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    • 2. 发明申请
    • PHOTORESIST COMPOSITION
    • 光电组合物
    • US20130137038A1
    • 2013-05-30
    • US13482595
    • 2012-05-29
    • Mingqi LiAmad AqadCong LiuChing-Lung ChenShintaro YamadaCheng-bai XuJoseph Mattia
    • Mingqi LiAmad AqadCong LiuChing-Lung ChenShintaro YamadaCheng-bai XuJoseph Mattia
    • G03F7/004
    • G03F7/004G03F7/0045G03F7/0397
    • A photoresist composition comprises an acid-sensitive polymer, and a cyclic sulfonium compound having the formula: (Ra)1—(Ar)—S+(—CH2—)m·−O3S—(CRb2)n-(L)p-X wherein each Ra is independently a substituted or unsubstituted C1-30 alkyl group, C6-30 aryl group, C7-30 aralkyl group, or combination comprising at least one of the foregoing, Ar is a monocyclic, polycyclic, or fused polycyclic C6-30 aryl group, each Rb is independently H, F, a linear or branched C1-10 fluoroalkyl or a linear or branched heteroatom-containing C1-10 fluoroalkyl, L is a C1-30 linking group optionally comprising a heteroatom comprising O, S, N, F, or a combination comprising at least one of the foregoing heteroatoms, X is a substituted or unsubstituted, C5 or greater monocyclic, polycyclic or fused polycyclic cycloaliphatic group, optionally comprising a heteroatom comprising O, S, N, F, or a combination comprising at least one of the foregoing, and 1 is an integer of 0 to 4, m is an integer of 3 to 20, n is an integer of 0 to 4, and p is an integer of 0 to 2.
    • 光致抗蚀剂组合物包含酸敏感性聚合物和具有下式的环状锍化合物:(Ra)1-(Ar)-S +( - CH2-)m·-O3S-(CRb2)n-(L) R a独立地是取代或未取代的C 1-30烷基,C 6-30芳基,C 3-30芳烷基或包含至少一个前述的组合,Ar是单环,多环或稠合多环C 6-30芳基 ,每个R b独立地是H,F,直链或支链C 1-10氟代烷基或含有直链或支链含杂原子的C 1-10氟代烷基,L是任选地包含O,S,N,F 或包含至少一个前述杂原子的组合,X是取代或未取代的C5或更大单环,多环或稠合的多环脂环族基团,任选地包含包含O,S,N,F的杂原子,或包含在 上述中的至少一个,1为0〜4的整数,m为3〜20的整数,n为In 0〜4的整数,p为0〜2的整数。
    • 5. 发明授权
    • Surface active additive and photoresist composition comprising same
    • 包含其的表面活性添加剂和光致抗蚀剂组合物
    • US08722825B2
    • 2014-05-13
    • US13482574
    • 2012-05-29
    • Deyan WangChunyi WuCong LiuGerhard PohlersCheng-bai XuGeorge G. Barclay
    • Deyan WangChunyi WuCong LiuGerhard PohlersCheng-bai XuGeorge G. Barclay
    • C08F226/06C08F214/18C08F220/34
    • G03F7/0397C08F220/18C08F220/24C08F220/32C08F220/34C08F220/36C08F220/38C08F220/58C08F226/06C08F2220/1833C08F2220/283G03F7/0045G03F7/0046G03F7/09G03F7/2041
    • A polymer comprises the polymerized product of monomers comprising a nitrogen-containing monomer comprising formula (Ia), formula (Ib), or a combination of formulas (Ia) and (Ib), and an acid-deprotectable monomer having the formula (II): wherein a is 0 or 1, each Ra is independently H, F, C1-10 alkyl, or C1-10 fluoroalkyl, L1 is a straight chain or branched C1-20 alkylene group, or a monocyclic, polycyclic, or fused polycyclic C3-20 cycloalkylene group, each Rb is independently H, C1-10 alkyl, C3-20 cycloalkyl, C3-20 heterocycloalkyl, an aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group, where each Rb is separate or at least one Rb is attached to an adjacent Rb; LN is a nitrogen-containing monocyclic, polycyclic, or fused polycyclic C3-20 heterocycloalkylene group, and X is H, C1-10 alkyl, aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group; and each Rc is independently C1-10 alkyl, C3-20 cycloalkyl, or C3-20 heterocycloalkyl, wherein each Rc is separate or at least one Rc is attached to an adjacent Rc.
