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1. 发明申请

WO2007096359A3 METHOD FOR HIGH DENSITY DATA STORAGE AND IMAGING 审中-公开
标题翻译：高密度数据存储和成像方法
公开(公告)号：WO2007096359A3
公开(公告)日：2008-01-10
申请号：PCT/EP2007051622
申请日：2007-02-20
申请人： IBM , IBM UK , HEDRICK JAMES LUPTON , FROMMER JANE ELIZABETH , WINDELN JOHANNES , DUERIG URS , LEE VICTOR YEE-WAY , GOTSMANN BERND , MILLER ROBERT DENNIS , HAGBERG ERIK , MAGBITANG TEDDIE , KNOLL ARMIN , PRATT RUSSELL CLAYTON , WADE CHARLES
发明人： HEDRICK JAMES LUPTON , FROMMER JANE ELIZABETH , WINDELN JOHANNES , DUERIG URS , LEE VICTOR YEE-WAY , GOTSMANN BERND , MILLER ROBERT DENNIS , HAGBERG ERIK , MAGBITANG TEDDIE , KNOLL ARMIN , PRATT RUSSELL CLAYTON , WADE CHARLES
IPC分类号： C08G73/12 , G11B9/00
CPC分类号： G11B9/149 , B82Y10/00 , C08G73/101 , C08G73/1046 , C08G73/105 , C08G73/1053 , C08G73/1064 , G11B9/1409 , G11B9/1454 , G11B11/007 , G11B2005/0021 , Y10T428/265 , Y10T428/31721
摘要： An approach is presented for designing a polymeric layer for nanometer scale thermo-mechanical storage devices. Cross-linked polyimide oligomers are used as the recording layers in atomic force data storage device, giving significantly improved performance when compared to previously reported cross-linked and linear polymers. The cross-linking of the polyimide oligomers may be tuned to match thermal and force parameters required in read-write-erase cycles. Additionally, the cross-linked polyimide oligomers are suitable for use in nano-scale imaging.
摘要翻译：提出了一种用于设计用于纳米级热机械存储装置的聚合物层的方法。交联聚酰亚胺低聚物用作原子力数据存储装置中的记录层，与先前报道的交联和线性聚合物相比，显着提高了性能。可以调整聚酰亚胺低聚物的交联以匹配读写擦除周期中所需的热和强度参数。另外，交联聚酰亚胺低聚物适用于纳米级成像。

2. 发明申请

WO2008002889A3 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002889A3
公开(公告)日：2008-03-27
申请号：PCT/US2007072071
申请日：2007-06-26
申请人： GEN ELECTRIC , CHAN KWOK PONG , HAGBERG ERIK , MULLEN TARA J , ODLE ROY RAY , WHITE JAMES MITCHELL , YAMAGUCHI NORIMITSU
发明人： CHAN KWOK PONG , HAGBERG ERIK , MULLEN TARA J , ODLE ROY RAY , WHITE JAMES MITCHELL , YAMAGUCHI NORIMITSU
IPC分类号： C08K9/04 , C08J5/10 , C08J5/18 , C08K3/34 , C08K5/18 , C08K5/19 , C08K5/3432 , C08K5/50 , C08L71/00 , C08L79/08 , C08L81/04 , C08L81/06
CPC分类号： C08J3/201 , B82Y30/00 , C01B33/44 , C08J5/005 , C08K3/346 , C08K5/50 , C08K9/04
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a method of making a polymer-organoclay composite composition, said method comprising melt mixing a quaternary organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary organic cation with a polymeric resin comprising at least one polymer selected from the group consisting of polyamides, polyesters, polyarylene sulfides, polyarylene ethers, polyether sulfones, polyether ketones, polyether ether ketones, polyphenylenes, and polyphenylenes said polymeric resin being substantially free of polyetherimides; said melt mixing being carried out at a temperature in a range between about 300 °C and about 450 °C to provide a polymer-organoclay composite composition, said polymer-organoclay composite composition being characterized by a percent exfoliation of at least 10 percent.
摘要翻译：本发明涉及可用于制备有机粘土组合物，聚合物 - 有机粘土复合材料组合物和制备聚合物纳米复合材料的方法的有机盐组合物。在一个实施方案中，本发明提供了制备聚合物 - 有机粘土复合材料组合物的方法，所述方法包括熔融混合包含交替的无机硅酸盐层和有机层的季有机粘土组合物，所述有机层包含季铵有机阳离子与聚合树脂，选自聚酰胺，聚酯，聚亚芳基硫醚，聚亚芳基醚，聚醚砜，聚醚酮，聚醚醚酮，聚苯和聚苯的至少一种聚合物，所述聚合物树脂基本上不含聚醚酰亚胺; 所述熔体混合在约300℃至约450℃之间的温度下进行，以提供聚合物 - 有机粘土复合材料组合物，所述聚合物 - 有机粘土复合组合物的特征在于至少10％的剥离百分比。

