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11. 发明授权

US5866663A Processes of polymerizing olefins 失效
标题翻译：聚合烯烃的方法
公开(公告)号：US5866663A
公开(公告)日：1999-02-02
申请号：US891332
申请日：1997-07-10
申请人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
发明人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
IPC分类号： B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号： C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译：本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。聚合由选择的过渡金属化合物，有时是其他助催化剂催化。由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。所生产的许多聚合物通常是新颖的，特别是在它们的微结构方面，这给出了其中一些不寻常的性质。公开了许多新颖的催化剂，以及一些制备它们的新方法。制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。

12. 发明授权

US5504248A Preparation of halogenated compounds 失效
标题翻译：卤化物的制备
公开(公告)号：US5504248A
公开(公告)日：1996-04-02
申请号：US281809
申请日：1994-07-28
申请人： Paul J. Krusic , Zhen-Yu Yang
发明人： Paul J. Krusic , Zhen-Yu Yang
IPC分类号： C07B39/00 , C07C17/013 , C07C17/263 , C07C17/35 , C07C19/08 , C07C41/22 , C07C43/12 , C07C61/15 , C07C62/08 , C07C62/34 , C07C67/307 , C07C69/708 , C07C255/13 , C07C255/30 , C07C303/22 , C07C309/82 , C07C53/38 , C07C55/36 , C07C69/66 , C07C255/00
CPC分类号： C07C309/82 , C07B39/00 , C07C17/013 , C07C17/272 , C07C17/35 , C07C255/13 , C07C41/01 , C07C41/22 , C07C69/708 , C07C2101/02
摘要： Halogenated compounds are prepared by ring opening reactions of highly fluorinated cyclopropanes with chlorine, bromine, iodine, or mixtures thereof at temperatures over 100.degree. C. A novel compound, which is one type of compound produced, is a highly fluorinated and halogenated ether and other novel compounds are starting materials or products. The products of the process are useful as chain transfer agents for certain free radical polymerizations, and as chemical intermediates in the preparation of various products such as surfactants and textile surface treatments.
摘要翻译：卤化的化合物是通过高温氟化环丙烷与氯，溴，碘或其混合物在100℃以上的开环反应来制备的。作为一种生成的一种化合物的新型化合物是高度氟化和卤化的醚等新型化合物是原料或产品。该方法的产物可用作某些自由基聚合的链转移剂，以及用于制备各种产物如表面活性剂和纺织品表面处理的化学中间体。

13. 发明授权

US5350821A Fluorinated monomers and polymers 失效
标题翻译：氟化单体和聚合物
公开(公告)号：US5350821A
公开(公告)日：1994-09-27
申请号：US197780
申请日：1994-02-16
申请人： Andrew E. Feiring , Bruce E. Smart , Zhen-Yu Yang
发明人： Andrew E. Feiring , Bruce E. Smart , Zhen-Yu Yang
IPC分类号： C07C17/275 , C07C17/278 , C07C21/18 , C07C31/34 , C07C43/17 , C07C53/21 , C07C53/50 , C07C69/63 , C08F14/18 , C08F16/14 , C08F16/32 , C08F214/18 , C08F216/12 , C08F216/14 , C08F16/24
CPC分类号： C08F16/32 , C07C17/275 , C07C17/278 , C07C21/18 , C07C31/34 , C07C43/17 , C07C53/21 , C07C53/50 , C07C69/63
摘要： Disclosed herein are novel monomers of the formula CF.sub.2 .dbd.CF(CF.sub.2).sub.n CH.sub.2 OCF.dbd.CF.sub.2, wherein n is 1, 2 or 3, and novel intermediates of the formula CF.sub.2 C1CFCl(CF.sub.2).sub.n CH.sub.2 OCF.dbd.CF.sub.2 wherein n is 1, 2 or 3. Also disclosed is a fluoro-polymer containing cyclic units when the monomer wherein n is 1 is free radically polymerized. The polymer is particularly useful in for coatings and encapsulants.
摘要翻译：本文公开了式CF2 = CF（CF2）nCH2OCF = CF2的新型单体，其中n为1,2或3，并且式CF2ClCFCl（CF2）nCH2OCF = CF2的新型中间体，其中n为1,2或3.也是当其中n为1的单体被自由基聚合时，公开了含氟聚合物的环状单元。聚合物特别适用于涂料和密封剂。

