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    • 1. 发明申请
    • METHOD FOR REDUCING ARSENIC CONTENT IN ARSENIC-BEARING GOLD MATERIAL
    • 降低含砷金材料中砷含量的方法
    • WO2017185158A1
    • 2017-11-02
    • PCT/CA2016/000128
    • 2016-04-28
    • ELDORADO GOLD CORPORATION
    • BEREZOWSKY, RomanSKAYMAN, PaulJl, Jinxing
    • C22B1/11C22B3/04C22B3/22C22B3/44C22B11/00C22B30/04
    • C22B1/11C22B3/08C22B3/22C22B3/44C22B11/00C22B11/04C22B30/04Y02P10/234
    • A process for reducing arsenic content from arsenic-bearing gold concentrate or other arsenic-bearing gold materials to produce the low arsenic-bearing gold concentrate. The process comprises: (i) optionally regrinding the input arsenic-bearing gold concentrate; (ii) optionally treating the reground gold concentrate with sulfuric or other aqueous acid in an acidulation step; (iii) adding oxygen, water and/or acid to the acidulated concentrate slurry and reacting them together in an autoclave at an elevated pressure and temperature in a pressure oxidation step; (iv) processing the oxidized concentrate slurry in an arsenic re-dissolution step to dissolve unstable solid arsenic compounds; (v) applying a first solid/liquid separation and wash step, comprising at least one of a thickening step, a counter current decantation (CCD) wash step, and a filter and wash step, to form a first washed slurry/solid and first acid-containing solutions; (vi) reacting the first washed slurry/solid with sulfur dioxide (and optionally sulfuric acid and/or water) in a reductive leach step; (vii) applying a second solid/liquid separation and wash step, comprising at least one of a thickening step, a CCD wash step and a filter and wash step, to form a second washed slurry/solid and second acid-containing solutions, wherein the first and second acid-containing solutions can be recycled to the acidulation and/or pressure oxidation steps; and (viii) applying an optional surface cleaning step, to produce low arsenic bearing gold concentrate.
    • 一种减少含砷的金精矿或其他含砷金材料中的砷含量以生产低含砷金精矿的方法。 该方法包括:(i)任选地重磨含有输入含砷的金精矿; (ii)任选在酸化步骤中用硫酸或其它含水酸处理重磨的金浓缩物; (iii)向酸化浓缩浆料中加入氧气,水和/或酸,并在压力氧化步骤中在升高的压力和温度下在高压釜中将它们一起反应; (iv)在砷重溶步骤中处理氧化的浓缩物浆料以溶解不稳定的固体砷化合物; (v)施加第一固/液分离和洗涤步骤,所述第一固/液分离和洗涤步骤包括增稠步骤,逆流倾析(CCD)洗涤步骤和过滤和洗涤步骤中的至少一个,以形成第一洗涤的浆料/ 含酸溶液; (vi)在还原浸出步骤中使第一次洗涤的浆料/固体与二氧化硫(和任选的硫酸和/或水)反应; (vii)施加包含增稠步骤,CCD洗涤步骤和过滤和洗涤步骤中的至少一个的第二固/液分离和洗涤步骤以形成第二洗涤的浆料/固体和第二含酸溶液,其中 第一和第二含酸溶液可循环至酸化和/或压力氧化步骤; 和(viii)应用任选的表面清洁步骤,以生产低含砷金精矿。
    • 5. 发明申请
    • METHOD AND PROCESS ARRANGEMENT OF SEPARATING ELEMENTAL SULPHUR
    • 分离元素硫的方法和工艺布置
    • WO2015086906A1
    • 2015-06-18
    • PCT/FI2014/050983
    • 2014-12-11
    • OUTOTEC (FINLAND) OY
    • SINISALO, PiaKOTIRANTA, Tuukka
    • C01B17/033C22B3/02C22B3/16
    • C01B17/033C22B1/11C22B3/02Y02P10/234
    • The invention relates to a method of separating elemental sulphur from elemental sulphur-containing starting material, wherein the method comprises a) a leaching step, wherein the starting material is contacted with a water soluble organic solvent at a temperature below the flash point of the water soluble organic solvent for leaching the elemental sulphur contained in the starting material into the water soluble organic solvent, b)a first solid-liquid separation step, wherein the water soluble organic solvent containing the elemental sulphur is separated from a leaching residue, c) a crystallization step, wherein elemental sulphur is crystallized from the water soluble organic solvent; and d) a second solid-liquid separation step, wherein the water soluble organic solvent is separated from the crystallized elemental sulphur. The invention relates also to an apparatus of separating elemental sulphur from elemental sulphur-containing starting material.
    • 本发明涉及从元素含硫起始原料中分离元素硫的方法,其中该方法包括a)浸出步骤,其中起始材料在低于水的闪点的温度下与水溶性有机溶剂接触 可溶性有机溶剂,用于将原料中所含的元素硫浸入水溶性有机溶剂中,b)第一固液分离步骤,其中含有元素硫的水溶性有机溶剂与浸出残渣分离,c) 结晶步骤,其中元素硫从水溶性有机溶剂中结晶; 和d)第二固液分离步骤,其中水溶性有机溶剂与结晶的元素硫分离。 本发明还涉及从元素含硫原料分离元素硫的装置。