3. 发明申请

WO2008002870A3 METHODS OF PREPARING POLYMER-ORGANOCLAY COMPOSITES AND ARTICLES DERIVED THEREFROM 审中-公开
标题翻译：制备聚合物 - 组织复合材料的方法及其衍生物
公开(公告)号：WO2008002870A3
公开(公告)日：2008-02-28
申请号：PCT/US2007072019
申请日：2007-06-25
申请人： GEN ELECTRIC , CHAN KWOK PONG , ODLE ROY RAY , HALL DAVID BRUCE , MAXAM JOHN LESTER , STELLA ALBERT SANTO , GENOVESE SARAH ELIZABETH , MULLEN TARA J , WHITE JAMES MITCHELL , HAGBERG ERIK
发明人： CHAN KWOK PONG , ODLE ROY RAY , HALL DAVID BRUCE , MAXAM JOHN LESTER , STELLA ALBERT SANTO , GENOVESE SARAH ELIZABETH , MULLEN TARA J , WHITE JAMES MITCHELL , HAGBERG ERIK
IPC分类号： C08F2/44 , C08K3/34 , C08K5/19 , C08K5/3432 , C08K5/50 , C08K9/04 , C08L79/08
CPC分类号： C08F2/44
摘要： A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.
摘要翻译：一种制备聚合物 - 有机粘土复合材料组合物的方法，包括将溶剂和未剥离的有机粘土组合以提供第一混合物，其中未剥离的有机粘土包含交替的无机硅酸盐层和有机层，并且在硅酸盐层之间具有初始间隔; 将第一混合物暴露于足够强度和持续时间的通电状态以增加无机硅酸盐层的初始间隔，以提供第二混合物; 使所述第二混合物与聚合物组合物接触，使得所述聚合物组合物填充位于至少一对硅酸盐层之间的至少一个区域，其中所述聚合物组合物至少部分地可溶于所述溶剂中; 以及从所述第二混合物中除去至少一部分所述溶剂，其中在去除所述溶剂之后，所述无机硅酸盐层保持被所述聚合物分离。

4. 发明申请

WO2008002888A2 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002888A2
公开(公告)日：2008-01-03
申请号：PCT/US2007072070
申请日：2007-06-26
申请人： GEN ELECTRIC , CHAN KWOK PONG , CROLL JOSHUA MCCLELLAN , GANESAN BALAKRISHNAN , HAGBERG ERIK , HARRIGAN MARCUS , KHOURI FARID FOUAD , KISHAN GURRAM , MATHUR RITESH , MAXAM JOHN LESTER , MULLEN TARA J , ODLE ROY RAY , RANGANATHAN SATHISH KUMAR , SUFFIELD RACHEL MARIE , WANG WENHUI , WHITE JAMES MITCHELL
发明人： CHAN KWOK PONG , CROLL JOSHUA MCCLELLAN , GANESAN BALAKRISHNAN , HAGBERG ERIK , HARRIGAN MARCUS , KHOURI FARID FOUAD , KISHAN GURRAM , MATHUR RITESH , MAXAM JOHN LESTER , MULLEN TARA J , ODLE ROY RAY , RANGANATHAN SATHISH KUMAR , SUFFIELD RACHEL MARIE , WANG WENHUI , WHITE JAMES MITCHELL
CPC分类号： C08K5/50
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a polymer-organoclay composite composition comprising (a) a polymeric resin; and (b) an organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary phosphonium cation having structure X wherein Ar 1 , Ar 2 , and Ar 3 are independently C 2 -C 50 aromatic radicals; Ar 4 is a bond or a C 2 -C 50 aromatic radical; "a" is a number from 1 to about 200; "c" is a number from 0 to 3; R 1 is independently at each occurrence a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, or a C 2 -C 20 aromatic radical; and R 2 is a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, a C 2 -C 50 aromatic radical, or a polymer chain.
摘要翻译：本发明涉及可用于制备有机粘土组合物的有机盐组合物，聚合物 - 有机粘土复合组合物和用于制备聚合物纳米复合材料的方法。在一个实施方案中，本发明提供了一种聚合物 - 有机粘土复合组合物，其包含（a）聚合物树脂; 和（b）包含交替的无机硅酸盐层和有机层的有机粘土组合物，所述有机层包含具有结构X的季鏻阳离子，其中Ar 1，Ar 2，Ar和Ar 3独立地为C 2 -C 50芳族基团; Ar 4是一个键或一个C 2 -C 50芳族基团; “a”是从1到约200的数字; “c”是从0到3的数字; R 1在每次出现时独立地为卤素原子，C 1 -C 20脂肪族基团，C 5 SUB > - C _{20 脂环族基团或C _{<2> _{20 芳族基团; 和R 2是卤素原子，C 1 -C 20脂肪族基团，C 5 -C 5脂肪族基团 20脂环族基团，C 2 -C 50芳族基团或聚合物链。}}}

