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1. 发明授权

US5476597A Liquid softener composition, novel quaternary ammonium salt, and process for the preparation of said salt 失效
标题翻译：液体软化剂组合物，新型季铵盐及其制备方法
公开(公告)号：US5476597A
公开(公告)日：1995-12-19
申请号：US302213
申请日：1994-09-08
申请人： Yushi Sakata , Junichi Inokoshi , Tohru Katoh , Osamu Tachizawa , Uichiro Nishimoto , Yasuki Ohtawa , Masaaki Yamamura
发明人： Yushi Sakata , Junichi Inokoshi , Tohru Katoh , Osamu Tachizawa , Uichiro Nishimoto , Yasuki Ohtawa , Masaaki Yamamura
IPC分类号： C07C233/36 , C07C233/38 , C07C237/06 , C11D1/52 , C11D1/62 , C11D1/645 , C11D3/00 , C11D3/37 , D06M13/02 , D06M13/188 , D06M13/322 , D06M13/402 , D06M13/46 , D06M13/463
CPC分类号： C07C233/38 , C07C233/36 , C07C237/06 , C11D1/62 , C11D1/645 , C11D3/0015 , C11D3/3707 , C11D1/52
摘要： To provide an aqueous fabric softener composition, which is excellent in softening performance, elasticity and storage stability, and a quaternary ammonium salt which is useful as a softening base of this composition and nondetrimental to the natural environment because of its excellent biodegradability and a process for the preparation of this salt.The aqueous fabric softener composition of the present invention comprises from 3 to 40% by weight of a quaternary ammonium salt represented by the following formula (I), and water: ##STR1## wherein R.sup.1 and R.sup.2 represent each a C.sub.1-4 alkyl group, etc.; R.sup.3 and R.sup.4 represent each a C.sub.7-35 alkyl group, etc.; and X.sup.- represents an anion group.
摘要翻译：提供软化性能，弹性和储存稳定性优异的水性织物柔软剂组合物，和由于其优异的生物降解性而可用作该组合物的软化碱并且不利于天然环境的季铵盐，以及用于这种盐的制备。本发明的水性织物柔软剂组合物包含3至40重量％的由下式（I）表示的季铵盐和水：其中R 1和R 2各自表示C1-4 烷基等; R3和R4各自表示C7-35烷基等; X表示阴离子基团。

