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1. 发明授权

US5705707A Preparation of n-butyraldehyde and/or n-butanol 失效
标题翻译：正丁醛和/或正丁醇的制备
公开(公告)号：US5705707A
公开(公告)日：1998-01-06
申请号：US676185
申请日：1996-07-12
申请人： Jurgen Kanand , Michael Roper , Rolf Pinkos , Rocco Paciello , Alfred Thome
发明人： Jurgen Kanand , Michael Roper , Rolf Pinkos , Rocco Paciello , Alfred Thome
IPC分类号： B01J21/16 , B01J27/18 , B01J29/06 , C07B61/00 , C07C27/00 , C07C29/17 , C07C31/12 , C07C41/06 , C07C41/32 , C07C43/15 , C07C45/51 , C07C47/02 , C07C47/52
CPC分类号： C07C41/32 , C07C29/172 , C07C41/06 , C07C45/513
摘要： A process for the preparation of n-butyraldehyde and/or n-butanol, wherein a) 1,3-butadiene is caused to react with an alcohol of the formula I ROH I, to form a mixture of adducts of the formulas II ##STR1## and III ##STR2## b) the adduct III is isomerized to the adduct II, c) the adduct II is isomerized in the presence of a homogeneous or heterogeneous transition metal element catalyst to form the enol ether of the formula IV ##STR3## and d) n-butyraldehyde and/or n-butanol is/are produced from this ether IV by the reaction thereof with hydrogen and water or water only in the presence of a homogeneous or heterogeneous catalyst.
摘要翻译： PCT No.PCT / EP94 / 00114 Sec。 371日期：1996年7月12日 102（e）日期1996年7月12日PCT提交1995年1月12日PCT公布。公开号WO95 / 19334 日期1995年7月20日一种用于制备正丁醛和/或正丁醇的方法，其中使a）1,3-丁二烯与式IROHI的醇反应，形成下式的加合物的混合物 II）III和III IIIa）b）加合物III异构化为加合物II，c）加合物II在均相或不均匀的过渡金属元素催化剂的存在下异构化以形成式 IV和d）只有在均相或多相催化剂的存在下，通过与氢和水或水的反应，由该醚IV产生正丁醛和/或正丁醇。

2. 发明授权

US5892125A Preparation of n-butyraldehyde and/or n-butanol 失效
标题翻译：正丁醛和/或正丁醇的制备
公开(公告)号：US5892125A
公开(公告)日：1999-04-06
申请号：US793480
申请日：1997-07-23
申请人： Jurgen Kanand , Michael Roper , Rocco Paciello , Alfred Thome
发明人： Jurgen Kanand , Michael Roper , Rocco Paciello , Alfred Thome
IPC分类号： C07C27/00 , C07B61/00 , C07C29/00 , C07C29/09 , C07C29/17 , C07C31/12 , C07C45/51 , C07C45/56 , C07C47/02 , C07D295/023
CPC分类号： C07D295/023 , C07C29/00 , C07C45/516 , C07C45/56 , C07C45/562
摘要： A process for the preparation of n-butyraldehyde and/or n-butanol, in whicha) 1,3-butadiene is caused to react with an amine of the formula IR.sup.1 R.sup.2 NH, I in which R.sup.1 and R.sup.2 independently denote hydrogen, optionally substituted aliphatic or cycloaliphatic radicals, or aryl or aralkyl radicals or are linked to form a bridging member which can contain hetero atoms, at elevated temperature and under superatmospheric pressure in the presence of a compound of a Group VIIIb element and in the presence of an alkali metal amide or a basic metal oxide to form a mixture of the adducts of the formulas II ##STR1## and III ##STR2## b) the adduct III is isomerized to the adduct II, c) the adduct II is isomerized in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous catalyst containing a transition metal element in the gaseous phase to form the enamine of the formula IV ##STR3## and d) n-butyraldehyde and/or n-butanol is/are produced from this enamine.
摘要翻译： PCT No.PCT / EP95 / 03358 Sec。 371日期1997年7月23日 102（e）日期1997年7月23日PCT 1995年8月24日PCT PCT。出版物WO96 / 07630 日期：1996年3月14日制备正丁醛和/或正丁醇的方法，其中a）使1,3-丁二烯与式ⅠR1R2NH，Ⅰ的胺反应，其中R1和R2独立地为表示氢，任选取代的脂族或脂环族基团，或芳基或芳烷基，或连接形成可含有杂原子的桥连构件，在高温和超大气压下，在VIIIb族元素的化合物存在下，存在碱金属酰胺或碱性金属氧化物以形成式II II和III III的加合物的混合物b）加合物III异构化为加合物II，c）加合物II为在均相或非均相过渡金属元素催化剂存在下在液相中或在气相中含有过渡金属元素的多相催化剂存在下异构化，形成式IV的烯胺IV和d）n -但从该烯胺产生乙醛和/或正丁醇。

