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1. 发明申请

US20210017310A1 Method for producing temperature-stable polyalkenylenes 有权
公开(公告)号：US20210017310A1
公开(公告)日：2021-01-21
申请号：US15733679
申请日：2019-03-29
申请人： Evonik Operations GmbH
发明人： Kévin MICOINE , Velichka Koleva , Dagmar Isabell Hackenberger , Pedro Vazquez Toran
IPC分类号： C08F132/04
摘要： The polymerization of cycloalkenamer is stopped by adding an alkyl vinyl derivative. Subsequently compound A is added, wherein compound A has at least one of the features i) or ii): i) at least one functional group or ii) at least one saturated or unsaturated aliphatic or aromatic heterocyclic ring having 3 to 14 ring atoms, wherein the ring atoms contain at least one carbon atom and at least one atom selected from oxygen, nitrogen and sulfur. A membrane filtration is subsequently carried out. This type of production produces polyalkenamers which are temperature-stable at 180° C.

2. 发明授权

US10781274B2 Polymerizable monomers and method of polymerizing the same 有权
公开(公告)号：US10781274B2
公开(公告)日：2020-09-22
申请号：US16403435
申请日：2019-05-03
申请人： Align Technology, Inc.
发明人： Robert Liska , Christian Gorsche , Markus Kury , Yan Chen , Chunhua Li , Srinivas Kaza
IPC分类号： A61C7/00 , A61C7/08 , A61C7/10 , A61K6/093 , C08F120/30 , G03F7/00 , C08F120/10 , C08F132/04 , C08F2/48 , B33Y80/00 , B33Y10/00 , B33Y70/00
摘要： Provided herein are photopolymerizable monomers, optionally for use as reactive diluents in a high temperature lithography-based photopolymerization process, a method of producing polymers using said photopolymerizable monomers, the polymers thus produced, and orthodontic appliances comprising the polymers.

3. 发明授权

US09896527B2 Highly selective polynorbornene homopolymer membranes for natural gas upgrading 有权
公开(公告)号：US09896527B2
公开(公告)日：2018-02-20
申请号：US15057894
申请日：2016-03-01
申请人： Saudi Arabian Oil Company
发明人： Benjamin J. Sundell , John A. Lawrence, III
IPC分类号： C08F132/08 , C08F132/04 , C08F8/12 , B01D53/22 , B01D71/70 , C08G61/08 , B01D67/00 , B01D71/44 , B01D71/72 , C08F4/80
CPC分类号： C08F132/08 , B01D53/228 , B01D67/0009 , B01D71/44 , B01D71/70 , B01D2053/221 , B01D2256/245 , B01D2257/7022 , B01D2323/30 , C08G61/08 , C08G2261/11 , C08G2261/135 , C08G2261/144 , C08G2261/3324 , C08G2261/418 , C08G2261/76 , C08G2261/80 , C08L45/00 , C08L65/00 , C08L101/10
摘要： Embodiments for a crosslinked alkoxysilyl polynorbornene homopolymer and methods of making crosslinked alkoxysilyl polynorbornene homopolymer are provided, where the method comprises polymerizing through addition polymerization or ring opening metathesis polymerization a norbornene monomer comprising an alkoxysilyl moiety in the presence of a catalyst to produce an alkoxysilyl modified polynorbornene homopolymer, and producing a crosslinked alkoxysilyl polynorbornene homopolymer through sol-gel initiated crosslinking of the alkoxysilyl modified polynorbornene homopolymer at ambient conditions, or acid-catalyzed conditions.

