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1. 发明申请

WO2016187303A1 NANO-TO-NANO FE/PPM PD CATALYSIS OF CROSS-COUPLING REACTIONS IN WATER 审中-公开
标题翻译： NANO-TO-NANO FE / PPM PD催化水中交联反应
公开(公告)号：WO2016187303A1
公开(公告)日：2016-11-24
申请号：PCT/US2016/033083
申请日：2016-05-18
申请人： LIPSHUTZ, Bruce, H. , HANDA, Sachin
发明人： LIPSHUTZ, Bruce, H. , HANDA, Sachin
IPC分类号： B01J31/24
CPC分类号： B01J31/2404 , B01J23/8906 , B01J31/0202 , B01J31/0209 , B01J31/068 , B01J31/22 , B01J35/0013 , B01J35/10 , B01J35/12 , B01J37/16 , B01J2231/4211 , B01J2231/4227 , B01J2231/4266 , B01J2231/64 , B01J2531/004 , B01J2531/007 , B01J2531/824 , B01J2531/842 , B01J2531/96 , B01J2531/985 , C07B37/04 , C07C37/18 , C07C41/30 , C07C45/68 , C07C201/12 , C07C205/12 , C07C209/325 , C07C209/68 , C07C211/45 , C07C269/06 , C07C269/08 , C07C319/20 , C07C2603/24 , C07D211/70 , C07D213/30 , C07D213/64 , C07D215/06 , C07D239/26 , C07D239/54 , C07D241/18 , C07D317/22 , C07D317/46 , C07D333/60 , C07D401/04 , C07D403/04 , C07D405/04 , C07D405/14 , C07D409/04 , C07D471/04 , C07F9/12 , C07C271/28 , C07C321/28 , C07C43/215 , C07C43/205 , C07C43/2055 , C07C47/546 , C07C47/575 , C07C39/21
摘要： In one embodiment, the present application discloses a catalyst composition comprising: a) a reaction solvent or a reaction medium; b) organometallic nanoparticles comprising: i) a nanoparticle (NP) catalyst, prepared by a reduction of an iron salt in an organic solvent, wherein the catalyst comprises at least one other metal selected from the group consisting of Pd, Pt, Au, Ni, Co, Cu, Mn, Rh, Ir, Ru and Os or mixtures thereof; c) a ligand; and d) a surfactant; wherein the metal or mixtures thereof is present in less than or equal to 50,000 ppm relative to the iron salt.
摘要翻译：在一个实施方案中，本申请公开了一种催化剂组合物，其包含：a）反应溶剂或反应介质; b）有机金属纳米颗粒，其包含：i）通过在有机溶剂中还原铁盐制备的纳米颗粒（NP）催化剂，其中所述催化剂包含至少一种选自Pd，Pt，Au，Ni ，Co，Cu，Mn，Rh，Ir，Ru和Os或其混合物; c）配体; 和d）表面活性剂; 其中所述金属或其混合物相对于所述铁盐以小于或等于50,000ppm的量存在。

2. 发明申请

WO2015063543A8 HYDRIDOPALLADIUM(II) HALIDES AS PREFORMED CATALYSTS FOR SUZUKI-MIYAURA CROSS-COUPLING REACTIONS 审中-公开
标题翻译：作为SUZUKI-MIYAURA交联反应的预制催化剂的HYDRIDOPALLADIUM（II）HALIDES
公开(公告)号：WO2015063543A8
公开(公告)日：2016-05-06
申请号：PCT/IB2013059779
申请日：2013-10-30
申请人： LATVIAN INST ORGANIC SYNTHESIS
发明人： BERZINA BEATRISE , MUTULE ILGA , SUNA EDGARS
IPC分类号： B01J31/24 , B01J31/12 , C07B37/04
CPC分类号： B01J31/2404 , B01J31/121 , B01J31/24 , B01J31/2447 , B01J2231/4211 , B01J2231/4227 , B01J2531/824 , C07B37/04 , C07F15/0066
摘要： The invention relates to application of well-defined air and moisture stable hydridopalladium(ll) halides LnPd(H)(X), where L is ligand and X is halide, as preformed catalysts in the Suzuki-Miyaura cross-coupling reactions between arylboron derivatives (boronic acids, pinacolylboronates) and aryl halides in the production of biaryl compounds.
摘要翻译：本发明涉及在芳基硼衍生物的Suzuki-Miyaura交叉偶联反应中应用明确定义的空气和水分稳定的卤化钯（II）卤化物LnPd（H）（X），其中L是配体并且X是卤化物作为预先形成的催化剂（硼酸，pinacolylboronates）和芳基卤化物在生产联芳基化合物。