14. 发明授权

US5326917A Fluorinated monomers and polymers 失效
标题翻译：氟化单体和聚合物
公开(公告)号：US5326917A
公开(公告)日：1994-07-05
申请号：US61888
申请日：1993-05-14
申请人： Andrew E. Feiring , Bruce E. Smart , Zhen-Yu Yang
发明人： Andrew E. Feiring , Bruce E. Smart , Zhen-Yu Yang
IPC分类号： C07C17/275 , C07C17/278 , C07C21/18 , C07C31/34 , C07C43/17 , C07C53/21 , C07C53/50 , C07C69/63 , C08F14/18 , C08F16/14 , C08F16/32 , C08F214/18 , C08F216/12 , C08F216/14 , C07C41/00
CPC分类号： C08F16/32 , C07C17/275 , C07C17/278 , C07C21/18 , C07C31/34 , C07C43/17 , C07C53/21 , C07C53/50 , C07C69/63
摘要： Disclosed herein are novel monomers of the formula CF.sub.2 .dbd.CF(CF.sub.2).sub.n CH.sub.2 OCF.dbd.CF.sub.2, wherein n is 1, 2 or 3, and novel intermediates of the formula CF.sub.2 ClCFCl(CF.sub.2).sub.n CH.sub.2 OCF.dbd.CF.sub.2 wherein n is 1, 2 or 3. Also disclosed is a fluoropolymer containing cyclic units when the monomer wherein n is 1 is free radically polymerized. The polymer is particularly useful in for coatings and encapsulants.
摘要翻译：本文公开了新颖的式CF2 = CF（CF2）nCH2OCF = CF2的单体，其中n为1,2或3，新的中间体式为CF2ClCFCl（CF2）nCH2OCF = CF2，其中n为1,2或3.另外公开的是当其中n为1的单体自由基聚合时含有环状单元的含氟聚合物。聚合物特别适用于涂料和密封剂。

15. 发明授权

US5260492A Fluorinated monomers and polymers 失效
标题翻译：氟化单体和聚合物
公开(公告)号：US5260492A
公开(公告)日：1993-11-09
申请号：US994032
申请日：1992-12-21
申请人： Andrew E. Feiring , Bruce E. Smart , Zhen-Yu Yang
发明人： Andrew E. Feiring , Bruce E. Smart , Zhen-Yu Yang
IPC分类号： C07C17/275 , C07C17/278 , C07C21/18 , C07C31/34 , C07C43/17 , C07C53/21 , C07C53/50 , C07C69/63 , C08F16/32 , C07C41/00
CPC分类号： C08F16/32 , C07C17/275 , C07C17/278 , C07C21/18 , C07C31/34 , C07C43/17 , C07C53/21 , C07C53/50 , C07C69/63
摘要： Disclosed herein are novel monomers of the formula CF.sub.2 .dbd.CF(CF.sub.2).sub.n CH.sub.2 OCF.dbd.CF.sub.2, wherein n is 1, 2 or 3, and novel intermediates of the formula CF.sub.2 ClCFCl(CF.sub.2).sub.n CH.sub.2 OCF.dbd.CF.sub.2 wherein n is 1, 2 or 3. Also disclosed is a fluoropolymer containing cyclic units when the monomer wherein n is 1 is free radically polymerized. The polymer is particularly useful in for coatings and encapsulants.
摘要翻译：本文公开了新颖的式CF2 = CF（CF2）nCH2OCF = CF2的单体，其中n为1,2或3，新的中间体式为CF2ClCFCl（CF2）nCH2OCF = CF2，其中n为1,2或3.另外公开的是当其中n为1的单体自由基聚合时含有环状单元的含氟聚合物。聚合物特别适用于涂料和密封剂。

16. 发明申请

US20120304516A1 SUPPORT MECHANISM WITH MOUNTING MEMBER ROTATINGLY RECEIVED IN SUPPORT SEAT 审中-公开
标题翻译：支持机构安装在支持座位上旋转的机构
公开(公告)号：US20120304516A1
公开(公告)日：2012-12-06
申请号：US13337174
申请日：2011-12-26
申请人： ZHEN-YU YANG
发明人： ZHEN-YU YANG
IPC分类号： G09F15/00
CPC分类号： F16M11/08 , F16M11/105 , F16M13/02 , F16M13/027
摘要： A support mechanism includes a hinge assembly, a hollow support seat, a positioning member and a mounting member. The support seat includes a plurality of restricting portions and a plurality of support portions corresponding to the restricting portions, the restricting portions and the support portions cooperatively defining a receiving space therebetween. The support seat further defines a positioning hole in the circumferential wall thereof, the positioning hole communicating with the receiving space. The positioning member is received in the positioning hole. The mounting member is connected to the hinge assembly and includes a peripheral position portion, the position portion is capable of passing the restricting portions when inserted into the support seat and rotating within the receiving space to a predetermined position in which the positioning member is engagable with the position portion of the mounting member to fix the hinge assembly to the support seat.
摘要翻译：支撑机构包括铰链组件，中空支撑座，定位构件和安装构件。支撑座包括多个限制部分和对应于限制部分的多个支撑部分，限制部分和支撑部分协作地限定其间的容纳空间。支撑座还在其周向壁上限定定位孔，定位孔与容纳空间连通。定位构件被容纳在定位孔中。安装构件连接到铰链组件并且包括周边位置部分，当插入到支撑座中并且在接收空间内旋转到定位构件可接合的预定位置时，位置部分能够通过限制部分安装构件的位置部分将铰链组件固定到支撑座上。

