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1. 发明申请

WO2015086060A1 METHOD FOR TREATING SULFIDE-FREE MINERALS 审中-公开
标题翻译：用于处理无硫化矿物的方法
公开(公告)号：WO2015086060A1
公开(公告)日：2015-06-18
申请号：PCT/EP2013/076214
申请日：2013-12-11
申请人： OUTOTEC (FINLAND) OY
发明人： SCHNEIDER, Günter , ANASTASIJEVIC, Nikola , GÜNTNER, Jochen
IPC分类号： C22B1/06
CPC分类号： C22B1/06 , C22B3/04 , C22B3/06 , C22B3/22
摘要： The present invention provides a method of producing metal oxide(s) by sulfatizing a sulfide-free ore and/or concentrate comprising the steps of providing a sulfide-free ore and/or concentrate comprising sulfide-free mineral(s); and contacting the sulfide-free ore and/or concentrate with gaseous SO3 for sulfatizing the sulfide-free mineral(s) thereby forming metal sulfate(s) and metal oxide(s).
摘要翻译：本发明提供了一种通过硫化硫化物矿石和/或浓缩物来生产金属氧化物的方法，其包括提供包含无硫化物矿物的无硫化物矿石和/或浓缩物的步骤; 并使硫化物矿石和/或浓缩物与气态SO 3接触，以使硫化物不含矿物硫化，从而形成金属硫酸盐和金属氧化物。

2. 发明申请

WO2005007898A3 METHOD FOR PROCESSING OXIDISES NICKEL-COBALT ORE (VARIANTS) 审中-公开
标题翻译：加工氧化物镍 - 钴矿的方法（变体）
公开(公告)号：WO2005007898A3
公开(公告)日：2005-05-19
申请号：PCT/RU2004000283
申请日：2004-07-22
申请人： OBSCHESTVO S OGRANICHENNOY OTV , BATSHEV VASILIY IVANOVICH , KALASHNIKOV ALEXEY VLADIMIROVI , KOLTSOV VASILIY YURIEVICH , MELNIK DMITRIY VIKTOROVICH , SINEGRIBOV VIKTOR ANDREEVICH , SHCHUKIN MIKHAIL IGOREVICH
发明人： BATSHEV VASILIY IVANOVICH , KALASHNIKOV ALEXEY VLADIMIROVI , KOLTSOV VASILIY YURIEVICH , MELNIK DMITRIY VIKTOROVICH , SINEGRIBOV VIKTOR ANDREEVICH , SHCHUKIN MIKHAIL IGOREVICH
IPC分类号： C22B1/02 , C22B1/06 , C22B23/00
CPC分类号： C22B1/02 , C22B1/06 , C22B23/043
摘要： The group of invention relates to methods for extracting nickel and cobalt from oxidises nickel-cobalt ores and makes it possible to increase a nickel extraction ratio. In the first variant, the inventive method for processing an oxidised nickel-cobalt ore consists in treating said ore with sulphuric acid associated with the transfer thereof to a soluble sulphate solution. The ore is granulated with sulphuric acid, the thus obtained granules are sulphated at a temperature of 250-450 DEG C during 1-2 hours in one or two operations. Afterwards, the water leaching of nickel sulphates and other metals is carried out, the metals being extracted from the solution by means of known methods. The first operation is carried out at a temperature of 250-300 DEG C, the second operation at a temperature of 350-450 DEG C, and the granules are sulphated with a stechiometric sulphuric acid consumption. In the second variant, the inventive method for processing the oxidised nickel-cobalt ore also consists in treating said ore with sulphuric acid associated with the transfer thereof to soluble sulphate solution. The ore is granulated with sulphuric acid in a required stechiometric quantity, the granules are calcined at a temperature ranging from 650 to 700 DEG C during 2.5-3.0 hours, afterwards the water leaching being carried out. The granule calcination is carried out until the content of soluble iron therein is attained a range of 1.0-3.9 %, said granules being sulphated at a temperature of 200-250 DEG C during 1 hour prior to the calcination thereof. In the third variant, the inventive method for processing the oxidised nickel-cobalt ore consists in treating said ore with sulphuric acid associated with the transfer thereof to a soluble sulphate solution. The ore is granulated with sulphuric acid, the granules are calcined in the atmosphere of gases produced during the oxidation of elementary sulphur or sulphides by air oxygen. Afterwards, said gases together with sulphur oxides released during the granule calcination are sent for sulphuric acid production and the granules for water leaching.
摘要翻译：本发明组涉及从氧化镍钴矿石中提取镍和钴的方法，并且可以提高镍提取率。在第一变体中，本发明的用于处理氧化的镍 - 钴矿石的方法包括用硫酸处理所述矿石并将其转移到可溶性硫酸盐溶液中。矿石用硫酸造粒，这样得到的颗粒在250-450℃的温度下硫酸化1-2小时，一次或两次操作。之后，进行硫酸镍和其它金属的水浸，通过已知方法从溶液中提取金属。第一种操作是在250-300℃的温度下进行的，第二种操作是在350-450℃的温度下进行的，并且使用硫酸化学计量法将颗粒硫酸化。在第二变体中，本发明的用于处理氧化镍钴矿的方法还包括用硫酸处理所述矿石，所述硫酸与其转移至可溶性硫酸盐溶液有关。用硫酸按要求的化学计量量将矿石制粒，在2.5-3.0小时期间将颗粒在650-700℃的温度下煅烧，然后进行水浸。进行颗粒煅烧直至其中可溶性铁的含量达到1.0-3.9％的范围，所述颗粒在煅烧前1小时在200-250℃的温度下硫酸化。在第三变体中，本发明的用于处理氧化镍钴矿石的方法包括用硫酸处理所述矿石，所述硫酸与将其转移到可溶性硫酸盐溶液中有关。将矿石用硫酸造粒，将颗粒在通过空气氧氧化元素硫或硫化物期间产生的气体的气氛中煅烧。之后，将所述气体与在颗粒煅烧过程中释放的硫氧化物一起送入硫酸生产，并将颗粒送入水浸出。

