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1. 发明授权

US08383866B2 Process for preparing diols by hydrogenating a carboxylic acid-comprising mixture by means of cobalt-comprising catalysts 失效
标题翻译：通过使含钴催化剂氢化含羧酸的混合物来制备二醇的方法
公开(公告)号：US08383866B2
公开(公告)日：2013-02-26
申请号：US12953004
申请日：2010-11-23
申请人： Rolf Pinkos , Axel Paul , Rolf-Hartmuth Fischer , Roman Dostalek
发明人： Rolf Pinkos , Axel Paul , Rolf-Hartmuth Fischer , Roman Dostalek
IPC分类号： C07C29/156
CPC分类号： C07C29/149 , C07C31/20
摘要： The present invention relates to a process for preparing diols by hydrogenating a mixture comprising carboxylic acid, carboxylic anhydrides and/or carboxylic esters/lactones by means of a cobalt-comprising catalyst, wherein alkali metal and/or alkaline earth metal ions are added to the hydrogenation feed, excluding alkali metal and/or alkaline earth metal ions of mineral acids.
摘要翻译：本发明涉及通过使含钴催化剂氢化包含羧酸，羧酸酐和/或羧酸酯/内酯的混合物来制备二醇的方法，其中将碱金属和/或碱土金属离子加入到氢化进料，不含碱金属和/或无机酸的碱土金属离子。

2. 发明申请

US20120178948A1 PROCESS FOR THE HYDROGENATION OF 1,4-BUTYNEDIOL TO TETRAHYDROFURAN IN THE GAS PHASE 审中-公开
标题翻译： 1,4-丁二烯在气相中氢化四氢呋喃的方法
公开(公告)号：US20120178948A1
公开(公告)日：2012-07-12
申请号：US13346144
申请日：2012-01-09
申请人： Rolf PINKOS , Olga Osetska , Lucia Königsmann
发明人： Rolf PINKOS , Olga Osetska , Lucia Königsmann
IPC分类号： C07D307/08
CPC分类号： C07D307/08
摘要： The present invention relates to a process for the catalytic hydrogenation of 1,4-butynediol to tetrahydrofuran at at least the decomposition temperature of 1,4-butynediol, wherein 1,4-butynediol is vaporized in a hydrogen-comprising gas stream and is hydrogenated in gaseous form over at least one catalyst, comprising at least one of the elements from groups 7 to 11 of the Periodic Table of the Elements.
摘要翻译：本发明涉及在至少1,4-丁炔二醇的分解温度下将1,4-丁炔二醇催化氢化成四氢呋喃的方法，其中1,4-丁炔二醇在含氢气流中蒸发并氢化在至少一种催化剂上形成气态，其包含元素周期表第7-11族元素中的至少一种元素。

3. 发明申请

US20120059174A1 PROCESS FOR PREPARING EPSILON-CAPROLACTONE AND 1,6-HEXANEDIOL 审中-公开
标题翻译：制备EPSILON-CAPROLACTONE和1,6-HEXANEDIOL的方法
公开(公告)号：US20120059174A1
公开(公告)日：2012-03-08
申请号：US13226049
申请日：2011-09-06
申请人： Olivier ABILLARD , Daniel BREUNINGER , Eva KRETZSCHMAR , Rolf PINKOS
发明人： Olivier ABILLARD , Daniel BREUNINGER , Eva KRETZSCHMAR , Rolf PINKOS
IPC分类号： C07D313/04
CPC分类号： C07D313/04
摘要： The invention relates to processes for preparing 1,6-hexanediol and very pure ε-caprolactone from a dicarboxylic acid solution (DCS), comprising the steps of (a) esterification of the DCS with alcohols, (b) partial catalytic hydrogenation of the esters, (c) distillative removal of 1,6-hexanediol and low boilers as the top product, and (d) cyclization of the 6-hydroxycaproic ester present in the bottoms fraction in the presence of a higher-boiling alcohol than caprolactone.
摘要翻译：本发明涉及从二羧酸溶液（DCS）制备1,6-己二醇和非常纯的己内酯的方法，包括以下步骤：（a）将DCS与醇酯化，（b）部分催化氢化酯，（c）作为顶级产物的1,6-己二醇和低沸点的蒸馏除去，和（d）在高沸点醇存在下，在己内酯中存在底部馏分中的6-羟基己酸酯的环化。