17. 发明申请

US20100093878A1 CROSSLINKABLE FLUOROPOLYMER, CROSSLINKED FLUOROPOLYMERS AND CROSSLINKED FLUOROPOLYMER MEMBRANES 审中-公开
标题翻译：可交联氟聚合物，交联氟聚合物和交联氟聚合物膜
公开(公告)号：US20100093878A1
公开(公告)日：2010-04-15
申请号：US12344768
申请日：2008-12-29
申请人： ZHEN-YU YANG , Amy Qi Han , Mark Gerrit Roelofs , Randal L. Perry
发明人： ZHEN-YU YANG , Amy Qi Han , Mark Gerrit Roelofs , Randal L. Perry
IPC分类号： C08J5/20 , C08F28/02 , C08F214/18 , C08F24/00 , B05D5/12
CPC分类号： C08F214/18 , C08F24/00 , C08F28/02 , C08J5/2206 , C08J5/225 , C08J5/2293 , C08J2327/18 , H01M8/1023 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： Crosslinkable fluoropolymers and crosslinked fluoropolymers prepared from select fluorinated monomers by dimerization and trimerization. Also disclosed are proton conductive membranes of these crosslinked fluoropolymers.
摘要翻译：可交联的含氟聚合物和由选择的氟化单体通过二聚和三聚制备的交联的含氟聚合物。还公开了这些交联的含氟聚合物的质子传导膜。

18. 发明申请

US20080161612A1 PARTIALLY FLUORINATED IONIC COMPOUNDS 有权
标题翻译：部分氟化离子化合物
公开(公告)号：US20080161612A1
公开(公告)日：2008-07-03
申请号：US11955508
申请日：2007-12-13
申请人： Zhen-Yu Yang , Amy Qi Han
发明人： Zhen-Yu Yang , Amy Qi Han
IPC分类号： C07C317/02
CPC分类号： C07C309/82 , H01M8/1023 , H01M8/1025 , H01M8/1039 , H01M2300/0082
摘要： Partially fluorinated ionic compounds are prepared. They are useful in the preparation of partially fluorinated dienes, in which the repeat units are cycloaliphatic.
摘要翻译：制备部分氟化的离子化合物。它们可用于制备部分氟化的二烯，其中重复单元是环脂族的。

19. 发明申请

US20070208092A1 Stable Trifluorostyrene Containing Compounds Grafted To Base Polymers, And Their Use As Polymer Electrolyte Membranes 失效
标题翻译：稳定的三氟苯乙烯含有化合物接枝到基础聚合物上，并用作聚合物电解质膜
公开(公告)号：US20070208092A1
公开(公告)日：2007-09-06
申请号：US11547239
申请日：2004-06-25
申请人： Zhen-Yu Yang
发明人： Zhen-Yu Yang
IPC分类号： B01J39/20
CPC分类号： C08F291/18 , C08F255/02 , C08F259/08 , C08F291/185 , C08J5/225 , C08J2327/12 , C08J2351/06 , H01B1/122 , H01M8/1023 , H01M8/1039 , H01M8/1053 , H01M8/106 , H01M8/1072 , H01M2300/0082 , H01M2300/0091 , Y02P70/56 , C08F212/14
摘要： A fluorinated ion exchange polymer prepared by grafting at least one grafting monomer on to at least one base polymer, wherein the grafting monomer comprises structure 1a or 1b: wherein Z comprises S, SO2, or POR wherein R comprises a linear or branched perfluoroalkyl group of 1 to 14 carbon atoms optionally containing oxygen or chlorine, an alkyl group of 1 to 8 carbon atoms, an aryl group of 6 to 12 carbon atoms or a substituted aryl group of 6 to 12 carbon atoms; RF comprises a linear or branched perfluoroalkene group of I to 20 carbon atoms, optionally containing oxygen or chlorine; Q is chosen from F, —OM, NH2, —N(M)SO2R2F, and C(M)(SO2R2F)2, wherein M comprises H, an alkali cation, or ammonium; R2F groups comprises alkyl of 1 to 14 carbon atoms which may optionally include ether oxygens or aryl of 6 to 12 carbon atoms where the alkyl or aryl groups may be perfluorinated or partially fluorinated; and n is 1 or 2 for 1a, and n is 1, 2, or 3 for 1b. These ion exchange polymers are useful in preparing catalyst coated membranes and membrane electrode assemblies used in fuel cells.
摘要翻译：通过将至少一种接枝单体接枝到至少一种基础聚合物上制备的氟化离子交换聚合物，其中接枝单体包含结构1a或1b：其中Z包含S，SO 2或POR，其中R 包括任选含有氧或氯的碳原子数为1〜14的直链或支链全氟烷基，碳原子数为1〜8的烷基，碳原子数6〜12的芳基或碳原子数6〜12的取代芳基。 R F包括任选含有氧或氯的1-20个碳原子的直链或支链全氟烯基; Q选自F，-OM，NH 2，-N（M）SO 2，R 2，，和C（M）（SO 2 R 2）2，其中M包括H，碱阳离子或铵; R 2基团包括1至14个碳原子的烷基，其可任选地包括醚氧基或6至12个碳原子的芳基，其中烷基或芳基可以是全氟化的，或部分氟化; 对于1a，n为1或2，对于1b，n为1,2或3。这些离子交换聚合物可用于制备用于燃料电池的催化剂涂覆的膜和膜电极组件。

