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1. 发明专利

JP2007218795A Electrode material, biosensor using it, and fuel cell 有权
标题翻译：电极材料，使用它的生物传感器和燃料电池
公开(公告)号：JP2007218795A
公开(公告)日：2007-08-30
申请号：JP2006041245
申请日：2006-02-17
申请人： Kyoto Univ , Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 国立大学法人京都大学 , 株式会社豊田中央研究所
发明人： KAJINO TSUTOMU , SETOYAMA NORIHIKO , KAMIMURA KEIKO , FUKUSHIMA YOSHIAKI , KATO HISAO , TSUJIMURA SEIYA , KANO KENJI
IPC分类号： G01N27/30 , C12M1/34 , G01N27/327 , H01M8/16
CPC分类号： G01N27/308
摘要： PROBLEM TO BE SOLVED: To provide an electrode material capable of acquiring sufficient stability and excellent activity of a carried component, and performing efficient electronic conduction between a carrier and the carried component. SOLUTION: This electrode material is characterized by being equipped with a carbon porous body, and oxidoreductase carried on the carbon porous body. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供能够获得足够的稳定性和极好的携带部件的活性的电极材料，并且在载体和被承载部件之间执行有效的电子传导。解决方案：该电极材料的特征在于具有碳多孔体和承载在碳多孔体上的氧化还原酶。版权所有（C）2007，JPO＆INPIT

2. 发明专利

JP2004071253A Electrocatalyst for fuel cell and fuel cell 有权
公开(公告)号：JP2004071253A
公开(公告)日：2004-03-04
申请号：JP2002226648
申请日：2002-08-02
申请人： Toyota Central Res & Dev Lab Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社豊田中央研究所
发明人： KATO HISAO , SETOYAMA NORIHIKO , FUKUSHIMA YOSHIAKI , INAGAKI SHINJI
IPC分类号： H01M4/96 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide electrocatalyst for a fuel cell using a new carrier and providing a fuel cell with higher output density than that of the conventional electrocatalyst for the fuel cell when used for the fuel cell. SOLUTION: This electrocatalyst for the fuel cell is characterized in having the carrier composed of a carbon material including mesoporous carbon particles in one part and a catalyst layer carried by the carrier. The mesoporous carbon particle has a smaller pore size distribution than that of a general carbon material so as to exhibit favorable dispersion of the catalyst carried and to reduce the wastefulness of the catalyst carried in the pore. The mixing of the carbon material except for the mesoporous carbon particles can solve a problem of insufficient diffusion of reaction gas, when the mesoporous carbon particle is singularly used so as to efficiently form a network of electron transfer and reduce the inner DC resistance of the fuel cell. COPYRIGHT: (C)2004,JPO

3. 发明专利

JP2004149579A Material composition for preparing optical waveguide and method for producing optical waveguide 有权
公开(公告)号：JP2004149579A
公开(公告)日：2004-05-27
申请号：JP2002313422
申请日：2002-10-28
申请人： Toagosei Co Ltd , Toyoda Gosei Co Ltd , Toyota Central Res & Dev Lab Inc , 東亞合成株式会社 , 株式会社豊田中央研究所 , 豊田合成株式会社
发明人： SATO SHIN , KATO HISAO , YAMASHITA TATSUYA , KAGAMI MANABU , INUI YUKITOSHI , KONDO KUNIYOSHI
IPC分类号： G02B6/12 , C08F2/00 , C08F2/48 , C08G85/00 , G02B6/13
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an optical waveguide having good productivity and the highest refractive index in the core central part and to provide a material composition suitable therefor. SOLUTION: A composition 2 comprising a radical-polymerizable material having a low refractive index, a cationic-polymerizable material having a high refractive index, a radical polymerization initiator effective at a high wavelength and a cationic polymerization initiator effective at a shorter wavelength is used. A transparent container 1 is filled with the composition 2 and irradiated with a first irradiating light 3 effective for the radical-polymerization initiator (a) to thereby polymerize the radical-polymerizable material having the low refractive index in an incorporated state of the cationic-polymerizable material having the high refractive index and the cationic polymerization initiator into a pattern according to the shape of light irradiation. An optically transparent optical path part 4 is once formed (b). When the first irradiating light 3 is continued, a layer 5 having a lower refractive index than that of the surface of the optical path part 4 is formed by a light component to the lateral side from the optical path part 4 (c). An uncured product remaining in the interior of the transparent container 1 is subsequently cured with a second irradiating light 6 (d). COPYRIGHT: (C)2004,JPO