4. 发明申请

US20110263907A1 PROCESS FOR PREPARING 1,6-HEXANEDIOL 审中-公开
公开(公告)号：US20110263907A1
公开(公告)日：2011-10-27
申请号：US13133006
申请日：2009-11-30
申请人： Olivier Abillard , Gerd-Dieter Tebben , Rolf Pinkos , Tobias Wabnitz
发明人： Olivier Abillard , Gerd-Dieter Tebben , Rolf Pinkos , Tobias Wabnitz
IPC分类号： C07C31/20
CPC分类号： C07C67/08 , C07C29/149 , C07D313/04 , C07C31/20 , C07C69/675 , C07C69/44
摘要： A process for preparing 1,6-hexanediol from a carboxylic acid mixture which comprises adipic acid, 6-hydroxycaproic acid and small amounts of 1,4-cyclohexanediols and is obtained as a by-product of the oxidation of cyclohexane to cyclohexanone/cyclohexanol with oxygen or oxygen-comprising gases by water extraction of the reaction mixture, by esterification and hydrogenation to hexanediol, which comprises a) the mono- and dicarboxylic acids present in the aqueous reaction mixture are reacted with a low molecular weight alcohol to give the corresponding carboxylic esters, b) the resulting esterification mixture is freed of excess alcohol and low boilers in a first distillation stage, c) in a second distillation stage, a separation is performed of the bottom product into an ester fraction essentially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, d) the ester fraction from (c) is catalytically hydrogenated and 1,6-hexanediol is obtained in a manner known per se by distilling the hydrogenation product, e) optionally the bottom product of stage c) is subjected to a further esterification reaction with a low molecular weight alcohol, the low molecular weight alcohol is distillatively removed on completion of the esterification reaction, then adipic diesters and 6-hydroxycaproic esters are substantially separated from 1,4-cyclohexanediols and high boilers in the remaining bottom stream by distillation and said adipic diesters and 6-hydroxycaproic esters are fed to stage c), which comprises performing at least one of the esterification reactions with a catalyst which comprises at least one element of groups 3-14, and adding a monomeric or oligomeric polyol with at least 3 hydroxyl functions after the esterification reaction. After step c) of the process according to the invention, in a third distillation stage, a stream comprising essentially methyl 6-hydroxycaproate can be at least partly removed and heated to temperatures above 200° C. under reduced pressure, which cyclizes 6-hydroxycaproic ester to caprolactone, and pure ε-caprolactone can be obtained from the cyclization product by distillation.

5. 发明申请

US20110224401A1 APPARATUS FOR SEPARATION BY DISTILLATION 审中-公开
标题翻译：通过蒸馏分离的装置
公开(公告)号：US20110224401A1
公开(公告)日：2011-09-15
申请号：US13131790
申请日：2009-11-29
申请人： Stefan Käshammer , Rolf Pinkos , Tobias Wabnitz , Rolf-Hartmuth Fischer
发明人： Stefan Käshammer , Rolf Pinkos , Tobias Wabnitz , Rolf-Hartmuth Fischer
IPC分类号： B01D3/14 , C08G65/20 , C08G63/00
CPC分类号： B01D1/065 , B01D1/22 , B01D3/06 , C08G65/20 , C08G65/30
摘要： The invention relates to an apparatus for separating a liquid substance mixture by distillation, a method for producing a tetrahydrofuran homopolymer and copolymer in which the oligomers in a liquid starting mixture containing oligomers are separated by distillation in such an apparatus, tetrahydrofuran homopolymers and copolymers which can be obtained using said method and have a narrow distribution of the relative molar mass, and the use thereof.
摘要翻译：本发明涉及一种通过蒸馏分离液体物质混合物的装置，四氢呋喃均聚物和共聚物的制备方法，其中含有低聚物的液体起始混合物中的低聚物在这种装置中通过蒸馏分离，四氢呋喃均聚物和共聚物可以使用所述方法获得并且具有相对摩尔质量的窄分布及其用途。

6. 发明申请

US20100240913A1 PROCESS FOR PREPARING EPSILON-CAPROLACTONE 有权
标题翻译：制备EPSILON-CAPROLACTONE的方法
公开(公告)号：US20100240913A1
公开(公告)日：2010-09-23
申请号：US12741383
申请日：2008-10-28
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C. Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C. Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
IPC分类号： C07D313/02
CPC分类号： C07D313/04
摘要： The present invention provides a process for preparing ε-caprolactone in a purity of more than 99% by cyclizing 6-hydroxycaproic esters in the liquid phase at from 150 to 400° C. and from 1 to 1020 hPa abs., and removing and condensing the compounds which are volatile under cyclization conditions, which comprises thermally treating the remaining bottom product of the cyclization in at least one further reactor, removing and condensing volatile compounds and obtaining ε-caprolactone by distillation from the condensates.
摘要翻译：本发明提供一种制备纯度大于99％的己内酯的方法，其通过在150至400℃和1至1020hPa绝对压力下使液相中的6-羟基己酸酯环化，冷凝在环化条件下挥发的化合物，其包括在至少一个另外的反应器中热处理剩余的环化的底部产物，除去和冷凝挥发性化合物，并通过从冷凝物蒸馏获得ε-己内酯。