4. 发明授权

US08609789B2 Oligomeric and polymeric aromatic phosphonic acids, their blends, processes for preparing them and uses as polyelectrolytes 失效
标题翻译：低聚和聚合芳族膦酸，它们的共混物，其制备方法和用作聚电解质
公开(公告)号：US08609789B2
公开(公告)日：2013-12-17
申请号：US12279794
申请日：2007-02-12
申请人： Helmut Moehwald , Thorsten Bock , Rolf Muelhaupt
发明人： Helmut Moehwald , Thorsten Bock , Rolf Muelhaupt
IPC分类号： C08F32/00 , C08F32/04 , C08F132/04
CPC分类号： H01M8/1041 , B01D67/0009 , B01D67/0011 , B01D71/82 , B01D2325/04 , B01D2325/14 , C08G65/48 , C08G75/23 , C08J5/2256 , C08L65/00 , C08L71/126 , C08L81/06 , H01M8/0289 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , C08L2666/02
摘要： The present invention relates to halogen-free, oligomeric or polymeric phosphonic acids made up of units of the general formula (I) —[(O)m—{R1(X)n(Y)o}pR1(X)q]r—[(O)s—R5(X)t]v— (I), where: Xis —P═O(OH)2, Yis carbonyl or sulfonyl, R1, R5are, independently of one another, divalent or polyvalent, substituted or unsubstituted, heteroatom-free or heteroatom- comprising aromatic radicals, m, o, sare each, independently of one another, 0 or 1, n, q, tare each, independently of one another, 0 or an integer from 1 to 8, with n and s not simultaneously being 0, r, vare each, independently of one another, from 0 to 1, with the sum of r and v being from 0.95 to 1.05, and pis 0 or an integer ≧1, where the radicals X are substituents on R1 and R5 and the radicals Y are parts of polymer or oligomer chain, to a process for preparing these compounds and also to halogen-free mixtures comprising one or more compounds of the general formula (I) and a nitrogen-free solvent having a boiling point of >150° C.
摘要翻译：本发明涉及由通式（I） - [（O）m - {R 1（X）n（Y）o} p R 1（X）q] r的单元组成的无卤素，低聚或聚合膦酸 - [（O）s-R5（X）t] v-（I），其中：X是-P = O（OH）2，Y是羰基或磺酰基，R1，R5彼此独立地是二价或多价，取代或未取代的，无杂原子的或含杂原子的芳基，m，o，s各自独立地为0或1，n，q，t各自彼此独立地为0或整数 1至8，其中n和s不同时为0，r，v各自彼此独立地为0至1，r和v之和为0.95至1.05，p为0或整数 > = 1，其中基团X是R 1和R 5上的取代基，基团Y是聚合物或低聚物链的部分，用于制备这些化合物的方法以及含卤素的混合物，其包含一种或多种通式（ I）和沸点为的无氮溶剂 > 150°C

5. 发明申请

US20130012663A1 Process Technology For Recovering Brominated Styrenic Polymers From Reaction Mixtures in Which They Are Formed and/or Converting Such Mixtures into Pellets or into Granules or Pastilles 有权
公开(公告)号：US20130012663A1
公开(公告)日：2013-01-10
申请号：US13619256
申请日：2012-09-14
申请人： Charles H. Kolich , John F. Balhoff , Douglas W. Luther , Robert C. Herndon, JR. , Ronny W. Linn , Bruce C. Peters , Arthur G. Mack , David A. Lee
发明人： Charles H. Kolich , John F. Balhoff , Douglas W. Luther , Robert C. Herndon, JR. , Ronny W. Linn , Bruce C. Peters , Arthur G. Mack , David A. Lee
IPC分类号： C08F132/04
CPC分类号： C08F6/02 , B29C47/0004 , B29C47/0011 , B29C47/30 , B29C47/38 , B29C47/765 , B29C47/92 , B29C2947/92514 , B29C2947/92704 , C08F6/001 , C08F8/20 , Y10T428/2982 , C08L25/18 , C08F12/08
摘要： Brominated styrenic polymer is recovered from solution in a vaporizable solvent by converting the solution in a devolatilization extruder into a brominated styrenic polymer melt or flow and a separate vapor phase comprised predominately of vaporizable solvent, recovering the melt or flow from the devolatilization extruder, and allowing or causing the melt or flow to solidify. The solidified brominated styrenic polymer can be subdivided into a powder or pelletized form. Pellets so made have improved hardness and/or crush strength properties along with reduced formation of fines. Brominated anionic styrenic polymer is preferably used in the process.

6. 发明授权

US10538475B2 Amphiphilic cyclobutenes and cylobutanes 有权
公开(公告)号：US10538475B2
公开(公告)日：2020-01-21
申请号：US14403763
申请日：2013-05-28
申请人： NUtech Ventures
发明人： Wantanee Sittiwong , Patrick H. Dussault , Raul Barletta , Robert Powers
IPC分类号： C07C59/21 , C07C59/205 , C07C59/11 , C08F232/04 , C07C53/134 , C07C51/09 , C07C57/26 , C07C67/313 , C08F132/04 , C08F212/08 , C08F216/16
摘要： This disclosure relates to amphiphilic compounds containing a cyclobutene or cyclobutane moiety. In some embodiments, the compounds are useful for treating infection by Mycobacterium such as Mycobacterium tuberculosis. Cyclobutene containing compounds are also useful as monomers in the preparation of amphiphilic polymers.

7. 发明授权

US09676880B1 Highly selective polynorbornene homopolymer membranes for natural gas upgrading 有权
公开(公告)号：US09676880B1
公开(公告)日：2017-06-13
申请号：US15057894
申请日：2016-03-01
申请人： Saudi Arabian Oil Company
发明人： Benjamin J. Sundell , John A. Lawrence, III
IPC分类号： C08F132/08 , C08F132/04 , C08F8/12 , B01D53/22 , B01D71/70 , C08G61/08 , B01D67/00 , B01D71/44 , B01D71/72 , C08F4/80
摘要： Embodiments for a crosslinked alkoxysilyl polynorbornene homopolymer and methods of making crosslinked alkoxysilyl polynorbornene homopolymer are provided, where the method comprises polymerizing through addition polymerization or ring opening metathesis polymerization a norbornene monomer comprising an alkoxysilyl moiety in the presence of a catalyst to produce an alkoxysilyl modified polynorbornene homopolymer, and producing a crosslinked alkoxysilyl polynorbornene homopolymer through sol-gel initiated crosslinking of the alkoxysilyl modified polynorbornene homopolymer at ambient conditions, or acid-catalyzed conditions.

