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1. 发明申请

US20070135593A1 Halogen substituted metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的金属茂化合物
公开(公告)号：US20070135593A1
公开(公告)日：2007-06-14
申请号：US11300002
申请日：2005-12-14
申请人： Alexander Voskoboynikov , Alexey Ryabov , Mikhail Nikulin , Alexander Lygin , Vyatcheslav Izmer , Andrey Asachenko , Catalina Coker , Jo Ann Canich
发明人： Alexander Voskoboynikov , Alexey Ryabov , Mikhail Nikulin , Alexander Lygin , Vyatcheslav Izmer , Andrey Asachenko , Catalina Coker , Jo Ann Canich
IPC分类号： B01J31/00 , C08F4/44 , C07F17/00
CPC分类号： C07F17/00 , Y10S526/941 , Y10S526/943
摘要： A metallocene compound comprises a transition metal and at least one substituted monocyclic or polycyclic arene ligand bonded to the transition metal, wherein said arene ligand comprises at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of an aromatic five-membered ring of said arene ligand.
摘要翻译：茂金属化合物包含过渡金属和至少一个与过渡金属键合的取代的单环或多环芳族配体，其中所述芳族配体包含至少一个直接连接到sp 2 O 2原子上的卤素取代基所述芳族配体的芳族五元环的可键合环位置。

2. 发明申请

US20060160968A1 Process for producing substituted metallocene compounds for olefin polymerization 失效
公开(公告)号：US20060160968A1
公开(公告)日：2006-07-20
申请号：US11302997
申请日：2005-12-14
申请人： Alexander Voskoboynikov , Alexey Ryabov , Catalina Coker , Jo Ann Canich
发明人： Alexander Voskoboynikov , Alexey Ryabov , Catalina Coker , Jo Ann Canich
IPC分类号： C08F4/44 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.

3. 发明申请

US20060160967A1 Halogen substituted metallocene compounds for olefin polymerization 失效
标题翻译：用于烯烃聚合的卤素取代的金属茂化合物
公开(公告)号：US20060160967A1
公开(公告)日：2006-07-20
申请号：US11300032
申请日：2005-12-14
申请人： Alexander Voskoboynikov , Mikhail Nikulin , Vyatcheslav Izmer , Andrey Asachenko , Alexey Ryabov , Catalina Coker , Jo Ann Canich
发明人： Alexander Voskoboynikov , Mikhail Nikulin , Vyatcheslav Izmer , Andrey Asachenko , Alexey Ryabov , Catalina Coker , Jo Ann Canich
IPC分类号： C08F4/44 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A metallocene compound comprising a transition metal, a first substituted or unsubstituted indenyl or fluorenyl ligand pi-bonded to the transition metal, a second monoanionic ligand bonded to the transition metal, and a divalent bridging group bonded to the indenyl ligand and said second monoanionic ligand, wherein said bridging group is connected to the four, five, six or seven position of the indenyl ligand or to the one, two, three, four, five, six, seven or eight position of the fluorenyl ligand, and wherein at least one of one of the first and second ligands comprises at least one halogen substituent directly bonded to any sp2 carbon atom at a bondable ring position of the ligand.
摘要翻译：包含过渡金属，与过渡金属键合的第一取代或未取代的茚基或芴基配体的金属茂化合物，与过渡金属键合的第二单离子配体和键合到茚基配体和所述第二单离子配体的二价桥连基团其中所述桥连基团连接到茚基配体的四，五，六或七位，或连接到芴基配体的一个，二个，三个，四个，五个，六个，七个或八个位置，并且其中至少一个第一和第二配体之一包含在配体的可键合环位置处直接键合到任何sp 2 O 2碳原子上的至少一个卤素取代基。