3. 发明申请

WO2008142333A2 METHOD FOR THE SYNTHESIS OF HETEROGENEOUS PALLADIUM CATALYSTS, CATALYSTS OBTAINED AND USE OF SAME 审中-公开
标题翻译：合成异源钯催化剂的方法，获得的催化剂及其用途
公开(公告)号：WO2008142333A2
公开(公告)日：2008-11-27
申请号：PCT/FR2008050639
申请日：2008-04-11
申请人： UNIV HAUTE ALSACE ETABLISSEMEN , CENTRE NAT RECH SCIENT , LE DRIAN CLAUDE , BECHT JEAN-MICHEL , SCHWEIZER STEPHANE
发明人： LE DRIAN CLAUDE , BECHT JEAN-MICHEL , SCHWEIZER STEPHANE
IPC分类号： B01J31/24 , B01J23/44 , B01J27/185 , B01J31/02 , B01J31/16 , B01J31/28 , B01J37/02 , C07C45/68 , C07F9/50
CPC分类号： B01J31/2404 , B01J31/1658 , B01J31/2447 , B01J2231/4211 , B01J2231/4227 , B01J2531/824 , C07F9/5027 , C07F15/006
摘要： The invention relates to the field of chemistry, especially organic chemistry, and more specifically the field of heterogenous palladium catalysts used to catalyse chemical reactions generating the formation of carbon-carbon bonds. The invention also relates to a method for synthesising a heterogeneous palladium catalyst that can catalyse a C-C bonding reaction, said method comprising steps of essentially providing a solid substrate onto which groups of formula -PR1R2, wherein R1 represents an optionally substituted alkyl group, or an optionally substituted cycloalkyl group, et R2 represents an optionally substituted aryl group or an optionally substituted heteroaryl group, have been covalently bound, and of incorporating a catalytically effective quantity of palladium into said substrate substituted in this way. The invention further relates to the catalysts obtained and to the uses thereof in C-C bonding reactions.
摘要翻译：本发明涉及化学领域，特别是有机化学领域，更具体地涉及用于催化产生碳 - 碳键形成的化学反应的异种钯催化剂领域。本发明还涉及一种合成可催化CC键合反应的多相钯催化剂的方法，所述方法包括以下步骤：基本上提供固体底物，其中R 1表示任选取代的烷基的式-PR 1 R 2基团，或任选取代的环烷基，和R 2表示任选取代的芳基或任选取代的杂芳基，已经共价结合，并且将以催化有效量的钯掺入到以这种方式取代的所述底物中。本发明还涉及所获得的催化剂及其在C-C键合反应中的用途。

4. 发明申请

WO2006074315A3 TRANSITION-METAL-CATALYZED CARBON-NITROGEN AND CARBON-CARBON BOND-FORMING REACTIONS 审中-公开
标题翻译：过渡金属催化的碳 - 碳和碳 - 碳结合反应
公开(公告)号：WO2006074315A3
公开(公告)日：2006-08-31
申请号：PCT/US2006000365
申请日：2006-01-09
申请人： MASSACHUSETTS INST TECHNOLOGY , BUCHWALD STEPHEN L , ANDERSON KEVIN W
发明人： BUCHWALD STEPHEN L , ANDERSON KEVIN W
IPC分类号： B01J31/20
CPC分类号： C07C51/367 , B01J31/2404 , B01J2231/4211 , B01J2231/4227 , B01J2231/4266 , B01J2531/0266 , B01J2531/824 , B01J2531/847 , B01J2531/96 , C07B37/04 , C07B43/04 , C07C41/30 , C07C51/353 , C07C51/363 , C07C227/16 , C07C231/12 , C07C303/22 , C07C303/40 , C07D409/06 , C07F9/5022 , C07C65/105 , C07C63/331 , C07C63/72 , C07C311/16 , C07C229/60 , C07C233/65 , C07C309/30 , C07C43/215
摘要： One aspect of the present invention relates to ligands for transition metals. A second aspect of the present invention relates to the use of catalysts comprising these ligands in various transition-metal-catalyzed carbon-heteroatom and carbon-carbon bond- forming reactions. The subject methods provide improvements in many features of the transition-metal-catalyzed reactions, including the range of suitable substrates, number of catalyst turnovers, reaction conditions, and efficiency. For example, improvements have been realized in transition metal-catalyzed: aryl amination reactions; aryl amidation reactions; Suzuki couplings; and Sonogashira couplings. In certain embodiments, the invention relates to catalysts and methods of using them that operate in aqueous solvent systems.
摘要翻译：本发明的一个方面涉及过渡金属配体。本发明的第二方面涉及包含这些配体的催化剂在各种过渡金属催化的碳 - 杂原子和碳 - 碳键形成反应中的用途。本发明的方法提供了过渡金属催化反应的许多特征的改进，包括适当底物的范围，催化剂周转数，反应条件和效率。例如，在过渡金属催化下已经实现了改进：芳基胺化反应; 芳基酰胺化反应; 铃木联轴器和Sonogashira联轴器。在某些实施方案中，本发明涉及在含水溶剂系统中使用它们的催化剂和使用它们的方法。

