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1. 发明授权

US06506859B1 Polymerization using late transition metal catalyst complexes formed in situ 失效
标题翻译：使用晚期形成的过渡金属催化剂复合物进行聚合
公开(公告)号：US06506859B1
公开(公告)日：2003-01-14
申请号：US09642487
申请日：2000-08-18
申请人： Abhimanyu O. Patil , Robert T. Stibrany , Stephen Zushma , Enock Berluche , Donald N. Schulz
发明人： Abhimanyu O. Patil , Robert T. Stibrany , Stephen Zushma , Enock Berluche , Donald N. Schulz
IPC分类号： C08F442
CPC分类号： C08F10/00 , C08F110/02 , C08F210/02 , C08F4/54 , C08F2500/03 , C08F220/12
摘要： The invention is directed towards the formation of polymers and copolymers using late transition metal polymerization catalyst complexes which are formed in situ. In the first process step of the instant invention, a composition having the formula MXZn is simultaneously contacted with a ligand and an activating cocatalyst. Referring to the formula, M is selected from the group consisting of Cu, Ag, and Au; X is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, and any other moiety into which a monomer can insert; Z is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, a neutral coordinating ligand, and any other moiety into which a monomer can insert; n equals 0, 1 or 2. In the second process step of the instant invention, olefinic monomers are contacted with the activated catalyst composition under polymerization conditions.
摘要翻译：本发明涉及使用在原位形成的后过渡金属聚合催化剂络合物形成聚合物和共聚物。在本发明的第一工艺步骤中，具有式MXZn的组合物与配体和活化助催化剂同时接触。参考式，M选自Cu，Ag和Au; X选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃和单体可以插入的任何其他部分; Z选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃，中性配位配体和单体可插入的任何其它部分; n等于0,1或2.在本发明的第二工艺步骤中，烯烃单体在聚合条件下与活化的催化剂组合物接触。

2. 发明申请

US20080221275A1 Ethylene/dicyclopentadiene/norbornene terpolymer materials having desirable structural and thermal properties 审中-公开
标题翻译：乙烯/二环戊二烯/降冰片烯三元共聚物材料具有理想的结构和热性能
公开(公告)号：US20080221275A1
公开(公告)日：2008-09-11
申请号：US12074213
申请日：2008-02-29
申请人： Lisa S. Baugh , Enock Berluche , Abhimanyu O. Patil , Beverly J. Poole , Kevin D. Robinson , Kevin R. Squire
发明人： Lisa S. Baugh , Enock Berluche , Abhimanyu O. Patil , Beverly J. Poole , Kevin D. Robinson , Kevin R. Squire
IPC分类号： C08F4/76 , C08F36/00 , C08F36/04 , C08F4/80
CPC分类号： C08C19/06 , C08F8/04 , C08F8/08 , C08F210/02
摘要： Provided are selected types of terpolymer components comprising terpolymers having monomer units derived from ethylene (E), dicyclopentadiene (DCPD) and norbornene-based (NB) co-monomers. Such terpolymer components have certain specified amounts of each co-monomer as well as certain specified molecular weight and glass transition temperature characteristics. Terpolymer components which are derivatized by hydrogenation and/or by epoxidation and/or hydroxylation are also disclosed, as well as thermoplastic polyolefin compositions which contain the terpolymer components and which have especially desirable structural and thermal properties.Also provided are processes for preparing and derivatizing the terpolymer components herein. Such preparation processes comprise: a) contacting ethylene with a polymerization mixture comprising selected amounts of both DCPD and NB co-monomers, in the presence of a selected activated cyclopentadienyl-fluorenyl metallocene catalyst under specific polymerization conditions to thereby form the desired ethylene-dicyclopentadiene-norbornene terpolymer components within the polymerization mixture. These terpolymer components can then be subsequently derivatized by hydrogenation or functionalization of the residual double bonds therein.
摘要翻译：提供了包含来自乙烯（E），二环戊二烯（DCPD）和降冰片烯基（NB））共聚单体的单体单元的三元共聚物的选择类型的三元共聚物组分。这些三元共聚物组分具有特定量的每种共聚单体以及某些特定的分子量和玻璃化转变温度特性。还公开了通过氢化和/或通过环氧化和/或羟基化衍生化的三元共聚物组分，以及含有三元共聚物组分并且具有特别期望的结构和热性质的热塑性聚烯烃组合物。还提供了用于制备和衍生本文中三元共聚物组分的方法。这样的制备方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂存在下，在特定的聚合条件下，使乙烯与包含选定量的DCPD和NB共聚单体的聚合混合物接触，从而形成所需的乙烯 - 二环戊二烯 - 降冰片烯三元共聚物组分在聚合混合物内。然后可以通过氢化或官能化其中的残余双键将这些三元共聚物组分衍生化。