4. 发明专利

JP2008237160A Electron transmitter-immobilized base material 有权
标题翻译：电子发射机固定基材
公开(公告)号：JP2008237160A
公开(公告)日：2008-10-09
申请号：JP2007085251
申请日：2007-03-28
申请人： Oita Univ , Toyota Central R&D Labs Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 国立大学法人大分大学 , 株式会社豊田中央研究所
发明人： AMAO YUTAKA , SEKITO TAKESHI , KATO HISAO , KAJINO TSUTOMU
IPC分类号： C12M1/00
摘要： PROBLEM TO BE SOLVED: To provide a reduced electron transmitter-immobilized material relatively long in service life as a reduced form even in the presence of oxygen in an air open system, especially in a system in the presence of a photosensitizing coloring matter ( also referred to as a photosensitizer), insoluble in a medium, especially in an aqueous solution, and transportable, without the need of using any special immobilizing substance.
SOLUTION: The reduced electron transmitter-immobilized base material is such that at least the surface of a base material is immobilized with a reduced electron transmitter represented by general formula in Fig. (wherein, R
1 is methyl; FG is a functional group; and l means an integer of 1-29).
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：即使在空气开放系统中的氧气存在下，特别是在光敏色素存在下的系统中，为了提供使用寿命较短的还原型电子发射体固定化材料，（也称为光敏剂），不溶于介质，特别是在水溶液中，可运输，而不需要使用任何特殊的固定物质。解决方案：还原电子发射器固定的基底材料使得至少基底材料的表面被固定在图1中由通式表示的还原电子发射器。（其中，R SB 1是甲基; FG是官能团; l表示1-29的整数）。版权所有（C）2009，JPO＆INPIT

5. 发明专利

JP2008064514A Electrode catalyst and enzyme electrode 有权
标题翻译：电极催化剂和酶电极
公开(公告)号：JP2008064514A
公开(公告)日：2008-03-21
申请号：JP2006240867
申请日：2006-09-05
申请人： Kanazawa Univ , Kyoto Univ , Toyota Central R&D Labs Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 国立大学法人京都大学 , 国立大学法人金沢大学 , 株式会社豊田中央研究所
发明人： KAJINO TSUTOMU , SETOYAMA NORIHIKO , KAMIMURA KEIKO , KATO HISAO , KANO KENJI , TSUJIMURA SEIYA , SAKURAI TAKESHI , KATAOKA KUNISHIGE
IPC分类号： G01N27/327 , C12N9/00 , C12N9/02 , C12N11/14 , G01N27/30 , H01L21/28 , H01L31/04 , H01M8/16
CPC分类号： C12N11/14 , C12N9/0091 , G01N27/3271 , H01M4/8605 , H01M4/9008 , H01M4/9083 , H01M8/16 , Y02E60/527
摘要： PROBLEM TO BE SOLVED: To provide a novel electrode catalyst comprising oxidase high in electron transmission efficiency, and an enzyme electrode using it.
SOLUTION: The electrode catalyst comprises CueO and the enzyme electrode is equipped with a porous carbon body and the electrode catalyst comprising CueO supported on the surface of the porous carbon body. CueO is preferably CueO originating from a coli. The porous carbon body which constitutes the enzyme electrode is preferably a carbon gel. The enzyme electrode preferably further includes a mediator for accelerating the giving and receiving of the electron between the porous carbon body and CueO.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种包含电子传输效率高的氧化酶的新型电极催化剂和使用它的酶电极。解决方案：电极催化剂包含CueO，酶电极配备有多孔碳体，并且包含支撑在多孔碳体表面上的CueO的电极催化剂。 CueO优选来自大肠杆菌的CueO。构成酶电极的多孔碳体优选为碳凝胶。酶电极优选还包括用于加速在多孔碳体和CueO之间产生和接收电子的介体。版权所有（C）2008，JPO＆INPIT

6. 发明专利

JP2008239581A Long-life reduced-type electron carrier 有权
标题翻译：长寿命减电型电子载体
公开(公告)号：JP2008239581A
公开(公告)日：2008-10-09
申请号：JP2007085661
申请日：2007-03-28
申请人： Oita Univ , Toyota Central R&D Labs Inc , Toyota Motor Corp , トヨタ自動車株式会社 , 国立大学法人大分大学 , 株式会社豊田中央研究所
发明人： AMAO YUTAKA , SEKITO TAKESHI , KATO HISAO , KAJINO TSUTOMU
IPC分类号： C07D213/22 , C07D213/36 , C12Q1/26
摘要： PROBLEM TO BE SOLVED: To provide a methyl viologen-based reduced-type elecron carrier which is long in a life as a reduced-type electron carrier even in the presence of oxygen in an open air system particularly in the system wherein a photosensitizing dye and a coenzyme exist.
SOLUTION: The reduced-type electron carrier is represented by the general formula (wherein R
1 is a methyl group; FG is a functional group; and n is an integer of 5-29).
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：即使在露天系统中，即使在存在氧的情况下，特别是在系统中，提供作为还原型电子载体长寿命的甲基紫精型还原型电子载体，其中a 光敏染料和辅酶存在。解决方案：还原型电子载体由通式（其中R 1 是甲基; FG是官能团; n是5-29的整数）表示。版权所有（C）2009，JPO＆INPIT

