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1. 发明申请

WO2017035250A1 HYDRATED POROUS MATERIALS FOR SELECTIVE CO2 CAPTURE 审中-公开
标题翻译：用于选择性CO2捕获的水合物多孔材料
公开(公告)号：WO2017035250A1
公开(公告)日：2017-03-02
申请号：PCT/US2016/048430
申请日：2016-08-24
申请人： WILLIAM MARSH RICE UNIVERSITY
发明人： TOUR, James, M. , JALILOV, Almaz, S
IPC分类号： B01D53/62
CPC分类号： B01J20/20 , B01D53/025 , B01D53/62 , B01D2253/102 , B01D2253/204 , B01D2253/311 , B01D2256/24 , B01D2257/504 , B01J20/28073 , B01J20/28076 , B01J20/3085 , C10L3/104 , C10L2290/542 , Y02A50/2342 , Y02C10/04
摘要： The present disclosure pertain to porous materials with a plurality of hydrated pores imbibed with water molecules. The present disclosure also pertains to methods of capturing CO 2 from an environment by associating the environment with the porous materials. The association can result in the capture of CO 2 from the environment by CO 2 -hydrate formation within the pores of the porous material. Moreover, the capture of CO 2 by the porous materials can occur selectively over hydrocarbons in the environment. The methods can also include steps of releasing the captured CO 2 from the porous material, disposing the released CO 2 , and reusing the porous material for additional CO 2 capture. The present disclosure also pertains to methods of forming the porous materials by pre-treating a precursor material, activating the pre-treated precursor material to form a porous material, and hydrating the pores of the porous material.
摘要翻译：本公开涉及具有多个吸收有水分子的水合孔的多孔材料。本公开还涉及通过将环境与多孔材料相关联从环境捕获CO 2的方法。该缔合可以通过在多孔材料的孔内形成二氧化碳 - 水合物从环境中捕获二氧化碳。此外，通过多孔材料捕获CO 2可以在环境中的碳氢化合物上选择性地发生。所述方法还可以包括从多孔材料中释放所捕获的CO 2，配置释放的CO 2和重新利用多孔材料以进行额外的CO 2捕获的步骤。本公开还涉及通过预处理前体材料，活化预处理的前体材料以形成多孔材料并且使多孔材料的孔隙水合而形成多孔材料的方法。

2. 发明申请

WO2016133571A2 LASER INDUCED GRAPHENE HYBRID MATERIALS FOR ELECTRONIC DEVICES 审中-公开
标题翻译：用于电子器件的激光诱导石墨烯杂化材料
公开(公告)号：WO2016133571A2
公开(公告)日：2016-08-25
申请号：PCT/US2015/062832
申请日：2015-11-27
申请人： WILLIAM MARSH RICE UNIVERSITY
发明人： TOUR, James, M. , LI, Lei , PENG, Zhiwei , ZHANG, Jibo
IPC分类号： H01L21/26 , C01B31/04
CPC分类号： H01G11/36 , C01B32/184 , C01B32/194 , C01B32/20 , C01B2204/04 , C01B2204/22 , C01B2204/32 , H01M4/587 , H01M4/625 , Y02E60/13
摘要： In some embodiments, the present disclosure pertains to methods of producing a graphene hybrid material by exposing a graphene precursor material to a laser source to form a laser-induced graphene, where the laser-induced graphene is derived from the graphene precursor material. The methods of the present disclosure also include a step of associating a pseudocapacitive material (e.g., a conducting polymer or a metal oxide) with the laser-induced graphene to form the graphene hybrid material. The formed graphene hybrid material can become embedded with or separated from the graphene precursor material. The graphene hybrid materials can also be utilized as components of an electronic device, such as electrodes in a microsupercapacitor. Additional embodiments of the present disclosure pertain to the aforementioned graphene hybrid materials and electronic devices.
摘要翻译：在一些实施例中，本公开涉及通过将石墨烯前体材料暴露于激光源以形成激光诱导石墨烯来产生石墨烯混合材料的方法，其中衍生出激光诱导石墨烯来自石墨烯前体材料。本公开的方法还包括将赝电容材料（例如，导电聚合物或金属氧化物）与激光诱导石墨烯相关联以形成石墨烯混合材料的步骤。所形成的石墨烯混合材料可以嵌入或与石墨烯前体材料分离。石墨烯混合材料也可以用作电子器件的组件，例如微型超级电容器中的电极。本公开的另外的实施方式涉及前述的石墨烯混合材料和电子设备。