3. 发明授权

US07498390B2 Chromium complexes and their use in olefin polymerization 失效
标题翻译：铬络合物及其在烯烃聚合中的应用
公开(公告)号：US07498390B2
公开(公告)日：2009-03-03
申请号：US11904057
申请日：2007-09-25
申请人： Smita Kacker , Enock Berluche , Robert T. Stibrany , Joseph A. Sissano , Lisa S. Baugh
发明人： Smita Kacker , Enock Berluche , Robert T. Stibrany , Joseph A. Sissano , Lisa S. Baugh
IPC分类号： C08F4/69
CPC分类号： C07F11/005 , B01J31/143 , B01J31/183 , C08F110/02 , C08F4/69034
摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, ps where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.
摘要翻译：具有式I的组合物，其中R1和R2独立地为氢，C1至C12直链和支链烷基，C3至C12环烷基，芳基，C1至C12烷氧基，F，C1，SO3，C1至C12全氟烷基和N（CH3） 2，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 3至C 12环烷基，芳基和2,2,2-三氟乙基，A是-C（R 4） - ， - （CH 2） x - ， - （CH 2）x NH（CH 2）x - 或-CY 2 CY 2 - ，其中R 4是烃基，卤代烃基或具有1至12个碳原子的烷氧基，x是1至12的整数， Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。当与活化助催化剂组合时，可用于聚合烯烃单体。

4. 发明授权

US07297805B2 Chromium complexes and their use in olefin polymerization 有权
标题翻译：铬络合物及其在烯烃聚合中的应用
公开(公告)号：US07297805B2
公开(公告)日：2007-11-20
申请号：US11152802
申请日：2005-06-14
申请人： Smita Kacker , Enock Berluche , Robert T. Stibrany , Joseph A. Sissano , Lisa S. Baugh
发明人： Smita Kacker , Enock Berluche , Robert T. Stibrany , Joseph A. Sissano , Lisa S. Baugh
IPC分类号： C07F11/00 , C08F4/69
CPC分类号： C07F11/005 , B01J31/143 , B01J31/183 , C08F110/02 , C08F4/69034
摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.
摘要翻译：具有式I的组合物，其中R 1和R 2独立地是氢，C 1至C 12直链和支链烷基，C 3至C 12环烷基，芳基，C 1至C 12烷氧基，F， Cl，SO 3，C 1至C 12全氟烷基和N（CH 3 3）2 R 3，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 1〜 C 1 -C 4 - （CH 3） - ，其中C（R 4） - ， x（CH 2）2 - ， - （CH 2 CH 2）x NH 2（CH 2））其中R 4是烃基，卤代烃基，卤代烃基，或1至12个碳原子的烷氧基，x是1至12的整数，Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。当与活化助催化剂组合时，可用于聚合烯烃单体。

5. 发明授权

US07498287B2 Chromium complexes and their use in olefin polymerization 失效
标题翻译：铬络合物及其在烯烃聚合中的应用
公开(公告)号：US07498287B2
公开(公告)日：2009-03-03
申请号：US11904056
申请日：2007-09-25
申请人： Smita Kacker , Enock Berluche , Robert T. Stibrany , Joseph A. Sissano , Lisa S. Baugh
发明人： Smita Kacker , Enock Berluche , Robert T. Stibrany , Joseph A. Sissano , Lisa S. Baugh
IPC分类号： C08F4/69
CPC分类号： C07F11/005 , B01J31/143 , B01J31/183 , C08F110/02 , C08F4/69034
摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful polymerizing olefinic monomers.
摘要翻译：具有式I的组合物，其中R1和R2独立地为氢，C1至C12直链和支链烷基，C3至C12环烷基，芳基，C1至C12烷氧基，F，C1，SO3，C1至C12全氟烷基和N（CH3） 2，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 3至C 12环烷基，芳基和2,2,2-三氟乙基，A是-C（R 4） - ， - （CH 2） x - ， - （CH 2）x NH（CH 2）x - 或-CY 2 CY 2 - ，其中R 4是烃基，卤代烃基或具有1至12个碳原子的烷氧基，x是1至12的整数，Y 是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。当与活化助催化剂组合时，有用的是使烯烃单体聚合。

