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    • 5. 发明授权
    • .OMEGA.silylalkynyl silane compound and method for preparation thereof
    • OMEGA甲硅烷基炔基硅烷化合物及其制备方法
    • US4921989A
    • 1990-05-01
    • US359897
    • 1989-06-01
    • Toshinobu IshiharaMikio EndoTohru KubotaYasuhisa Tanaka
    • Toshinobu IshiharaMikio EndoTohru KubotaYasuhisa Tanaka
    • C07F7/12C07F7/18
    • B82Y30/00B82Y40/00C07F7/12C07F7/1832C07F7/1836
    • The novel organosilicon compound of the invention is an .omega.-silylalkynyl silane compound represented by the general formula R.sub.3 SiC.tbd.C(CH.sub.2).sub.n Si(CH.sub.3).sub.m X.sub.3-m, in which each R is, independently from the others, a hydrogen atom, lower alkyl group or aryl group, X is a halogen atom or a lower alkoxy group, the subscript m is 0,1 or 2 and the subscript n is an integer in the range from 10 to 30 which forms a uniform monomolecular layer on a substrate surface with silyl ethynyl groups arranged in alignment. The compound can be prepared by a Grignard reaction starting form an .omega.-silylalkynyl halide represented by the general formula R.sub.3 SiC.tbd.C(CH.sub.2).sub.n Y, in which R and n each have the same meaning as defined above and Y is a halogen atom, and a methyl alkoxy or halosilane of the formula (CH.sub.3).sub.m SiX.sub.4-m, in which X and m each have the same meaning as defined before.
    • 本发明的新型有机硅化合物是通式为R 3 SiC 3 CF(CH 2)n Si(CH 3)m X 3-m表示的ω-甲硅烷基炔基硅烷化合物,其中R各自独立地为氢原子,低级烷基 基团或芳基,X为卤素原子或低级烷氧基,下标m为0,1或2,下标n为10〜30的整数,在基材表面上形成均匀的单分子层, 甲硅烷基乙炔基排列成对齐。 该化合物可以通过由通式R3SiC 3BOND C(CH2)nY表示的ω-甲硅烷基炔基卤化物的格利雅反应制备,其中R和n各自具有与上述相同的含义,Y是卤素原子, 式(CH3)mSiX4-m的甲基烷氧基或卤代硅烷,其中X和m各自具有与上述相同的含义。
    • 6. 发明授权
    • Terminal perfluoroalkylsilane compounds
    • 末端全氟烷基硅烷化合物
    • US5011963A
    • 1991-04-30
    • US307968
    • 1989-02-09
    • Kazufumi OgawaHideharu TamuraToshinobu IshiharaYasuhisa TanakaMikio Endou
    • Kazufumi OgawaHideharu TamuraToshinobu IshiharaYasuhisa TanakaMikio Endou
    • C07F7/12C07F7/18
    • C07F7/12C07F7/1832
    • A terminal perfluoroalkylsilane compound F(CF.sub.2).sub.m (CH.sub.2).sub.n Si(CH.sub.3).sub.p X.sub.3-p (m+n=10 to 32 carbon atoms in fluoroalkyl group) is prepared by a hydrosilylation reaction of a terminal perfluoroalkene compounds F(CF.sub.2).sub.m (CH.sub.2).sub.1+q CH.dbd.CH.sub.2 (1+q+2=n) with the hydrodiensilane HSi(CH.sub.3).sub.p X.sup.3.sub.3-p. The F(CF.sub.2).sub.m (CH.sub.2).sub.1+q CH.dbd.CH.sub.2 are synthesized by a Grignard's reaction of a Grignard's reagent X.sup.2 Mg(CH.sub.2).sub.q CH.dbd.CH.sub.2 obtained from a terminal alkenyl halogen compound X.sup.2 (CH.sub.2).sub.q CH.dbd.CH.sub.2 with a terminal fluoroalkyl halogen compound F(CF.sub.2).sub.m (CH.sub.2).sub.1 X.sup.1.The terminal perfluoroalkylsilane compound has a sufficient lubricating effect and is useful for a coating agent with long and continuous lubricity.
