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    • 4. 发明授权
    • Hair cosmetic compositions
    • 头发化妆品组合物
    • US06737050B2
    • 2004-05-18
    • US10026641
    • 2001-12-27
    • Yasuhiro DoiKeiko HasebeHiroyuki MasudaTetsuaki FukushimaUichiro NishimotoHiroshi Abe
    • Yasuhiro DoiKeiko HasebeHiroyuki MasudaTetsuaki FukushimaUichiro NishimotoHiroshi Abe
    • A61K7075
    • A61K8/898A61K8/416A61K8/44A61K8/463A61K8/60A61K8/73A61K8/891A61Q5/00A61Q5/02A61Q5/12
    • Provided are a hair cosmetic composition comprising an ether type cationic surfactant represented by the following formula (1): wherein, R1 represents a linear or branched C6-24 alkyl or alkenyl group, R2 and R4 each represents a C1-6 alkyl group or —(AO)nH (A: a C2-4 alkylene group, n: a number of from 1 to 6 with the proviso that n pieces of A may be the same or different and their sequence is optional), R3 represents a C1-6 alkyl group or —(A′O)mH (A′: a C2-4 alkylene group, m: a number of from 1 to 6 with the proviso that m pieces of A may be the same or different and their sequence is optional), and X− represents an anion; a hair cleansing composition containing the cationic surfactant(1); and a method of treating hair with these compositions. The hair cosmetic composition of the present invention can impart good flexibility and smoothness to hair not only when it is wetted but also after drying. When used as a hair cleansing composition, it provides excellent quality of foam and feeling upon use and exhibits good low-temperature stability.
    • 提供一种包含由下式(1)表示的醚型阳离子表面活性剂的毛发化妆品组合物:其中,R 1表示直链或支链的C 6-24烷基或链烯基,R 2和R 4各自 表示C 1-6烷基或 - (AO)n H(A:C 2-4亚烷基,n:1至6的数,条件是n个A可以相同或不同,它们的顺序为 可选),R 3表示C 1-6烷基或 - (A'O)m H(A':C 2-4亚烷基,m:1至6的数,条件是m个A 可以相同或不同,它们的顺序是任选的),而X“表示阴离子; 含有阳离子表面活性剂(1)的毛发清洁组合物; 以及使用这些组合物处理毛发的方法。本发明的毛发化妆品组合物可以赋予头发良好的柔韧性和光滑性,不仅当其被润湿时,而且在干燥之后。 当用作头发清洁组合物时,它提供优异的泡沫质量和使用感,并表现出良好的低温稳定性。
    • 6. 发明授权
    • Process for production of ether amine
    • 醚胺生产工艺
    • US06576794B2
    • 2003-06-10
    • US10015657
    • 2001-12-17
    • Tetsuaki FukushimaHiroyuki MasudaUichiro NishimotoHiroshi Abe
    • Tetsuaki FukushimaHiroyuki MasudaUichiro NishimotoHiroshi Abe
    • C07C25330
    • C07C253/30C07C213/02C07C255/13C07C217/08
    • A process for producing an ether amine (3), which comprises reacting a primary or secondary alcohol (1), ROH, with acrylonitrile in an amount of 0.8 to 1.2 equivalents of the alcohol (1) in the presence of an alkali metal hydroxide in an amount of not less than 0.01 part by weight, but less than 0.05 part by weight per 100 parts by weight of the alcohol (1) to obtain an alkyloxypropionitrile (2), and then adding water to the reaction system without removing the alkali metal hydroxide therefrom and effecting hydrogenation using a hydrogenation catalyst: ROH(1)+CH2=CHCN→ROCH2CH2CN(2)→ROCH2CH2CH2NH2(3) wherein R denotes a linear or branched alkyl or alkenyl group having 6 to 24 carbon atoms. Also disclosed are a process for producing an ether tertiary amine (5), R—O—CH2—CH2—CH2—N(CH2R1)2, which comprises adding an aldehyde to the resulting ether amine (3) in the presence of a metal catalyst or a Raney nickel catalyst, and a process for producing an ether quaternary ammonium salt (6), R—O—CH2—CH2—CH2—N(CH2R1)2(R2), which comprises reacting a quaternizing agent with the ether tertiary amine (5).
    • 一种制备醚胺(3)的方法,其包括在碱金属氢氧化物存在下,将伯醇或仲醇(1),ROH与丙烯腈的量为0.8至1.2当量的醇(1) 相对于每100重量份的醇(1),不少于0.01重量份,但小于0.05重量份,得到烷氧基丙腈(2),然后向反应体系中加入水而不除去碱金属 使用氢化催化剂氢化,其中R表示碳原子数为6〜24的直链或支链烷基或链烯基。 还公开了制备醚叔胺(5),RO-CH2-CH2-CH2-N(CH2R1)2的方法,其包括在金属催化剂存在下将醛加到得到的醚胺(3)中,或 阮内镍催化剂和制备醚季铵盐(6),RO-CH2-CH2-CH2-N(CH2R1)2(R2)的方法,其包括使季铵化剂与醚叔胺(5)反应, 。