2. 发明授权

US5580481A Aqueous fabric softener composition, novel quaternary ammonium salt, and process for the preparation of said salt 失效
标题翻译：水性织物柔软剂组合物，新型季铵盐及其制备方法
公开(公告)号：US5580481A
公开(公告)日：1996-12-03
申请号：US410299
申请日：1995-03-24
申请人： Yushi Sakata , Junichi Inokoshi , Tohru Katoh , Osamu Tachizawa , Uichiro Nishimoto , Yasuki Ohtawa , Masaaki Yamamura
发明人： Yushi Sakata , Junichi Inokoshi , Tohru Katoh , Osamu Tachizawa , Uichiro Nishimoto , Yasuki Ohtawa , Masaaki Yamamura
IPC分类号： C07C233/36 , C07C233/38 , C07C237/06 , C11D1/52 , C11D1/62 , C11D1/645 , C11D3/00 , C11D3/37 , D06M13/02 , D06M13/188 , D06M13/322 , D06M13/402 , D06M13/46 , D06M13/463
CPC分类号： C07C233/38 , C07C233/36 , C07C237/06 , C11D1/62 , C11D1/645 , C11D3/0015 , C11D3/3707 , C11D1/52
摘要： To provide an aqueous fabric softener composition, which is excellent in softening performance, elasticity and storage stability, and a quaternary ammonium salt which is useful as a softening base of this composition and nondetrimental to the natural environment because of its excellent biodegradability, and a process for the preparation of this salt.The aqueous fabric softener composition of the present invention comprises from 8 to 40% by weight of a quaternary ammonium salt represented by the following formula (I), a quaternary ammonium salt represented by the following formula (II) or a mixture thereof, and water: ##STR1## wherein R.sup.1 and R.sup.2 represent each a C.sub.1-4 alkyl group, etc.; R.sup.3 and R.sup.4 represent each a C.sub.7-35 alkyl group, etc.; and X.sup.- represents an anion group; and ##STR2## wherein R.sup.5 and R.sup.6 represent each a C.sub.1-4 group, etc.; R.sup.7 and R.sup.8 represent each a C.sub.1-5 alkylene group, etc.; R.sup.9 and R.sup.10 represent each a C.sub.8-36 alkyl group, etc.; Q represents a C.sub.2-6 alkylene group; n is from 0 to 10; and X.sup.- represents an anion group.
摘要翻译：提供软化性，弹性和储存稳定性优异的水性织物柔软剂组合物，和由于其优异的生物降解性而可用作该组合物的软化碱并且不利于天然环境的季铵盐，以及工艺用于制备这种盐。本发明的水性织物柔软剂组合物包含8至40重量％的由下式（I）表示的季铵盐，由下式（II）表示的季铵盐或其混合物，以及水（Ⅰ）其中R1和R2各自表示C1-4烷基等; R3和R4各自表示C7-35烷基等; X表示阴离子基团; 和其中R 5和R 6表示各自为C 1-4基团的化合物（II）等。 R7和R8分别表示C1-5亚烷基等。 R9和R10各自表示C8〜36烷基等。 Q表示C2-6亚烷基; n为0〜10; X表示阴离子基团。

3. 发明授权

US5851982A Liquid softener compositions and quaternary ammonium salt 失效
标题翻译：液体软化剂组合物和季铵盐
公开(公告)号：US5851982A
公开(公告)日：1998-12-22
申请号：US619644
申请日：1996-03-27
申请人： Yuushi Sakata , Junichi Inokoshi , Osamu Tachizawa , Tohru Katoh , Uichiro Nishimoto , Yasuki Ohtawa , Akira Sakaguchi , Kohshiroh Sotoya, deceased , Noriko Yamaguchi
发明人： Yuushi Sakata , Junichi Inokoshi , Osamu Tachizawa , Tohru Katoh , Uichiro Nishimoto , Yasuki Ohtawa , Akira Sakaguchi , Kohshiroh Sotoya, deceased , Noriko Yamaguchi
IPC分类号： C07C229/12 , C11D1/62 , C11D3/00 , D06M13/463 , D06M13/46 , C07C211/62
CPC分类号： C11D1/62 , C07C229/12 , C11D3/0015 , D06M13/463 , D06M2200/50
摘要： To provide a liquid softener composition which is satisfactory in respects of softening effect, storage stability and water absorption properties, is excellent in biodegradability and is gentle with the environment. A liquid softener composition comprising 3 to 40% by weight of a quaternary ammonium salt (7-I) and water ##STR1## wherein R.sup.1 represents C.sub.20 -C.sub.44 alkyl or alkenyl group; R.sup.2, R.sup.3, and R.sup.4 are the same of different from each other and are C.sub.1 -C.sub.5 alkyl or hydroxyalkyl group; Y represents C.sub.2 -C.sub.4 alkylene group; m is a number of 0 to 20; n is an integer of 1 to 6; and X.sup.- represents an anion group.
摘要翻译： PCT No.PCT / JP95 / 01498 Sec。 371日期：1996年7月5日 102（e）日期1996年7月5日PCT提交1995年7月27日PCT公布。公开号WO96 / 03370 日期1996年2月8日为了提供在软化效果，保存稳定性和吸水性方面令人满意的液体软化剂组合物，其生物降解性优异，与环境温和。包含3-40重量％的季铵盐（7-I）和水（7-I）的液体软化剂组合物，其中R1代表C20-C44烷基或烯基; R2，R3和R4彼此相同，为C1-C5烷基或羟烷基; Y表示C2-C4亚烷基; m为0〜20的数; n为1〜6的整数。 X表示阴离子基团。