4. 发明申请

US20060135353A1 Metallocene complexes, their synthesis and use in catalyst systems for olefin polymerization 有权
公开(公告)号：US20060135353A1
公开(公告)日：2006-06-22
申请号：US11284885
申请日：2005-11-22
申请人： Yanlong Qian , Jiling Huang , Jo Ann Canich , Catalina Coker
发明人： Yanlong Qian , Jiling Huang , Jo Ann Canich , Catalina Coker
IPC分类号： C08F4/44 , B01J31/00 , C07F17/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F110/02 , C08F210/16 , C08F4/65925 , C08F4/6592 , C08F2500/03 , C08F210/06 , C08F210/14
摘要： A metallocene complex is represented by the the formula (CpR5)nMXk where Cp (each occurrence) is a cyclopentadienyl group; each of the five R substituents on the or each cyclopentadienyl group is independently selected from hydrogen, C1 to C30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure, and SiR′2NR″2 where each of the two R′ substituents is independently selected from hydrogen, C1 to C30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R′ substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure, and each of the two R″ substituents is independently selected from C2 to C30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R″ substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure; n is 1 or 2; M is a metal of valence m from Groups 4 to 11 of the Periodic Table of Elements, k is equal to m minus n and the or each X substituent is a univalent anionic ligand, or two X substituents are joined and bound to the metal atom to form a metallocycle ring, or two X substituents are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand, provided that at least one R substituent on the or one cyclopentadienyl group is SiR′2NR″2, provided that at least one R substituent on at least one Cp is SiR′2NR″2 and provided that one or the Cp may be bridged by a bridging group to another Cp group, or a heteroatom containing group, where the bridging group replaces one R group on the Cp group(s) or a hydrogen on a heteratom containing group.

5. 发明申请

US20050239980A1 Phosphorus substituted metallocene compounds for olefin polymerization 失效
标题翻译：用于烯烃聚合的磷取代的茂金属化合物
公开(公告)号：US20050239980A1
公开(公告)日：2005-10-27
申请号：US11078588
申请日：2005-03-11
申请人： Alexander Voskoboynikov , Denis Kazyulkin , Vyatcheslav Izmer , Alexey Ryabov , Jo Ann Canich
发明人： Alexander Voskoboynikov , Denis Kazyulkin , Vyatcheslav Izmer , Alexey Ryabov , Jo Ann Canich
IPC分类号： B01J31/00 , B01J31/14 , B01J31/22 , B01J31/24 , C07F5/00 , C07F17/00 , C08F4/44 , C08F4/659 , C08F10/00 , C08F110/02 , C08F210/16
CPC分类号： B01J31/2295 , B01J31/143 , B01J31/146 , B01J31/2447 , B01J31/2457 , B01J2531/0225 , B01J2531/0297 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65925 , C08F2500/03 , C08F210/14
摘要： This invention relates to a metallocene compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is an indenyl ligand that is substituted with a PR2 group in the two position of the indenyl ligand, where each R is, independently a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl substituent, and additionally, E may be substituted with 0, 1, 2, 3, 4, 5 or 6 Rn where each Rn is, independently, a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent, and optionally, two or more adjacent Rn substituents may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E or as X; each X is, independently, an univalent anionic ligand, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的茂金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是在茚基配体的两个位置被PR 2 N 2基团取代的茚基配体，其中每个R独立地是烃基，取代的烃基，卤代烃基或取代的卤代烃基取代基，另外 E可以被0,1,2,3,4,5或6个R n取代，其中每个R n独立地是烃基，取代的烃基，卤代烃基取代的卤代烃基，甲硅烷基，取代的甲硅烷基，甲硅烷基或取代的烯基羰基取代基，以及任选地，两个或多个相邻的R n取代基可以连接在一起以形成取代或未取代的，饱和的，部分不饱和的或芳族的环状或多环取代基; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体，或A可以独立地定义为E或X定义; 每个X独立地是一价阴离子配体，或者两者X连接并结合到金属原子以形成金属环，或者两者X连接形成螯合配体，二烯配体或亚烷基配体。