    • 末端全氟烷基硅烷化合物F(CF2)m(CH2)nSi(CH3)pX3-p(m + n =氟代烷基中的10至32个碳原子)通过末端全氟链烯烃化合物F(CF 2)m CH2)1 + qCH = CH2(1 + q + 2 = n)与氢二硅烷HSi(CH3)pX33-p。 F(CF 2)m(CH 2)1 + q CH = CH 2通过Grignard's反应合成,格利雅反应由末端链烯基卤素化合物X2(CH2)qCH = CH2获得的格氏试剂X2Mg(CH2)qCH = CH2与末端氟烷基卤素 化合物F(CF 2)m(CH 2)1 X 1。 末端全氟烷基硅烷化合物具有足够的润滑效果,并且可用于具有长且连续润滑性的涂布剂。
    • 7. 发明申请
    • FERRITIC STAINLESS STEEL SHEET WITH EXCELLENT THERMAL FATIGUE PROPERTIES, AND AUTOMOTIVE EXHAUST-GAS PATH MEMBER
    • 具有极好的热疲劳性能的FERRITIC不锈钢板和汽车排气通路成员
    • US20100223927A1
    • 2010-09-09
    • US12756935
    • 2010-04-08
    • Manabu OKUTakeo TomitaYosuke SumiYasuhisa Tanaka
    • Manabu OKUTakeo TomitaYosuke SumiYasuhisa Tanaka
    • F01B31/26C21D8/02C22C38/50C22C38/54C22C38/42
    • C22C38/28C22C38/20C22C38/26C22C38/32
    • Disclosed is a ferritic stainless steel sheet with excellent thermal fatigue properties, including, by mass %, 0.03% or less of C, 1.0% or less of Si, 1.5% or less of Mn, 0.6% or less of Ni, 10˜20% of Cr, 0.05˜0.30% of Ti, 0.51˜0.65% of Nb, 0˜less than 0.10% of Mo, 0.8˜2.0% of Cu, 0˜0.10% of Al, 0.0005˜0.02% of B, 0˜0.20% of V, and 0.03% or less of N, with the balance being Fe and inevitable impurities, having a composition satisfying the following equations (1) and (2) and having a structure in which ε-Cu phase grains each having a long diameter of 0.5 μm or more are present in a density of 10 or less per 25 μm2: Nb−8(C+N)≧0 . . . (1), 10Si+20Mo+30Cu+20(Ti+V)+160Nb−(Mn+Ni)≧100 . . . (2). The ferritic stainless steel sheet, having a relatively inexpensive component composition, has excellent thermal fatigue properties, and is suitable for use in an automotive exhaust-gas path member, including an exhaust manifold, a catalyst converter, a front pipe, or a center pipe.
