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    • 1. 发明申请
    • HETEROCYCLIC ALLYL DERIVATIVES
    • 杂环衍生物
    • WO2005068445A2
    • 2005-07-28
    • PCT/EP2005/000094
    • 2005-01-07
    • SYNGENTA PARTICIPATIONS AGHALL, Roger, GrahamTRAH, StephanZAMBACH, WernerTULEJA, Juraj
    • HALL, Roger, GrahamTRAH, StephanZAMBACH, WernerTULEJA, Juraj
    • C07D285/12
    • C07D271/113C07D233/72C07D237/14C07D239/36C07D241/18C07D249/12C07D273/04C07D285/13
    • The invention relates to compounds of formula (I) wherein Het, A 1 , A 2 , A 3 , A 4 , D, W, T, Q, Y, X 1 , X 2 , R 1 , R 2 , R 3 , R 4 , k and m are as defined hereinabove, and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, to a process for the preparation of and to the use of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, to pesticidal compositions in which the active ingredient has been selected from those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in agrochemically usable salt form, to a process for the preparation of and to the use of those compositions, to plant propagation material treated with those compositions, to a method of controlling pests, to intermediates and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, for the preparation of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, and to a process for the preparation of and to the use of those intermediates and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof.
    • 本发明涉及式(I)化合物,其中Het,A1,A2,A3,A4,D,W,T,Q,Y,X1,X2,R1,R2,R3,R4,k和m如上所定义 ,以及(如适用)可能的E / Z异构体,E / Z异构体和/或其互变异构体的混合物,在每种情况下为游离形式或盐形式,用于制备和使用这些化合物的方法 ,E / Z异构体,E / Z异构体和/或互变异构体的混合物,其中活性成分选自那些化合物,E / Z异构体,E / Z异构体和/或互变异构体的混合物的农药组合物 游离形式或农业可用盐形式的情况,制备和使用这些组合物的方法,用这些组合物处理的繁殖材料,控制害虫的方法,中间体以及在适用的情况下 可能的E / Z异构体,E / Z异构体和/或其互变异构体的混合物,在每种情况下为游离形式或盐形式,用于制备那些 磅,E / Z异构体,E / Z异构体和/或互变异构体的混合物,以及制备和使用那些中间体的方法,以及可能的E / Z异构体,E / Z异构体的混合物 和/或其互变异构体。
    • 2. 发明申请
    • DIHALO-ALLYLOXY-PHENOL DERIVATIVES HAVING PESTICIDAL ACTIVITY
    • 具有杀虫活性的二氢 - 全氟代苯酚衍生物
    • WO2004052816A1
    • 2004-06-24
    • PCT/EP2003/014009
    • 2003-12-10
    • SYNGENTA PARTICIPATIONS AGZAMBACH, WernerRENOLD, PeterHALL, Roger, GrahamTRAH, Stephan
    • ZAMBACH, WernerRENOLD, PeterHALL, Roger, GrahamTRAH, Stephan
    • C07C43/225
    • A01N37/34C07C43/225C07C43/23C07C43/315C07C45/29C07C45/71C07C49/255C07C69/76C07C205/32C07C251/40C07C255/37C07C255/41C07C271/16C07C2601/02C07D213/57C07D261/08C07D307/54C07D307/81C07D333/24C07C49/84
    • Compounds of formula (I), wherein A 1 and A 2 are each independently of the other a bond or a C 1 -C 6 alkylene bridge; A 3 is a C 1 -C 6 alkylene bridge; X 1 and X 2 are each independently of the other fluorine, chlorine or bromine; Y is O, NR 7 , S, SO or SO 2 ; R 1 , R 2 and R 3 are each independently of the others, for example, H, halogen, OH, SH, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkylcarbonyl or C 2 -C 6 alkenyl; Q is O, NR 5 , S, SO or SO 2 ; W is, for example, O, NR 5 or SO; T is for example, a bond, O or NR 5 ; D is CH or N; R 4 is, for example, H, halogen, OH, SH, CN or nitro; R 5 and R 7 are, for example, H, C 1 -C 6 alkyl or C 1 -C 3 haloalkyl; k is 1, 2, 3 or 4; m is 1 or 2; R 10 is a radical which contains O, N or S; R 11 is, for example, H, C 1 -C 12 alkyl or a radical which contains from one to three hetero atoms selected from O, N and S; or R 11 together with R 12 is a bond; R 12 is, for example, H, C 1 -C 6 alkyl, halo-C 1 -C 6 alkyl or C 1 -C 6 alkoxy-C 1 -C 6 -alkyl; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free from or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof; a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.