6. 发明申请

US20050003955A1 Late transition metal catalysts for olefin oligomerizations 有权
标题翻译：用于烯烃低聚的晚期过渡金属催化剂
公开(公告)号：US20050003955A1
公开(公告)日：2005-01-06
申请号：US10692827
申请日：2003-10-24
申请人： Baiyi Zhao , Smita Kacker , Jo Ann Canich
发明人： Baiyi Zhao , Smita Kacker , Jo Ann Canich
IPC分类号： B01J31/00 , C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06 , C08F2/00 , C08F4/00 , C08F4/70 , C08F10/00
CPC分类号： B01J31/1805 , B01J31/189 , B01J31/2295 , B01J31/2404 , B01J2231/122 , B01J2231/20 , B01J2531/80 , B01J2531/824 , B01J2531/847 , C07F15/0026 , C07F15/004 , C07F15/0053 , C07F15/006 , C07F15/0066 , C07F15/008 , C07F15/0093 , C07F15/02 , C07F15/025 , C07F15/04 , C07F15/045 , C07F15/06 , C07F15/065 , C08F10/00 , C08F4/7006
摘要： A series of novel late transition metal catalysts for olefin oligomerization have been invented. The catalysts demonstrate high activity and selectivity for linear α-olefins.
摘要翻译：已经发明了一系列用于烯烃低聚的新型后期过渡金属催化剂。催化剂表现出对线性α-烯烃的高活性和选择性。

7. 发明申请

US20090005279A1 Polyalpha-Olefin Compositions and Processes to Produce the Same 有权
标题翻译： Polyalpha-Olefin组合物及其制备方法
公开(公告)号：US20090005279A1
公开(公告)日：2009-01-01
申请号：US11995118
申请日：2006-06-02
申请人： Margaret May-Som Wu , Lisa Saunders Baugh , Jo Ann Canich , Chia Shian Chee , Mark Paul Hagemeister , Andrew Jackson , Peijun Jiang , Gordon H. Lee , Frederick Yip-Kwai Lo , Steven P. Rucker , Shakeel Tirmizi , John F. Walzer, JR. , Norman Yang
发明人： Margaret May-Som Wu , Lisa Saunders Baugh , Jo Ann Canich , Chia Shian Chee , Mark Paul Hagemeister , Andrew Jackson , Peijun Jiang , Gordon H. Lee , Frederick Yip-Kwai Lo , Steven P. Rucker , Shakeel Tirmizi , John F. Walzer, JR. , Norman Yang
IPC分类号： C10L1/20 , C08F114/14 , C08F4/42 , C10L1/16
CPC分类号： C07C11/02 , C07C2/02 , C07C2/34 , C07C5/05 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/14 , C08F110/14 , C08F210/04 , C08F210/14 , C10M107/10 , C10M143/08 , C10M2205/026 , C10M2205/0265 , C10M2205/028 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2220/024 , C10N2220/025 , C10N2220/026 , C10N2220/028 , C10N2220/033 , C10N2270/00 , C08F2500/03 , C08F2500/17 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a polyalpha-olefin (and hydrogenated analogs thereof) comprising more than 50 mole % of one or more C5 to C24 alpha-olefin monomers where the polyalpha-olefin has: a) 40 mole % or more of mm triads, b) a Bromine number of Y or greater, where Y is equal to 89.92*(V)′°5863, where V is the Kinematic Viscosity of the polyalpha-olefin measured at 100° C. in cSt, and c) 1,2 disubstituted olefins present at 7 mole % or more, preferably having Z mole % or more of units represented by the formula: where j, k and m are each, independently, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, or 22, n is an integer from 1 to 350, and where Z=8.420*Log(V)−4.048, where V is the kinematic viscosity of the polyalpha-olefin measured at 1000 C in cSt This invention also relates to process to produce such polyalpha-olefins.
摘要翻译：本发明涉及包含大于50摩尔％的一种或多种C 5〜C 24α-烯烃单体的聚α-烯烃（及其氢化类似物），其中聚α-烯烃具有：a）40摩尔％以上的mm三单元组，b ）Y或更大的溴数，其中Y等于89.92 *（V）'°5863，其中V是在100℃下在cSt中测量的聚α-烯烃的运动粘度，c）1,2二取代存在7摩尔％以上的烯烃，优选具有Z摩尔％以上的由下式表示的单元：其中j，k和m各自独立地为3，4，5，6，7，8，9，10， 11，12，13，14，15，16，17，18，19，20，21或22，n为1〜350的整数，Z = 8.420 * Log（V）-4.048，其中V为在1000℃下测量的聚α-烯烃的运动粘度在cSt中本发明还涉及生产这种聚α-烯烃的方法。