6. 发明授权

US07504465B2 Linear functional copolymers of ethylene with precise and minimum run length distributions and methods of making thereof 失效
标题翻译：具有精确和最小游程长度分布的乙烯的线性官能团共聚物及其制备方法
公开(公告)号：US07504465B2
公开(公告)日：2009-03-17
申请号：US12214189
申请日：2008-06-17
申请人： Lisa S. Baugh , Stephen E. Lehman, Jr. , Kenneth B. Wagener , Donald N. Schulz , Enock Berluche
发明人： Lisa S. Baugh , Stephen E. Lehman, Jr. , Kenneth B. Wagener , Donald N. Schulz , Enock Berluche
IPC分类号： C08F216/36
CPC分类号： C08F210/02 , C08F210/16 , C08F4/80 , C08F236/20 , C08F2500/02 , C08F2500/03 , C08F220/10 , C08F218/00 , C08F218/08 , C08F232/00
摘要： The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.
摘要翻译：本发明涉及具有重复单元A，B和D的线性官能聚合物。单元A表示-CH 2 - ，单元B表示，单元D表示其中R 1表示极性官能团。每个B单元，每个D单元和每个B和D单元分开至少四个A单元。值y表示B个单位的总数，并且是大于或等于1的整数.D单位的总数由h表示，并且是大于或等于0的整数。x表示A的总数单位，并且是足以使线性官能聚合物中B和D单元的摩尔分数由以下等式定义的值j表示的整数： < 数学溢出=“滚动”> j = y + h x + y +

7. 发明申请

US20080312393A1 Linear functional copolymers of ethylene with precise and minimum run length distributions and methods of making thereof 失效
标题翻译：具有精确和最小游程长度分布的乙烯的线性官能团共聚物及其制备方法
公开(公告)号：US20080312393A1
公开(公告)日：2008-12-18
申请号：US12214189
申请日：2008-06-17
申请人： Lisa S. Baugh , Stephen E. Lehman, JR. , Kenneth B. Wagener , Donald N. Schulz , Enock Berluche
发明人： Lisa S. Baugh , Stephen E. Lehman, JR. , Kenneth B. Wagener , Donald N. Schulz , Enock Berluche
IPC分类号： C08F4/80
CPC分类号： C08F210/02 , C08F210/16 , C08F4/80 , C08F236/20 , C08F2500/02 , C08F2500/03 , C08F220/10 , C08F218/00 , C08F218/08 , C08F232/00
摘要： The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.
摘要翻译：本发明涉及具有重复单元A，B和D的线性官能聚合物。单元A表示-CH 2 - ，单元B表示，单元D表示其中R 1表示极性官能团。每个B单元，每个D单元和每个B和D单元分开至少四个A单元。值y表示B个单位的总数，并且是大于或等于1的整数.D单位的总数由h表示，并且是大于或等于0的整数。x表示A的总数单位，并且是足以使线性官能聚合物中B和D单元的摩尔分数由以下等式定义的值j表示的整数： < 数学溢出=“滚动”> j = y + h x + y +

8. 发明授权

US4663408A Tetrapolymers of N-vinyl pyrrolidone/acrylamide/salt of acrylic acid/N-alkyl acrylamide 失效
标题翻译： N-乙烯基吡咯烷酮/丙烯酰胺/丙烯酸/ N-烷基丙烯酰胺盐的四元共聚物
公开(公告)号：US4663408A
公开(公告)日：1987-05-05
申请号：US814362
申请日：1985-12-30
申请人： Donald N. Schulz , Enock Berluche , John J. Maurer , Jan Bock
发明人： Donald N. Schulz , Enock Berluche , John J. Maurer , Jan Bock
IPC分类号： C08F8/12 , C09K8/12 , C09K8/588 , C08F20/06
CPC分类号： C09K8/588 , C08F8/44 , C09K8/12
摘要： The present invention relates to improved viscosification agents for an aqueous or brine solutions. Typically, the viscosification agents are tetrapolymers of N-vinyl pyrrolidone/acrylamide/salt of acrylic acid/N-alkyl acrylamide wherein said tetrapolymers have the formula: ##STR1## wherein w is about 1 to about 80 mole percent, more preferably about 5 to about 75 mole percent, and most preferably about 10 to about 70 mole percent; x is about 10 to about 90 mole percent, more preferably about 20 to about 80 mole percent, and most preferably about 30 to about 70 mole percent; and y is about 0.1 to about 10.0 mole percent, more preferably about 0.15 to about 5.0 mole percent; and most preferably about 0.2 to about 3.0 mole percent; z is about 1.0 to about 30.0 mole percent, more preferably about 2.0 to about 25.0 mole percent, and most preferably about 5.0 to about 20.0 mole percent; R is an alkyl group having about 6 to about 30 carbon atoms, more preferably about 7 to about 20, and most preferably about 8 to about 18; and M is a cation selected from the group consisting of monovalent cations, preferably Na.sup.+, K.sup.+ or R.sub.4 N.sup.+.
摘要翻译：本发明涉及用于水溶液或盐水溶液的改进的增粘剂。通常，增粘剂是N-乙烯基吡咯烷酮/丙烯酰胺/丙烯酸/ N-烷基丙烯酰胺盐的四元共聚物，其中所述四元共聚物具有下式：其中w为约1至约80摩尔％，更优选约5至约75摩尔％，最优选约10至约70摩尔％; x为约10至约90摩尔％，更优选约20至约80摩尔％，最优选约30至约70摩尔％ y为约0.1至约10.0摩尔％，更优选约0.15至约5.0摩尔％; 最优选约0.2至约3.0摩尔％; z为约1.0至约30.0摩尔％，更优选约2.0至约25.0摩尔％，最优选约5.0至约20.0摩尔％ R是具有约6至约30个碳原子，更优选约7至约20，最优选约8至约18的烷基; 并且M是选自一价阳离子，优选Na +，K +或R 4 N +的阳离子。