4. 发明授权

US5563111A Agricultural chemical composition comprising amine surfactants with at least one ester or amide linkage 失效
标题翻译：包含具有至少一个酯或酰胺键的胺表面活性剂的农业化学组合物
公开(公告)号：US5563111A
公开(公告)日：1996-10-08
申请号：US274718
申请日：1994-07-18
申请人： Yuichi Hioki , Keiko Hasebe , Tadayuki Suzuki , Osamu Tachizawa , Takeshi Tomifuji , Tohru Katoh , Kohshiro Sotoya , Keiichiro Tomioka , Uichiro Nishimoto , Yoshifumi Nishimoto , Yasuki Ohtawa
发明人： Yuichi Hioki , Keiko Hasebe , Tadayuki Suzuki , Osamu Tachizawa , Takeshi Tomifuji , Tohru Katoh , Kohshiro Sotoya , Keiichiro Tomioka , Uichiro Nishimoto , Yoshifumi Nishimoto , Yasuki Ohtawa
IPC分类号： A01N25/30 , A01N37/12 , A01N37/20 , A01N37/36 , A01N37/44
CPC分类号： A01N37/44 , A01N25/30 , A01N37/12 , A01N37/20 , A01N37/36 , Y10S514/946 , Y10S514/975
摘要： A method for enhancing the effectiveness of an agricultural chemical which comprises incorporating a specific enhancer into a diluted solution of the agricultural chemical.The specific enhancer is a quaternary ammonium salt or a amine.
摘要翻译：一种用于增强农药的有效性的方法，其包括将特定增强剂掺入农药的稀释溶液中。特异性增强剂是季铵盐或胺。

5. 发明授权

US07351685B2 Softener composition 失效
标题翻译：软化剂组成
公开(公告)号：US07351685B2
公开(公告)日：2008-04-01
申请号：US10368374
申请日：2003-02-20
申请人： Yasuki Ohtawa , Tohru Katoh , Uichiro Nishimoto , Yoshio Hatayama , Yohei Kaneko
发明人： Yasuki Ohtawa , Tohru Katoh , Uichiro Nishimoto , Yoshio Hatayama , Yohei Kaneko
IPC分类号： C11D1/825
CPC分类号： C11D17/047 , C11D1/40 , C11D1/52 , C11D1/523 , C11D1/526 , C11D1/528 , C11D1/62 , C11D1/645 , C11D1/886 , C11D1/90 , C11D1/92 , C11D1/94 , C11D3/001 , D06M13/402 , D06M13/419 , D06M13/463 , D06M2200/50
摘要： The present invention provides a softener composition which contains a softening base having an excellent softening effect and satisfactory biodegradability. That is, the present invention provides the softener composition which comprises (A) a nonionic compound which has at least one C5-36 alkyl or alkenyl group and an amide bond but contains no dissociative group of amino or carboxyl group; and (B) at least one member selected among (B-α) cationic or ampholytic surfactants having one C5-36 alkyl or alkenyl group or one optionally substituted aryl group and (B-β) amino compounds having at least one C5-36 alkyl or alkenyl group and salts of the compounds.
摘要翻译：本发明提供一种软化剂组合物，其含有软化性优异的软化效果和令人满意的生物降解性。也就是说，本发明提供了一种软化剂组合物，其包含（A）非离子化合物，其具有至少一个C 5〜5〜36个烷基或链烯基和酰胺键，但不含离解氨基或羧基; 和（B）选自（B-α）阳离子或两性表面活性剂中的至少一种，其具有一个C 5〜5〜36个的烷基或烯基或一个任意取代的芳基，（B-β）的氨基化合物具有至少一个C 5 -C 36 - 烷基或链烯基和该化合物的盐。

