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1. 发明申请

WO2012093271A1 A NEW PALLADIUM CATALYST, METHOD FOR ITS PREPARATION AND ITS USE 审中-公开
标题翻译：一种新的钯催化剂，其制备方法及其用途
公开(公告)号：WO2012093271A1
公开(公告)日：2012-07-12
申请号：PCT/HU2011/000122
申请日：2011-12-13
申请人： H4SEP KFT , CHINOIN GYÓGYSZER-ÉS VEGYÉSZETI TERMÉKEK GYÁRA ZRT , DALICZEK, Zoltán , SOÓS Tibor , FINTA, Zoltán , TIMÁRI, Géza , VLÁD, Gábor
发明人： DALICZEK, Zoltán , SOÓS Tibor , FINTA, Zoltán , TIMÁRI, Géza , VLÁD, Gábor
IPC分类号： C07B35/02 , C07B37/04 , B01J31/24 , C07C41/30 , C07C201/12 , C07C43/205 , C07C43/215 , C07C205/06 , C07C15/52 , C07C15/54 , C07D213/30 , C07D217/02 , C07D217/16
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/2447 , C07B35/02 , C07B37/04 , C07C2/66 , C07C2/88 , C07C15/52 , C07C15/54 , C07C17/26 , C07C41/30 , C07C201/12 , C07C205/06 , C07D209/08 , C07D213/127 , C07D213/14 , C07D213/26 , C07D213/30 , C07D215/06 , C07D215/12 , C07D215/14 , C07D217/02 , C07D217/16 , C07D217/18 , C07D217/20 , C07D295/023
摘要： The invention relates to palladium(0)-tetrakis{tri-[3,5-bis(trifluoromethyl)- phenylj-phosphine} complex of formula (I), as well as to its preparation and use. This compound is outstandingly stable, and can be used as catalyst with excellent results.
摘要翻译：本发明涉及式（I）的钯（0） - 四（三 - [3,5-双（三氟甲基）苯基]膦基）络合物，以及其制备和用途。该化合物稳定，可用作催化剂，效果优异。

2. 发明申请

WO2011121797A1 HYBRID INORGANIC/ORGANIC POLYMER CATALYTIC MEMBRANE MATERIALS COMPRISING IMMOBILIZED MOLECULAR CATALYSTS AND THEIR PREPARATION 审中-公开
标题翻译：混合无机/有机聚合物催化膜材料包含固定分子催化剂及其制备
公开(公告)号：WO2011121797A1
公开(公告)日：2011-10-06
申请号：PCT/JP2010/056288
申请日：2010-03-31
申请人： NIPPON KODOSHI CORPORATION , BARBARO, Pierluigi , BIANCHINI, Claudio , LIGUORI, Francesca , SAWA, Haruo , VIZZA, Francesco
发明人： BARBARO, Pierluigi , BIANCHINI, Claudio , LIGUORI, Francesca , SAWA, Haruo , VIZZA, Francesco
IPC分类号： B01J31/16 , B01J31/24 , B01J35/06 , B01J37/03 , C07C5/03 , C07B53/00 , B01J31/06 , B01J21/08 , B01J23/28 , B01J23/30 , B01J23/14
CPC分类号： B01J31/069 , B01J31/1683 , B01J31/1691 , B01J31/2226 , B01J31/2295 , B01J31/2414 , B01J31/2447 , B01J31/2466 , B01J2231/645 , B01J2531/0266 , B01J2531/0272 , B01J2531/18 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/847 , C07B53/00 , C07B2200/07 , C07C231/18 , C07C233/47
摘要： A low cost, viable and modular method to prepare new, highly selective "catalytic membranes" and their use in various types of reactors is described. The membranes are versatile and reusable with negligible catalyst leaching, particularly in the asymmetric hydrogenation of substituted α, β-unsaturated acids or esters. The membranes comprise a hybrid inorganic/polymeric support material (i) and a molecular catalyst (ii) immobilized onto them, wherein: - (i) consists of a hybrid inorganic/polymeric compound in which inorganic compounds and organic polymers are chemically combined; - the inorganic compound is at least one selected from silicic, tungstic, molybdic and stannic acid compounds; - the organic polymers have hydroxy groups, preferably being polyvinylalcohol (PVA); - (ii) is a preformed metal catalyst, which contains at least one transition metal selected from Ru, Rh, Pd, Ir, Ni, Pt, Au and at least one chiral ligand selected from phosphino, amino and/or amino-phosphino species, preferably DIOP, BINAP Monophos or TMBTP.
摘要翻译：描述了一种低成本，可行和模块化的方法来制备新的，高选择性的“催化膜”及其在各种类型的反应器中的应用。膜是多功能的并且可重复使用，具有可忽略的催化剂浸出，特别是在取代的α，β-不饱和酸或酯的不对称氢化中。膜包含杂化无机/聚合物载体材料（i）和固定在其上的分子催化剂（ii），其中：（i）由化学组合无机化合物和有机聚合物的杂化无机/聚合化合物组成; - 无机化合物是选自硅，钨，钼和锡酸化合物中的至少一种; - 有机聚合物具有羟基，优选为聚乙烯醇（PVA）; - （ii）是预先形成的金属催化剂，其含有至少一种选自Ru，Rh，Pd，Ir，Ni，Pt，Au的至少一种过渡金属和至少一种选自膦基，氨基和/或氨基 - 膦基物质的手性配体，最好是DIOP，BINAP Monophos或TMBTP。