8. 发明申请

US20130018160A1 Nonconjugated Conductive Polymers for Protection against Nuclear Radiation including Radioactive Iodine 审中-公开
标题翻译：用于防辐射的非共轭导电聚合物，包括放射性碘
公开(公告)号：US20130018160A1
公开(公告)日：2013-01-17
申请号：US13179876
申请日：2011-07-11
申请人： Mrinal Thakur
发明人： Mrinal Thakur
IPC分类号： C08F132/04 , C08F236/20 , C08F136/20
CPC分类号： G21F9/04 , C08L21/00 , C08L47/00 , G21F9/06 , G21F9/12 , G21F9/28
摘要： Nonconjugated conductive polymers absorb radioactive iodine, therefore are useful for protection against nuclear radiation. These polymers have at least one double bond per repeat unit. The ratio of the number of double bonds to the total number of bonds along the polymer chain is less than half. Examples of nonconjugated conductive polymers include: cis-1,4-polyisoprene (natural rubber), trans-1,4-polyisoprene (gutta percha), polybutadiene, polydimethyl butadiene, poly(b-pinene), styrene butadiene rubber (SBR), polyalloocimene, polynorbornene and many others. Through interaction with iodine atoms the double bonds in the nonconjugated polymers transform into radical cations leading to a dark color. The iodine atoms remain (immobile) bound to the polymer chain through the charge-transfer interaction, these polymers are very inexpensive and can be easily processed into any shape, structure and size. Therefore, these are useful for protection against nuclear radiation including radioactive iodine. These polymers when used as a thick cover can provide safe storage of nuclear waste materials including spent fuel rods.
摘要翻译：非共轭导电聚合物吸收放射性碘，因此可用于防止核辐射。这些聚合物每个重复单元具有至少一个双键。双键数与沿聚合物链的总键数的比例小于一半。非共轭导电聚合物的实例包括：顺式-1,4-聚异戊二烯（天然橡胶），反式-1,4-聚异戊二烯（gutta percha），聚丁二烯，聚二甲基丁二烯，聚（b-蒎烯），丁苯橡胶（SBR）多烯烃，聚降冰片烯等。通过与碘原子的相互作用，非共轭聚合物中的双键转化成自由基阳离子，导致暗色。碘原子通过电荷转移相互作用而保持（固定）与聚合物链结合，这些聚合物非常便宜，并且可以容易地加工成任何形状，结构和尺寸。因此，这些可用于防止包括放射性碘在内的核辐射。当用作厚盖时，这些聚合物可以提供包括乏燃料棒在内的核废料的安全储存。

9. 发明授权

US5891963A .alpha.-olefins and olefin polymers and processes therefor 失效
标题翻译： α-烯烃和烯烃聚合物及其工艺
公开(公告)号：US5891963A
公开(公告)日：1999-04-06
申请号：US891442
申请日：1997-07-10
申请人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Elizabeth Forrester McCord , Stephan James McLain
发明人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Elizabeth Forrester McCord , Stephan James McLain
IPC分类号： B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号： C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microsructure, which give some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译：本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。聚合由选择的过渡金属化合物，有时是其他助催化剂催化。由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。所生产的许多聚合物通常是新颖的，特别是关于它们的微结构，其中给出了其中一些不寻常的性质。公开了许多新颖的催化剂，以及一些制备它们的新方法。制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。

10. 发明授权

US3780009A Process for polymerizing cycloolefins to polyalkenamers 失效
标题翻译：将环烯烃聚合到聚烯烃的方法
公开(公告)号：US3780009A
公开(公告)日：1973-12-18
申请号：US3780009D
申请日：1971-12-15
申请人： MONTEDISON SPA
发明人： DALL ASTA G
IPC分类号： C08F132/04 , C08F4/608 , C08F8/34 , C08F10/00 , C08G61/08 , C08F1/56
CPC分类号： C08G61/08 , C08F10/00 , C08F4/00
摘要： THERE IS DISCLOSED A PROCESS FOR POLYMERIZING CYCLOOLEFINS TO POLYALKENAMERS IN CONTACT WITH CATALYSTS PREPARED BY MIXING TRANSITION METAL COMPOUNDS AND HYDRIDES OR ORGANOMETALLIC COMPOUNDS (WHICH MAY BE HALOGENATED) OF METALS BELONGING TO GROUPS I, II, III-A AND IV-A OF THE MENDELYEEV PERIODIC TABLE, AND WHICH ALSO INCLUDE CARBON DIOXIDE AS ACTIVATOR OF THE CATALYTIC MIXTURE.

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