6. 发明授权

US06541444B1 Softener composition 失效
标题翻译：软化剂组成
公开(公告)号：US06541444B1
公开(公告)日：2003-04-01
申请号：US09700498
申请日：2000-12-29
申请人： Yasuki Ohtawa , Tohru Katoh , Uichiro Nishimoto , Yoshio Hatayama , Yohei Kaneko
发明人： Yasuki Ohtawa , Tohru Katoh , Uichiro Nishimoto , Yoshio Hatayama , Yohei Kaneko
IPC分类号： C11D1825
CPC分类号： C11D17/047 , C11D1/526 , C11D1/528 , C11D1/62 , C11D1/645 , C11D3/001 , C11D17/041 , D06M13/419 , D06M13/463 , D06M2200/50
摘要： The present invention provides a softener composition which contains a softening base having an excellent softening effect and satisfactory biodegradability. That is, the present invention provides the softener composition that has (A) a nonionic compound which has at least one C5-C36 alkyl or alkenyl group and an amide bond but contains no dissociative group of amino or carboxyl group; and (B) at least one member selected among (B-&agr;) cationic or ampholytic surfactants having one C5-C36 alkyl or alkenyl group or one optionally substituted aryl group and (B-&bgr;) amino compounds, having at least one C5-C36 alkyl or alkenyl group and salts of the compunds.
摘要翻译：本发明提供一种软化剂组合物，其含有软化性优异的软化效果和令人满意的生物降解性。也就是说，本发明提供了具有（A）非离子化合物的软化剂组合物，其具有至少一个C 5 -C 36烷基或烯基和酰胺键，但不含氨基或羧基的解离基团; 和（B）选自具有一个C 5 -C 36烷基或烯基或一个任选取代的芳基的（B-α）阳离子或两性表面活性剂中的至少一种，（B-β）氨基化合物具有至少一个C5-C36 烷基或链烯基和化合物的盐。

7. 发明授权

US06855682B2 Softener composition 失效
标题翻译：软化剂组成
公开(公告)号：US06855682B2
公开(公告)日：2005-02-15
申请号：US10092983
申请日：2002-03-08
申请人： Yasuki Ohtawa , Takeshi Tomifuji , Akira Sakaguchi , Tohru Katoh
发明人： Yasuki Ohtawa , Takeshi Tomifuji , Akira Sakaguchi , Tohru Katoh
IPC分类号： C11D1/40 , C11D1/42 , C11D1/44 , C11D1/62 , C11D1/645 , C11D1/72 , C11D1/74 , C11D1/835
CPC分类号： C07C213/06 , C07C213/08 , C11D1/40 , C11D1/42 , C11D1/44 , C11D1/62 , C11D1/645 , C11D1/72 , C11D1/74 , C11D1/835 , C07C219/06
摘要： A softener composition, which contains tri-long-chain alkyl quaternary ammonium salt that has been considered to be difficult to use as a softener base agent, and which can provide a softener composition that provides a sufficient softening performance, is provided with (A) a cationic surfactant comprising at least one selected from the group consisting of quaternary ammonium salts represented by the formulae (I), (II) or (III), wherein the ratio of quaternary ammonium salt represented by the formula (I) to the total amount of these salts exceeds 50 weight %, with the ratio thereof represented by (III) being set to not more than 10%, and (B) at least one nonionic surfactant. In this case, (A) may include tertiary amine. (wherein, R1, R2 and R3 represent long-chain alkyl groups, etc. having total carbon atoms of 8 to 40, which may be intersected by an ether group, an ester group or an amide group; R4 represents an alkyl group, etc. having carbon atoms of 1 to 6, and X− represents an anionic group.)
摘要翻译：（A）提供了一种软化剂组合物，其含有被认为难以用作软化剂基剂的三长链烷基季铵盐，并且可以提供提供足够的软化性能的柔软剂组合物，包含选自由式（I），（II）或（III）表示的季铵盐中的至少一种的阳离子表面活性剂，其中由式（I）表示的季铵盐与总计的这些盐超过50重量％，其由（III）表示的比例设定为不超过10％，和（B）至少一种非离子表面活性剂。在这种情况下，（A）可以包括叔胺（其中，R 1，R 2和R 3表示总碳原子数为8〜40的长链烷基等，其可以是由醚基，酯基或酰胺基相交; R 4表示碳原子数1〜6的烷基等，X 1表示阴离子基）。