5. 发明申请

WO2015030682A2 PHOSPHORUS-CONTAINING CATALYSTS 审中-公开
标题翻译：含磷催化剂
公开(公告)号：WO2015030682A2
公开(公告)日：2015-03-05
申请号：PCT/SG2014/000413
申请日：2014-08-29
申请人： AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH
发明人： JOHANNES, Charles William , GEORGE ROBINS, Edward , JONG, Howard , LIM, Yee Hwee , CHIA, Saei Weng , YANG, Yong , PODICHETTY, Anil
IPC分类号： B01J31/18
CPC分类号： B01J31/2409 , B01J31/1875 , B01J31/189 , B01J31/2404 , B01J31/2414 , B01J31/2495 , B01J2231/321 , B01J2231/40 , B01J2231/4205 , B01J2231/4211 , B01J2231/4227 , B01J2231/4233 , B01J2231/4261 , B01J2231/4266 , B01J2231/4277 , B01J2231/4283 , B01J2531/824 , C07C2/861 , C07C17/361 , C07C37/18 , C07D209/10 , C07D295/033 , C07D409/04 , C07F9/5063 , C07F15/006 , C07F15/0066
摘要： The invention provides compounds of general structure I: (Ar 1 -Ar 2 -Ar 3 -E-P(=D)R 2 -) n M m X n L n ". In this structure: • Ar 1 , Ar 2 and Ar 3 are aromatic groups wherein: - Ar 1 and Ar 3 are in a 1,3 relationship on Ar 2 , - each of Ar 1 , Ar 2 and Ar 3 optionally comprises one or more ring substituents of formula YR' r wherein each Y independently is absent or is O, S, B, N or Si and each R' is independently H, halogen, alkyl, cycloalkyl, aryl or heteroaryl and r is 1, 2 or 3, where r is 1 if Y is absent or is O or S, 2 if Y is B or N and 3 if Y is Si, - Ar 1 , Ar 2 and Ar 3 are each independently carbocyclic or heterocyclic and each is independently monocyclic, bicyclic or polycyclic and each ring of each of Ar 1 , Ar 2 and Ar 3 independently has 5, 6 or 7 ring atoms; • E is absent or is selected from the group consisting of O, S, NR", SiR" 2 , AsR" 2 and CR" 2 ; • M is a complexing metal; • X is selected from the group consisting of H, F, Br, CI, I, OTf, dba (dibenzylidene acetone), OC(=O)CF 3 and OAc; • L is selected from the group consisting of PR" 2 , NR" 2 , OR", SR", SiR" 3 , AsR" 3 , alkene, alkyne, aryl and heteroaryl, each of said alkene, alkyne, aryl and heteroaryl being optionally substituted, for example with one or more halogens and/or with one or more R groups as defined herein; • each R is independently alkyl, cycloalkyl, heterocyclyl, heterocycloalkyl, aryl or -, heteroaryl; • D is absent or is =S or -O or -Z-linker-Z-, where each Z independently is O or NH or N- alkyl and linker is an alkyl chain of 2-5 carbon atoms in length; • each R" is independently H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl, each other than H being optionally substituted, or R" 2 is -Z-linker-Z-as defined above; and • m is 0 or 1 or 2; wherein if m is 0, n is 1, n' and n" are 0 and -- is absent; and if m is 1 or 2, n is 1 or 2 and n' and n" are integers such that the coordination sphere of M is filled, and D is absent.
摘要翻译：本发明提供了通式结构I的化合物：（Ar 1 -Ar 2 -Ar 3 -EP（ = D）R 2 - ）n M m m X n n L n “ ;。在这种结构中：·Ar 1，Ar 2和Ar 3是芳族基团，其中：-Ar 1和 Ar 3在Ar 2上处于1,3的关系， - Ar 1，Ar 2和 Ar 3任选地包含一个或多个式YR'r'的环取代基，其中每个Y独立地不存在或为O，S，B，N或Si，并且每个R'为独立地为H，卤素，烷基，环烷基，芳基或杂芳基且r为1,2或3，其中如果Y不存在则r为1或者为O或S，如果Y为B或N则为2，如果Y为Si则为3， Ar 1，Ar 2和Ar 3各自独立地为碳环或杂环，并且各自独立地为单环，双环或多环，并且每个 Ar 1，Ar 2和Ar 3独立地具有5,6或7个环原子; ·E不存在或者选自由O，S，NR“，SiR”2，AsR“2和CR”2“组成的组中 >; •M是一种络合金属; ·X选自由H，F，Br，Cl，I，OTf，dba（二亚苄基丙酮），OC（= O）CF 3和OAc组成的组; ●L选自由PR“2R，NR”2R，OR“，SR”，SiR“3R，AsR”和R“组成的组。烯烃，炔烃，芳基和杂芳基，所述烯烃，炔烃，芳基和杂芳基各自任选被例如一个或多个卤素和/或一个或多个如本文所定义的R基团取代 ; ·每个R独立地为烷基，环烷基，杂环基，杂环烷基，芳基或 - 杂芳基; ●D不存在或者是= S或-O或-Z-连接基-Z-，其中每个Z独立地是O或NH或N-烷基并且连接基是长度为2-5个碳原子的烷基链; •每个R“ 独立地为H，烷基，环烷基，杂环烷基，芳基或杂芳基，除H以外的任选取代，或R“2为-Z-接头-Z-如上定义; 并且·m是0或1或2; 其中如果m是0，则n是1，n'和n“ 是0并且 - 不存在; 并且如果m是1或2，则n是1或2，并且n'和n“ 是整数，使得M的协调球被填充，并且D不存在。