3. 发明申请

WO02048036A1 EXTRACTION OF SILICA AND MAGNESIUM COMPOUNDS FROM OLIVINE 审中-公开
标题翻译：从奥林匹亚提取二氧化硅和镁化合物
公开(公告)号：WO02048036A1
公开(公告)日：2002-06-20
申请号：PCT/NO2001/000428
申请日：2001-10-29
IPC分类号： C01B33/187 , C01F5/24 , C22B1/06 , C22B3/08 , C22B26/22
CPC分类号： C22B26/22 , C01B33/187 , C01F5/24 , C01P2006/12 , C01P2006/80 , C22B1/06 , C22B3/08 , Y02P10/234
摘要： A method is described for extraction of silica and magnesium compounds, by chemical and thermal treatment of the mineral olivine. The method comprises sulphating of olivine, where olivine is mixed with concentrated sulphuric acid at a weight ratio olivine/sulphuric acid of approx. 0.5-0.67, and by heating the mixture to approx. 250 DEG C and giving the mixture a reaction time of approx. 8 hours, and thereafter dissolve the mixture in water, whereby silica percipitates to a solid and where the silica after filtration is purified in a weak solution of soda, and eventually with a weak aqueous solution of an acid or a mixture of acids. This method provides manufacturing of a purified silica solid, leaving a filtrate consisting mainly of dissolved magnesium which after further processing is transformed to magnesium compounds.
摘要翻译：描述了通过化学和热处理矿物橄榄石来提取二氧化硅和镁化合物的方法。该方法包括硫酸化橄榄石，其中橄榄石与浓硫酸以重量比橄榄石/硫酸约约 0.5-0.67，并将混合物加热至约 250℃，给出混合物的反应时间约为 8小时，然后将混合物溶解在水中，由此二氧化硅对固体进行过滤，过滤后的二氧化硅在苏打的弱溶液中纯化，最后用弱酸的酸水溶液或酸的混合物进行纯化。该方法提供纯化的二氧化硅固体的制造，留下主要由溶解的镁组成的滤液，其进一步处理后转化为镁化合物。

4. 发明申请

WO01042518A1 METHOD OF DIGESTING METAL CONTAINING MATERIAL AT ELEVATED TEMPERATURE IN THE PRESENCE OF SULPHUR OXIDE COMPOUND SOURCE SUCH AS H2S04 审中-公开
标题翻译：在硫化氢化合物源如H2S04存在下在高温下吸收含金属材料的方法
公开(公告)号：WO01042518A1
公开(公告)日：2001-06-14
申请号：PCT/ZA2000/000245
申请日：2000-12-12
IPC分类号： C22B1/06 , C22B3/08 , C22B34/12 , C01G23/053 , C01G25/06 , C22B34/14
CPC分类号： C22B1/06 , C22B3/08 , C22B34/1213 , C22B34/125 , Y02P10/234
摘要： According to the present invention there is provided a method of digesting metal containing material comprising the steps of providing the metal containing material; and reacting the metal containing material with a source of at least one sulphur oxide compound at a furnace temperature above 340 DEG C to form at least one metal containing sulphate. The reaction product of said method may also be leached with a suitable solvent to separate certain metal values from other material in a metal containing compound.
摘要翻译：根据本发明，提供一种消化含金属材料的方法，包括提供含金属材料的步骤; 以及使所述含金属材料与至少一种硫氧化物源的源在高于340℃的炉温下反应，以形成至少一种含硫酸盐的金属。所述方法的反应产物也可以用合适的溶剂浸出，以将某些金属值与含金属化合物中的其它物质分离。