8. 发明申请

US20060183874A1 Halogen substituted metallocene compounds for olefin polymerization 有权
公开(公告)号：US20060183874A1
公开(公告)日：2006-08-17
申请号：US11300054
申请日：2005-12-14
申请人： Alexander Voskoboynikov , Alexey Ryabov , Mikhail Nikulin , Alexander Lygin , Vyatcheslav Izmer , Andrey Asachenko , Catalina Coker , Jo Ann Canich
发明人： Alexander Voskoboynikov , Alexey Ryabov , Mikhail Nikulin , Alexander Lygin , Vyatcheslav Izmer , Andrey Asachenko , Catalina Coker , Jo Ann Canich
IPC分类号： C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A metallocene compound is represented by the formula (1): A2YyMXn-2 wherein: M is a transition metal atom having a coordination number of n selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; each A is independently a substituted polycyclic arenyl ligand pi-bonded to M, each A ligand includes at least one halogen substituent directly bonded to an sp2 carbon at a bondable ring position and, when each A is a substituted indenyl ligand and y is equal to one and the ligand includes at least one chloro, bromo or iodo substituent at the 4, 5, or 6 position of the indenyl ligand, then A also includes at least one other substituent in the indenyl ligand selected from hydrocarbyl, substituted hydrocarbyl, halogen, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, substituted germylcarbyl, or other heteroatom substituents wherein the heteroatom is bonded directly to a ring carbon of the ring structure ligand and is boron, a Group 15 atom, or a Group 16 atom, preferably boron, nitrogen, oxygen, phosphorus, or sulfur; Y is an optional bridging group containing at least one Group 13, 14, 15, or 16 element and is bonded to any single position of the ring structure of A, y is zero or 1, indicating the absence (y=0) or presence (y=1) of Y; and the or each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when y is equal to 1, then A is not 5,6-dichloroindenyl or an indenyl group having a fluoro- or chloro substituent at the 7 position and a hydrocarbyl or substituted hydrocarbyl substituent at the 4 position, and provided further that when y is equal to 0, then A is not 5,6-difluoroindenyl.

9. 发明申请

US20090186995A1 Production of Propylene-Based Polymers 有权
标题翻译：丙烯基聚合物的生产
公开(公告)号：US20090186995A1
公开(公告)日：2009-07-23
申请号：US12016346
申请日：2008-01-18
申请人： Jo Ann Canich , Peijun Jiang , Gary L. Casty , Gabor Kiss , Alexander Z. Voskoboynikov
发明人： Jo Ann Canich , Peijun Jiang , Gary L. Casty , Gabor Kiss , Alexander Z. Voskoboynikov
IPC分类号： C08F2/00
CPC分类号： C08F10/06 , C08F4/65908 , C08F4/65912 , C08F210/06 , Y02P20/544 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/03 , C08F2500/17 , C08F2500/20
摘要： In a process for producing a propylene-based olefin homopolymer or copolymer, a monomer composition comprising propylene is contacted with a polymerization catalyst system under homogeneous polymerization conditions (such as solution, supersolution or supercritical conditions), wherein the polymerization catalyst system includes an activator and a bridged bis-indenyl transition metal (group 4) compound substituted with a carbazole (unsubstituted or substituted) at the 4 position.
摘要翻译：在制备丙烯类烯烃均聚物或共聚物的方法中，包含丙烯的单体组合物在均相聚合条件（例如溶液，超溶剂或超临界条件）下与聚合催化剂体系接触，其中聚合催化剂体系包括活化剂和在4位被咔唑（未取代或取代的）取代的桥连双茚基过渡金属（4族）化合物。

10. 发明申请

US20070135623A1 Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的含杂原子的茂金属化合物
公开(公告)号：US20070135623A1
公开(公告)日：2007-06-14
申请号：US11300240
申请日：2005-12-14
申请人： Alexander Voskoboynikov , Alexey Ryabov , Mikhail Nikulin , Alexander Lygin , Dmitry Uborsky , Catalina Coker , Jo Ann Canich
发明人： Alexander Voskoboynikov , Alexey Ryabov , Mikhail Nikulin , Alexander Lygin , Dmitry Uborsky , Catalina Coker , Jo Ann Canich
IPC分类号： C07F17/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配位体，其与金属原子键合，并且包含至少一个与可结合环上的sp 2碳原子键合的卤素取代基配体的位置，其中所述或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

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