6. 发明申请

WO2011161451A1 COMPLEXES 审中-公开
标题翻译：配合
公开(公告)号：WO2011161451A1
公开(公告)日：2011-12-29
申请号：PCT/GB2011/051171
申请日：2011-06-22
申请人： JOHNSON MATTHEY PLC , COLACOT, Thomas John , JOHANSSON SEECHURN, Carin C. C. , PARISEL, Sebastien Laurent
发明人： COLACOT, Thomas John , JOHANSSON SEECHURN, Carin C. C. , PARISEL, Sebastien Laurent
IPC分类号： B01J31/22 , B01J31/24 , C07F15/00 , C07F15/04
CPC分类号： C07F17/02 , B01J31/2291 , B01J31/2295 , B01J31/24 , B01J31/2404 , B01J2231/4205 , B01J2231/4211 , B01J2231/4227 , B01J2231/4283 , B01J2531/0205 , B01J2531/824 , B01J2531/842 , B01J2531/847 , C07F15/006 , C07F15/04
摘要： The present invention provides a complex of formula (1), wherein, M is palladium or nickel, R 1 and R 2 are independently organic groups having 1-20 carbon atoms, or R 1 and R 2 are linked to form a ring structure with the phosphorus atom, R 3 is selected from the group consisting of substituted and unsubstituted aryl, substituted and unsubstituted heteroaryl, and substituted and unsubstituted metallocenyl, R 4 is an organic group having 1-20 carbon atoms, n is 0, 1, 2, 3, 4 or 5, X is an anionic ligand. The invention also provides a process for the preparation of the complex, and its use in carbon-carbon or carbon-nitrogen coupling reactions.
摘要翻译：本发明提供式（1）的配合物，其中M为钯或镍，R 1和R 2为独立地为具有1-20个碳原子的有机基团，或者R 1和R 2连接形成具有磷原子的环结构， R3选自取代和未取代的芳基，取代和未取代的杂芳基，以及取代和未取代的金属茂基，R4是具有1-20个碳原子的有机基团，n是0,1,2,3,4或5， X是阴离子配体。本发明还提供了制备复合物的方法及其在碳 - 碳或碳 - 氮偶联反应中的应用。