3. 发明申请

US20130183222A1 PROCESS FOR WORKING UP AN EXHAUST GAS FROM A SYSTEM FOR PRODUCING HYDROXYLAMINE OR HYDROXYLAMMONNIUM SALTS 失效
标题翻译：从用于生产羟基胺或羟基磺酸钠盐的系统中除去排气的方法
公开(公告)号：US20130183222A1
公开(公告)日：2013-07-18
申请号：US13876496
申请日：2011-09-27
申请人： Arnd Garsuch , Alexander Panchenko , Sigmar Bräuninger , Jens Scheidel , Alfred Thome
发明人： Arnd Garsuch , Alexander Panchenko , Sigmar Bräuninger , Jens Scheidel , Alfred Thome
IPC分类号： B01D53/46
CPC分类号： B01D53/46 , B01D53/229 , B01D53/326 , B01D69/148 , B01D71/024 , B01D71/32 , B01D71/52 , B01D71/62 , B01D71/82 , B01D2257/108 , B01D2313/345 , C01B3/501 , C01B3/503 , C01B21/1418 , C01B2203/0405 , C01B2203/041 , C01B2203/0465 , H01M8/086 , H01M8/1023 , H01M8/1025 , H01M8/106 , H01M8/1246 , Y02E60/525 , Y02P70/56
摘要： A process for working up an exhaust gas A from a system for producing hydroxylamine or hydroxylammonium salts by catalytic reduction of nitrogen monoxide with hydrogen, wherein the exhaust gas A comprises nitrogen monoxide, hydrogen, dinitrogen monoxide, nitrogen and ammonia, and at least some of the hydrogen present in the exhaust gas A is separated off from the exhaust gas A by means of a gas-tight membrane-electrode assembly which comprises at least one selectively proton-conducting membrane, a retentate side, a permeate side, and, on each side of the membrane, at least one electrode catalyst, wherein, on the retentate side of the membrane, at least some of the hydrogen is oxidized to protons at the anode catalyst and the protons, after crossing the membrane, are, on the permeate side, at the cathode catalyst according to I reduced to hydrogen and/or II reacted with oxygen to form water, wherein the oxygen originates from an oxygen-comprising stream O which is contacted with the permeate side.
摘要翻译：用于通过用氢气一氧化氮催化还原一种一氧化氮，从用于生产羟胺或羟基铵盐的系统中处理废气A的方法，其中废气A包括一氧化氮，氢气，一氧化二氮，氮气和氨，以及至少一些废气A中存在的氢气通过气密膜电极组件与废气A分离，该气密膜电极组件包括至少一个选择性质子传导膜，滞留物侧，渗透侧，并且每个至少一个电极催化剂，其中在膜的截留侧上，至少一些氢被氧化成在阳极催化剂和质子之间的质子，在穿过膜之后，在渗透侧在根据I的阴极催化剂被还原为氢和/或II与氧反应形成水时，其中氧源自含氧物流O，其与第身材瘦削