5. 发明申请

WO99063121A1 MELT AND MELT COATING SULPHATION PROCESS 审中-公开
标题翻译：熔融和熔融涂装工艺
公开(公告)号：WO99063121A1
公开(公告)日：1999-12-09
申请号：PCT/FI1999/000486
申请日：1999-06-04
IPC分类号： C22B1/06 , C22B19/02 , C22B23/00 , C22B15/00
CPC分类号： C22B1/06 , C22B19/02 , C22B23/005 , Y02P10/216
摘要： The invention relates to a method for recovering non-ferrous metals, particularly nickel, cobalt, copper, zinc, manganese and magnesium, from materials containing said metals by converting said non-ferrous metals into sulphates by means of melt and melt coating sulphation, i.e. by a thermal treatment under oxidizing conditions within a temperature range of 400 to 800 DEG C, during which a reaction mixture is formed containing at least one said non-ferrous metal, iron(III)sulphate and alkali metal sulphate, and appropriate reaction conditions are selected to substantially prevent iron(III)sulphate from thermally decomposing to hematite, and finally, said non-ferrous metals are recovered as metallic compounds. In the method of the invention, a process is formed around the melt and melt coating sulphation, which comprises nine steps. The invention is particularly characterized by the manner of pelletizing the material to be fed into step 2 with an alkali metal (Na, K) sulphate - sulphuric acid - water solution, during which the hematite (Fe2O3) contained in the feed material will at a suitable temperature react with sulphuric acid and form hydrous iron(III)sulphate which together with sodium sulphate also acts as the bonding agent required in the pelletizing.
摘要翻译：本发明涉及通过熔融和熔融涂覆硫酸化将所述有色金属转化为硫酸盐，从含有所述金属的材料中回收有色金属，特别是镍，钴，铜，锌，锰和镁的方法，即通过在400至800℃的温度范围内的氧化条件下进行热处理，其间形成含有至少一种所述有色金属，硫酸铁（III）和碱金属硫酸盐的反应混合物，合适的反应条件是被选择为基本上防止硫酸铁（III）热分解成赤铁矿，最后所述有色金属作为金属化合物回收。在本发明的方法中，在熔融和熔融涂覆硫酸化周围形成一个工艺，其包括九个步骤。本发明特别的特征在于用碱金属（Na，K）硫酸盐 - 硫酸 - 水溶液将待进料到步骤2中的材料造粒的方式，在此期间，原料中所含的赤铁矿（Fe 2 O 3）将在合适的温度与硫酸反应形成硫酸氢铁（III），与硫酸钠一起也用作造粒所需的粘合剂。

6. 发明申请

WO2015172217A1 SYSTEM AND PROCESS FOR SELECTIVE RARE EARTH EXTRACTION WITH SULFUR RECOVERY 审中-公开
标题翻译：选择性稀土吸收与硫酸还原的系统和方法
公开(公告)号：WO2015172217A1
公开(公告)日：2015-11-19
申请号：PCT/BR2015/000068
申请日：2015-05-13
申请人： VALE S.A.
发明人： TEIXEIRA, Leandro Augusto Viana , SILVA, Ruberlan Gomes
IPC分类号： C22B59/00 , C22B1/06
CPC分类号： C22B59/00 , C22B1/06 , C22B3/08 , C22B7/007 , Y02P10/234
摘要： The application relates to a process for rare earth extraction and thorium removal from monazite or bastnasite bearing ores or ore beneficiation and industrial waste containing a variable amount of rare earth elements as oxides, phosphates, carbonates or sulfates, comprising (i) controlled mixture between sulfuric acid and the material containing rare earth and (ii) water leaching under controlled conditions.
摘要翻译：本申请涉及一种用于从独居石或含有矿物矿石或矿物选矿和含有可变量的稀土元素作为氧化物，磷酸盐，碳酸盐或硫酸盐的工业废物进行稀土提取和钍去除的方法，其包括（i）硫酸酸和含稀土的材料和（ii）在受控条件下进行水浸。