3. 发明申请

WO2015077281A1 POROUS SIOX MATERIALS FOR IMPROVEMENT IN SIOX SWITCHING DEVICE PERFORMANCES 审中-公开
标题翻译：用于改进SIOX切换设备性能的多孔SIOX材料
公开(公告)号：WO2015077281A1
公开(公告)日：2015-05-28
申请号：PCT/US2014/066303
申请日：2014-11-19
申请人： WILLIAM MARSH RICE UNIVERSITY
发明人： TOUR, James, M. , WANG, Gunuk , YANG, Yang , JI, Yongsung
IPC分类号： H01L29/04
CPC分类号： H01L45/1675 , B82Y10/00 , B82Y40/00 , H01L27/2409 , H01L27/2436 , H01L29/0665 , H01L29/0673 , H01L29/1606 , H01L29/413 , H01L45/04 , H01L45/1253 , H01L45/145 , H01L45/146 , H01L45/1608 , H01L45/1641
摘要： A porous memory device, such as a memory or a switch, may provide a top and bottom electrodes with a memory material layer (e.g. SiO x ) positioned between the electrodes. The memory material layer may provide a nanoporous structure. In some embodiments, the nanoporous structure may be formed electrochemically, such as from anodic etching. Electroformation of a filament through the memory material layer may occur internally through the layer rather than at an edge at extremely low electroforming voltages. The porous memory device may also provide multi-bit storage, high on-off ratios, long high-temperature lifetime, excellent cycling endurance, fast switching, and lower power consumption.
摘要翻译：诸如存储器或开关的多孔存储器件可以向顶部和底部电极提供位于电极之间的存储材料层（例如SiOx）。记忆材料层可以提供纳米多孔结构。在一些实施例中，纳米多孔结构可以电化学形成，例如从阳极蚀刻形成。通过存储材料层的细丝的电化可以通过层而不是在极低的电铸电压下在边缘内部发生。多孔存储器件还可以提供多位存储，高开关比，长的高温寿命，优异的循环耐久性，快速切换和更低的功耗。

4. 发明申请

WO2014179708A1 METHODS OF PRODUCING GRAPHENE QUANTUM DOTS FROM COAL AND COKE 审中-公开
标题翻译：从煤和焦炭生产石墨量子的方法
公开(公告)号：WO2014179708A1
公开(公告)日：2014-11-06
申请号：PCT/US2014/036604
申请日：2014-05-02
申请人： WILLIAM MARSH RICE UNIVERSITY
发明人： TOUR, James, M. , YE, Ruquan , XIANG, Changsheng , LIN, Jian , PENG, Zhiwei
IPC分类号： C01B31/04
CPC分类号： C01B32/182 , B82Y40/00 , C01B32/184 , C01B32/192 , C01B32/194 , C01B2204/02 , C01B2204/04 , C01B2204/32 , Y10S977/774
摘要： In some embodiments, the present disclosure pertains to methods of making graphene quantum dots from a carbon source (e.g., coal, coke, and combinations thereof) by exposing the carbon source to an oxidant. In some embodiments, the methods of the present disclosure further comprise a step of separating the formed graphene quantum dots from the oxidant. In some embodiments, the methods of the present disclosure further comprise a step of reducing the formed graphene quantum dots. In some embodiments, the methods of the present disclosure further comprise a step of enhancing a quantum yield of the graphene quantum dots. In further embodiments, the methods of the present disclosure also include a step of controlling the diameter of the formed graphene quantum dots by selecting the carbon source. In some embodiments, the formed graphene quantum dots comprise oxygen addends or amorphous carbon addends on their edges.
摘要翻译：在一些实施方案中，本公开涉及通过将碳源暴露于氧化剂从碳源（例如，煤，焦炭及其组合）制备石墨烯量子点的方法。在一些实施方案中，本公开的方法进一步包括从形成的石墨烯量子点与氧化剂分离的步骤。在一些实施方案中，本公开的方法还包括减少形成的石墨烯量子点的步骤。在一些实施方案中，本发明的方法还包括提高石墨烯量子点的量子产率的步骤。在另外的实施方案中，本公开的方法还包括通过选择碳源来控制形成的石墨烯量子点的直径的步骤。在一些实施方案中，形成的石墨烯量子点在其边缘上包括氧加成物或无定形碳添加物。