4. 发明授权

US08894960B2 Process for removing NO and N2O from gas mixtures 有权
标题翻译：从气体混合物中除去NO和N2O的工艺
公开(公告)号：US08894960B2
公开(公告)日：2014-11-25
申请号：US12517495
申请日：2007-11-30
申请人： Carsten Oost , Wolfgang Rohde , Christian Miller , Manfred Stroezel , Alfred Thome , Wilfried Berning
发明人： Carsten Oost , Wolfgang Rohde , Christian Miller , Manfred Stroezel , Alfred Thome , Wilfried Berning
IPC分类号： C01C3/08 , C01B21/00 , C01B21/20 , B01D53/86 , C01B21/24 , C01B21/14 , B01D53/77
CPC分类号： C01B21/1418 , B01D53/77 , B01D53/86 , B01D53/8625 , B01D2251/202 , B01D2255/1021 , B01D2255/1023 , B01D2255/104 , B01D2255/20761 , B01D2257/402 , B01D2257/404 , B01D2259/40 , C01B21/24 , Y02C20/10 , Y02P20/153
摘要： A process is proposed for reprocessing the exhaust gas from a plant for producing hydroxylamine or hydroxylammonium salts by catalytic reduction of nitrogen monoxide with hydrogen for the purpose of utilization of at least a part of the nitrogen monoxide and if appropriate hydrogen present in the exhaust gas for producing hydroxylamine or hydroxylammonium salts, which comprises, in a first separation stage, selectively separating off nitrogen monoxide from the exhaust gas of the plant for producing hydroxylamine or hydroxylammonium salts.
摘要翻译：提出了一种用于通过用氢气一氧化氮催化还原一氧化氮以生产羟胺或羟基铵盐的废气再处理方法，以利用至少一部分一氧化氮，如果废气中存在适当的氢气，则产生羟胺或羟铵盐，其在第一分离阶段包括选择性地将一氧化氮与用于生产羟胺或羟铵盐的设备的废气分离出来。

5. 发明授权

US08679436B2 Process for working up an exhaust gas from a system for producing hydroxylamine or hydroxylammonium salts 失效
标题翻译：从用于生产羟胺或羟铵盐的系统处理废气的方法
公开(公告)号：US08679436B2
公开(公告)日：2014-03-25
申请号：US13876496
申请日：2011-09-27
申请人： Arnd Garsuch , Alexander Panchenko , Sigmar Bräuninger , Jens Scheidel , Alfred Thome
发明人： Arnd Garsuch , Alexander Panchenko , Sigmar Bräuninger , Jens Scheidel , Alfred Thome
IPC分类号： B01D53/34 , B01D53/46 , C07C215/00
CPC分类号： B01D53/46 , B01D53/229 , B01D53/326 , B01D69/148 , B01D71/024 , B01D71/32 , B01D71/52 , B01D71/62 , B01D71/82 , B01D2257/108 , B01D2313/345 , C01B3/501 , C01B3/503 , C01B21/1418 , C01B2203/0405 , C01B2203/041 , C01B2203/0465 , H01M8/086 , H01M8/1023 , H01M8/1025 , H01M8/106 , H01M8/1246 , Y02E60/525 , Y02P70/56
摘要： Process for working up an exhaust gas from a system for producing hydroxylamine or hydroxylammonium salts by catalytic reduction of nitrogen monoxide with hydrogen, the exhaust gas containing nitrogen monoxide, hydrogen, dinitrogen monoxide, nitrogen and ammonia. At least some of the hydrogen present in the exhaust gas is separated off from the exhaust gas by means of a gas-tight membrane-electrode assembly which comprises at least one selectively proton-conducting membrane, a retentate side, a permeate side, and, on each side of the membrane, at least one electrode catalyst, wherein, on the retentate side of the membrane, at least some of the hydrogen is oxidized to protons at the anode catalyst and the protons, after crossing the membrane, are, on the permeate side, at the cathode catalyst according to (I) reduced to hydrogen and/or (II) reacted with oxygen to form water, the oxygen originating from an oxygen-containing stream which is contacted with the permeate side.
摘要翻译：通过用氢气还原一氧化氮，含有一氧化氮，氢气，一氧化二氮，氮气和氨的废气来处理来自用于生产羟胺或羟铵盐的系统的排气的方法。存在于废气中的至少一部分氢气通过气密膜电极组件与废气分离，所述气 - 气膜 - 电极组件包括至少一个选择性质子传导膜，滞留物侧，渗透侧，在膜的每一侧上，至少一个电极催化剂，其中在膜的截留侧上，至少一些氢被氧化成在阳极催化剂和质子之间的质子，在穿过膜之后，在渗透侧，根据（I）的阴极催化剂还原为氢和/或（II）与氧反应形成水，所述氧来源于与渗透侧接触的含氧流。