    • 式(I)化合物,其中A1和A2各自独立地为一个键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥; X1和X2各自独立地为氟,氯或溴; Y是O,NR7,S,SO或SO2; R 1,R 2和R 3各自独立地为H,卤素,OH,SH,CN,硝基,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷基羰基或C 2 -C 6烯基; Q是O,NR5,S,SO或SO2; W是例如O,NR5或SO; T为例如O或NR5的键; D是CH或N; R4是例如H,卤素,OH,SH,CN或硝基; R5和R7是例如H,C1-C6烷基或C1-C3卤代烷基; k为1,2,3或4; m为1或2; R10是含有O,N或S的基团; R 11是例如H,C 1 -C 12烷基或含有1至3个选自O,N和S的杂原子的基团; 或R11与R12一起为键; R 12是例如H,C 1 -C 6烷基,卤代-C 1 -C 6烷基或C 1 -C 6烷氧基-C 1 -C 6 - 烷基; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体在每种情况下不含或以盐形式,制备这些化合物的方法及其用途,其中 从这些化合物或其农业化学上可接受的盐中选择活性成分; 制备这些组合物及其用途的方法,用这些组合物处理的植物繁殖材料以及防治害虫的方法。
    • 5. 发明申请
    • PESTICIDALLY ACTIVE PHENOL DERIVATIVES
    • 杀虫活性酚醛衍生物
    • WO2005019147A2
    • 2005-03-03
    • PCT/EP2004/009500
    • 2004-08-25
    • SYNGENTA PARTICIPATIONS AGZAMBACH, WernerTRAH, StephanHALL, Roger, GrahamLUTZ, William
    • ZAMBACH, WernerTRAH, StephanHALL, Roger, GrahamLUTZ, William
    • C07C43/00
    • A01N37/20A01N31/16A01N35/10A01N43/10A01N43/40A01N43/54A01N43/56A01N43/653A01N43/713A01N43/80A01N43/82A01N43/84C07C43/225C07C49/255C07C49/84C07C69/65C07C205/37C07C233/22C07C251/48C07C255/54C07D213/53C07D213/64C07D231/20C07D239/38C07D249/12C07D257/04C07D261/18C07D271/07C07D295/096C07D333/22C07D401/04C07F7/0818
    • There are described compounds of formula (I) wherein X 1 and X 2 are each independently of the other fluorine, chlorine or bromine; A 1 and A 2 are, for example, a bond or a C 1 -C 6 alkylene bridge; A 3 is a C 1 -C 6 alkylene bridge; R 1 and R 2 are, for example, halogen, OH, SH, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkyl-carbonyl, C 2 ­C 6 alkenyl, C 2 -C 6 haloalkenyl or C 3 -C 6 alkynyl; R, 3 is, for example, H, halogen, OH, SH, CN, nitro, C 1 -C 6 alkyl or C 1 -C 6 haloaikyl; R 4 and R 5 are, for example, H, halogen, cyano, nitro, C 1 -C 6 alkyl or C 1 -C 3 haloalkyl; m is 1 or 2; Y is, for example, O, S, SO or SO 2 ; Q is, for example, O, S, SO or SO 2 ; W is, for example, a bond, O, S, SO, S02, -C(=O)-O- or -O-C(=O)-; T is, for example, a bond, O, S, SO, SO 2 , -C(=O)-O- or -O-C(=O)-; and E is aryl unsubstituted or substituted from one to five times or heterocyclyl unsubstituted or, depending upon the possibilities of substitution on the ring, substituted from one to four times; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.
