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    • 1. 发明授权
    • Surface active additive and photoresist composition comprising same
    • 包含其的表面活性添加剂和光致抗蚀剂组合物
    • US08722825B2
    • 2014-05-13
    • US13482574
    • 2012-05-29
    • Deyan WangChunyi WuCong LiuGerhard PohlersCheng-bai XuGeorge G. Barclay
    • Deyan WangChunyi WuCong LiuGerhard PohlersCheng-bai XuGeorge G. Barclay
    • C08F226/06C08F214/18C08F220/34
    • G03F7/0397C08F220/18C08F220/24C08F220/32C08F220/34C08F220/36C08F220/38C08F220/58C08F226/06C08F2220/1833C08F2220/283G03F7/0045G03F7/0046G03F7/09G03F7/2041
    • A polymer comprises the polymerized product of monomers comprising a nitrogen-containing monomer comprising formula (Ia), formula (Ib), or a combination of formulas (Ia) and (Ib), and an acid-deprotectable monomer having the formula (II): wherein a is 0 or 1, each Ra is independently H, F, C1-10 alkyl, or C1-10 fluoroalkyl, L1 is a straight chain or branched C1-20 alkylene group, or a monocyclic, polycyclic, or fused polycyclic C3-20 cycloalkylene group, each Rb is independently H, C1-10 alkyl, C3-20 cycloalkyl, C3-20 heterocycloalkyl, an aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group, where each Rb is separate or at least one Rb is attached to an adjacent Rb; LN is a nitrogen-containing monocyclic, polycyclic, or fused polycyclic C3-20 heterocycloalkylene group, and X is H, C1-10 alkyl, aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group; and each Rc is independently C1-10 alkyl, C3-20 cycloalkyl, or C3-20 heterocycloalkyl, wherein each Rc is separate or at least one Rc is attached to an adjacent Rc.
    • 聚合物包含包含式(Ia),式(Ib)或式(Ia)和(Ib)的组合的含氮单体的单体的聚合产物和具有式(II)的酸可去保护的单体, :其中a为0或1,每个R a独立地为H,F,C 1-10烷基或C 1-10氟烷基,L 1为直链或支链C 1-20亚烷基,或单环,多环或稠合多环C3 -20个亚环烷基,每个R b独立地为H,C 1-10烷基,C 3-20环烷基,C 3-20杂环烷基,脂族C 5-20氧羰基或任选地包含杂原子取代基的C1-30酰基,其中每个R b 是分开的或至少一个Rb连接到相邻的Rb; LN是含氮单环,多环或稠合多环C 3-20杂环亚烷基,X是H,C 1-10烷基,脂肪族C 5-20氧羰基或任选包含杂原子取代基的C 1-3酰基; 并且每个R c独立地为C 1-10烷基,C 3-20环烷基或C 3-20杂环烷基,其中每个R c是分开的或至少一个R c连接到相邻的Rc。
    • 2. 发明申请
    • SURFACE ACTIVE ADDITIVE AND PHOTORESIST COMPOSITION COMPRISING SAME
    • 表面活性添加剂和包含其的光电组合物
    • US20130137035A1
    • 2013-05-30
    • US13482574
    • 2012-05-29
    • Deyan WangChunyi WuCong LiuGerhard PohlersCheng-bai XuGeorge G. Barclay
    • Deyan WangChunyi WuCong LiuGerhard PohlersCheng-bai XuGeorge G. Barclay
    • C08F220/34C08F226/06
    • G03F7/0397C08F220/18C08F220/24C08F220/32C08F220/34C08F220/36C08F220/38C08F220/58C08F226/06C08F2220/1833C08F2220/283G03F7/0045G03F7/0046G03F7/09G03F7/2041
    • A polymer comprises the polymerized product of monomers comprising a nitrogen-containing monomer comprising formula (Ia), formula (Ib), or a combination of formulas (Ia) and (Ib), and an acid-deprotectable monomer having the formula (II): wherein a is 0 or 1, each Ra is independently H, F, C1-10 alkyl, or C1-10 fluoroalkyl, L1 is a straight chain or branched C1-20 alkylene group, or a monocyclic, polycyclic, or fused polycyclic C3-20 cycloalkylene group, each Rb is independently H, C1-10 alkyl, C3-20 cycloalkyl, C3-20 heterocycloalkyl, an aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group, where each Rb is separate or at least one Rb is attached to an adjacent Rb; LN is a nitrogen-containing monocyclic, polycyclic, or fused polycyclic C3-20 heterocycloalkylene group, and X is H, C1-10 alkyl, aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group; and each Rc is independently C1-10 alkyl, C3-20 cycloalkyl, or C3-20 heterocycloalkyl, wherein each Rc is separate or at least one Rc is attached to an adjacent Rc.