7. 发明申请

WO2011127579A1 CATIONIC PALLADIUM COMPLEXES COMPRISING DIAMINO CARBENE LIGANDS AND THEIR USE IN CATALYSIS 审中-公开
标题翻译：包含二氨基碳配体的阳离子钯复合物及其在催化中的用途
公开(公告)号：WO2011127579A1
公开(公告)日：2011-10-20
申请号：PCT/CA2011/000414
申请日：2011-04-14
申请人： KANATA CHEMICAL TECHNOLOGIES INC. , ABDUR-RASHID, Kamaluddin , AMOROSO, Dino , TSANG, Chi-Wing , JIA, Wenli
发明人： ABDUR-RASHID, Kamaluddin , AMOROSO, Dino , TSANG, Chi-Wing , JIA, Wenli
IPC分类号： C07F15/00 , B01J31/22 , C07B61/00
CPC分类号： C07B37/04 , B01J31/2265 , B01J31/2269 , B01J2231/4211 , B01J2231/4227 , B01J2231/4238 , B01J2231/4261 , B01J2231/4266 , B01J2531/0205 , B01J2531/824 , C07F15/006
摘要： Cationic palladium catalysts comprising diamino carbene ligands, wherein the catalysts are of the formula [Pd(X) q (LBX) t (DC)] r+ [Y m- ] p or [Pd(X) q (LB) n (LBX) t (DC)] 2 a+ [V - ]u[Z 2- ]y, wherein DC is a diamino carbene ligand, X is an anionic ligand, LBX is a combined anionic and neutral ligand, and Y, V, and Z are non-coordinating anions. The compounds are useful in catalytic reactions, including cross-coupling reactions and hydroamination reactions. In particular, the catalysts are used in the following reactions: Suzuki-Miyaura coupling, Kumada coupling, Negishi coupling, Sonogashira coupling, Hartwig-Buchwald amination, and Heck-Mizoroki coupling.
摘要翻译：包含二氨基卡宾配体的阳离子钯催化剂，其中催化剂具有式[Pd（X）q（LBX）t（DC）] r + [Ym-] p或[Pd（X）q（LB）n（LBX）t （DC）] 2 a + [V-] u [Z2-] y，其中DC是二氨基卡宾配体，X是阴离子配体，LBX是阴离子和中性配体的组合，Y，V和Z是非 - 协调阴离子这些化合物可用于催化反应，包括交叉偶联反应和水解反应。特别地，催化剂用于以下反应：铃木 - Miyaura偶联剂，Kumada偶联剂，Negishi偶联剂，Sonogashira偶联剂，Hartwig-Buchwald胺化和Heck-Mizoroki偶联剂。

8. 发明申请

WO2011062109A1 パラジウム触媒及びそれを用いたビスアリール化合物の製造方法审中-公开
标题翻译：钯催化剂和使用其制备双相化合物的方法
公开(公告)号：WO2011062109A1
公开(公告)日：2011-05-26
申请号：PCT/JP2010/070101
申请日：2010-11-11
申请人：国立大学法人新潟大学 , 萩原久大 , 坪川紀夫
发明人：萩原　久大 , 坪川　紀夫
IPC分类号： C07C1/32 , B01J31/04 , C07C15/14 , C07C41/30 , C07C43/205 , C07C45/68 , C07C49/784 , C07C49/84 , C07B61/00 , C07F7/18 , C07F15/00
CPC分类号： C07F15/0066 , B01J31/0284 , B01J31/0297 , B01J2231/4227 , B01J2531/824 , C07B2200/11 , C07C41/30 , C07C45/68 , C07F7/1836 , C07C43/205 , C07C49/84 , C07C49/784
摘要：漏洩がなくリサイクル使用可能であり、リン系配位子の使用を必要としない高い触媒活性を有する新規のパラジウム触媒と、このパラジウム触媒を用いた新規のビスアリール化合物の製造方法を提供する。パラジウム触媒及び塩基の存在下において、芳香族ハロゲン化物と芳香族ボロン酸とを反応させてビスアリール化合物を製造するに際し、前記パラジウム触媒として、シリカ粒子を核とするデンドリマーにイオン液体に溶解したパラジウム化合物を担持させてなるパラジウム触媒を用いた。
摘要翻译：公开了：不经泄漏的新型钯催化剂可以再循环，不需要使用任何含磷配体，并具有高催化活性; 以及使用钯催化剂生产新型二芳基化合物的方法。在钯催化剂和碱的存在下，通过使芳族卤化物与芳香族硼酸反应制备双芳基化合物时，钯催化剂包含以二氧化硅颗粒为芯的树枝状大分子和溶解在离子液体中的钯化合物并支持树枝状大分子。