8. 发明授权

US06624137B1 Softening finish composition 失效
标题翻译：软化成品组成
公开(公告)号：US06624137B1
公开(公告)日：2003-09-23
申请号：US09807894
申请日：2001-06-15
申请人： Tohru Katoh , Yohei Kaneko , Yasuki Ohtawa
发明人： Tohru Katoh , Yohei Kaneko , Yasuki Ohtawa
IPC分类号： C11D1645
CPC分类号： D06M13/368 , C11D1/528 , C11D1/62 , C11D1/645 , C11D3/001 , D06M13/332 , D06M13/372 , D06M13/405 , D06M13/419 , D06M13/463 , D06M13/467 , D06M2200/50
摘要： The present invention provides a softener exhibiting a excellent softening effect and a satisfactory biodegradability. That is, the present invention provides a softener composition comprising the following components (A) and (B): (A) an amine represented by the formula (I), a salt thereof with an acid or a quaternary product thereof, or a mixture thereof: wherein R1 represents an alkyl or hydroxyalkyl group having 1 to 4 carbon atoms, —(CmH2mO)p—H or —(CmH2mO)p—COR3; R3 represents a linear or branched alkyl or alkenyl group having 5 to 35 carbon atoms; when R1 is the alkyl or hydroxyalkyl group having 1 to 4 carbon atoms, q is a number selected from 2 to 60; when R1 is —(CmH2mO)p—H or —(CmH2mO)p—COR3, p is not less than 1 and q is not less than 2, provided that p+q equals 3 to 60; m and n are the same or different and represent 2 to 6; and m in the number of p and m in the number of q may be the same or different and (B) a quaternary ammonium salt represented by the formula (II): wherein R4 represents an alkyl group having 1 to 3 carbon atoms; R5 and R6 are the same or different and represent an alkyl group having 1 to 3 carbon atoms, —CnH2nOH or —CnH2nOCOR3; X− represents an anion; and n and R 3 have the same meanings as defined above.
摘要翻译：本发明提供具有优异的软化效果和令人满意的生物降解性的软化剂。也就是说，本发明提供一种软化剂组合物，其包含以下组分（A）和（B）：（A）由式（I）表示的胺，其与酸或其季铵盐的盐或其混合物其中R 1表示具有1至4个碳原子的烷基或羟烷基， - （CmH2mO）pH或 - （CmH2mO）p-COR3; R 3表示碳原子数为5〜35的直链状或支链状的烷基或烯基，当R 1为具有1至4个碳原子的烷基或羟烷基时，q为选自2至60的数; 当R 1为 - （C m H 2 m O）p -H或 - （C m H 2 m O）p-COR 3时，p不小于1且q不小于2，条件是p + q等于3至60; m和n相同或不同，表示2至6; m的p和m数q可以相同或不同，（B）由式（II）表示的季铵盐：其中R 4表示具有1〜3个碳原子的烷基原子 R 5和R 6相同或不同，表示具有1至3个碳原子的烷基，-C n H 2n OH或-C n H 2n OOR 3。 X“表示阴离子; 和n和R 3具有与上述相同的含义。

