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    • 2. 发明专利
    • MANUFACTURE OF SEMICONDUCTOR DEVICE
    • JPS60149149A
    • 1985-08-06
    • JP481984
    • 1984-01-17
    • HITACHI LTD
    • TADAKI YOSHITAKANAKADA MASAYUKIMOTOYOSHI MAKOTOSAKAI YOSHIOKAWAMOTO YOSHIFUMI
    • H01L27/08H01L21/316H01L21/76
    • PURPOSE:To provide an isolation groove in self-alignment by a method wherein a well pattern is made of an insulation film or the like, the side surface of which pattern is coated with an organic film, and an Si substrate is deeply etched only at the region of the side surface. CONSTITUTION:An SiO2 9, an Si3N4 8, and a CVDSiO2 7 are laminated on the Si substrate 6, and the film 7 is processed with a resist mask 10; then, a wall of organic film 11 is formed on the side surfaces of the films 10 and 7. The film 8 is etch-removed after implantation of phosphorus ions 12 with the films 10 and 11 as a mask. The masks 10 and 11 are removed, and an SiO2 13 is produced by heat treatment. After implantation of boron ions 14 with the SiO2's 7 and 13 as a mask, the groove 15 is provided by etching the films 8' and 9 and the substrate 6, and the films 7 and 13 are removed. Next, the whole is covered with an SiO2 16, and boron ions 17 are implanted after removal of an Si3N4 8''; then, a P-well 23 and an N-well 24 are formed by annealing. An Si3N4 mask 18 is formed with a photo resist 20, and the surface inversion of the P-well 23 is prevented by implanting boron ions 19. The resist 20 is removed and an SiO2 21 is formed, and the groove is filled with poly Si or SiO2; beside, an Si3N4 18 is removed, resulting in the completion of a CMOS. This construction enables the isolation groove for latch-up prevention to be provided in self-alignment.
    • 6. 发明专利
    • SEMICONDUCTOR DEVICE AND MANUFACTURE THEREOF
    • JPS60249345A
    • 1985-12-10
    • JP10451784
    • 1984-05-25
    • HITACHI LTD
    • KAWAMOTO YOSHIFUMINAKADA MASAYUKI
    • H01L21/76H01L21/763
    • PURPOSE:To obtain good performance of element isolation without crystal defects in a semiconductor substrate by advancing the initial oxidation outside a groove by a method wherein a semiconductor or conductor larger than the upper part of the groove is formed over the groove. CONSTITUTION:The groove 102 is formed in a P type Si substrate 101. A double- layer film 103 of SiO2 and Si3N4 is formed on the surface of the Si substrate, and the first polycrystalline Si 104 and the second polycrystalline Si 105 are left at the groove section. The multilayer film 103 is left in the active region A, and boron is ion-implanted after the multilayer film of the element isolation region B is removed by etching. Next, using the multilayer film 103 as a mask, the polycrystalline Si 105, part of the polycrystalline Si 104 in the groove, and the surface of the substrate 101 are oxidized, resulting in the formation of an SiO2 film 106. Thereafter, the exposed multilayer film 103 of the active region A is removed, and a gate insulation film 107, a gate electrode 108, N type impurity layers 109 and 110 of high concentration, and a phosphosilicate glass 111 are formed. A contact hole is bored, and an aluminum electrode 112 is formed; accordingly, a MOS type transistor is produced. This manner eliminates the generation of crystal defects accompanying the oxidation of the SiO2 film 106.
    • 7. 发明专利
    • ELEMENT ISOLATION METHOD OF SEMICONDUCTOR DEVICE
    • JPS6080244A
    • 1985-05-08
    • JP18687583
    • 1983-10-07
    • HITACHI LTD
    • KAWAMOTO YOSHIFUMIKURE TOKUONAKADA MASAYUKIOKAZAKI SHINJI
    • H01L21/76H01L21/762
    • PURPOSE:To reduce stress to a substrate and eliminate generation of crystal defect by vertically providing many pole-like projections consisting of substrate within a groove without filling the groove provided in the isolation region with an oxide at one time on the occasion of insulating and isolating a pluality of semiconductor elements formed on the semiconductor substrate but instead changing it to an oxide in expanded volume by the heat processing and filling the groove with the oxide. CONSTITUTION:On the occasion of providing element isolation regions between the active regions 208 formed on the semiconductor substrate 204, the SiO2 film 205 and Si3N4 film 206 are stacked and deposited on the entire part of substrate. Next, the active region 208 is covered with a resist film 207 and a groove 213 for element isolation is formed by the etching. In this case, the groove 213 is not provided entirely and many pole-like projections 210 consisting of substrate 204 having the films 206 and 205 at the surface vertically remain herein. Thereafter, the projections 210 is changed to oxide in expanded volume by the heat processing and simultaneously the oxide directly connected thereto is generated at the bottom surface. After this area is buried with the oxide 212, the films 206 and 205 are removed.
    • 10. 发明专利
    • MANUFACTURING METHOD OF SEMICONDUCTOR DEVICE
    • JPH0374878A
    • 1991-03-29
    • JP21007189
    • 1989-08-16
    • HITACHI LTD
    • JINRIKI HIROSHINAKADA MASAYUKIMUKAI KIICHIRO
    • H01L29/78H01L21/8242H01L27/108H01L29/72
    • PURPOSE:To obtain an IGFET using a transition metal oxide film especially for a gate insulation film by penetrating the gate insulation film without performing light oxidation and by implanting ion. CONSTITUTION:An SiO2 is provided on the surface of a p-type Si substrate 1 for implanting a channel of BF2. The SiO2 film is eliminated and a tantalum pentoxide 2 is sputtered. Treatment is performed within dry O2 at 800 deg.C and an SiO2 film 3 is formed between the substrate 1 and the tantalum pentoxide 2. Then, a W film 4 is sputtered and a PSG 5 is superposed. The PSG 5 is subjected to patterning and the W film 4 is machined with the PSG 5 as a mask. Then, As ion is implanted, thermal treatment is performed within N2 for producing an n layer 6, and a drain layer is provided in self-aligned manner to a W gate pattern. Further, an interlayer insulation film 7 is superposed and a wiring metal film 8 is provided for completing an FET. With this method, it is possible to form an IGFET without performing light oxidation even if a material with an extremely rapid diffusion of an oxidation seed such as tantalum pentoxide is used as a gate insulation film.