3. 发明申请

WO2005121157A1 MONOPHOSPHINE COMPOUNDS, TRANSITION METAL COMPLEXES THEREOF AND PRODUCTION OF OPTICALLY ACTIVE COMPOUNDS USING THE COMPLEXES AS ASYMMETRIC CATALYSTS 审中-公开
标题翻译：单膦酸化合物，其过渡金属络合物和使用复合物作为不对称催化剂生产光学活性化合物
公开(公告)号：WO2005121157A1
公开(公告)日：2005-12-22
申请号：PCT/JP2005/010746
申请日：2005-06-07
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , CARREIRA, Erick, M.
发明人： CARREIRA, Erick, M.
IPC分类号： C07F9/6509
CPC分类号： C07B53/00 , B01J31/2447 , B01J2231/323 , B01J2231/324 , B01J2231/326 , B01J2231/34 , B01J2231/346 , B01J2231/4205 , B01J2531/0266 , B01J2531/16 , B01J2531/17 , B01J2531/821 , B01J2531/822 , B01J2531/824 , C07B2200/07 , C07C29/04 , C07C41/26 , C07C211/21 , C07C211/27 , C07D211/74 , C07D319/06 , C07D407/06 , C07F9/650947 , C07F15/0073 , C07C33/22 , C07C33/20 , C07C33/46 , C07C33/18 , C07C43/23
摘要： The present invention provides a compound represented by the formula (I): wherein ring A is void or a benzene ring optionally having substituent(s), R 1 and R 2 are each independently a phenyl group optionally having substituent(s), a cyclohexyl group and the like, R 3 and R 4 are each independently a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxy group and the like, and X is a residue represented by -OR 5 or -NHR 6 wherein R 5 and R 6 are a lower alkyl group optionally having substituent(s), an aralkyl group optionally having substituent(s) and the like, a asymmetric transition metal complex containing the compound as a ligand and a production method of optically active compound using the complex as an asymmetric catalyst.
摘要翻译：本发明提供由式（I）表示的化合物：其中环A为空白或任选具有取代基的苯环，R 1和R 2各自独立地为任选具有取代基的苯基（s ），环己基等，R 3和R 4各自独立地为氢原子，卤素原子，低级烷基，低级烷氧基等，X为 - OR 5或-NHR 6，其中R 5和R 6为任选具有取代基的低级烷基，任选具有取代基的芳烷基等，不对称过渡金属络合物含有该化合物作为配体和使用该络合物作为不对称催化剂的光学活性化合物的制备方法。

4. 发明申请

WO2005108410A1 PHOSPHORUS SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的磷取代金属化合物
公开(公告)号：WO2005108410A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/008388
申请日：2005-03-11
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , KAZYULKIN, Denis, N. , IZMER, Vyatcheslav, V. , RYABOV, Alexey, N. , CANICH, Jo Ann M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , KAZYULKIN, Denis, N. , IZMER, Vyatcheslav, V. , RYABOV, Alexey, N. , CANICH, Jo Ann M.
IPC分类号： C07F17/00
CPC分类号： B01J31/2295 , B01J31/143 , B01J31/146 , B01J31/2447 , B01J31/2457 , B01J2531/0225 , B01J2531/0297 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65925 , C08F2500/03 , C08F210/14
摘要： This invention relates to a metallocene compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is an indenyl ligand that is substituted with a PR2 group in the two position of the indenyl ligand, where each R is, independently a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl substituent, and additionally, E may be substituted with 0, 1, 2, 3, 4, 5 or 6 R ° where each R" is, independently, a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent, and optionally, two or more adjacent R ° substituents may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E or as X; each X is, independently, an univalent anionic ligand, cz both X are joined and bound to the metal atom to, form a metallocycle ring, or, both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的茂金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是在茚基配体的两个位置被PR 2基团取代的茚基配体，其中每个R独立地是烃基，取代的烃基，卤代烃基或取代的卤代烃基取代基，另外E可以被0， 1,2,3,4,5或6个R“，其中每个R”独立地是烃基，取代的烃基，卤代烃基，取代的卤代烃基，甲硅烷基，取代的甲硅烷基，锗烷基或取代的己基羰基取代基，以及任选的两个或更多相邻的R 0取代基可以连接在一起以形成取代或未取代的，饱和的，部分不饱和的或芳族的环状或多环取代基; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的取代或未取代的杂茚基配体，取代或未取代的芴基配体，取代或未取代的杂环芴基配体或其它单阴离子配体，或A可以独立地定义为E或X定义; 每个X独立地是一价阴离子配体，两个X连接并结合到金属原子上，形成金属环，或者两者X连接形成螯合配体，二烯配体或亚烷基配体。