5. 发明申请

WO2014179670A1 MANUFACTURE OF OXIDATIVELY MODIFIED CARBON (OMC) 审中-公开
标题翻译：氧化改性碳（OMC）的制造
公开(公告)号：WO2014179670A1
公开(公告)日：2014-11-06
申请号：PCT/US2014/036543
申请日：2014-05-02
申请人： WILLIAM MARSH RICE UNIVERSITY
发明人： TOUR, James, M. , DIMIEV, Ayrat , DIMIEVA, Elena
IPC分类号： C02F1/68 , B32B5/16
CPC分类号： C02F1/283 , B01J20/20 , B01J20/3085 , C01B31/00 , C01B32/00 , C02F1/001 , C02F1/38 , C02F1/4696 , C02F1/52 , C02F1/56 , C02F1/683 , C02F2101/006 , C02F2101/20 , C02F2303/18
摘要： In some embodiments, the present disclosure pertains to methods of capturing contaminants (i.e., radionuclides and metals) from a water source by applying an oxidatively modified carbon to the water source. This leads to the sorption of the contaminants in the water source to the oxidatively modified carbon. In some embodiments, the methods also include a step of separating the oxidatively modified carbon from the water source after the applying step. In some embodiments, the oxidatively modified carbon comprises an oxidized carbon source. In some embodiments, the carbon source is coal. In some embodiments, the oxidatively modified carbon comprises oxidized coke. In some embodiments, the oxidatively modified carbon is in the form of free-standing, three dimensional and porous particles. Further embodiments of the present disclosure pertain to materials for capturing contaminants from a water source, where the materials comprise the aforementioned oxidatively modified carbons.
摘要翻译：在一些实施方案中，本公开涉及通过将氧化性改性的碳施加到水源而从水源捕获污染物（即，放射性核素和金属）的方法。这导致水源中的污染物吸附到氧化改性的碳上。在一些实施方案中，所述方法还包括在施加步骤之后从水源分离氧化性改性的碳的步骤。在一些实施方案中，氧化性改性碳包括氧化碳源。在一些实施方案中，碳源是煤。在一些实施方案中，氧化改性的碳包括氧化焦炭。在一些实施方案中，氧化改性的碳为独立的三维和多孔颗粒的形式。本公开的另外的实施方案涉及用于从水源捕获污染物的材料，其中所述材料包含上述氧化改性的碳。

6. 发明申请

WO2013040356A1 SOLVENT-BASED METHODS FOR PRODUCTION OF GRAPHENE NANORIBBONS 审中-公开
标题翻译：用于生产石墨纳米粒子的溶剂型方法
公开(公告)号：WO2013040356A1
公开(公告)日：2013-03-21
申请号：PCT/US2012/055414
申请日：2012-09-14
申请人： WILLIAM MARSH RICE UNIVERSITY , TOUR, James, M. , LU, Wei , GENORIO, Bostjan
发明人： TOUR, James, M. , LU, Wei , GENORIO, Bostjan
IPC分类号： B05D5/12
CPC分类号： C08F112/08 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B32/178 , C01B32/18 , C01B32/184 , C01B32/194 , C01B2202/06 , C01B2204/06 , C07C2/76 , C07C15/56 , C07C29/32 , C07C67/035 , C07C69/76 , D01F9/12 , Y10S977/734 , Y10S977/846 , Y10S977/961
摘要： The present invention provides methods of preparing functionalized graphene nanoribbons. Such methods include: (1) exposing a plurality of carbon nanotubes (CNTs) to an alkali metal source in the presence of an aprotic solvent to open them; and (2) exposing the opened CNTs to an electrophile to form functionalized graphene nanoribbons (GNRs). The methods may also include a step of exposing the opened CNTs to a protic solvent to quench any reactive species on them. Additional methods include preparing unfunctionalized GNRs by: (1) exposing a plurality of CNTs to an alkali metal source in the presence of an aprotic solvent to open them; and (2) exposing the opened CNTs to a protic solvent to form unfunctionalized GNRs.
摘要翻译：本发明提供了制备官能化石墨烯纳米带的方法。这些方法包括：（1）在非质子溶剂的存在下将多个碳纳米管（CNT）暴露于碱金属源以将其打开; 和（2）将开放的CNT暴露于亲电子试剂以形成官能化的石墨烯纳米带（GNR）。所述方法还可以包括将开放的CNT暴露于质子溶剂以淬灭其上的任何反应性物质的步骤。另外的方法包括：通过以下步骤制备未官能化的GNR：（1）在非质子溶剂存在下将多个CNT暴露于碱金属源以打开它们; 和（2）将开放的CNT暴露于质子溶剂以形成未官能化的GNR。