5. 发明申请

WO2008039577A3 POLYIMIDE SOLVENT CAST FILMS HAVING LOW COEFFICIENT OF THERMAL EXPANSION AND METHOD OF MANUFACTURE THEREOF 审中-公开
标题翻译：具有低膨胀系数的聚酰亚胺溶剂型铸塑膜及其制造方法
公开(公告)号：WO2008039577A3
公开(公告)日：2008-12-04
申请号：PCT/US2007071205
申请日：2007-06-14
申请人： SABIC INNOVATIVE PLASTICS IP , CHAN KWOK PONG , HAGBERG ERIK , MULLEN TARA J , ODLE ROY RAY
发明人： CHAN KWOK PONG , HAGBERG ERIK , MULLEN TARA J , ODLE ROY RAY
IPC分类号： C08K3/08 , B32B5/18 , B32B27/32 , B44C5/04 , C08J5/18 , C08K5/134 , C08K13/02 , C08L79/08 , C23C18/54 , H05K9/00
CPC分类号： H05K1/0346 , B82Y30/00 , C08G73/1007 , C08J5/005 , C08J5/18 , C08J2379/08 , H05K1/0373 , H05K2201/0154 , H05K2201/0209 , H05K2201/0257 , H05K2201/068
摘要： A solvent cast film comprises a polyimide comprising structural units derived from polymerization of a dianhydride component comprising a dianhydride selected from the group consisting of 3,4'-oxydiphthalic dianhydride, 3,3'-oxydiphthalic dianhydride, 4,4'-oxydiphthalic dianhydride, and combinations thereof, with a diamine component wherein the polyimide has a glass transition temperature of at least 190°C; wherein the film has a coefficient of thermal expansion of less than 60 ppm/°C, a thickness from 0.1 to 250 micrometers, and less than 5% residual solvent by weight; wherein the polyimide has less than 15 molar % of structural units derived from a member selected from the group consisting of biphenyltetracarboxylic acid, a dianhydride of biphenyltetracarboxylic acid, an ester of biphenyltetracarboxylic acid, and a combination thereof.
摘要翻译：溶剂流延膜包含聚酰亚胺，所述聚酰亚胺包含衍生自包含选自3,4'-氧二邻苯二甲酸二酐，以及它们的组合，其中所述聚酰亚胺具有至少190℃的玻璃化转变温度; 其中所述膜具有小于60ppm /℃的热膨胀系数，0.1-250微米的厚度和小于5重量％的残留溶剂; 其中所述聚酰亚胺具有小于15摩尔％的衍生自选自联苯四羧酸，联苯四羧酸的二酐，联苯四羧酸的酯及其组合的成员的结构单元。