7. 发明专利

JP2008071584A Electron transfer mediator modification enzyme electrode, and biological fuel cell equipped with this 审中-公开
标题翻译：电子转移介质修改酶电极和与此配套的生物燃料电池
公开(公告)号：JP2008071584A
公开(公告)日：2008-03-27
申请号：JP2006248206
申请日：2006-09-13
申请人： Kyoto Univ , Toyota Motor Corp , トヨタ自動車株式会社 , 国立大学法人京都大学
发明人： KATO HISAO , NISHIGORI HIDETAKA , KANO KENJI , TSUJIMURA SEIYA
IPC分类号： H01M8/16 , G01N27/327 , H01M4/86
CPC分类号： C12Q1/004 , C12Q1/006
摘要： PROBLEM TO BE SOLVED: To provide an electron transfer mediator modification enzyme electrode capable of obtaining high current density and stable electrode performance by covalent bonding an electron transfer mediator through a specific spacer on the surface of a conductive base material constituting an electrode, and to provide a biological fuel cell equipped with the same. SOLUTION: In the electron transfer mediator modification enzyme electrode provided with a conductive base material connected with an external circuit, an oxidoreductase capable of transferring electron with the conductive base material, and an electron transfer mediator capable of mediating electron transfer between the conductive base material and the oxidoreductase, the electron transfer mediator is covalent bonded on the surface of the conductive base material through the spacer containing at least a direct-chain structure, and the biological fuel cell is provided with the electron transfer mediator modification enzyme electrode. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种电子转移介质修饰酶电极，其能够通过电子转移介体通过在构成电极的导电性基材的表面上的特定间隔物共价键来获得高电流密度和稳定的电极性能，并提供配备有该燃料电池的生物燃料电池。解决方案：在具有与外部电路连接的导电基材的电子转移介质修饰酶电极中，能够与导电性基体材料一起转移电子的氧化还原酶，以及能够介导导电性的电子转移的电子转移介体基质材料和氧化还原酶，电子转移介体通过至少含有直链结构的间隔物共价结合在导电性基材的表面上，生物燃料电池配置有电子转移介质修饰酶电极。版权所有（C）2008，JPO＆INPIT

8. 发明专利

JP2008177088A Enzyme electrode, and biofuel cell equipped with it 审中-公开
标题翻译： ENZYME ELECTRODE，和BIOFUEL CELL EQUIPPED WITH IT
公开(公告)号：JP2008177088A
公开(公告)日：2008-07-31
申请号：JP2007010310
申请日：2007-01-19
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： NISHIGORI HIDETAKA , KATO HISAO , KANO KENJI , TSUJIMURA SEIYA
IPC分类号： H01M8/16
CPC分类号： Y02E60/527
摘要： PROBLEM TO BE SOLVED: To provide an enzyme electrode capable of extracting a high-density current by immobilizing a sufficient quantity of enzyme and an electron mediator on an electrode surface in a state suitable for electron transport among enzyme, the electron mediator and the electrode; and a biofuel cell equipped with the enzyme electrode and exerting excellent power generation performance. SOLUTION: This enzyme electrode includes an electrode, the enzyme, and the electron mediator mediating electron transmission between the electrode and the enzyme. The enzyme electrode is composed by alternately stacking first charged layers containing the enzyme and the electron mediator and positively or negatively charged, and second charged layers charged in polarity reverse to that of the first charged layer on the electrode surface formed of a conductor, and is structured such that, in the first charged layer, the enzyme and the electron mediator form molecular orbits between the same organic polymer and themselves, and are chemically connected to each other. This biofuel cell has the enzyme electrode. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种能够通过在酶，电子介体和电子介体中适合于电子传输的状态下将足够量的酶和电子介体固定在电极表面上来提取高密度电流的酶电极电极; 配备有酶电极的生物燃料电池，发挥出色的发电性能。解决方案：该酶电极包括介导电极和酶之间的电子传递的电极，酶和电子介体。酶电极通过交替堆叠含有酶和电子介体的带正电荷或带负电荷的第一带电层和与由导体形成的电极表面上的第一带电层的极性相反的第二带电层，并且是结构化使得在第一带电层中，酶和电子介体在相同的有机聚合物和它们之间形成分子轨道，并且彼此化学连接。该生物燃料电池具有酶电极。版权所有（C）2008，JPO＆INPIT