7. 发明申请

WO2009069005A3 MICROBIAL PRE-TREATMENT OF DOUBLE REFRACTORY GOLD ORES 审中-公开
标题翻译：双重耐火金矿的微生物预处理
公开(公告)号：WO2009069005A3
公开(公告)日：2011-04-28
申请号：PCT/IB2008003905
申请日：2008-11-21
申请人： BARRICK GOLD CORP , YEN WAN-TAI , AMANKWAY RICHARD KWASI , CHOI YEONUK
发明人： YEN WAN-TAI , AMANKWAY RICHARD KWASI , CHOI YEONUK
IPC分类号： C22B3/18 , C22B11/00
CPC分类号： C22B11/04 , C22B1/06 , C22B1/11 , C22B3/18 , C22B3/24 , C22B11/08 , Y02P10/234
摘要： The present invention is directed to recovery of gold from refractory and double refractory ores using a fungal agent and/or culture media. The fungal agent is inoculated in the feed material to either decompose sulfide sulfur or deactivate preg robbing carbon The culture media is applied, m the absence of a microbe, to decompose some sulfide sulfur and release a portion of the gold.
摘要翻译：本发明涉及使用真菌剂和/或培养基从耐火和双重难熔矿中回收金。将真菌剂接种在饲料中以分解硫化硫或去除抢夺碳。在不存在微生物的情况下，施用培养基以分解一些硫化物硫并释放一部分金。

8. 发明申请

WO2009034482A2 PROCESS FOR RECOVERING PLATINUM GROUP METALS USING REDUCTANTS 审中-公开
标题翻译：使用还原剂回收铂族金属的方法
公开(公告)号：WO2009034482A2
公开(公告)日：2009-03-19
申请号：PCT/IB2008003610
申请日：2008-09-11
申请人： BARRICK GOLD CORP , FEKETE SIMON O , STUBINA NATHAN M , MCMULLEN JACQUES
发明人： FEKETE SIMON O , STUBINA NATHAN M , MCMULLEN JACQUES
IPC分类号： C22B11/00 , C22B1/06 , C22B5/00 , C22B5/08
CPC分类号： C22B1/06 , C22B4/00 , C22B4/04 , C22B5/02 , C22B7/04 , C22B9/10 , C22B11/02 , C22B23/025 , C22B34/32 , Y02P10/212
摘要： In the process of recovering platinum group metals from platinum group metal-and base metal-containing materials, the present invention uses reductants and a sulfur- deficient matte to aide the separation of the furnace matte from the furnace slag and therefore improve recovery of platinum group metals.
摘要翻译：在从铂族金属和贱金属的材料中回收铂族金属的过程中，本发明使用还原剂和不含硫的锍来防止炉膛与炉渣的分离，从而提高铂族金属的回收率金属。

9. 发明申请

WO2004106564A3 METHOD FOR RECOVERING AT LEAST ONE METALLIC ELEMENT LIKE CESIUM FROM ORE 审中-公开
标题翻译：从ORE恢复至少一个金属元素像CESIUM的方法
公开(公告)号：WO2004106564A3
公开(公告)日：2005-05-19
申请号：PCT/US2004015990
申请日：2004-05-21
申请人： CABOT CORP , BAKKE BART F , MADDEN DAVID
发明人： BAKKE BART F , MADDEN DAVID
IPC分类号： C01B17/96 , C01D17/00 , C01F11/18 , C01F11/46 , C22B1/06 , C22B3/44 , C22B26/10
CPC分类号： C22B1/06 , C01B17/96 , C01D17/00 , C01F11/18 , C01F11/46 , C22B3/44 , C22B26/10 , Y02P10/234
摘要： A method for recovering at least one metallic element from ore or other material is described and includes reacting ore or other material with a salt capable of recovering the metallic element from the ore or other material to form a reaction product that includes the metallic element. The method also includes recovering the metallic element from the reaction product. To remove the metallic element from the reaction product, the method can involve crushing the reaction product to form a crushed material and dissolving the crushed material in a solvent to remove the precipitates, thereby leaving a sulfate solution containing the metallic element. The method is particularly directed to the recovery of cesium from silicate- or aluminosilicate-based ore like pollucite via clinker formation by reacting the ore at elevated temperature in the presence of a metal sulfate salt.
摘要翻译：描述了一种从矿石或其他材料中回收至少一种金属元素的方法，包括使矿石或其他材料与能够从矿石或其他材料回收金属元素的盐反应形成包含金属元素的反应产物。该方法还包括从反应产物中回收金属元素。为了从反应产物中除去金属元素，该方法可以包括粉碎反应产物以形成破碎的材料，并将破碎的材料溶解在溶剂中以除去沉淀物，从而留下含有金属元素的硫酸盐溶液。该方法特别涉及通过在金属硫酸盐的存在下在升高的温度下使矿石通过熟料形成从硅酸盐或硅铝酸盐基矿石如矾石回收铯。