6. 发明申请

WO2008002891A2 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002891A2
公开(公告)日：2008-01-03
申请号：PCT/US2007072073
申请日：2007-06-26
申请人： GEN ELECTRIC , CAO FENG , CHAN KWOK PONG , HAGBERG ERIK , KHOURI FARID FOUAD , MULLEN TARA J , ODLE ROY RAY , WHITE JAMES MITCHELL , YAMAGUCHI NORIMITSU
发明人： CAO FENG , CHAN KWOK PONG , HAGBERG ERIK , KHOURI FARID FOUAD , MULLEN TARA J , ODLE ROY RAY , WHITE JAMES MITCHELL , YAMAGUCHI NORIMITSU
IPC分类号： C08F2/44 , C08K3/34 , C08K5/17 , C08K5/50 , C08K9/04 , C08L79/08
CPC分类号： C08F2/44
摘要： In one embodiment, the present invention provides a method of making a polymer- organoclay composite composition comprising (a) contacting under condensation polymerization conditions a first monomer, a second monomer, a solvent, and an organoclay composition, said organoclay composition comprising alternating inorganic silicate layers and organic layers, to provide a first polymerization reaction mixture, wherein one of said first monomer and second monomers is a diamine and the the other is an dianhydride; (b) carrying out a stoichiometry verification step on the first polymerization reaction mixture; (c) optionally adding additional reactant (monomer 1, monomer 2, or chainstopper) to the first polymerization reaction mixture to provide a second polymerization reaction mixture; and (d) removing solvent from the first polymerization reaction mixture or the second polymerization reaction mixture to provide a first polymer-organoclay composite composition comprising a polymer component and an organoclay component wherein the organoclay component is at least 10% exfoliated.
摘要翻译：在一个实施方案中，本发明提供制备聚合物 - 有机粘土复合组合物的方法，其包括（a）在缩聚条件下使第一单体，第二单体，溶剂和有机粘土组合物接触，所述有机粘土组合物包含交替的无机硅酸盐层和有机层，以提供第一聚合反应混合物，其中所述第一单体和第二单体之一是二胺，另一个是二酐; （b）在第一聚合反应混合物上进行化学计量验证步骤; （c）任选地向第一聚合反应混合物中加入另外的反应物（单体1，单体2或链闭锁剂）以提供第二聚合反应混合物; （d）从第一聚合反应混合物或第二聚合反应混合物中除去溶剂，以提供包含聚合物组分和有机粘土组分的第一聚合物 - 有机粘土复合组合物，其中有机粘土组分至少10％剥离。

7. 发明申请

WO2008002867A2 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002867A2
公开(公告)日：2008-01-03
申请号：PCT/US2007072015
申请日：2007-06-25
申请人： GEN ELECTRIC , CHAN KWOK PONG , ODLE ROY RAY , WHITE JAMES MITCHELL , HAGBERG ERIK
发明人： CHAN KWOK PONG , ODLE ROY RAY , WHITE JAMES MITCHELL , HAGBERG ERIK
IPC分类号： C08K9/04 , C08K3/34 , C08K5/3432
CPC分类号： C08K9/04 , C08K5/50
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a polymer-organoclay composite composition comprising (a) a polymeric resin; and (b) an organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a pyridinium cation having structure (Formula XXV), wherein Ar 6 , Ar 7, and Ar 8 are independently C 2 -C 50 aromatic radicals; "b" is a number from 0 to 2; R 3 is independently at each occurrence a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, or a C 2 -C 20 aromatic radical; and Ar 11 is a C 2 - C 200 aromatic radical, or a polymer chain comprising at least one aromatic group.
摘要翻译：本发明涉及可用于制备有机粘土组合物的有机盐组合物，聚合物 - 有机粘土复合组合物和用于制备聚合物纳米复合材料的方法。在一个实施方案中，本发明提供了一种聚合物 - 有机粘土复合组合物，其包含（a）聚合物树脂; 和（b）包含交替的无机硅酸盐层和有机层的有机粘土组合物，所述有机层包含具有结构（式XXV）的吡啶鎓阳离子，其中Ar 6，Ar 7，和Ar 8独立地为C 2 -C 50芳族基团; “b”是从0到2的数字; R 3在每次出现时独立地为卤素原子，C 1 -C 20脂肪族基团，C 5 SUB > - C _{20 脂环族基团或C _{<2> _{20 芳族基团; 并且Ar 11是C 2-20芳族基团或包含至少一个芳族基团的聚合物链。}}}

8. 发明申请

WO2011090812A3 PROCESSES FOR MAKING HIGH PURITY RENEWABLE SOURCE-BASED PLASTICIZERS AND PRODUCTS MADE THEREFROM 审中-公开
标题翻译：制造高纯度可再生能源的增塑剂及其制备方法
公开(公告)号：WO2011090812A3
公开(公告)日：2013-03-14
申请号：PCT/US2011020095
申请日：2011-01-04
申请人： ARCHER DANIELS MIDLAND CO , POLYONE CORP , HAGBERG ERIK , HORTON STEPHEN D , HOWARD STEPHEN , POPPE GEORGE B
发明人： HAGBERG ERIK , HORTON STEPHEN D , HOWARD STEPHEN , POPPE GEORGE B
IPC分类号： C08K5/1515
CPC分类号： C07D303/42 , C07C67/03 , C07C67/60 , C07C69/52 , C08K5/1515 , C11C3/003 , C08L27/06
摘要： Presently disclosed are high purity unsaturated fatty acid esters with an ester moiety characterized by having from five to seven members in a ring structure, which esters when epoxidized find particular utility as primary plasticizers in flexible polyvinyl halide applications. Also disclosed are processes for making the high purity esters.
摘要翻译：目前公开的是具有酯部分的高纯度不饱和脂肪酸酯，其特征在于在环结构中具有5-7个成员，当环氧化时，该酯特别用作柔性聚卤乙烯应用中的主要增塑剂。还公开了制备高纯度酯的方法。