20. 发明申请

US20060275636A1 Fuel cell membrane containing zirconium phosphate 失效
标题翻译：含有磷酸锆的燃料电池膜
公开(公告)号：US20060275636A1
公开(公告)日：2006-12-07
申请号：US10566940
申请日：2004-05-21
申请人： Zhen-Yu Yang
发明人： Zhen-Yu Yang
IPC分类号： H01M8/10 , H01M10/36 , C07F9/02 , C07F7/28
CPC分类号： H01M8/1016 , C07F9/3808 , C07F9/3856 , C07F9/4006 , C07F9/4037 , C07F9/65031 , C07F9/6506 , C07F9/65068 , C07F9/65312 , H01M8/1004 , H01M8/1009
摘要： The present invention provides for a compound having the following structure: Zr(O3PZqYnX)2-m(03PR)m, wherein X=a functional group such as CO2H, PO(OH)2, and SO3H, and SO2NHSO2W, wherein W=aryl of 6 to 10 carbon atoms or Y; Y=perfluoro-linear, branched or cyclic alkylene group, wherein the alkylene is 1-20 carbon atoms, or a fluorinated group containing at least one substituent selected from the group consisting of oxygen, chlorine and bromine; Z=alkylene of 1-12 carbon atoms, aryl of 6-10 carbon atoms, or a heterocyclic aryl group of 3-10 carbons atoms; R=alkyl of 1-12 carbon atoms, aryl of 6-10 carbon atoms, substituted alkyl, or substituted aryl, wherein the substituent is selected from the group consisting of F, Cl, perfluoroalkyl, alkyl of 1-12 carbon atoms and aryl of 6-10 carbon atoms; n=0 or 1; q=0 or 1; and m=0 to 1.5; with the proviso that when n=0, and q=1, Z=at least one heterocyclic group having 3 to 10 carbon atoms, 1 to 5 nitrogen atoms and 0 to 4 oxygen atoms. The invention also provides a polymer electrolyte membrane, a catalyst coated membrane and a fuel cell having this compound.
摘要翻译：本发明提供具有以下结构的化合物：Zr（O 3 PZ）X Y X 2）2-m < 其中X = CO 2 H，PO（OH）2，SO 2等官能团，其中W = 6至10个碳原子的芳基或Y;其中W = 6至10个碳原子的芳基或Y; Y =全氟直链，支链或环状的亚烷基，其中亚烷基为1-20个碳原子，或含有至少一个选自氧，氯和溴的取代基的氟化基团; Z = 1-12个碳原子的亚烷基，6-10个碳原子的芳基或3-10个碳原子的杂环芳基; R = 1-12个碳原子的烷基，6-10个碳原子的芳基，取代的烷基或取代的芳基，其中取代基选自F，Cl，全氟烷基，1-12个碳原子的烷基和芳基 6-10个碳原子; n = 0或1; q = 0或1; m = 0〜1.5; 条件是当n = 0且q = 1时，Z =至少一个具有3至10个碳原子，1至5个氮原子和0至4个氧原子的杂环基。本发明还提供了一种聚合物电解质膜，催化剂涂覆膜和具有该化合物的燃料电池。

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