9. 发明专利

JP2005129358A Cathode catalyst for fuel cell 有权
标题翻译：用于燃料电池的CATHODE催化剂
公开(公告)号：JP2005129358A
公开(公告)日：2005-05-19
申请号：JP2003363734
申请日：2003-10-23
申请人： Cataler Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 株式会社キャタラー
发明人： ITO TETSUO , TERADA TOMOAKI , KATO HISAO , NAGAMI TETSUO
IPC分类号： B01J21/18 , B01J23/89 , H01M4/90 , H01M4/92 , H01M8/10
CPC分类号： H01M4/921 , B01J21/18 , B01J23/8906 , B01J23/8993 , C22C5/04 , H01M4/926
摘要： PROBLEM TO BE SOLVED: To provide a cathode catalyst for a fuel cell which contains platinum and iron that are capable of maintaining durability of a cell and are capable of making the cell have a high output. SOLUTION: This is a cathode catalyst for the fuel cell which comprises a carrying layer composed of an alloy containing platinum, iron, and furthermore one kind or more of elements out of tungsten, titanium, molybdenum, rhenium, zinc, manganese, tin, tantalum, and rhodium that are third components having affinity with iron, and a carrier carrying the carrying layer. The catalyst using the alloy containing platinum and iron can make the cell have a high output. By making the alloy containing platinum and iron an alloy that contains one kind or more of elements out of third components having affinity with iron, elution of iron into the electrolyte can be prevented. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：解决的问题：提供一种能够维持电池的耐久性并且能够使电池具有高输出量的含有铂和铁的燃料电池用阴极催化剂。解决方案：这是一种用于燃料电池的阴极催化剂，其包括由含有铂，铁以及另外一种或多种钨，钛，钼，铼，锌，锰等元素的合金构成的载体层，作为与铁具有亲和性的第三成分的锡，钽和铑以及承载层的载体。使用含有铂和铁的合金的催化剂可以使电池具有高产量。通过使含有铂和铁的合金是含有与铁具有亲和性的第三成分中的一种以上的元素的合金，可以防止铁向电解液中的溶出。版权所有（C）2005，JPO＆NCIPI

10. 发明专利

JP2003045442A Noble metal-base metal alloy based catalyst, its evaluation and method for manufacturing it 有权
标题翻译：贵金属基金属合金催化剂，其评估及制造方法
公开(公告)号：JP2003045442A
公开(公告)日：2003-02-14
申请号：JP2001235958
申请日：2001-08-03
申请人： Toyota Motor Corp , トヨタ自動車株式会社
发明人： KATO HISAO , ASAOKA MASAHIKO , HIROSHIMA KAZUTAKA
IPC分类号： B01J37/025 , H01M4/86 , H01M4/88 , H01M4/90 , H01M4/92 , H01M8/02 , H01M8/04 , H01M8/10
CPC分类号： H01M4/881 , H01M4/8605 , H01M4/92 , H01M4/926 , H01M8/1004 , Y02P70/56
摘要： PROBLEM TO BE SOLVED: To manufacture a fuel cell having high performance by accurately and simply evaluating the performance of the fuel cell. SOLUTION: Iron is reduced by carrying platinum as one of noble metals and iron as one of base metals on carbon having a large specific surface, and by heating the iron to a reducible temperature. A platinum-iron alloy based electrode catalyst thus obtained has a high function as a catalyst, and the IR correction voltage of a fuel cell manufactured by using it is high. This kind of electrode catalyst is a new catalyst and can be specified by numerical values, such as the adsorption quantity of carbon monoxide which is 14 Ncc or more per 1 gram of platinum, the ratio of the number of Pt atoms to the number of Fe atoms by EDX analysis which is 0.14 or more, or the ratio of the number of coupling of both atoms by EXAFS analysis which is 0.1 or more. The electrode catalyst can be evaluated with these numerical values, and the fuel cell having high performance can be manufactured by manufacturing by using the evaluation result.
摘要翻译：要解决的问题：通过准确且简单地评估燃料电池的性能来制造具有高性能的燃料电池。解决方案：通过将铂作为贵金属之一和作为具有大比表面积的碳上的贱金属之一的铁，并通过将铁加热至可还原温度来还原铁。由此获得的铂 - 铁合金基电极催化剂作为催化剂具有高功能，并且通过使用它制造的燃料电池的IR校正电压高。这种电极催化剂是一种新的催化剂，可以通过数值来表示，例如每1克铂为14Ncc以上的一氧化碳的吸附量，Pt原子数与Fe的比例原子通过EDX分析为0.14以上，或通过EXAFS分析的两个原子的偶合数比例为0.1以上。可以用这些数值评价电极催化剂，通过使用评价结果可以制造具有高性能的燃料电池。

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