9. 发明申请

WO2009027729A1 PARACYCLOPHANE-BASED LIGANDS, THEIR PREPARATION AND USE IN CATALYSIS 审中-公开
标题翻译：基于分子结构的配体，其在制备和使用中的应用
公开(公告)号：WO2009027729A1
公开(公告)日：2009-03-05
申请号：PCT/GB2008/050730
申请日：2008-08-21
申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY , XIAO, Jianliang , RUAN, Jiwu
发明人： XIAO, Jianliang , RUAN, Jiwu
IPC分类号： C07F9/50 , C07B37/04 , C07B53/00 , C07C43/205
CPC分类号： C07D295/033 , B01J31/2404 , B01J31/2447 , B01J2231/4211 , B01J2231/4227 , B01J2231/4283 , B01J2531/0263 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07B53/00 , C07C25/22 , C07C41/30 , C07C45/68 , C07C209/10 , C07C253/30 , C07C2603/92 , C07D295/096 , C07D295/155 , C07F9/5022 , C07C211/48 , C07C211/55 , C07C43/205 , C07C43/2055 , C07C43/202
摘要： A substituted paracyclophane is described of formula (I) wherein X 1 and X 2 are linking groups comprising between 2 to 4 carbon atoms, Y 1 and Y 2 are selected from the group consisting of hydrogen, halide, oxygen, nitrogen, alkyl, cycloalkyl, aryl or heteroaryl and Z is a substituted or unsubstituted alkyl group, aryl group or heteroaryl group. Preferably X 1 and X 2 are -(C 2 H 4 )- and Z is a substituted aryl group. The substituted paracyclophane provides transition metal catalysts that are useful in C-C and C-N bond formation and asymmetric hydrogenation reactions.
摘要翻译：描述了式（I）的取代的对环芳烷，其中X 1和X 2是包含2至4个碳原子的连接基团，Y 1和Y 2选自氢，卤素，氧，氮，烷基，环烷基，芳基或杂芳基 Z是取代或未取代的烷基，芳基或杂芳基。优选X1和X2是 - （C2H4） - ，Z是取代的芳基。取代的对环烷烃提供了可用于C-C和C-N键形成和不对称氢化反应的过渡金属催化剂。

10. 发明申请

WO2017059181A1 NI(0) CATALYSTS 审中-公开
标题翻译： NI（0）催化剂
公开(公告)号：WO2017059181A1
公开(公告)日：2017-04-06
申请号：PCT/US2016/054628
申请日：2016-09-30
申请人： THE REGENTS OF THE UNIVERSITY OF MICHIGAN , THE FUNDACIO INSTITUT CATALA D'INVESTIGACIO QUIMICA (ICIQ)
发明人： MONTGOMERY, John , NETT, Alex, J. , ROBO, Michael , CANELLAS ROMAN, Santiago
IPC分类号： B01J31/22 , C07D233/10
CPC分类号： B01J31/2291 , B01J31/2273 , B01J2231/4227 , B01J2231/4283 , B01J2231/4288 , B01J2531/847 , B01J2540/10 , C07B37/04 , C07B43/04 , C07B47/00
摘要： Provided herein are nickel(O) catalysts that are stable when exposed to air and can be used to catalyze the formation of a C-C, C-O, or C-N bond.
摘要翻译：本文提供的是当暴露于空气时是稳定的并且可以用于催化C-C，C-O或C-N键的形成的镍（O）催化剂。

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