5. 发明申请

WO0210178A8 ADAMANTYL GROUPS CONTAINING PHOSPHANE LIGANDS, THE PRODUCTION AND USE THEREOF IN CATALYTICAL REACTIONS 审中-公开
标题翻译：金刚含膦催化反应的制备方法及其用途
公开(公告)号：WO0210178A8
公开(公告)日：2002-04-04
申请号：PCT/EP0108749
申请日：2001-07-27
申请人： DEGUSSA , BELLER MATTHIAS , EHRENTRAUT ANDREAS , FUHRMANN CHRISTA , ZAPF ALEXANDER
发明人： BELLER MATTHIAS , EHRENTRAUT ANDREAS , FUHRMANN CHRISTA , ZAPF ALEXANDER
IPC分类号： B01J31/18 , B01J31/24 , C07B37/04 , C07B43/04 , C07B61/00 , C07C1/26 , C07C17/26 , C07C45/68 , C07C209/10 , C07C211/48 , C07C211/55 , C07C211/56 , C07C213/02 , C07C217/84 , C07C253/30 , C07C255/50 , C07D295/023 , C07F9/50 , C07F15/00 , C07F15/04 , C07F15/06
CPC分类号： C07F15/065 , B01J31/24 , B01J31/2447 , B01J2231/4211 , B01J2231/4261 , B01J2231/4266 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/845 , B01J2531/847 , C07B37/04 , C07C1/26 , C07C17/263 , C07C45/68 , C07C209/10 , C07C213/02 , C07C253/30 , C07C2531/22 , C07C2603/74 , C07D295/023 , C07F9/5018 , C07F9/5027 , C07F15/0033 , C07F15/004 , C07F15/0046 , C07F15/0053 , C07F15/006 , C07F15/0066 , C07F15/0086 , C07F15/0093 , C07F15/04 , C07F15/045 , C07F15/06 , C07C49/84 , C07C49/233 , C07C49/813 , C07C49/657 , C07C49/784 , C07C49/213 , C07C49/67 , C07C211/48 , C07C211/55 , C07C211/56 , C07C217/84 , C07C255/50
摘要： The invention relates to novel phosphane ligands of formula (Ia) and (Ib): (adamantyl)n P(alkyl)m (1a); (adamantyl)o (Alkyl)q P(alkylen') P(adamantyl)r (alkyl)s (1b), wherein adamantyl represents an adamantyl radical (IIa, IIb) bonded to the phosphorous atom in position 1 or 2. The invention also relates to the production and use of the above-mentioned ligands in the presence of transitional metal compounds of the 8th. Subgroup of PSE for catalytic reactions, particularly for the refining of halogen aromatics for producing aryl olefins, dienes, diarylene, benzoic acid and acrylic acid derivatives, aryl alkanes and also amines.
摘要翻译：本发明涉及式（Ia）和（Ib）的新的膦配体：（金刚烷基）的NP（烷基）米; （金刚烷基）O（烷基）QP（亚烷基“）P（金刚烷基）R（烷基）S，其中金刚烷基在1-或2-位上与磷原子金刚烷基（IIA，IIB），它们的制备和它们的用途的约束在用于催化反应的PSE的VIII。子组的过渡金属化合物的存在下，特别是对卤代芳族化合物的生产arylolefins，二烯，二芳基，苯甲酸和丙烯酸衍生物，芳烷烃和胺的精加工。

