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1. 发明申请

WO2012110383A2 HIGH YIELD STRENGTH LIGHTWEIGHT POLYMER-METAL HYBRID ARTICLES 审中-公开
标题翻译：高强度轻质聚合物 - 金属混合物品
公开(公告)号：WO2012110383A2
公开(公告)日：2012-08-23
申请号：PCT/EP2012/052155
申请日：2012-02-08
申请人： INTEGRAN TECHNOLOGIES , TOMANTSCHGER, Klaus , WANG, Andrew , NAGARAJAN, Nandakumar , NEACSU, Mioara
发明人： TOMANTSCHGER, Klaus , WANG, Andrew , NAGARAJAN, Nandakumar , NEACSU, Mioara
IPC分类号： C08J7/06
CPC分类号： C23C18/1653 , C23C18/31 , C23C24/08 , C25D5/54 , Y10T428/12569 , Y10T428/1355 , Y10T428/26 , Y10T428/30 , Y10T428/31507 , Y10T428/31511 , Y10T428/31544 , Y10T428/31605 , Y10T428/31678 , Y10T428/31681 , Y10T428/31688 , Y10T428/31696 , Y10T428/31699
摘要： A metal-clad polymer article includes a polymeric material with or without particulate addition. The polymeric material defines a permanent substrate. A metallic material covers at least part of a surface of the polymeric material. The metallic material has a microstructure which, at least in part, is at least one of fine-grained with an average grain size between 2 and 5,000 nm and amorphous. The metallic material has an elastic limit between 0.2% and 15%. At least one intermediate layer can be provided between the polymeric material and the metallic material. A stress on the polymeric material, at a selected operating temperature, reaches at least 60% of its ultimate tensile strength at a strain equivalent to the elastic limit of said metallic material.
摘要翻译：包覆金属的聚合物制品包括具有或不具有微粒添加的聚合物材料。聚合物材料限定永久性基材。金属材料覆盖聚合材料表面的至少一部分。所述金属材料具有至少部分为平均晶粒尺寸在2至5,000nm之间的细晶粒中的至少一种和非晶体的微结构。金属材料的弹性极限在0.2％至15％之间。可以在聚合材料和金属材料之间提供至少一个中间层。在所选择的工作温度下，聚合物材料的应力在与所述金属材料的弹性极限相当的应变下达到其极限拉伸强度的至少60％。

2. 发明申请

WO2011147757A1 ARTICLES WITH SUPER-HYDROPHOBIC AND/OR SELF-CLEANING SURFACES AND METHOD OF MAKING SAME 审中-公开
标题翻译：超级疏水和/或自清洁表面的制品及其制造方法
公开(公告)号：WO2011147757A1
公开(公告)日：2011-12-01
申请号：PCT/EP2011/058311
申请日：2011-05-21
申请人： INTEGRAN TECHNOLOGIES , VICTOR, Jared J. , ERB, Uwe , TOMANTSCHGER, Klaus , NAGARAJAN, Nandakumar , FACCHINI, Diana , NEACSU, Mioara
发明人： VICTOR, Jared J. , ERB, Uwe , TOMANTSCHGER, Klaus , NAGARAJAN, Nandakumar , FACCHINI, Diana , NEACSU, Mioara
IPC分类号： B29C37/00 , B29C59/02 , B08B17/06 , B29C39/02 , B29C39/14 , B29C43/02 , B29C43/22 , B29C45/26
CPC分类号： B29C59/02 , B29C37/0053 , B29C43/021 , B29C59/022 , B29C2043/025 , B29C2059/023 , Y10T428/139 , Y10T428/24355
摘要： Super-hydrophobic and self-cleaning articles produced by imprinting exposed surfaces with suitable fine-grained and/or amorphous metallic embossing dies to transfer a dual surface structure, including ultra- fine features less than or equal to 100nm embedded in and overlaying a surface topography with macro-surface structures greater than or equal to 1 micron are disclosed.
摘要翻译：通过用合适的细粒和/或无定形金属压花模印制暴露表面而制造的超疏水和自清洁制品，以转移双表面结构，包括嵌入在表面形貌中并覆盖表面形貌的超微细特征小于或等于100nm 公开了大于或等于1微米的宏观表面结构。