9. 发明授权

US07115779B2 Softener composition 有权
标题翻译：软化剂组成
公开(公告)号：US07115779B2
公开(公告)日：2006-10-03
申请号：US10967176
申请日：2004-10-19
申请人： Yasuki Ohtawa , Takeshi Tomifuji , Akira Sakaguchi , Tohru Katoh
发明人： Yasuki Ohtawa , Takeshi Tomifuji , Akira Sakaguchi , Tohru Katoh
IPC分类号： C07C211/00 , C07C213/00 , C07C215/00 , C07C217/00 , C07C221/00
CPC分类号： C07C213/06 , C07C213/08 , C11D1/40 , C11D1/42 , C11D1/44 , C11D1/62 , C11D1/645 , C11D1/72 , C11D1/74 , C11D1/835 , C07C219/06
摘要： A softener composition, which contains tri-long-chain alkyl quaternary ammonium salt that has been considered to be difficult to use as a softener base agent, and which can provide a softener composition that provides a sufficient softening performance, is provided with (A) a cationic surfactant comprising at least one selected from the group consisting of quaternary ammonium salts represented by the formulae (I), (II) or (III), wherein the ratio of quaternary ammonium salt represented by the formula (I) to the total amount of these salts exceeds 50 weight %, with the ratio thereof represented by (III) being set to not more than 10%, and (B) at least one nonionic surfactant. In this case, (A) may include tertiary amine. (wherein, R1, R2 and R3 represent long-chain alkyl groups, etc. having total carbon atoms of 8 to 40, which may be intersected by an ether group, an ester group or an amide group; R4 represents an alkyl group, etc. having carbon atoms of 1 to 6, and X− represents an anionic group.)
摘要翻译：（A）提供了一种软化剂组合物，其含有被认为难以用作软化剂基剂的三长链烷基季铵盐，并且可以提供提供足够的软化性能的柔软剂组合物，包含选自由式（I），（II）或（III）表示的季铵盐中的至少一种的阳离子表面活性剂，其中由式（I）表示的季铵盐与总计的这些盐超过50重量％，其由（III）表示的比例设定为不超过10％，和（B）至少一种非离子表面活性剂。在这种情况下，（A）可以包括叔胺。（其中，R 1，R 2，R 3和R 3代表总碳原子数为8〜40的长链烷基等，其可以被醚基，酯基或酰胺基相交; R 4表示具有1至6个碳原子的烷基等，而X-O >表示阴离子基团。）

10. 发明授权

US06521588B1 Softener composition 失效
标题翻译：软化剂组成
公开(公告)号：US06521588B1
公开(公告)日：2003-02-18
申请号：US09700497
申请日：2000-12-28
申请人： Tohru Katoh , Yasuki Ohtawa , Yohei Kaneko
发明人： Tohru Katoh , Yasuki Ohtawa , Yohei Kaneko
IPC分类号： C11D1835
CPC分类号： C11D1/645 , C11D1/40 , C11D1/42 , C11D1/52 , C11D1/62 , C11D3/001 , C11D3/0015
摘要： The present invention provides a softener composition exhibiting an excellent softening effect and high biodegradability. That is, the present invention provides a softener composition having (A) at least one quaternary ammonium salt having at least two C5-C36 alkyl or alkenyl groups which may be interrupted by an ester linkage, amide linkage or ether linkage and (B) a tertiary amino compound (I) a salt thereof or a mixture of the same: wherein R1 and R2 represent a C1-C3 alkyl, hydroxyalkyl, aminoalkyl group or the like and R3 represents a C5-C36 alkyl group which is interrupted by an ester linkage, amide linkage or ether linkage, or the like.
摘要翻译：本发明提供了具有优异的软化效果和高生物降解性的柔软剂组合物。也就是说，本发明提供了一种柔软剂组合物，其具有（A）至少一种具有至少两个可被酯键，酰胺键或醚键中断的C 5 -C 36烷基或链烯基的季铵盐，（B）叔胺化合物（I）或其盐或其混合物：其中R 1和R 2表示C 1 -C 3烷基，羟基烷基，氨基烷基等，R 3表示被酯键中断的C 5 -C 36烷基，酰胺键或醚键等。

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