6. 发明申请

WO1998028074A1 NOVEL SUPPORTED CATALYSTS 审中-公开
标题翻译：新型支持的催化剂
公开(公告)号：WO1998028074A1
公开(公告)日：1998-07-02
申请号：PCT/US1997023540
申请日：1997-12-19
申请人： SETON HALL UNIVERSITY
发明人： SETON HALL UNIVERSITY , TANIELYAN, Setrak, K. , AUGUSTINE, Robert, L.
IPC分类号： B01J23/00
CPC分类号： C07C231/18 , B01J27/188 , B01J31/1616 , B01J31/1625 , B01J31/2404 , B01J31/2409 , B01J31/2447 , B01J2231/321 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , C07B2200/07 , C07C45/50 , C07C51/36 , C07C67/303 , C07C67/343 , Y02P20/588 , C07C69/34 , C07C69/593 , C07C233/47 , C07C237/22 , C07C47/02
摘要： A supported catalyst comprising a support, an anchoring agent such as a heteropoly acid or anion, and a metal complex which is useful in a wide variety of organic reactions, especially the hydrogenation of substituted alpha , beta unsaturated acids and esters, is provided. Various methods of preparing the supported catalyst of the present invention is also disclosed.
摘要翻译：提供了一种载体催化剂，其包括载体，锚定剂如杂多酸或阴离子，以及可用于多种有机反应的金属络合物，特别是取代的α，β-不饱和酸和酯的氢化。还公开了制备本发明的负载型催化剂的各种方法。

7. 发明申请

WO2015063543A8 HYDRIDOPALLADIUM(II) HALIDES AS PREFORMED CATALYSTS FOR SUZUKI-MIYAURA CROSS-COUPLING REACTIONS 审中-公开
标题翻译：作为SUZUKI-MIYAURA交联反应的预制催化剂的HYDRIDOPALLADIUM（II）HALIDES
公开(公告)号：WO2015063543A8
公开(公告)日：2016-05-06
申请号：PCT/IB2013059779
申请日：2013-10-30
申请人： LATVIAN INST ORGANIC SYNTHESIS
发明人： BERZINA BEATRISE , MUTULE ILGA , SUNA EDGARS
IPC分类号： B01J31/24 , B01J31/12 , C07B37/04
CPC分类号： B01J31/2404 , B01J31/121 , B01J31/24 , B01J31/2447 , B01J2231/4211 , B01J2231/4227 , B01J2531/824 , C07B37/04 , C07F15/0066
摘要： The invention relates to application of well-defined air and moisture stable hydridopalladium(ll) halides LnPd(H)(X), where L is ligand and X is halide, as preformed catalysts in the Suzuki-Miyaura cross-coupling reactions between arylboron derivatives (boronic acids, pinacolylboronates) and aryl halides in the production of biaryl compounds.
摘要翻译：本发明涉及在芳基硼衍生物的Suzuki-Miyaura交叉偶联反应中应用明确定义的空气和水分稳定的卤化钯（II）卤化物LnPd（H）（X），其中L是配体并且X是卤化物作为预先形成的催化剂（硼酸，pinacolylboronates）和芳基卤化物在生产联芳基化合物。

8. 发明申请

WO2015038872A1 BIARYL LIGANDS 审中-公开
公开(公告)号：WO2015038872A1
公开(公告)日：2015-03-19
申请号：PCT/US2014/055356
申请日：2014-09-12
申请人： THE UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.
发明人： APONICK, Aaron , CARDOSO, Flavio, S. P.
IPC分类号： C07D295/195 , C07D233/20
CPC分类号： C07F9/65062 , B01J31/2447 , B01J2231/766 , C07C209/22 , C07C213/02 , C07D211/74 , C07D233/20 , C07F7/083
摘要： Embodiments of the present disclosure provide for biaryl ligands (also referred to herein as "biaryl compound"), biaryl complexes, methods of making biaryl compounds, methods of making single enantiomers of these biaryl compounds, methods of use ( e . g ., catalysis) and the like.
摘要翻译：本公开的实施方案提供了联芳基配体（本文中也称为“联芳基化合物”），联芳基络合物，制备联芳基化合物的方法，制备这些联芳基化合物的单一对映异构体的方法，使用方法（例如催化）和喜欢。