    • 公开了一种具有优异的热疲劳特性的铁素体系不锈钢板,以质量%计含有0.03%以下的C,1.0%以下的Si,1.5%以下的Mn,0.6%以下的Ni,10〜20 Cr的%,Ti的0.05〜0.30%,Nb的0.51〜0.65%,Mo的0.10%,Cu的0.8〜2.0%,Al的0〜0.10%,B的0.0005〜0.02% 具有满足下述式(1)和(2)的组成的Fe和不可避免的杂质的平均值为0.03%以下,N 2为0.03%以下,且具有以下结构: 0.5μm以上的长径以每25μm2 :Nb-8(C + N)≥0的密度为10以下而存在。 。 。 (1),10Si + 20Mo + 30Cu + 20(Ti + V)+ 160Nb-(Mn + Ni)≥100。 。 。 (2) 具有相对便宜的组分组成的铁素体不锈钢板具有优异的热疲劳性能,并且适用于包括排气歧管,催化剂转化器,前管或中心管的汽车尾气通道构件 。
    • 9. 发明授权
    • Ultrasonic oscillator
    • 超音波振荡器
    • US4734659A
    • 1988-03-29
    • US34235
    • 1987-04-02
    • Yasuhisa TanakaHiroyuki TakeziMasami EndohMakoto Yoneda
    • Yasuhisa TanakaHiroyuki TakeziMasami EndohMakoto Yoneda
    • B06B1/06B05B17/06B06B1/02H04R3/00H03B5/32H03B5/38
    • B06B1/0253B06B2201/77
    • In an ultrasonic oscillator which comprises an ultrasonic vibrator for driving an ultrasonic vibrator horn of an ultrasonic atomizer, a balanced circuit in which the ultrasonic vibrator is connected so that a balanced condition is established with respect to the damping capacity of the ultrasonic vibrator, and amplifier means for sending a signal to the balanced circuit and which includes a feedback circuit for positively feeding back the signal output from the balanced circuit, the feedback circuit is connected to means for adjusting the feedback quantity so that, when the ultrasonic oscillator starts the oscillation, the signal feedback quantity output from the balanced circuit is adjusted to make the gain of the amplifier means much greater than 1, and when the oscillator is in the steadily oscillating condition, the signal feedback quantity output from the balanced circuit is adjusted to broaden the allowable frequency band width of the ultrasonic vibrator.
    • 在超声波振荡器中,包括用于驱动超声波雾化器的超声波振子的超声波振动器,连接超声波振子的平衡电路,使得相对于超声波振子的阻尼能力建立平衡状态,以及放大器 用于将信号发送到平衡电路并且包括用于对从平衡电路输出的信号进行正反馈的反馈电路的装置,反馈电路连接到用于调整反馈量的装置,使得当超声波振荡器开始振荡时, 调整从平衡电路输出的信号反馈量,使放大器的增益远大于1,当振荡器处于稳定的振荡状态时,调整从平衡电路输出的信号反馈量, 超声波振动器的频带宽度。
    • 10. 发明授权
    • Automatic three stage centrifugal sludge separator
    • 自动三级离心式污泥分离机
    • US4069969A
    • 1978-01-24
    • US727562
    • 1976-09-28
    • Yasuhisa Tanaka
    • Yasuhisa Tanaka
    • B04B1/18B04B11/04B04B11/00
    • B04B1/18B04B11/04
    • A centrifugal separator for fuel oil contaminated by water and sludge particles includes an inlet 41, nested separator plates 15, a clean oil outlet 1, a separated water outlet 2, and sludge outlets 48 controlled by a valve cylinder 50 closed by a water pressure chamber 32 and opened by a water pressure chamber 31. When the sludge layer 28 builds up and closes off the water discharge passage 27, the trapped water similarly builds up and overflows into chamber 33 to force piston 36 downwardly. This opens a valve 38, 39 to allow water from chamber 24 to enter chamber 31 and force the cylinder 50 downwardly to open the sludge outlets. The water in chambers 31 and 33 is slowly bled off through vent nozzles, whereby water in chamber 23 enters chamber 32 to raise the cylinder 50 and close the sludge outlets, and enters chamber 34 to raise the piston 36 and close the valve 38, 39.
    • 用于污染水和污泥颗粒的燃料油的离心分离器包括入口41,嵌套隔板15,清洁出油口1,分离出的水出口2和由阀缸50控制的污泥出口48,该阀缸由水压室 32并由水压室31打开。当污泥层28积聚并关闭排水通道27时,被捕获的水类似地积聚并溢出到室33中以迫使活塞36向下。 这打开阀门38,39以允许来自腔室24的水进入腔室31并迫使气缸50向下以打开污泥出口。 室31和33中的水通过排气喷嘴缓慢地排出,由此室23中的水进入室32以升高缸50并关闭污泥出口,并进入室34以升高活塞36并关闭阀38,39 。