9. 发明申请

WO2012121913A3 IMPROVED METHOD FOR QUANTITATIVE ANALYSIS OF SUGARS, SUGAR ALCOHOLS AND RELATED DEHYDRATION PRODUCTS 审中-公开
标题翻译：糖，糖和有关脱水产品的定量分析改进方法
公开(公告)号：WO2012121913A3
公开(公告)日：2013-01-31
申请号：PCT/US2012026707
申请日：2012-02-27
申请人： ARCHER DANIELS MIDLAND CO , HOWARD STEPHEN J , HAGBERG ERIK , ROCKAFELLOW ERIN
发明人： HOWARD STEPHEN J , HAGBERG ERIK , ROCKAFELLOW ERIN
IPC分类号： G01N33/00 , G01N30/02
CPC分类号： G01N33/98 , G01N30/88 , G01N33/0013 , G01N33/50 , G01N2030/884 , Y10T436/143333
摘要： An improved method is provided for the quantitative analysis of mixtures including various sugars, sugar alcohols and related dehydration products, whereby these are enabled to be effectively and accurately quantitated through gas chromatography, for example, by their derivatization with a carboxylic acid, carboxylic acid anhydride or halide in the presence of a metal triflate catalyst. The method can be carried out at essentially room temperature conditions, with a sufficiently rapid and complete derivatization, even in the presence of substantial amounts of water, that the materials to be quantitated do not substantially break down or degrade and substantially completely accounted for in a derivatized form.
摘要翻译：提供了一种改进的方法，用于定量分析包括各种糖，糖醇和相关脱水产物的混合物，由此可以通过气相色谱法有效和准确地定量，例如通过它们用羧酸，羧酸酐衍生化或卤化物在金属三氟甲磺酸酯催化剂存在下进行。该方法可以在基本上室温条件下进行，甚至在存在大量水的情况下也能充分快速和完全的衍生化，待定量的材料基本上不会分解或降解，并且基本上完全占据了衍生形式。

10. 发明申请

WO2008002880A3 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002880A3
公开(公告)日：2008-04-24
申请号：PCT/US2007072036
申请日：2007-06-25
申请人： GEN ELECTRIC , CHAN KWOK PONG , MAXAM JOHN LESTER , ODLE ROY RAY , MULLEN TARA J , WHITE JAMES MITCHELL , HAGBERG ERIK
发明人： CHAN KWOK PONG , MAXAM JOHN LESTER , ODLE ROY RAY , MULLEN TARA J , WHITE JAMES MITCHELL , HAGBERG ERIK
IPC分类号： C08K9/04 , C08K3/34 , C08K5/50 , C08L71/00 , C08L79/08 , C08L81/06
CPC分类号： C08F2/44 , C01P2002/72 , C01P2004/04 , C08K9/04 , C08L79/08 , C09C1/42
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a polymer-organoclay composite composition comprising (a) a polymeric resin; and (b) an organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary phosphonium cation having structure (XXXIII) wherein Ar 12 , Ar 13 , Ar 14 and Ar 15 are independently C 2 -C 50 aromatic radicals; and Ar 16 is a C 2 -C 200 aromatic radical, or a polymer chain comprising at least one aromatic group.
摘要翻译：本发明涉及可用于制备有机粘土组合物，聚合物 - 有机粘土复合材料组合物和制备聚合物纳米复合材料的方法的有机盐组合物。在一个实施方案中，本发明提供了一种聚合物 - 有机粘土复合材料组合物，其包含（a）聚合物树脂; 和（b）包含交替的无机硅酸盐层和有机层的有机粘土组合物，所述有机层包含具有结构（XXXIII）的季鏻阳离子，其中Ar 12，Ar 13， Ar 14和Ar 15独立地是C 2 -C 50芳族基团; 和Ar 16是C 2 -C 20芳族基团，或包含至少一个芳族基团的聚合物链。

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