9. 发明授权

US4650848A Terpolymers of acrylamide, alkylacrylamide and betaine monomers 失效
标题翻译：丙烯酰胺，烷基丙烯酰胺和甜菜碱单体的三元共聚物
公开(公告)号：US4650848A
公开(公告)日：1987-03-17
申请号：US814252
申请日：1985-12-30
申请人： Donald N. Schulz , Ilan Duvdevani , Jan Bock , Enock Berluche
发明人： Donald N. Schulz , Ilan Duvdevani , Jan Bock , Enock Berluche
IPC分类号： C08F220/56 , C08F20/56
CPC分类号： C08F220/56
摘要： A water soluble terpolymer having the structure: ##STR1## wherein x is selected from the group consisting of ##STR2## wherein x is about 1 to about 95 mole percent; y is about 0.1 to about 5.0 mole percent; R.sub.1 is methyl or hydrogen; z is about 1 to about 30 mole percent; R.sub.2 is an alkyl group of 1-5 carbon atoms; R.sub.3 is an alkyl group of 3 to 4 carbon atoms; R.sub.4 is an alkyl group of 1-5 carbon atoms; and R.sub.5 is an alkyl group of 4-20.
摘要翻译：具有以下结构的水溶性三元共聚物：其中x选自由下列组成的组：其中x为约1至约95摩尔％; y为约0.1至约5.0摩尔％; R1是甲基或氢; z为约1至约30摩尔％; R2是1-5个碳原子的烷基; R3是3〜4个碳原子的烷基; R4是1-5个碳原子的烷基; R5为4-20的烷基。

10. 发明授权

US07402642B2 Linear functional copolymers of ethylene with precise and minimum run length distributions and method of making thereof 失效
标题翻译：具有精确和最小游程长度分布的乙烯的线性官能团共聚物及其制备方法
公开(公告)号：US07402642B2
公开(公告)日：2008-07-22
申请号：US10962086
申请日：2004-10-08
申请人： Lisa S. Baugh , Stephen E. Lehman, Jr. , Kenneth B. Wagener , Donald N. Schulz , Enock Berluche
发明人： Lisa S. Baugh , Stephen E. Lehman, Jr. , Kenneth B. Wagener , Donald N. Schulz , Enock Berluche
IPC分类号： C08F216/36
CPC分类号： C08F210/02 , C08F210/16 , C08F4/80 , C08F236/20 , C08F2500/02 , C08F2500/03 , C08F220/10 , C08F218/00 , C08F218/08 , C08F232/00
摘要： The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.
摘要翻译：本发明涉及具有重复单元A，B和D的线性官能聚合物。单元A表示-CH 2 - ，单元B表示，单元D表示其中R 1 表示极性官能团。每个B单元，每个D单元和每个B和D单元分开至少四个A单元。值y表示B个单位的总数，并且是大于或等于1的整数.D单位的总数由h表示，并且是大于或等于0的整数。x表示A的总数单位，并且是足以使线性官能聚合物中B和D单元的摩尔分数由以下等式定义的值j表示的整数： < MATH OVERFLOW =“SCROLL”> j = y + h x + y + > <= 0.032

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