7. 发明申请

WO2012100178A1 GRAPHENE-BASED THIN FILMS IN HEAT CIRCUITS AND METHODS OF MAKING THE SAME 审中-公开
标题翻译：加热电路中基于石墨的薄膜及其制造方法
公开(公告)号：WO2012100178A1
公开(公告)日：2012-07-26
申请号：PCT/US2012/022052
申请日：2012-01-20
申请人： WILLIAM MARSH RICE UNIVERSITY , LOCKHEED MARTIN CORPORATION , TOUR, James, M. , VOLMAN, Vladimir , ZHU, Yu
发明人： TOUR, James, M. , VOLMAN, Vladimir , ZHU, Yu
IPC分类号： B05D5/12 , B32B9/04
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/174 , C01B32/18 , C01B32/194 , H01B1/04 , Y10T428/265 , Y10T428/31511 , Y10T428/31551 , Y10T428/31721 , Y10T428/31855
摘要： In various embodiments, the present invention provides electrically conductive and radio frequency (RF) transparent films that include a graphene layer and a substrate associated with the graphene layer. In some embodiments, the graphene layer has a thickness of less than about 100 nm. In some embodiments, the graphene layer of the film is adhesively associated with the substrate. In more specific embodiments, the graphene layer includes graphene nanoribbons that are in a disordered network. Further embodiments of the present invention pertain to methods of making the aforementioned electrically conductive and RF transparent films. Such methods generally include associating a graphene composition with a substrate to form a graphene layer on a surface of the substrate.
摘要翻译：在各种实施例中，本发明提供了包括石墨烯层和与石墨烯层相关联的衬底的导电和射频（RF）透明膜。在一些实施例中，石墨烯层具有小于约100nm的厚度。在一些实施例中，膜的石墨烯层与衬底粘合地相关联。在更具体的实施方案中，石墨烯层包括位于无序网络中的石墨烯纳米带。本发明的其它实施方案涉及制备上述导电和RF透明膜的方法。这样的方法通常包括将石墨烯组合物与基材缔合以在基材的表面上形成石墨烯层。