    • 聚合物包含包含式(Ia),式(Ib)或式(Ia)和(Ib)的组合的含氮单体的单体的聚合产物和具有式(II)的酸可去保护的单体, :其中a为0或1,每个R a独立地为H,F,C 1-10烷基或C 1-10氟烷基,L 1为直链或支链C 1-20亚烷基,或单环,多环或稠合多环C3 -20个亚环烷基,每个R b独立地为H,C 1-10烷基,C 3-20环烷基,C 3-20杂环烷基,脂族C 5-20氧羰基或任选地包含杂原子取代基的C1-30酰基,其中每个R b 是分开的或至少一个Rb连接到相邻的Rb; LN是含氮单环,多环或稠合多环C 3-20杂环亚烷基,X是H,C 1-10烷基,脂肪族C 5-20氧羰基或任选包含杂原子取代基的C 1-3酰基; 并且每个R c独立地为C 1-10烷基,C 3-20环烷基或C 3-20杂环烷基,其中每个R c是分开的或至少一个R c连接到相邻的Rc。
    • 7. 发明授权
    • Compositions and processes for photolithography
    • 光刻的组成和工艺
    • US09507260B2
    • 2016-11-29
    • US12592160
    • 2009-11-19
    • Deyan WangChunyi WuCheng-Bai XuGeorge G. Barclay
    • Deyan WangChunyi WuCheng-Bai XuGeorge G. Barclay
    • G03F7/039G03F7/20G03F7/004G03F7/038G03F7/11G03F7/075
    • G03F7/0046G03F7/0382G03F7/0392G03F7/0397G03F7/0757G03F7/11G03F7/2041
    • New photoresist compositions are provided that are useful for immersion lithography. In one preferred aspect, photoresist composition are provided that comprise: (i) one or more resins that comprise photoacid-labile groups, (ii) a photoactive component, and (iii) one or more materials that comprise photoacid labile groups and that are distinct from the one or more resins; wherein the deprotection activation energy of photoacid-labile groups of the one or more materials is about the same as or lower than the deprotection activation energy of photoacid-labile groups of the one or more resins. In another preferred aspect, photoresist compositions are provided that comprise (i) one or more resins, (ii) a photoactive component, and (iii) one or more materials that comprise a sufficient amount of acidic groups to provide a dark field dissolution rate of at least one angstrom per second.
    • 提供了可用于浸没式光刻的新的光致抗蚀剂组合物。 在一个优选的方面,提供光致抗蚀剂组合物,其包含:(i)一种或多种包含光酸不稳定基团的树脂,(ii)光活性组分,和(iii)一种或多种包含光致酸不稳定基团并且是不同的 从一种或多种树脂; 其中所述一种或多种材料的光致酸不稳定基团的去保护活化能大约等于或低于所述一种或多种树脂的光致酸不稳定基团的去保护活化能。 在另一个优选的方面,提供光致抗蚀剂组合物,其包含(i)一种或多种树脂,(ii)光活性组分,和(iii)一种或多种包含足够量的酸性基团以提供暗场溶解速率的材料 每秒至少一埃。
    • 8. 发明申请
    • Compositions and processes for photolithography
    • 光刻的组成和工艺
    • US20100304290A1
    • 2010-12-02
    • US12592160
    • 2009-11-19
    • Deyan WangChunyi WuCheng-Bai XuGeorge G. Barclay
    • Deyan WangChunyi WuCheng-Bai XuGeorge G. Barclay
    • G03F7/20G03B27/52G03F7/004
    • G03F7/0046G03F7/0382G03F7/0392G03F7/0397G03F7/0757G03F7/11G03F7/2041
    • New photoresist compositions are provided that are useful for immersion lithography. In one preferred aspect, photoresist composition are provided that comprise: (i) one or more resins that comprise photoacid-labile groups, (ii) a photoactive component, and (iii) one or more materials that comprise photoacid labile groups and that are distinct from the one or more resins; wherein the deprotection activation energy of photoacid-labile groups of the one or more materials is about the same as or lower than the deprotection activation energy of photoacid-labile groups of the one or more resins. In another preferred aspect, photoresist compositions are provided that comprise (i) one or more resins, (ii) a photoactive component, and (iii) one or more materials that comprise a sufficient amount of acidic groups to provide a dark field dissolution rate of at least one angstrom per second.
    • 提供了可用于浸没式光刻的新的光致抗蚀剂组合物。 在一个优选的方面,提供光致抗蚀剂组合物,其包含:(i)一种或多种包含光酸不稳定基团的树脂,(ii)光活性组分,和(iii)一种或多种包含光致酸不稳定基团并且是不同的 从一种或多种树脂; 其中所述一种或多种材料的光致酸不稳定基团的去保护活化能大约等于或低于所述一种或多种树脂的光致酸不稳定基团的去保护活化能。 在另一个优选的方面,提供光致抗蚀剂组合物,其包含(i)一种或多种树脂,(ii)光活性组分,和(iii)一种或多种包含足够量的酸性基团以提供暗场溶解速率的材料 每秒至少一埃。