    • 聚合物包含包含式(Ia),式(Ib)或式(Ia)和(Ib)的组合的含氮单体的单体的聚合产物和具有式(II)的酸可去保护的单体, :其中a为0或1,每个R a独立地为H,F,C 1-10烷基或C 1-10氟烷基,L 1为直链或支链C 1-20亚烷基,或单环,多环或稠合多环C3 -20个亚环烷基,每个R b独立地为H,C 1-10烷基,C 3-20环烷基,C 3-20杂环烷基,脂族C 5-20氧羰基或任选地包含杂原子取代基的C1-30酰基,其中每个R b 是分开的或至少一个Rb连接到相邻的Rb; LN是含氮单环,多环或稠合多环C 3-20杂环亚烷基,X是H,C 1-10烷基,脂肪族C 5-20氧羰基或任选包含杂原子取代基的C 1-3酰基; 并且每个R c独立地为C 1-10烷基,C 3-20环烷基或C 3-20杂环烷基,其中每个R c是分开的或至少一个R c连接到相邻的Rc。
    • 6. 发明申请
    • SURFACE ACTIVE ADDITIVE AND PHOTORESIST COMPOSITION COMPRISING SAME
    • 表面活性添加剂和包含其的光电组合物
    • US20130137035A1
    • 2013-05-30
    • US13482574
    • 2012-05-29
    • Deyan WangChunyi WuCong LiuGerhard PohlersCheng-bai XuGeorge G. Barclay
    • Deyan WangChunyi WuCong LiuGerhard PohlersCheng-bai XuGeorge G. Barclay
    • C08F220/34C08F226/06
    • G03F7/0397C08F220/18C08F220/24C08F220/32C08F220/34C08F220/36C08F220/38C08F220/58C08F226/06C08F2220/1833C08F2220/283G03F7/0045G03F7/0046G03F7/09G03F7/2041
    • A polymer comprises the polymerized product of monomers comprising a nitrogen-containing monomer comprising formula (Ia), formula (Ib), or a combination of formulas (Ia) and (Ib), and an acid-deprotectable monomer having the formula (II): wherein a is 0 or 1, each Ra is independently H, F, C1-10 alkyl, or C1-10 fluoroalkyl, L1 is a straight chain or branched C1-20 alkylene group, or a monocyclic, polycyclic, or fused polycyclic C3-20 cycloalkylene group, each Rb is independently H, C1-10 alkyl, C3-20 cycloalkyl, C3-20 heterocycloalkyl, an aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group, where each Rb is separate or at least one Rb is attached to an adjacent Rb; LN is a nitrogen-containing monocyclic, polycyclic, or fused polycyclic C3-20 heterocycloalkylene group, and X is H, C1-10 alkyl, aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group; and each Rc is independently C1-10 alkyl, C3-20 cycloalkyl, or C3-20 heterocycloalkyl, wherein each Rc is separate or at least one Rc is attached to an adjacent Rc.
    • 聚合物包含包含式(Ia),式(Ib)或式(Ia)和(Ib)的组合的含氮单体的单体的聚合产物和具有式(II)的酸可去保护的单体, :其中a为0或1,每个R a独立地为H,F,C 1-10烷基或C 1-10氟烷基,L 1为直链或支链C 1-20亚烷基,或单环,多环或稠合多环C3 -20个亚环烷基,每个R b独立地为H,C 1-10烷基,C 3-20环烷基,C 3-20杂环烷基,脂族C 5-20氧羰基或任选地包含杂原子取代基的C1-30酰基,其中每个R b 是分开的或至少一个Rb连接到相邻的Rb; LN是含氮单环,多环或稠合多环C 3-20杂环亚烷基,X是H,C 1-10烷基,脂肪族C 5-20氧羰基或任选包含杂原子取代基的C 1-3酰基; 并且每个R c独立地为C 1-10烷基,C 3-20环烷基或C 3-20杂环烷基,其中每个R c是分开的或至少一个R c连接到相邻的Rc。