    • 描述了式(I)的化合物,其中X 1和X 2各自独立地为其它氟,氯或溴; A1和A2是例如键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥; R 1和R 2是例如卤素,OH,SH,CN,硝基,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷基 - 羰基,C 2 C 6烯基,C 2 -C 6卤代烯基或C 3 -C 6炔基; R 3是例如H,卤素,OH,SH,CN,硝基,C 1 -C 6烷基或C 1 -C 6卤代烷基; R4和R5是例如H,卤素,氰基,硝基,C1-C6烷基或C1-C3卤代烷基; m为1或2; Y是例如O,S,SO或SO 2; Q是例如O,S,SO或SO 2; W是例如键,O,S,SO,SO 2,-C(= O)-O-或-O-C(= O) - ; T是例如键,O,S,SO,SO 2,-C(= O)-O-或-O-C(= O) - ; 并且E是未取代的或未取代的取代的芳基或未取代的杂环基,或取决于环上取代的可能性,取代1-4次; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 从这些化合物及其农业化学上可接受的盐中选择活性成分,制备这些组合物的方法及其用途,用这些组合物处理的植物繁殖材料以及防治害虫的方法。
    • 6. 发明申请
    • PESTICIDALLY ACTIVE KETONE AND OXIME DERIVATIVES
    • 杀虫活性酮和氧化衍生物
    • WO2004113273A1
    • 2004-12-29
    • PCT/EP2004/006749
    • 2004-06-22
    • SYNGENTA PARTICIPATIONS AGZAMBACH, WernerHALL, Roger, GrahamRENOLD, PeterTRAH, Stephan
    • ZAMBACH, WernerHALL, Roger, GrahamRENOLD, PeterTRAH, Stephan
    • C07C251/44
    • C07D333/58A01N33/24A01N35/10A01N37/52A01N41/06A01N43/10A01N43/40A01N43/78A01N43/80C07C49/753C07C49/755C07C49/84C07C235/84C07C251/44C07C251/48C07C251/54C07C251/58C07C311/04C07C311/05C07C311/09C07C323/47C07D213/50C07D213/53C07D213/61C07D213/64C07D261/08C07D277/24C07D277/28C07D307/52C07D307/81C07D333/22
    • Compounds of formula (I), wherein A 0 , A 1 , and A 2 are each independently of the others a bond or a C l -C 6 alkylene bridge; A 3 is a C l -C 6 alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C 3 -C 8 cycloalkyl; Y is, for example, 0, S, SO or S0 2 ; M is 0 or NOR 6 , X 1 , and X 2 are each independently of the other fluorine, chlorine or bromine; R 1 , R 2 and R 3 are, for example, H, halogen, OH, SH, CN, nitro, C 1 -C 6 alkyl, C l -C 6 haloalkyl, C l -C 6 alkylcarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl or C 2 -C 6 alkynyl; Q is, for example, O, S, SO or SO 2 ; W is, for example, 0, S, SO, SO 2 , -C(=O)-O- or -0-C(=O)-; T is, for example, a bond, 0, S, SO, S0 2 , -C(=O)-O­or -0-C(=O)-; D is CH or N; R 4 is, for example, H, halogen, OH, SH, CN, nitro, C l -C 6 alkyl or C 1 -C 6 haloalkyl; R 5 is, for example, C l -C l2 alkyl, C 3 -C 8 cycloalkyl or -N(R 7 ) 2 ; R 7 is H, C 1 -C 6 alkyl, C l -C 3 haloalkyl, C l -C 6 alkylcarbonyl, C l -C 3 haloalkylcarbonyl, C l -C 6 alkoxycarbonyl, C 3 -C 8 Cycloalkyl, C 3 -C 8 cycloalkylcarbonyl or formyl; k is 0, 1, 2, 3 or 4; m is 1 or 2; and q is 0, 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, and a process for the preparation of those compositions and their use, to plant propagation material treated with those compositions, and a method of controlling pests.
