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    • 5. 发明申请
    • MULTI-DENTATE LATE TRANSITION METAL CATALYST COMPLEXES AND POLYMERIZATION METHODS USING THOSE COMPLEXES
    • 多叶酸过渡金属催化剂复合物和使用这些复合物的聚合方法
    • US20050004334A1
    • 2005-01-06
    • US10893429
    • 2004-07-16
    • Lisa BoffaAbhimanyu PatilDonald SchulzRobert StibranyJoseph SissanoStephen Zushma
    • Lisa BoffaAbhimanyu PatilDonald SchulzRobert StibranyJoseph SissanoStephen Zushma
    • C07F1/00C08F4/44C08F4/54C08F10/02C08F110/02C08F210/02B01J31/00C07F1/08C07F1/10
    • C08F4/54C07F1/005C08F10/02C08F110/02C08F210/02C08F220/10
    • The instant invention provides a late transition metal complex which can be used with an activating cocatalyst to produce polymers and copolymers. The invention also provides methods for polymerizing olefins, as well as copolymers having polar monomers incorporated therein. More specifically, the invention provides a composition having the formula LMXZn, wherein M is selected from the group consisting of Cu, Ag and Au; X is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, nitrate, sulfate, nitrile, hydroxide and any other moiety into which a monomer can insert; Z is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, carbon monoxide, nitrate, nitrile, hydroxide, sulfate, olefins, water, any other neutral coordinating ligand and any other moiety into which a monomer can insert; n equals 0, 1 or 2; and L is a multi-dentate nitrogen-containing ligand.
    • 本发明提供了可与活性助催化剂一起使用以产生聚合物和共聚物的后过渡金属络合物。 本发明还提供了聚合烯烃的方法以及其中掺入极性单体的共聚物。 更具体地,本发明提供具有式LMXZn的组合物,其中M选自Cu,Ag和Au; X选自卤化物,氢化物,三氟甲磺酸盐,乙酸盐,硼酸盐,C1至C12烷基,C1至C12烷氧基,C3至C12环烷基,C3至C12环烷氧基,芳基,硫醇盐,硝酸盐,硫酸盐,腈,氢氧化物和 单体可以插入的任何其他部分; Z选自卤化物,氢化物,三氟甲磺酸盐,乙酸盐,硼酸盐,C1至C12烷基,C1至C12烷氧基,C3至C12环烷基,C3至C12环烷氧基,芳基,硫醇盐,一氧化碳,硝酸盐,腈,氢氧化物 ,硫酸盐,烯烃,水,任何其它中性配位配体和单体可插入的任何其它部分; n等于0,1或2; L是多齿氮含量配体。