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    • 5. 发明申请
    • HIGHLY ORDERED POROUS CARBON MATERIALS HAVING WELL DEFINED NANOSTRUCTURES AND METHOD OF SYNTHESIS
    • 具有良好定义的纳米结构的高阶多孔碳材料和合成方法
    • WO2007024241A3
    • 2007-04-12
    • PCT/US2005031691
    • 2005-09-02
    • UT BATTELLE LLCUNIV TENNESSEE RES FOUNDATIONDAI SHENGLIANG CHENGDU
    • DAI SHENGLIANG CHENGDU
    • C01B31/00C01B31/02
    • C01B32/00C01B32/05
    • Applicant's present invention comprises a method for fabricating porous carbon materials having highly ordered nanostructures comprising the steps of first, forming a precursor solution comprising a block copolymer template and a carbon precursor; second, forming a self-assembled nanostructured material from the precursor solution; third annealing the nanostructured material thereby forming a highly ordered nanostructured material; fourth, polymerizing the carbon precursor to cure the nanostructured material; and pyrolyzing the nanostructured material wherein the block copolymer template is decomposed to generate ordered carbon nanopores and the nanostructured material is carbonized to form the walls of the carbon nanopores thereby forming a porous carbon material having a highly ordered nanostructure. In addition, the present invention further comprises a porous carbon material comprising a carbon nanostructure having ordered carbon nanopores that have uniform pore sizes ranging from about 4.5 nm up to about 100 nm.
    • 申请人的本发明包括一种用于制造具有高度有序纳米结构的多孔碳材料的方法,包括以下步骤:首先形成包含嵌段共聚物模板和碳前体的前体溶液; 第二,从前体溶液中形成自组装的纳米结构材料; 对纳米结构材料进行第三次退火,从而形成高度有序的纳米结构材料; 第四,聚合碳前体以固化纳米结构材料; 并且对纳米结构材料进行热解,其中分解嵌段共聚物模板以产生有序碳纳米孔,并将纳米结构材料碳化以形成碳纳米孔的壁,从而形成具有高度有序纳米结构的多孔碳材料。 此外,本发明还包括多孔碳材料,其包含碳纳米结构,所述碳纳米结构具有尺寸范围为约4.5nm至约100nm的均匀孔径的有序碳纳米孔。