9. 发明申请

WO2009091670A1 SULFONATED ORGANOPHOSPHINE COMPOUNDS AND USE THEREOF IN HYDROFORMYLATION PROCESSES 审中-公开
标题翻译：硫化有机磷化合物及其在氢化方法中的应用
公开(公告)号：WO2009091670A1
公开(公告)日：2009-07-23
申请号：PCT/US2009/030556
申请日：2009-01-09
申请人： DOW GLOBAL TECHNOLOGIES INC. , HEFNER, Robert, E., Jr. , TULCHINSKY, Michael, L.
发明人： HEFNER, Robert, E., Jr. , TULCHINSKY, Michael, L.
IPC分类号： C07F9/50
CPC分类号： B01J31/2404 , B01J31/2447 , B01J31/4046 , B01J31/4053 , B01J2231/321 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , B01J2531/96 , B01J2540/32 , B01J2540/64 , C07F9/5004 , C07F9/5018 , Y02P20/584
摘要： A compound comprising a class of sulfonated triorganophosphine compounds of formula R 1 R 2 P-R 3 [-O-(CH 2 ) n -(SO 3 M)] m , wherein the R 1 and R 2 are selected individually from alkyl, aralkyl, and alicyclic groups, wherein R 3 represents a divalent or polyvalent alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents via an alkylether link, and further wherein R 3 does not contain any aryl moieties; n is an integer reflecting a number of methylene groups in the alkylether link; M represents a monovalent cation; and m is an integer representing a total number of sulfonated alkylether substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alky-aryl exchange, thereby leading to reduced ligand usage and improving ligand and rhodium recovery and recycling.
摘要翻译：包含一类式R1R2P-R3 [-O-（CH2）n-（SO3M）] m的磺化三有机膦化合物的化合物，其中R1和R2分别选自烷基，芳烷基和脂环族基团，其中R3表示通过烷基醚连接键合到磷原子和一个或多个磺酸酯取代基的二价或多价亚烷基或脂环族基团，其中R3不含任何芳基部分; n是反映烷基链接中亚甲基数的整数; M表示一价阳离子; m为代表磺化烷基醚取代基总数的整数。该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的加氢甲酰化形成一种或多种相应的醛产物。配体不能进行烷基 - 芳基交换，从而导致配体使用减少，并改善配体和铑的回收和再循环。

10. 发明申请

WO2008142333A2 METHOD FOR THE SYNTHESIS OF HETEROGENEOUS PALLADIUM CATALYSTS, CATALYSTS OBTAINED AND USE OF SAME 审中-公开
标题翻译：合成异源钯催化剂的方法，获得的催化剂及其用途
公开(公告)号：WO2008142333A2
公开(公告)日：2008-11-27
申请号：PCT/FR2008050639
申请日：2008-04-11
申请人： UNIV HAUTE ALSACE ETABLISSEMEN , CENTRE NAT RECH SCIENT , LE DRIAN CLAUDE , BECHT JEAN-MICHEL , SCHWEIZER STEPHANE
发明人： LE DRIAN CLAUDE , BECHT JEAN-MICHEL , SCHWEIZER STEPHANE
IPC分类号： B01J31/24 , B01J23/44 , B01J27/185 , B01J31/02 , B01J31/16 , B01J31/28 , B01J37/02 , C07C45/68 , C07F9/50
CPC分类号： B01J31/2404 , B01J31/1658 , B01J31/2447 , B01J2231/4211 , B01J2231/4227 , B01J2531/824 , C07F9/5027 , C07F15/006
摘要： The invention relates to the field of chemistry, especially organic chemistry, and more specifically the field of heterogenous palladium catalysts used to catalyse chemical reactions generating the formation of carbon-carbon bonds. The invention also relates to a method for synthesising a heterogeneous palladium catalyst that can catalyse a C-C bonding reaction, said method comprising steps of essentially providing a solid substrate onto which groups of formula -PR1R2, wherein R1 represents an optionally substituted alkyl group, or an optionally substituted cycloalkyl group, et R2 represents an optionally substituted aryl group or an optionally substituted heteroaryl group, have been covalently bound, and of incorporating a catalytically effective quantity of palladium into said substrate substituted in this way. The invention further relates to the catalysts obtained and to the uses thereof in C-C bonding reactions.
摘要翻译：本发明涉及化学领域，特别是有机化学领域，更具体地涉及用于催化产生碳 - 碳键形成的化学反应的异种钯催化剂领域。本发明还涉及一种合成可催化CC键合反应的多相钯催化剂的方法，所述方法包括以下步骤：基本上提供固体底物，其中R 1表示任选取代的烷基的式-PR 1 R 2基团，或任选取代的环烷基，和R 2表示任选取代的芳基或任选取代的杂芳基，已经共价结合，并且将以催化有效量的钯掺入到以这种方式取代的所述底物中。本发明还涉及所获得的催化剂及其在C-C键合反应中的用途。

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