3. 发明申请

WO2011147756A1 METALLIC ARTICLES WITH HYDROPHOBIC SURFACES 审中-公开
标题翻译：具有疏水性表面的金属制品
公开(公告)号：WO2011147756A1
公开(公告)日：2011-12-01
申请号：PCT/EP2011/058310
申请日：2011-05-21
申请人： INTEGRAN TECHNOLOGIES , VICTOR, Jared, J. , ERB, Uwe , TOMANTSCHGER, Klaus , NAGARAJAN, Nandakumar , FACCHINI, Diana
发明人： VICTOR, Jared, J. , ERB, Uwe , TOMANTSCHGER, Klaus , NAGARAJAN, Nandakumar , FACCHINI, Diana
IPC分类号： C23C30/00 , C25D5/16 , C23C16/56 , C23C14/58
CPC分类号： C23C30/00 , C23C18/1653 , C23C24/04 , C25D1/006 , C25D1/02 , C25D1/10 , C25D5/16 , C25D5/48 , C25D15/00 , Y10T428/24355 , Y10T428/24372 , Y10T428/24405 , Y10T428/24413 , Y10T428/24421
摘要： Articles containing fine-grained and/or amorphous metallic coatings/layers on at least part of their exposed surfaces are imprinted with surface structures to raise the contact angle for water in the imprinted areas at room temperature by equal to or greater than 10°, when compared to the flat and smooth metallic material surface of the same composition.
摘要翻译：在其暴露表面的至少一部分上含有细粒和/或无定形金属涂层/层的制品印有表面结构，以在室温下的印刷区域中的水的接触角提高等于或大于10°，当相对于平整光滑的金属材料表面具有相同的组成。

4. 发明申请

WO2010139054A1 ELECTRODEPOSITED METALLIC MATERIALS COMPRISING COBALT 审中-公开
标题翻译：包含钴的电沉积金属材料
公开(公告)号：WO2010139054A1
公开(公告)日：2010-12-09
申请号：PCT/CA2010/000816
申请日：2010-05-31
申请人： INTEGRAN TECHNOLOGIES, INC. , FACCHINI, Diana , GONZALEZ, Francisco , MCCREA, Jonathan , UETZ, Mike , PALUMBO, Gino , TOMANTSCHGER, Klaus , NAGARAJAN, Nandakumar , VICTOR, Jared J. , ERB, Uwe
发明人： FACCHINI, Diana , GONZALEZ, Francisco , MCCREA, Jonathan , UETZ, Mike , PALUMBO, Gino , TOMANTSCHGER, Klaus , NAGARAJAN, Nandakumar , VICTOR, Jared J. , ERB, Uwe
IPC分类号： C25D3/12 , C25D7/00
CPC分类号： B32B15/01 , C22C19/07 , C25D3/12 , C25D3/562 , C25D15/00
摘要： Free standing articles or articles at least partially coated with substantially porosity free, fine-grained and/or amorphous Co-bearing metallic materials optionally containing solid particulates dispersed therein, are disclosed. The electrodeposited metallic layers and/or patches comprising Co provide, enhance or restore strength, wear and/or lubricity of substrates without reducing the fatigue performance compared to either uncoated or equivalent thickness Cr coated substrate. The fine-grained and/or amorphous metallic coatings comprising Co are particularly suited for articles exposed to thermal cycling, fatigue and other stresses and/or in applications requiring anti-microbial and hydrophobic properties.
摘要翻译：公开了至少部分地涂覆有基本上无孔隙的细颗粒和/或无定形的含Co金属材料的任选地含有分散在其中的固体颗粒的独立制品或制品。包含Co的电沉积金属层和/或贴剂提供，增强或恢复基材的强度，磨损和/或润滑性，而不降低与未涂覆或等效厚度的Cr涂覆的基材相比的疲劳性能。包含Co的细晶粒和/或无定形金属涂层特别适用于暴露于热循环，疲劳和其他应力的物品和/或需要抗微生物和疏水性质的应用中。