10. 发明申请

WO2005007898A2 METHOD FOR PROCESSING OXIDISES NICKEL-COBALT ORE (VARIANTS) 审中-公开
标题翻译：氧化镍钴矿（VARIANTS）的处理方法
公开(公告)号：WO2005007898A2
公开(公告)日：2005-01-27
申请号：PCT/RU2004/000283
申请日：2004-07-22
IPC分类号： C22B
CPC分类号： C22B1/02 , C22B1/06 , C22B23/043
摘要： The group of invention relates to methods for extracting nickel and cobalt from oxidises nickel-cobalt ores and makes it possible to increase a nickel extraction ratio. In the first variant, the inventive method for processing an oxidised nickel-cobalt ore consists in treating said ore with sulphuric acid associated with the transfer thereof to a soluble sulphate solution. The ore is granulated with sulphuric acid, the thus obtained granules are sulphated at a temperature of 250-450 DEG C during 1-2 hours in one or two operations. Afterwards, the water leaching of nickel sulphates and other metals is carried out, the metals being extracted from the solution by means of known methods. The first operation is carried out at a temperature of 250-300 DEG C, the second operation at a temperature of 350-450 DEG C, and the granules are sulphated with a stechiometric sulphuric acid consumption. In the second variant, the inventive method for processing the oxidised nickel-cobalt ore also consists in treating said ore with sulphuric acid associated with the transfer thereof to soluble sulphate solution. The ore is granulated with sulphuric acid in a required stechiometric quantity, the granules are calcined at a temperature ranging from 650 to 700 DEG C during 2.5-3.0 hours, afterwards the water leaching being carried out. The granule calcination is carried out until the content of soluble iron therein is attained a range of 1.0-3.9 %, said granules being sulphated at a temperature of 200-250 DEG C during 1 hour prior to the calcination thereof. In the third variant, the inventive method for processing the oxidised nickel-cobalt ore consists in treating said ore with sulphuric acid associated with the transfer thereof to a soluble sulphate solution. The ore is granulated with sulphuric acid, the granules are calcined in the atmosphere of gases produced during the oxidation of elementary sulphur or sulphides by air oxygen. Afterwards, said gases together with sulphur oxides released during the granule calcination are sent for sulphuric acid production and the granules for water leaching.
摘要翻译：本发明涉及从氧化镍 - 钴矿石中提取镍和钴的方法，并且可以提高镍提取率。在第一种变型中，用于处理氧化的镍钴矿石的本发明方法在于将硫酸转移到可溶性硫酸盐溶液中来处理所述矿石。矿石用硫酸造粒，所得颗粒在一个或两个操作中在1-24小时内在250-450℃的温度下硫酸化。之后，进行硫酸镍等金属的浸出，通过已知的方法从溶液中提取金属。第一次操作在250-300℃的温度下进行，第二次操作在350-450℃的温度下进行，并且以硫酸消耗硫酸化。在第二种变型中，用于处理氧化的镍钴矿石的本发明方法还包括用与其转移到可溶性硫酸盐溶液相关的硫酸处理所述矿石。矿石以所需的刻度计用硫酸造粒，颗粒在650-300℃的温度下煅烧2.5-3.0小时，然后进行水浸。进行颗粒煅烧直到其中可溶性铁的含量达到1.0-3.9％的范围，所述颗粒在煅烧之前1小时内在200-250℃的温度下硫酸化。在第三变型中，用于处理氧化的镍钴矿石的本发明方法在于将硫酸转移到可溶性硫酸盐溶液中来处理所述矿石。矿石用硫酸造粒，颗粒在通过空气氧氧化元素硫或硫化物时产生的气体气氛中煅烧。之后，将所述气体与在颗粒煅烧期间释放的硫氧化物一起送入硫酸生产，并将颗粒用于水浸。

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