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    • 2. 发明申请
    • 4-(3,3-DIHALO-ALLYLOXY)PHENOXY ALKYL DERIVATIVES
    • 4-(3,3-DIHALO-ALLYLOXY)苯氧基衍生物
    • WO2004002943A1
    • 2004-01-08
    • PCT/EP2003/006846
    • 2003-06-27
    • SYNGENTA PARTICIPATIONS AGZAMBACH, WernerRENOLD, PeterSTEIGER, ArthurTRAH, StephanHALL, Roger, Graham
    • ZAMBACH, WernerRENOLD, PeterSTEIGER, ArthurTRAH, StephanHALL, Roger, Graham
    • C07C233/75
    • C07D207/27C07C217/84C07C233/25C07C233/29C07C233/75C07C271/28C07D207/325C07D207/444C07D207/452C07D263/22C07D307/68C07D333/38
    • Compounds of formula (I), wherein A 1 , A 2 and A 3 are each independently of the others a bond or a C 1 -C 6 alkylene bridge; A 4 is a C 1 -C 6 alkylene bridge; Di s CH or N; W is, for example, O, NR 7 or S; T is, for example, a bond, O, NH or NR 7 ; Q is O, NR 7 , S, SO or SO 2 ; Y is O, NR 7 , S, SO, or SO 2 ; X 1 and X 2 are each independently of the other fluorine, chlorine or bromine; R 1 , R 2 and R 3 ar, for example, H, halogen, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkylcarbonyl or C 2 -C 6 alkenyl; R 4 is, for example, H, halogen, CN, nitro or C 1 -C 6 alkyl; R 5 and R 6 are, for example, H, CN, OH, C 1 -C 6 alkyl, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl-C 1 -C 6 alkyl, C 1 -C 6 haloalky, C 1 -C 6 alkoxy or C 1 -C 6 haloalkoxy; R 7 is H, C 1 -C 6 alkyl, C 1 -C 6 alkoxyalkyl or C 1 -C 6 alkylcarbonyl; k, when D is nitrogen, is 1, 2 or 3; or, when D is CH, is 1, 2, 3 or 4; and m is 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof, a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.
    • 式(I)的化合物,其中A1,A2和A3各自独立地为键或C1-C6亚烷基桥; A4是C1-C6亚烷基桥; Di s CH或N; W是例如O,NR7或S; T是例如键,O,NH或NR 7; Q是O,NR7,S,SO或SO2; Y是O,NR7,S,SO或SO2; X1和X2各自独立地为氟,氯或溴; R1,R2和R3Ar,例如H,卤素,CN,硝基,C1-C6烷基,C1-C6卤代烷基,C1-C6烷基羰基或C2-C6链烯基; R4是例如H,卤素,CN,硝基或C1-C6烷基; R 5和R 6是例如H,CN,OH,C 1 -C 6烷基,C 3 -C 8环烷基,C 3 -C 8环烷基-C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷氧基或C 1 -C 6卤代烷氧基; R 7是H,C 1 -C 6烷基,C 1 -C 6烷氧基烷基或C 1 -C 6烷基羰基; k,当D为氮时,为1,2或3; 或当D为CH时,为1,2,3或4; m为1或2; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 从这些化合物或其农业化学上可接受的盐中选择活性成分,制备这些组合物的方法及其用途,用这些组合物处理的植物繁殖材料以及防治害虫的方法。
    • 4. 发明申请
    • PESTICIDALLY ACTIVE AMINOACETONITRILES
    • 农药活性氨基嘌呤
    • WO2003004474A1
    • 2003-01-16
    • PCT/EP2002/007515
    • 2002-07-05
    • SYNGENTA PARTICIPATIONS AGSTEIGER, ArthurEBERLE, MartinRENOLD, PeterO'SULLIVAN, Anthony, CorneliusZAMBACH, Werner
    • STEIGER, ArthurEBERLE, MartinRENOLD, PeterO'SULLIVAN, Anthony, CorneliusZAMBACH, Werner
    • C07D239/28
    • C07D239/28C07D237/14C07D239/34C07D241/16C07D241/18C07D241/24C07D333/32
    • Compounds of formula (I), wherein A 1 and A 2 are each independently of the other unsubstituted or mono- to penta-substituted aryl or unsubstituted or, depending upon the possibility of substitution at the ring, mono- to tetra-substituted heteroaryl bonded via a ring carbon atom; X and y are each independently of the other a bond, C 1 -C 6 alkylene, C 2 -C 6 alkenylene, C 2 -C 6 alkynylene, phenylene, -O-, -S- or C(=O)-; R 1 is, for example, hydrogen, C 1 -C 6 alkyl or halo-C 1 -C 6 alkyl; R2 is, for example, C 1 -C 6 alkyl, halo-C 1 -C 6 alkyl or C 1 -C 6 alkoxy-C 1 -C 6 alkyl; V is C 1 -C 6 alkylene, C 2 -C 6 alkenylene or C 2 -C 6 Alkynylene; W is O, S, -S(O)-, -S(O)-, -S(O 2 )- or N(R 3 ); and R 3 is hydrogen, C 1 -C 6 alkyl, -C(=O)-C 1 -C 6 alkyl or C 1 -C 6 alkyl or C 1 -C 6 alkyl-O-C 1 -C 6 alkyl; n is 0 or 1; and, when n is 1, R 4 and R 5 are, for example, hydrogen, C 1 -C 6 alkyl or halo-C 1 -C 6 akyl; and, where applicable, diastereoisomers, E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form; a process for the preparation of those compounds and their tautomers and the use thereof; pesticidal compositions in which the active ingredient has been selected from those compounds and their tautomers, and a process for the preparation of such compositions and the use thereof; intermediates, in free form or in salt form, for the preparation of such compounds and, where applicable, their tautomers, in free form or in salt form are described.
    • 式(I)化合物,其中A 1和A 2各自独立地为另一个未取代或单 - 或五 - 取代的芳基或未被取代的或根据在环上取代的可能性,通过一个或多个 - 环碳原子; X和Y各自独立地为键,C1-C6亚烷基,C2-C6亚烯基,C2-C6亚炔基,亚苯基,-O - , - S-或C(= O) - ; R 1是例如氢,C 1 -C 6烷基或卤代-C 1 -C 6烷基; R 2是例如C 1 -C 6烷基,卤代-C 1 -C 6烷基或C 1 -C 6烷氧基-C 1 -C 6烷基; V是C 1 -C 6亚烷基,C 2 -C 6亚烯基或C 2 -C 6亚炔基; W是O,S,-S(O) - , - S(O) - , - S(O 2) - 或N(R 3)。 且R 3为氢,C 1 -C 6烷基,-C(= O)-C 1 -C 6烷基或C 1 -C 6烷基或C 1 -C 6烷基-O-C 1 -C 6烷基; n为0或1; 当n为1时,R 4和R 5为例如氢,C 1 -C 6烷基或卤代C 1 -C 6烷基; 和/或互变异构体,在各种情况下均为游离形式或盐形式;以及(如适用)非对映异构体,E / Z异构体,E / Z异构体混合物和/或互变异构体。 制备这些化合物及其互变异构体的方法及其用途; 活性成分选自那些化合物及其互变异构体的杀虫组合物及其制备方法及其用途; 描述了游离形式或盐形式的中间体,用于制备这些化合物,并且在适用的情况下,其互变异构体以游离形式或盐形式。