5. 发明申请

WO2010139053A1 METAL-CLAD POLYMER ARTICLE 审中-公开
标题翻译：金属聚合物制品
公开(公告)号：WO2010139053A1
公开(公告)日：2010-12-09
申请号：PCT/CA2010/000815
申请日：2010-05-31
申请人： INTEGRAN TECHNOLOGIES, INC. , TOMANTSCHGER, Klaus , MCCREA, Jonathan , NAGARAJAN, Nandakumar , GONZALEZ, Francisco , PALUMBO, Gino , PANAGIOTOPOULOS, Konstantinos , KATUGAHA, Herath , FACCHINI, Diana , VICTOR, Jared J. , ERB, Uwe
发明人： TOMANTSCHGER, Klaus , MCCREA, Jonathan , NAGARAJAN, Nandakumar , GONZALEZ, Francisco , PALUMBO, Gino , PANAGIOTOPOULOS, Konstantinos , KATUGAHA, Herath , VICTOR, Jared J. , ERB, Uwe
IPC分类号： B32B15/08 , C23C16/06
CPC分类号： C23C18/1641 , A63B59/70 , A63B2102/24 , B32B1/08 , B32B3/30 , B32B7/02 , B32B15/08 , B32B15/18 , B32B15/20 , B32B27/08 , B32B27/16 , B32B27/18 , B32B27/20 , B32B27/281 , B32B27/285 , B32B27/288 , B32B27/302 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B27/34 , B32B27/36 , B32B27/365 , B32B27/38 , B32B27/40 , B32B27/42 , B32B2255/06 , B32B2255/10 , B32B2255/20 , B32B2255/205 , B32B2262/101 , B32B2262/106 , B32B2264/02 , B32B2264/10 , B32B2264/12 , B32B2270/00 , B32B2307/202 , B32B2307/212 , B32B2307/30 , B32B2307/51 , B32B2307/538 , B32B2307/54 , B32B2307/718 , B32B2457/00 , B32B2509/00 , B32B2535/00 , B32B2597/00 , B32B2605/00 , C09J163/00 , C23C14/021 , C23C14/024 , C23C14/028 , C23C16/0227 , C23C16/0254 , C23C16/0272 , C23C18/1851 , C23C18/1855 , C23C18/1893 , C23C18/1896 , C25D5/54 , Y10T428/12111 , Y10T428/12389 , Y10T428/12451 , Y10T428/12472 , Y10T428/12569 , Y10T428/12944 , Y10T428/1355 , Y10T428/24355 , Y10T428/24545 , Y10T428/24612 , Y10T428/26 , Y10T428/269
摘要： Metal-clad polymer articles containing structural fine-grained and/or amorphous metallic coatings/layers optionally containing solid particulates dispersed therein, are disclosed. The fine-grained and/or amorphous metallic coatings are particularly suited for strong and lightweight articles, precision molds, sporting goods, automotive parts and components exposed to thermal cycling although the coefficient of linear thermal expansion (CLTE) of the metallic layer and the substrate are mismatched. The interface between the metallic layer and the polymer is suitably pretreated to withstand thermal cycling without failure.
摘要翻译：公开了包含分散在其中的任选地含有固体颗粒的结构细晶粒和/或非晶金属涂层/层的金属包层聚合物制品。细晶粒和/或非晶金属涂层特别适用于强而轻的制品，精密模具，运动用品，暴露于热循环的汽车部件和部件，尽管金属层和基材的线性热膨胀系数（CLTE）不匹配。金属层和聚合物之间的界面适当地经过预处理以承受热循环而不失败。

6. 发明申请

WO2009076777A1 METHOD FOR PREPARING POLYCRYSTALLINE STRUCTURES HAVING IMPROVED MECHANICAL AND PHYSICAL PROPERTIES 审中-公开
标题翻译：制备具有改进的机械和物理性能的多晶结构的方法
公开(公告)号：WO2009076777A1
公开(公告)日：2009-06-25
申请号：PCT/CA2008/002265
申请日：2008-12-18
申请人： INTEGRAN TECHNOLOGIES INC. , PALUMBO, Gino , BROOKS, Iain , TOMANTSCHGER, Klaus , LIN, Peter , AUST, Karl , NAGARAJAN, Nandakumar , GONZALEZ, Francisco
发明人： PALUMBO, Gino , BROOKS, Iain , TOMANTSCHGER, Klaus , LIN, Peter , AUST, Karl , NAGARAJAN, Nandakumar , GONZALEZ, Francisco
IPC分类号： C25D5/50
CPC分类号： C22F1/08 , C21D1/06 , C21D9/0068 , C25D3/12 , C25D3/38 , C25D5/50
摘要： Polycrystalline materials are prepared by electrodeposition of a precursor material that is subsequently heat-treated to induce at least a threefold increase in the grain size of the material to yield a relatively high fraction of 'special' low Σ grain boundaries and a randomized crystallographic texture. The precursor metallic material has sufficient purity and a fine-grained microstructure (e.g., an average grain size of 4 nm to 5 µm). The resulting metallic material is suited to the fabrication of articles requiring high mechanical or physical isotropy and/or resistance to grain boundary-mediated deformation or degradation mechanisms.
摘要翻译：通过电沉积前体材料来制备多晶材料，该前体材料随后进行热处理以诱导材料的晶粒尺寸至少增加三倍，从而产生相对较高的“特殊”低S晶界和随机晶体织构。前体金属材料具有足够的纯度和细粒度的微观结构（例如，平均粒度为4nm至5μm）。所得到的金属材料适于制造需要高机械或物理各向同性的物品和/或对晶界介导的变形或降解机理的抵抗力。