8. 发明申请

WO2009070380A2 WATER-SOLUBLE CARBON NANOTUBE COMPOSITIONS FOR DRUG DELIVERY AND MEDICAL APPLICATIONS 审中-公开
标题翻译：用于药物输送和医疗应用的可溶性碳纳米管组合物
公开(公告)号：WO2009070380A2
公开(公告)日：2009-06-04
申请号：PCT/US2008/078776
申请日：2008-10-03
申请人： WILLIAM MARSH RICE UNIVERSITY , TOUR, James, M. , LUCENTE-SCHULTZ, Rebecca , LEONARD, Ashley , KOSYNKIN, Dmitry, V. , PRICE, Brandi, Katherine , HUDSON, Jared, L. , CONYERS, Jodie, L. , MOORE, Valerie, C. , CASSCELLS, S., Ward , MYERS, Jeffrey, N. , MILAS, Zvonimir, L. , MASON, Kathy, A. , MILAS, Luka
发明人： TOUR, James, M. , LUCENTE-SCHULTZ, Rebecca , LEONARD, Ashley , KOSYNKIN, Dmitry, V. , PRICE, Brandi, Katherine , HUDSON, Jared, L. , CONYERS, Jodie, L. , MOORE, Valerie, C. , CASSCELLS, S., Ward , MYERS, Jeffrey, N. , MILAS, Zvonimir, L. , MASON, Kathy, A. , MILAS, Luka
IPC分类号： A61K47/48
CPC分类号： B82Y5/00 , A61K47/60 , A61K47/6925 , A61K47/6929
摘要： Compositions comprising a plurality of functionalized carbon nanotubes and at least one type of payload molecule are provided herein. The compositions are soluble in water and PBS in some embodiments. In certain embodiments, the payload molecules are insoluble in water. Methods are described for making the compositions and administering the compositions. An extended release formulation for paclitaxel utilizing functionalized carbon nanotubes is also described.
摘要翻译：本文提供了包含多个官能化碳纳米管和至少一种有效载荷分子的组合物。在一些实施方案中，组合物可溶于水和PBS。在某些实施方案中，有效载荷分子不溶于水。描述了制备组合物和施用组合物的方法。还描述了利用官能化碳纳米管的紫杉醇的延长释放制剂。

9. 发明申请

WO2004046099A2 METHOD OF MAKING A MOLECULE-SURFACE INTERFACE 审中-公开
标题翻译：制备分子表面接触的方法
公开(公告)号：WO2004046099A2
公开(公告)日：2004-06-03
申请号：PCT/US2003/003096
申请日：2003-02-03
申请人： WILLIAM MARSH RICE UNIVERSITY
发明人： TOUR, James, M. , STEWART, Michael, P.
IPC分类号： C07D
CPC分类号： H01L21/02118 , H01L21/02282 , H01L21/288 , H01L21/312 , H01L21/3205 , Y10T428/31663
摘要： This invention is generally related to a method of making a molecule-surface interface comprising at least one surface comprising at least one material and at least one organic group wherein the organic group is adjoined to the surface and the method comprises contacting at least one organic group precursor with at least one surface wherein the organic group precursor is capable of reacting with the surface in a manner sufficient to adjoin the organic group and the surface.
摘要翻译：本发明通常涉及一种制备分子 - 表面界面的方法，该分子 - 表面界面包括至少一个包含至少一种材料和至少一种有机基团的表面，其中有机基团与表面相邻，并且该方法包括使至少一种有机基团具有至少一个表面的前体，其中有机基团前体能够以足以邻接有机基团和表面的方式与表面反应。

10. 发明申请

WO2004041712A2 METHOD OF MAKING A NANOSCALE ELECTRONIC DEVICE 审中-公开
标题翻译：制造纳米电子器件的方法
公开(公告)号：WO2004041712A2
公开(公告)日：2004-05-21
申请号：PCT/US2003/014959
申请日：2003-05-13
申请人： WILLIAM MARSH RICE UNIVERSITY
发明人： PANG, Harry, F. , TOUR, James, M.
IPC分类号： B82B
CPC分类号： B82Y30/00 , B82Y10/00 , H01L51/0595 , Y10S977/932
摘要： The present invention relates to a method of making a nanoscale electronic device wherein said device comprises a gap between about 0.1 nm and about 100 nm between at least two conductors, semiconductors or the combination thereof. The method features complete assembly of electrical contacts before addition of a molecular component thereby preserving the integrity of the molecular electronic component and maintaining a well-formed gap. The gap produced is within the nanoscale regime, has uniform width and is further characterized by surfaces that are uniformly smooth.
摘要翻译：本发明涉及制造纳米级电子器件的方法，其中所述器件在至少两个导体，半导体或其组合之间包括约0.1nm至约100nm之间的间隙。该方法在添加分子组分之前完全组装电接触，从而保持分子电子部件的完整性并保持良好的间隙。产生的间隙在纳米尺度范围内，具有均匀的宽度，并且进一步由均匀光滑的表面表征。

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