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    • 10. 发明授权
    • Polymerization using late transition metal catalyst complexes formed in situ
    • 使用晚期形成的过渡金属催化剂复合物进行聚合
    • US06506859B1
    • 2003-01-14
    • US09642487
    • 2000-08-18
    • Abhimanyu O. PatilRobert T. StibranyStephen ZushmaEnock BerlucheDonald N. Schulz
    • Abhimanyu O. PatilRobert T. StibranyStephen ZushmaEnock BerlucheDonald N. Schulz
    • C08F442
    • C08F10/00C08F110/02C08F210/02C08F4/54C08F2500/03C08F220/12
    • The invention is directed towards the formation of polymers and copolymers using late transition metal polymerization catalyst complexes which are formed in situ. In the first process step of the instant invention, a composition having the formula MXZn is simultaneously contacted with a ligand and an activating cocatalyst. Referring to the formula, M is selected from the group consisting of Cu, Ag, and Au; X is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, and any other moiety into which a monomer can insert; Z is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, a neutral coordinating ligand, and any other moiety into which a monomer can insert; n equals 0, 1 or 2. In the second process step of the instant invention, olefinic monomers are contacted with the activated catalyst composition under polymerization conditions.
    • 本发明涉及使用在原位形成的后过渡金属聚合催化剂络合物形成聚合物和共聚物。 在本发明的第一工艺步骤中,具有式MXZn的组合物与配体和活化助催化剂同时接触。 参考式,M选自Cu,Ag和Au; X选自卤化物,氢化物,三氟甲磺酸盐,乙酸盐,硼酸盐,C1至C12烷基,C1至C12烷氧基,C3至C12环烷基,C3至C12环烷氧基,芳基,硫醇盐,一氧化碳,氰酸盐,烯烃和 单体可以插入的任何其他部分; Z选自卤化物,氢化物,三氟甲磺酸盐,乙酸盐,硼酸盐,C1至C12烷基,C1至C12烷氧基,C3至C12环烷基,C3至C12环烷氧基,芳基,硫醇盐,一氧化碳,氰酸盐,烯烃, 中性配位配体和单体可插入的任何其它部分; n等于0,1或2.在本发明的第二工艺步骤中,烯烃单体在聚合条件下与活化的催化剂组合物接触。