7. 发明授权

US07790930B2 Method for purifying cyclic ketones 有权
标题翻译：环酮纯化方法
公开(公告)号：US07790930B2
公开(公告)日：2010-09-07
申请号：US12306815
申请日：2007-06-27
申请人： Rolf Pinkos , Gerd Tebben , Christian Müller , Harald Rust
发明人： Rolf Pinkos , Gerd Tebben , Christian Müller , Harald Rust
IPC分类号： C07C45/27
CPC分类号： C07C45/85 , C07C45/34 , C07C45/62 , C07C2601/20 , C07C49/607 , C07C49/413
摘要： The present invention relates to a process for purifying a composition (I) comprising at least one cyclic ketone having from 7 to 16 carbon atoms, which comprises thermal treatment of the composition (I) with a catalyst comprising at least one transition metal and further purification by means of a process selected from the group consisting of distillation, extraction and crystallization. Furthermore, the present invention relates to a process for preparing cyclododecanone, which comprises such a purification, and the use of at least one catalyst comprising at least one transition metal for purifying a composition (I) comprising at least one cyclic ketone having from 7 to 16 carbon atoms by thermal treatment of the composition (I) with a catalyst comprising at least one transition metal.
摘要翻译：本发明涉及一种纯化包含至少一种具有7至16个碳原子的环酮的组合物（I）的方法，其包括用包含至少一种过渡金属的催化剂热处理组合物（I）并进一步纯化通过选自蒸馏，萃取和结晶的方法。此外，本发明涉及一种制备环十二烷酮的方法，其包括这种纯化，以及至少一种包含至少一种过渡金属的催化剂用于纯化组合物（I）的用途，所述组合物（I）包含至少一种具有7〜 16个碳原子通过用包含至少一种过渡金属的催化剂热处理组合物（I）。

8. 发明申请

US20100168445A1 PROCESS FOR PREPARING EPSILON-CAPROLACTONE 审中-公开
标题翻译：制备EPSILON-CAPROLACTONE的方法
公开(公告)号：US20100168445A1
公开(公告)日：2010-07-01
申请号：US12602837
申请日：2008-06-06
申请人： Rolf Pinkos , Gerd Tebben , Christophe Bauduin , Daniel Breuninger , Maria Guixa Guardia , Tilman Sirch , Thomas Krug
发明人： Rolf Pinkos , Gerd Tebben , Christophe Bauduin , Daniel Breuninger , Maria Guixa Guardia , Tilman Sirch , Thomas Krug
IPC分类号： C07D313/04
CPC分类号： C07D313/04
摘要： The present invention provides a process for preparing ε-caprolactone in a purity above 99%, in which 6-hydroxycaproic ester comprising from 0.5 to 40% by weight of adipic diester is cyclized in the gas phase at from 150 to 450° C. in the presence of oxidic catalysts and ε-caprolactone is obtained from the cyclization product by distillation.
摘要翻译：本发明提供了一种制备纯度高于99％的己内酯的方法，其中包含0.5至40重量％的己二酸二酯的6-羟基己酸酯在150至450℃的气相中环化。在氧化催化剂的存在下，通过蒸馏从环化产物得到ε-己内酯。

9. 发明授权

US07586011B2 Method for the production of tetrahydrofuran copolymers 失效
标题翻译：生产四氢呋喃共聚物的方法
公开(公告)号：US07586011B2
公开(公告)日：2009-09-08
申请号：US10537962
申请日：2003-12-16
申请人： Martin Haubner , Rolf Pinkos
发明人： Martin Haubner , Rolf Pinkos
IPC分类号： C07C43/00
CPC分类号： C08G65/20 , C08G65/2666
摘要： The present invention provides a process for preparing polyoxyalkylene glycols of a certain molecular weight in one stage by copolymerizing tetrahydrofuran and alpha,omega-diols as the comonomer in the presence of a heteropolyacid and of a hydrocarbon, by distilling off a mixture of water and this hydrocarbon from the copolymerization, which comprises terminating the polymerization when this molecular weight is attained by adding water, comonomer, butanediol or butanediol-water mixtures.
摘要翻译：本发明提供一种通过在杂多酸和烃的存在下共聚合四氢呋喃和α，ω-二醇作为共聚单体，通过蒸馏出水和该混合物的混合物来制备一定分子量的聚氧亚烷基二醇的方法烃，其包括当该分子量通过加入水，共聚单体，丁二醇或丁二醇 - 水混合物达到时终止聚合。

10. 发明申请

US20090215971A1 METHOD FOR THE PRODUCTION OF POLYTETRAHYDROFURANE OR TETRAHYDROFURANE COPOLYMERS 有权
标题翻译：聚四氢呋喃或四氢呋喃共聚物的制备方法
公开(公告)号：US20090215971A1
公开(公告)日：2009-08-27
申请号：US12303491
申请日：2007-05-25
申请人： Tobias Wabnitz , Stephan Hatscher , Stefan Käshammer , Rolf Pinkos
发明人： Tobias Wabnitz , Stephan Hatscher , Stefan Käshammer , Rolf Pinkos
IPC分类号： C08F2/01 , C08G67/00 , C08F4/06 , C08F4/16 , C08F4/12
CPC分类号： C08G65/20
摘要： The present invention relates to a process for preparing polytetrahydrofuran or tetrahydrofuran copolymers by polymerization of tetrahydrofuran in the presence of a telogen and/or a comonomer over a fixed bed of an acid catalyst, in which the temperature of the polymerization mixture increases in the direction of flow through the catalyst bed.
摘要翻译：本发明涉及在四氢呋喃的存在下，在酸催化剂的固定床上，在四氢呋喃和/或共聚单体存在下聚合制备聚四氢呋喃或四氢呋喃共聚物的方法，其中聚合混合物的温度在流过催化剂床。

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