： Heinz-Josef Kneuper , Maik Aron , Frank-Michael Korgitzsch , Michael Nilles , Wolfgang Harder , Michael Roper , Rocco Paciello
IPC分类号： B01J23/46 , B01J31/40 , C07B61/00 , C07C27/22 , C07C29/141 , C07C29/16 , C07C31/02 , C07C45/50 , C07C45/80 , C07C47/02 , C07C51/235 , C07C209/00 , C07C45/00
CPC分类号： B01J31/20 , B01J31/4046 , C07C209/00 , C07C29/141 , C07C29/16 , C07C45/50 , C07C45/80 , C07C51/235 , B01J2231/321 , B01J23/464 , B01J2531/822 , B01J31/181 , B01J31/1815 , B01J31/1825 , B01J31/183 , Y02P20/584
摘要： An industrial preparation of aldehydes and/or alcohols from olefins of more than 3 carbon atoms by a catalytic hydroformylation of the olefin reactant at a pressure of from 50 to 1000 bar and a temperature of from 50 to 180.degree. C. in the presence of an uncomplexed rhodium catalyst homogeneously dissolved in the reaction medium. The catalytic activity of the rhodium is maintained, first by extracting it from the initially discharged reaction mixture by means of an aqueous solution of a nitrogen-containing complexing agent such as sulfonated or carboxylated pyridines, quinolines or the like. In a recycle of the complexed rhodium to be reused in the hydroformylation reaction, the aqueous rhodium-containing extract is fed to a precarbonylation stage where it subjected to a required precarbonylation in the presence of an essentially water-insoluble organic liquid and in the presence of carbon monoxide, synthesis gas or another gas mixture containing carbon monoxide at from 50 to 1000 bar and from 50 to 180.degree. C. The mixture discharged from this precarbonylation stage is then separated into an organic phase containing the main part of the rhodium and an aqueous phase containing the complexing agent. The resulting rhodium-containing organic phase with the regenerated catalyst is then fed into the hydroformylation stage to complete its recycle.
摘要翻译： PCT No.PCT / EP95 / 00825 Sec。 371日期1996年9月13日 102（e）日期1996年9月13日PCT 1995年3月6日PCT公布。 WO95 / 25080 PCT公开日期1995年9月21日通过在50至1000巴的压力和50至180℃的温度下通过烯烃反应物的催化加氢甲酰化来工业制备大于3个碳原子的烯烃的醛和/或醇。在均匀溶解在反应介质中的未络合的铑催化剂存在下进行。保持铑的催化活性，首先通过含氮络合剂如磺化或羧化吡啶，喹啉等的水溶液从最初排出的反应混合物中提取铑的催化活性。在加氢甲酰化反应中重复使用的复合铑的再循环中，含水铑萃取物进料到预羰化阶段，其中在基本上不溶于水的有机液体存在下进行所需的预羰基化，一氧化碳，合成气或含有一氧化碳的另一种气体混合物，从50至1000巴和50至180℃。然后将从该预羰化阶段排出的混合物分离成含有主要部分铑的有机相，相含有络合剂。然后将所得到的含再生催化剂的含铑有机相进料到加氢甲酰化阶段以完成其再循环。

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