7. 发明申请

WO2014001401A1 METAL-CLAD HYBRID ARTICLE HAVING SYNERGETIC MECHANICAL PROPERTIES 审中-公开
标题翻译：具有协同机械性能的金属混合物
公开(公告)号：WO2014001401A1
公开(公告)日：2014-01-03
申请号：PCT/EP2013/063418
申请日：2013-06-26
申请人： INTEGRAN TECHNOLOGIES INC. , BROOKS, Iain
发明人： BROOKS, Iain , MCCREA, Jonathan , KATUGAHA, Herath , PALUMBO, Gino , PANAGIOTOPOULOS, Konstantinos , NAGARAJAN, Nandakumar , HIRMER, Gerhard
IPC分类号： C25D3/12 , C25D3/38 , C25D5/50 , C23C18/16 , H05K3/38 , C25D5/18 , C23C18/20
CPC分类号： C25D5/50 , B05D2201/06 , B32B15/06 , B32B15/18 , B32B15/20 , B32B25/08 , B32B27/20 , B32B2255/10 , B32B2255/205 , B32B2255/26 , B32B2262/106 , B32B2307/202 , B32B2307/702 , B32B2307/704 , B32B2307/714 , B32B2457/00 , B32B2605/00 , B32B2605/18 , C23C18/1653 , C23C18/2086 , C23C24/04 , H05K3/387 , Y10T428/31522 , Y10T428/31678
摘要： An article of manufacture includes a substrate having an outer surface clad with a metal construct including one or more continuous metal layers, at least one of which is an amorphous layer or a microcrystalline layer having a grain size below 5000 nm. A bonding layer is provided between the substrate and the layered metallic construct so that the bonding layer is in direct contact with the substrate and with the layered metallic construct. The bonding layer is made of a substantially fully cured resin including at least 10% of a rubber. The layered metallic construct has peel strength greater than 10N/cm. Also provided is a process for making the article including coating an article outer surface with a bonding layer and a layered metallic construct. The bonding layer is substantially fully cured before the layered metal construct is bonded to the article. The coated article is annealed.
摘要翻译：一种制品包括具有外表面的基材，该外表面包括金属构件，该金属构件包括一个或多个连续金属层，其中至少一个是非晶层或具有低于5000nm的晶粒尺寸的微晶层。在基板和层状金属构造体之间设置粘合层，使得粘结层与基底和层状金属构件直接接触。粘合层由包括至少10％的橡胶的基本完全固化的树脂制成。层状金属构造物的剥离强度大于10N / cm。还提供了一种用于制造制品的方法，包括用粘结层和层状金属构造物涂覆制品外表面。在层状金属构造物结合到制品之前，粘合层基本上完全固化。涂层制品退火。

8. 发明申请

WO2013064616A2 FLOW-THROUGH CONSUMABLE ANODES 审中-公开
标题翻译：流通消耗阳极
公开(公告)号：WO2013064616A2
公开(公告)日：2013-05-10
申请号：PCT/EP2012/071694
申请日：2012-11-02
申请人： INTEGRAN TECHNOLOGIES
发明人： TOMANTSCHGER, Klaus , FACCINI, Diana , GONZALES, Francisco , MCCREA, Jonathan , KRATOCHWIL, John , WOLOSHYN, Dan , BISMILLA, Yusuf , NAGARAJAN, Nandakumar , NEACSU, Mioara
IPC分类号： C25D5/06
CPC分类号： C25D5/06 , C25D1/00 , C25D5/08 , C25D5/18 , C25D17/14
摘要： Anode applicators include consumable anodes, that can be operated in a non-stationary mode and are insensitive to orientation, are used in selective plating/brush electrodeposition of coatings or free-standing components. The flow-through dimensionally- stable, consumable anodes employed are perforated/porous to provide relatively unimpeded electrolyte flow and operate at low enough electrochemical potentials to provide for anodic metal/alloy dissolution avoiding undesired anodic reactions. The consumable anodes include consumable anode material(s) in high surface area to reduce the local anodic current density. During electroplating, sufficient electrolyte is pumped through the consumable anodes at sufficient flow rates to minimize concentration gradient and/or avoid the generation of chlorine and/or oxygen gas and/or undesired reaction such as the anodic oxidation of P-bearing ions in the electrolyte. The active consumable anode material(s) can have a microstructure which is fine-grained and/or amorphous to ensure a uniform anodic dissolution.
摘要翻译：阳极施加器包括可以以非固定模式操作且对取向不敏感的消耗性阳极用于涂层或独立部件的选择性电镀/刷电沉积。所使用的流通尺寸稳定的消耗性阳极是穿孔/多孔的，以提供相对无阻抗的电解质流动并且在足够低的电化学电势下操作以提供阳极金属/合金溶解以避免不期望的阳极反应。消耗性阳极包括高表面积的消耗性阳极材料，以减少局部阳极电流密度。在电镀过程中，足够的电解液以足够的流速泵入消耗性阳极以使浓度梯度最小化和/或避免产生氯气和/或氧气和/或不期望的反应，例如电解液中含P离子的阳极氧化。活性消耗性阳极材料可以具有细晶粒和/或无定形的微结构，以确保均匀的阳极溶解。

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