6. 发明授权

US5349097A Catalytic isomerization of .alpha.-alkenols 失效
标题翻译： α-烯醇的催化异构化
公开(公告)号：US5349097A
公开(公告)日：1994-09-20
申请号：US99236
申请日：1993-07-29
申请人： Alfred Thome , Michael Roeper , Heinz-Josef Kneuper
发明人： Alfred Thome , Michael Roeper , Heinz-Josef Kneuper
IPC分类号： C07C29/56 , C07C33/02 , C07C35/17
CPC分类号： C07C29/56
摘要： A process for the catalytic isomerization of secondary .alpha.-alkenols of formula I ##STR1## in which R.sup.1 is a C.sub.1 -C.sub.20 alkyl group or a C.sub.2 -C.sub.2 alkenyl group and in which R.sup.2 stands for hydrogen, a halogen atom, a C.sub.1 -C.sub.10 alkoxy group, a carbonyl group, or a C.sub.1 -C.sub.20 alkyl group and in which R.sup.1 and R.sup.2 can be joined together to complete a five-membered or six-membered carbocyclic ring, to primary .alpha.-alkenols of formula II ##STR2## or for the isomerization of primary .alpha.-alkenols of formula II to secondary .alpha.-alkenols of formula I, wherein the isomerization is carried out in the presence of organotrioxorhenium(VII) compounds of formula III ##STR3## in which R.sup.3 is a C.sub.1 -C.sub.10 alkyl group, a cyclopentadienyl group substituted by from one to five C.sub.1 -C.sub.4 alkyl groups, an unsubstituted cyclopentadienyl group, a C.sub.6 -C.sub.10 aryl group, or a C.sub.7 -C.sub.11 aralkyl group, or wherein the isomerization is carried out in the presence of organotrioxorhenium(VII) compounds of formula III attached to a polymeric support.
摘要翻译：一种式Ⅰ的仲α-烯醇的催化异构化方法，其中R1是C1-C20烷基或C2-C2链烯基，其中R2代表氢，卤素原子， C 1 -C 10烷氧基，羰基或C 1 -C 20烷基，并且其中R 1和R 2可以连接在一起以完成五元或六元碳环，与式II的α-α-烯醇（II）化合物或式II的仲α-烯醇的异构化转化为式I的仲α-烯醇，其中异构化在式III的有机三氧化铼（VII）化合物（III）的存在下进行，其中其中R 3为C 1 -C 10烷基，被1至5个C 1 -C 4烷基取代的环戊二烯基，未取代的环戊二烯基，C 6 -C 10芳基或C 7 -C 11芳烷基，或其中异构化为在连接到a的式III的有机三氧化钌（VII）化合物的存在下进行聚合物支持。

7. 发明申请

US20100143226A1 PROCESS FOR REMOVING NO AND N2O FROM GAS MIXTURES 有权
标题翻译：从气体混合物中除去NO和N2O的方法
公开(公告)号：US20100143226A1
公开(公告)日：2010-06-10
申请号：US12517495
申请日：2007-11-30
申请人： Carsten Oost , Wolfgang Rohde , Christian Miller , Manfred Stroezel , Alfred Thome , Wilfried Berning
发明人： Carsten Oost , Wolfgang Rohde , Christian Miller , Manfred Stroezel , Alfred Thome , Wilfried Berning
IPC分类号： B01D53/56 , C01C1/28 , C01B21/087
CPC分类号： C01B21/1418 , B01D53/77 , B01D53/86 , B01D53/8625 , B01D2251/202 , B01D2255/1021 , B01D2255/1023 , B01D2255/104 , B01D2255/20761 , B01D2257/402 , B01D2257/404 , B01D2259/40 , C01B21/24 , Y02C20/10 , Y02P20/153
摘要： A process is proposed for reprocessing the exhaust gas from a plant for producing hydroxylamine or hydroxylammonium salts by catalytic reduction of nitrogen monoxide with hydrogen for the purpose of utilization of at least a part of the nitrogen monoxide and if appropriate hydrogen present in the exhaust gas for producing hydroxylamine or hydroxylammonium salts, which comprises, in a first separation stage, selectively separating off nitrogen monoxide from the exhaust gas of the plant for producing hydroxylamine or hydroxylammonium salts.
摘要翻译：提出了一种用于通过用氢气一氧化氮催化还原一氧化氮以生产羟胺或羟基铵盐的废气再处理方法，以利用至少一部分一氧化氮，如果废气中存在适当的氢气，则产生羟胺或羟铵盐，其在第一分离阶段包括选择性地将一氧化氮与用于生产羟胺或羟铵盐的设备的废气分离出来。

