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1. 发明申请

US20080071090A1 Chromium complexes and their use in olefin polymerization 失效
标题翻译：铬络合物及其在烯烃聚合中的应用
公开(公告)号：US20080071090A1
公开(公告)日：2008-03-20
申请号：US11904056
申请日：2007-09-25
申请人： Smita Kacker , Enock Berluche , Robert Stibrany , Joseph Sissano , Lisa Baugh
发明人： Smita Kacker , Enock Berluche , Robert Stibrany , Joseph Sissano , Lisa Baugh
IPC分类号： C07F11/00
CPC分类号： C07F11/005 , B01J31/143 , B01J31/183 , C08F110/02 , C08F4/69034
摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.
摘要翻译：具有式I的组合物，其中R 1和R 2独立地是氢，C 1至C 12直链和支链烷基，C 3至C 12环烷基，芳基，C 1至C 12烷氧基，F， Cl，SO 3，C 1至C 12全氟烷基和N（CH 3 3）2 R 3，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 1〜 C 1 -C 4 - （CH 3） - ，其中C（R 4） - ， x（CH 2）2 - ， - （CH 2 CH 2）x NH 2（CH 2））其中R 4是烃基，卤代烃基，卤代烃基，或1至12个碳原子的烷氧基，x是1至12的整数，Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。当与活化助催化剂组合时，可用于聚合烯烃单体。

2. 发明申请

US20080021181A1 Chromium complexes and their use in olefin polymerization 失效
公开(公告)号：US20080021181A1
公开(公告)日：2008-01-24
申请号：US11904057
申请日：2007-09-25
申请人： Smita Kacker , Enock Berluche , Robert Stibrany , Joseph Sissano , Lisa Baugh
发明人： Smita Kacker , Enock Berluche , Robert Stibrany , Joseph Sissano , Lisa Baugh
IPC分类号： C08F4/42 , B01J31/34 , C08F4/52
CPC分类号： C07F11/005 , B01J31/143 , B01J31/183 , C08F110/02 , C08F4/69034
摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.

3. 发明申请

US20050288464A1 Chromium complexes and their use in olefin polymerization 有权
标题翻译：铬络合物及其在烯烃聚合中的应用
公开(公告)号：US20050288464A1
公开(公告)日：2005-12-29
申请号：US11152802
申请日：2005-06-14
申请人： Smita Kacker , Enock Berluche , Robert Stibrany , Joseph Sissano , Lisa Baugh
发明人： Smita Kacker , Enock Berluche , Robert Stibrany , Joseph Sissano , Lisa Baugh
IPC分类号： C07F11/00 , C08F4/06 , C08F110/02
CPC分类号： C07F11/005 , B01J31/143 , B01J31/183 , C08F110/02 , C08F4/69034
摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.
摘要翻译：具有式I的组合物，其中R 1和R 2独立地是氢，C 1至C 12直链和支链烷基，C 3至C 12环烷基，芳基，C 1至C 12烷氧基，F， Cl，SO 3，C 1至C 12全氟烷基和N（CH 3 3）2 R 3，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 1〜 C 1 -C 4 - （CH 3） - ，其中C（R 4） - ， x（CH 2）2 - ， - （CH 2 CH 2）x NH 2（CH 2））其中R 4是烃基，卤代烃基，卤代烃基，或1至12个碳原子的烷氧基，x是1至12的整数，Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。当与活化助催化剂组合时，可用于聚合烯烃单体。

4. 发明申请

US20050004334A1 MULTI-DENTATE LATE TRANSITION METAL CATALYST COMPLEXES AND POLYMERIZATION METHODS USING THOSE COMPLEXES 失效
标题翻译：多叶酸过渡金属催化剂复合物和使用这些复合物的聚合方法
公开(公告)号：US20050004334A1
公开(公告)日：2005-01-06
申请号：US10893429
申请日：2004-07-16
申请人： Lisa Boffa , Abhimanyu Patil , Donald Schulz , Robert Stibrany , Joseph Sissano , Stephen Zushma
发明人： Lisa Boffa , Abhimanyu Patil , Donald Schulz , Robert Stibrany , Joseph Sissano , Stephen Zushma
IPC分类号： C07F1/00 , C08F4/44 , C08F4/54 , C08F10/02 , C08F110/02 , C08F210/02 , B01J31/00 , C07F1/08 , C07F1/10
CPC分类号： C08F4/54 , C07F1/005 , C08F10/02 , C08F110/02 , C08F210/02 , C08F220/10
摘要： The instant invention provides a late transition metal complex which can be used with an activating cocatalyst to produce polymers and copolymers. The invention also provides methods for polymerizing olefins, as well as copolymers having polar monomers incorporated therein. More specifically, the invention provides a composition having the formula LMXZn, wherein M is selected from the group consisting of Cu, Ag and Au; X is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, nitrate, sulfate, nitrile, hydroxide and any other moiety into which a monomer can insert; Z is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, carbon monoxide, nitrate, nitrile, hydroxide, sulfate, olefins, water, any other neutral coordinating ligand and any other moiety into which a monomer can insert; n equals 0, 1 or 2; and L is a multi-dentate nitrogen-containing ligand.
摘要翻译：本发明提供了可与活性助催化剂一起使用以产生聚合物和共聚物的后过渡金属络合物。本发明还提供了聚合烯烃的方法以及其中掺入极性单体的共聚物。更具体地，本发明提供具有式LMXZn的组合物，其中M选自Cu，Ag和Au; X选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，硝酸盐，硫酸盐，腈，氢氧化物和单体可以插入的任何其他部分; Z选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，硝酸盐，腈，氢氧化物，硫酸盐，烯烃，水，任何其它中性配位配体和单体可插入的任何其它部分; n等于0,1或2; L是多齿氮含量配体。

5. 发明申请

US20050054868A1 Use of a ionic halide free copper catalyst for the production of dialkyl carbonates 有权
标题翻译：使用不含离子卤化物的铜催化剂生产碳酸二烷基酯
公开(公告)号：US20050054868A1
公开(公告)日：2005-03-10
申请号：US10655995
申请日：2003-09-05
申请人： Robert Stibrany , Christian Mehnert , Michael Matturro
发明人： Robert Stibrany , Christian Mehnert , Michael Matturro
IPC分类号： B01J23/74 , B01J31/18 , C07C68/00 , C07C69/96
CPC分类号： B01J31/1815 , B01J23/74 , B01J31/183 , B01J2531/16 , C07C68/005 , C07C69/96
摘要： A non-corrosive process for the preparation of dialkyl carbonate by reacting carbon monoxide, alkanol and an oxygen-containing gas in the presence of a ionic halogen free copper catalyst.
摘要翻译：在一种离子型无卤素铜催化剂存在下使一氧化碳，链烷醇和含氧气体反应制备碳酸二烷基酯的非腐蚀性方法。

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