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    • 11. 发明专利
    • ION IMPLANTATION DEVICE
    • JPS643950A
    • 1989-01-09
    • JP15862987
    • 1987-06-25
    • HITACHI LTD
    • OSE YOICHITAKAGI TOSHIYUKISANO HIROKIMIKI KAZUYOSHI
    • H01J37/147H01J37/317H01L21/265
    • PURPOSE:To improve the mass separation performance by constituting a rear- stage accelerating/decelerating electrode system with the first electrode on the upstream side, the grounded second electrode on the downstream side facing a mass separating slit, and an intermediate electrode provided between the first and second electrodes and having an ion beam passing hole larger than the holes of the first and second electrodes. CONSTITUTION:A rear-stage accelerating/decelerating electrode system 4 is constituted of the first electrode 41 facing a mass separating magnet 3, the grounded second electrode 42 facing a mass separating slit 9, and an intermediate electrode 43 having an ion passing hole larger than the ion beam passing holes of the first electrode 41 and the second electrode 42 and provided between them. Virtual convex lens and concave lens formed by the potential difference between electrodes of the rear-stage accelerating/decelerating electrode system 4 can be made equal in thickness, and an ion beam can be focused most thinly at the position of the mass separating slit. The mass separation performance can be thereby improved.
    • 13. 发明专利
    • ION TRAP TYPE MASS SPECTROMETER AND ION TRAP MASS SPECTROMETRY
    • JP2000243347A
    • 2000-09-08
    • JP3974799
    • 1999-02-18
    • HITACHI LTD
    • YOSHINARI KIYOMIOSE YOICHINAKAJIMA FUMIHIKOKATO YOSHIAKI
    • H01J49/42G01N27/62G01N30/72H01J49/06
    • PROBLEM TO BE SOLVED: To increase ion concentration of a sample and to make mass spectrometry with high resolution and a high S/N ratio by deflecting an ion beam containing the ionized sample, and feeding the ion beam containing ions with the selected mass to an ion trap type mass spectrometric section. SOLUTION: A mixed sample subject to mass spectrometry is component-separated by a preprocessing system 2, the mixed sample and a solvent are ionized by an ionization section 3, unnecessary ions and neutral molecules are removed by a deflection mass selection section 10, and the mixed sample is fed to an ion trap type mass spectrometric section 5 through a focusing lens system 4. The mass spectrometric section 5 is composed of a ring electrode 51 and end cap electrodes 52, 53 facing each other across the ring electrode 51, and a DC voltage and a high-frequency voltage are applied between the electrodes from a high-frequency voltage power supply 8 to form the quadrupole electric field between the electrodes. An ion beam from the focusing lens system 4 is fed between the ring electrode 51 and the end cap electrodes 52, 53 through a center port 13, is captured by the quadrupole electric field, and is detected by a detector 6 through a center port 55, then a mass spectrum is obtained as the final analysis result.
    • 15. 发明专利
    • SCANNING ELECTRON MICROSCOPE
    • JPH10208683A
    • 1998-08-07
    • JP6189798
    • 1998-02-27
    • HITACHI LTD
    • SATO MITSUGIOSE YOICHIFUKUHARA SATORUTODOKORO HIDEOESUMI MAKOTO
    • H01J37/244H01J37/28H01J37/29
    • PROBLEM TO BE SOLVED: To enhance the detection efficiency by detecting both secondary electrons and reflected electrons together, by arranging a detector to cover the trajectories of reflected electrons and the secondary electrons for depicting the deflected trajectories orbit, and providing the detector on the electron source side from an objective lens. SOLUTION: A signal from a reflected electron detector 121 is inputted to a variable amplifier 160, and a signal from the secondary electron detector 120 is inputted to a variable amplifier 162 and after amplification they are converted to digital signals by means of A/D converters 178, 180 to be input to a data bus 158. Those signals are subjected to signal processing by means of CPU 150 for storing the data signals in a storage device 152. Signals of reflected electrons and the secondary electrons stored in the storage device 152 or processed signals are used, so that CPU 150 display on a display device 125 such as CRT, via an interface 156, a reflected electron image of the sample, secondary electron image and an expanded sample image due to the processed signals.
    • 16. 发明专利
    • MASS ANALYSIS METHOD AND DEVICE THEREOF
    • JPH08287866A
    • 1996-11-01
    • JP8707195
    • 1995-04-12
    • HITACHI LTD
    • YOSHINARI KIYOMIOSE YOICHIKATO YOSHIAKI
    • G01N27/62H01J49/42
    • PURPOSE: To provide a high-speed and high-resolution ion trap mass analyzer by controlling an auxiliary voltage, an amplitude factor of a high frequency voltage, and a scan speed of a high frequency voltage amplitude. CONSTITUTION: An ion trap is composed of a ring electrode 6, and two end cap electrodes 7, 8 disposed to face each other having the ring electrode 6 between them. A sample as subject to mass analysis which passes from a sample source 1 through a sample introducing part 2 to be injected to space between the electrodes collides with an electron getting through a center port 12 of the end cap electrode 7 into the space between the electrodes to be ionized. By a main power supply 4 for operation, a quadrupole electric field is generated in the space 15 between the electrodes by a DC voltage U and a high frequency voltage Vcos Ωt supplied into between the end cap electrodes 7, 8 and the ring electrodes 6. For causing resonance of ions as subject to detection to be radiated, a separate voltage from the quadrupole electric field to generate a micro-electric field is applied to between the end cap electrodes 7, 8 by an auxiliary voltage source 11, and a control part 3 adjusts an amplitude ratio between the resonance voltage and the high frequency voltage, and determines mass scan speed to radiate the ions from a detection port 13 in accordance with necessary resolution for each ion as subject to detection.
    • 19. 发明专利
    • SCANNING ELECTRON MICROSCOPE
    • JPH06181041A
    • 1994-06-28
    • JP33408892
    • 1992-12-15
    • HITACHI LTD
    • OSE YOICHIHIGUCHI YOSHIYAYOSHINARI KIYOMI
    • H01J37/141H01J37/28
    • PURPOSE:To provide a scanning electron microscope in which the yield of a secondary electron can be increased up to 100% and also aberration can be reduced, thereby making it feasible to perform observation with high resolution. CONSTITUTION:A primary electron beam 1 passes through a deflection coil 7 and then is throw on a sample 3. At that time, a magnetic field made by an objective lens is spread over the sample 3 and the upper space and the primary electron beam 1 is focused to a degree of being several nm in diameter. With the primary electron beam thrown on the sample 3, a secondary electron 2 is emitted from the sample 3 with angular distribution. Since the energy of secondary electron 2 is as low as several eV, the secondary electron 2 is twisted about the magnetic flux of the objective lens 5 to go up as it is making spiral motion. The magnetic flux density abruptly goes down apart from the direction of the sample, and the secondary electron is shaked off from the spiral motion to evaporate and then is deflected with the attracting electric field from a secondary electron detector 4 and is caught by the secondary electron detector 4.