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    • 9. 发明申请
    • NOVEL ALICYCLIC ALCOHOL
    • 新的ALICYCLIC酒精
    • US20130338403A1
    • 2013-12-19
    • US13977274
    • 2011-12-27
    • Mitsuharu KitamuraYoshiharu AtakaKazuyuki Fukuda
    • Mitsuharu KitamuraYoshiharu AtakaKazuyuki Fukuda
    • C07C35/08C07C29/149
    • C07C35/08C07C29/149C07C31/1355C07C51/58C07C67/14C07C2601/14C11B9/0034C07C61/08C07C69/75
    • Provided is an alicyclic alcohol compound which can be used as a raw material for a compound perfume, and which has excellent floral-green-like aromas which are crisp and fresh; also provided are a manufacturing method for the same, and a perfume composition which contains the alicyclic alcohol compound. An alicyclic alcohol compound having a specified structure represented by chemical formula (1) has excellent floral-green-like aromas which are crisp and fresh; and a method for manufacturing the alicyclic alcohol compound represented by chemical formula (1) by reacting, in the presence of hydrogen fluoride, 1-isopropyl-4-methylcyclohexene and carbon monoxide, reacting the resulting 4-isopropyl-1-methylcyclohexane carboxylic acid fluoride with alcohol, and, after having acquired a cyclohexane carbonyl compound, reducing the cyclohexane carbonyl compound.
    • 提供可用作复合香料的原料的脂环族醇化合物,其具有优良的鲜绿色的花绿色香气, 还提供了其制备方法和含有脂环族醇化合物的香料组合物。 由化学式(1)表示的具有特定结构的脂环族醇化合物具有优异的花绿色香气,其清爽新鲜; 以及在氟化氢,1-异丙基-4-甲基环己烯和一氧化碳的存在下使化学式(1)表示的脂环族醇化合物的制造方法,使得到的4-异丙基-1-甲基环己烷羧酸氟化物 与醇反应后,在获得环己烷羰基化合物后,还原环己烷羰基化合物。
    • 10. 发明授权
    • Aluminum complex and use thereof
    • 铝复合物及其用途
    • US08329930B2
    • 2012-12-11
    • US12991967
    • 2009-05-25
    • Hisanori ItohYoji Hori
    • Hisanori ItohYoji Hori
    • C07F5/06C07C35/08
    • C07C39/235C07B53/00C07B2200/07C07C29/56C07C45/67C07C2601/14C07F5/069C07C35/17C07C47/21
    • Provided is a process in which cyclization of a compound having, in a molecule, a formyl group and a double bond which allow carbonyl-ene cyclization, the compound existing as a mixture of optical isomers thereof, increases the ratio of a particular optical isomer not only in a cyclized compound, but also in an unreacted compound. The process comprises performing, in the presence of a specified aluminum complex represented by the general formula: [Al2(L1)n(L2)3-n]m, cyclization of a compound having, in a molecule, a formyl group and a double bond which allow carbonyl-ene cyclization, the compound existing as a mixture of optical isomers thereof, to increase the ratio of a particular optical isomer.
    • 提供一种方法,其中在分子中使具有允许羰基环环化的甲酰基和双键的化合物作为其光学异构体的混合物存在的化合物的环化增加了特定光学异构体的比例 仅在环化化合物中,而且在未反应的化合物中。 该方法包括在由通式[Al2(L1)n(L2)3-n] m表示的规定的铝络合物的存在下进行,分子中具有甲酰基和双 允许羰基环环化的键,作为其光学异构体的混合物存在的化合物,以增加特定光学异构体的比例。