    • 式(I)的化合物,其中A0,A1和A2各自独立地为键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥,其未被取代或被1-6个相同或不同的选自卤素和C 3 -C 8环烷基的取代基取代; Y是例如0,S,SO或SO 2; M为0或NOR6,X1和X2各自独立地为氟,氯或溴; R 1,R 2和R 3是例如H,卤素,OH,SH,CN,硝基,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷基羰基,C 2 -C 6烯基,C 2 -C 6卤代烯基或C 2 -C 6炔基; Q是例如O,S,SO或SO 2; W是例如0,S,SO,SO 2,-C(= O)-O-或-O-C(= O) - ; T是例如键,0,S,SO,SO 2,-C(= O)-O或-O-C(= O) - ; D是CH或N; R4是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基或C1-C6卤代烷基; R5是例如C1-C12烷基,C3-C8环烷基或-N(R7)2; R 7是H,C 1 -C 6烷基,C 1 -C 3卤代烷基,C 1 -C 6烷基羰基,C 1 -C 3卤代烷基羰基,C 1 -C 6烷氧基羰基,C 3 -C 8环烷基,C 3 -C 8环烷基羰基或甲酰基; k为0,1,2,3或4; m为1或2; q为0,1或2; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 已经从那些化合物和农业化学上可接受的盐中选择活性成分,以及这些组合物的制备方法及其用途,用这些组合物处理的植物繁殖材料和控制害虫的方法。
    • 7. 发明申请
    • 4-(3,3-DIHALO-ALLYLOXY)PHENOXY ALKYL DERIVATIVES
    • 4-(3,3-DIHALO-ALLYLOXY)苯氧基衍生物
    • WO2004002943A1
    • 2004-01-08
    • PCT/EP2003/006846
    • 2003-06-27
    • SYNGENTA PARTICIPATIONS AGZAMBACH, WernerRENOLD, PeterSTEIGER, ArthurTRAH, StephanHALL, Roger, Graham
    • ZAMBACH, WernerRENOLD, PeterSTEIGER, ArthurTRAH, StephanHALL, Roger, Graham
    • C07C233/75
    • C07D207/27C07C217/84C07C233/25C07C233/29C07C233/75C07C271/28C07D207/325C07D207/444C07D207/452C07D263/22C07D307/68C07D333/38
    • Compounds of formula (I), wherein A 1 , A 2 and A 3 are each independently of the others a bond or a C 1 -C 6 alkylene bridge; A 4 is a C 1 -C 6 alkylene bridge; Di s CH or N; W is, for example, O, NR 7 or S; T is, for example, a bond, O, NH or NR 7 ; Q is O, NR 7 , S, SO or SO 2 ; Y is O, NR 7 , S, SO, or SO 2 ; X 1 and X 2 are each independently of the other fluorine, chlorine or bromine; R 1 , R 2 and R 3 ar, for example, H, halogen, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkylcarbonyl or C 2 -C 6 alkenyl; R 4 is, for example, H, halogen, CN, nitro or C 1 -C 6 alkyl; R 5 and R 6 are, for example, H, CN, OH, C 1 -C 6 alkyl, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl-C 1 -C 6 alkyl, C 1 -C 6 haloalky, C 1 -C 6 alkoxy or C 1 -C 6 haloalkoxy; R 7 is H, C 1 -C 6 alkyl, C 1 -C 6 alkoxyalkyl or C 1 -C 6 alkylcarbonyl; k, when D is nitrogen, is 1, 2 or 3; or, when D is CH, is 1, 2, 3 or 4; and m is 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof, a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.
    • 式(I)的化合物,其中A1,A2和A3各自独立地为键或C1-C6亚烷基桥; A4是C1-C6亚烷基桥; Di s CH或N; W是例如O,NR7或S; T是例如键,O,NH或NR 7; Q是O,NR7,S,SO或SO2; Y是O,NR7,S,SO或SO2; X1和X2各自独立地为氟,氯或溴; R1,R2和R3Ar,例如H,卤素,CN,硝基,C1-C6烷基,C1-C6卤代烷基,C1-C6烷基羰基或C2-C6链烯基; R4是例如H,卤素,CN,硝基或C1-C6烷基; R 5和R 6是例如H,CN,OH,C 1 -C 6烷基,C 3 -C 8环烷基,C 3 -C 8环烷基-C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷氧基或C 1 -C 6卤代烷氧基; R 7是H,C 1 -C 6烷基,C 1 -C 6烷氧基烷基或C 1 -C 6烷基羰基; k,当D为氮时,为1,2或3; 或当D为CH时,为1,2,3或4; m为1或2; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 从这些化合物或其农业化学上可接受的盐中选择活性成分,制备这些组合物的方法及其用途,用这些组合物处理的植物繁殖材料以及防治害虫的方法。