8. 发明授权

US6083468A Method of manufacturing a hydrogenation catalyst 失效
标题翻译：制造氢化催化剂的方法
公开(公告)号：US6083468A
公开(公告)日：2000-07-04
申请号：US155908
申请日：1998-10-08
申请人： Daniel Heineke , Gunther Achhammer , Heinz-Walter Schneider , Alfred Thome
发明人： Daniel Heineke , Gunther Achhammer , Heinz-Walter Schneider , Alfred Thome
IPC分类号： B01J23/42 , B01J37/20 , C01B21/14 , C01C1/00
CPC分类号： B01J23/42 , C01B21/1418
摘要： A hydrogenation catalyst is prepared by reduction of platinum in an oxidation state of not less than two using a reducing agent in an aqueous medium in the presence of a carbon-containing support after partial poisoning, where use is made of a compound of the general formula I ##STR1## where X, Y and Z can be identical or different and are hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.10 -cycloalkyl, halogen, hydroxyl, C.sub.1 -C.sub.6 -alkoxy and --NR'R", where R, R' and R" can be identical or different and can be hydrogen, C.sub.1 -C.sub.18 -alkyl or C.sub.5 -C.sub.10 -cycloalkyl. Such a hydrogenation catalyst can be used for preparing hydroxylammonium salts and the process for preparing the above catalysts can also be used for regenerating hydrogenation catalysts based on platinum.
摘要翻译： PCT No.PCT / EP97 / 01617 Sec。 371日期：1998年10月8日 102（e）日期1998年10月8日PCT 1997年4月1日PCT PCT。出版物WO97 / 37758 日期：1997年10月16日氢化催化剂是通过在部分中毒后在含碳载体存在下，在水性介质中使用还原剂还原不少于2的铂的氢化催化剂，其中使用其中X，Y和Z可以相同或不同，为氢，C 1 -C 18 - 烷基，C 5 -C 10 - 环烷基，卤素，羟基，C 1 -C 6 - 烷氧基和-NR'R“的通式I化合物，其中R，R'和R“可以相同或不同，并且可以是氢，C 1 -C 18 - 烷基或C 5 -C 10 - 环烷基。这种氢化催化剂可用于制备羟铵盐，并且制备上述催化剂的方法也可用于再生基于铂的氢化催化剂。

9. 发明授权

US5882619A Preparation of a hydrogenation catalyst using M(OR).sub.m X.sub.n 失效
标题翻译：使用M（OR）mXn制备氢化催化剂
公开(公告)号：US5882619A
公开(公告)日：1999-03-16
申请号：US756477
申请日：1996-11-26
申请人： Daniel Heineke , Karsten Eller , Heinz-Walter Schneider , Alfred Thome
发明人： Daniel Heineke , Karsten Eller , Heinz-Walter Schneider , Alfred Thome
IPC分类号： C01B21/14 , B01J21/18 , B01J23/42 , B01J27/08 , B01J31/30 , B01J31/40 , B01J35/10 , B01J37/04 , C07B61/00 , C07F7/00 , C07F7/28 , C01B21/20 , B01J20/34
CPC分类号： B01J31/30 , B01J21/18 , B01J23/42 , B01J27/08 , B01J31/0212 , B01J31/1616 , B01J31/4038 , B01J2231/641
摘要： A carbon-containing catalyst support is prepared by treating the carbon-containing catalyst support with a compound of the formula IM(OR).sub.m X.sub.n Iwhere M is Ti or Zr, X is Cl or Br, and R is C.sub.1 -C.sub.20 -alkyl, and m and n are integers from zero to four, where the sum of m and n is equal to four.
摘要翻译：通过用式IM（OR）mXn I的化合物处理含碳催化剂载体来制备含碳催化剂载体，其中M为Ti或Zr，X为Cl或Br，R为C1-C20烷基，并且m和n是从零到四的整数，其中m和n之和等于4。

10. 发明授权

US5043487A Preparation of octadienols 失效
标题翻译：辛二烯醇的制备
公开(公告)号：US5043487A
公开(公告)日：1991-08-27
申请号：US547813
申请日：1990-07-02
申请人： Alfred Thome , Werner Bertleff
发明人： Alfred Thome , Werner Bertleff
IPC分类号： B01J31/24 , C07B61/00 , C07C29/36 , C07C33/02
CPC分类号： C07C29/36
摘要： Octadienols are prepared by reacting 1,3-butadiene with water in the presence of a catalyst system comprising a palladium compound, a triorganophosphorus compound and carbon dioxide and in the additional presence of a triorganophosphine oxide.
摘要翻译：在包含钯化合物，三有机磷化合物和二氧化碳的催化剂体系的存在下，以及另外存在三有机膦氧化物的情况下，通过使1,3-丁二烯与水反应制备辛二烯醇。

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