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1. 发明申请

WO2008002888A2 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002888A2
公开(公告)日：2008-01-03
申请号：PCT/US2007072070
申请日：2007-06-26
申请人： GEN ELECTRIC , CHAN KWOK PONG , CROLL JOSHUA MCCLELLAN , GANESAN BALAKRISHNAN , HAGBERG ERIK , HARRIGAN MARCUS , KHOURI FARID FOUAD , KISHAN GURRAM , MATHUR RITESH , MAXAM JOHN LESTER , MULLEN TARA J , ODLE ROY RAY , RANGANATHAN SATHISH KUMAR , SUFFIELD RACHEL MARIE , WANG WENHUI , WHITE JAMES MITCHELL
发明人： CHAN KWOK PONG , CROLL JOSHUA MCCLELLAN , GANESAN BALAKRISHNAN , HAGBERG ERIK , HARRIGAN MARCUS , KHOURI FARID FOUAD , KISHAN GURRAM , MATHUR RITESH , MAXAM JOHN LESTER , MULLEN TARA J , ODLE ROY RAY , RANGANATHAN SATHISH KUMAR , SUFFIELD RACHEL MARIE , WANG WENHUI , WHITE JAMES MITCHELL
CPC分类号： C08K5/50
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a polymer-organoclay composite composition comprising (a) a polymeric resin; and (b) an organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary phosphonium cation having structure X wherein Ar 1 , Ar 2 , and Ar 3 are independently C 2 -C 50 aromatic radicals; Ar 4 is a bond or a C 2 -C 50 aromatic radical; "a" is a number from 1 to about 200; "c" is a number from 0 to 3; R 1 is independently at each occurrence a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, or a C 2 -C 20 aromatic radical; and R 2 is a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, a C 2 -C 50 aromatic radical, or a polymer chain.
摘要翻译：本发明涉及可用于制备有机粘土组合物的有机盐组合物，聚合物 - 有机粘土复合组合物和用于制备聚合物纳米复合材料的方法。在一个实施方案中，本发明提供了一种聚合物 - 有机粘土复合组合物，其包含（a）聚合物树脂; 和（b）包含交替的无机硅酸盐层和有机层的有机粘土组合物，所述有机层包含具有结构X的季鏻阳离子，其中Ar 1，Ar 2，Ar和Ar 3独立地为C 2 -C 50芳族基团; Ar 4是一个键或一个C 2 -C 50芳族基团; “a”是从1到约200的数字; “c”是从0到3的数字; R 1在每次出现时独立地为卤素原子，C 1 -C 20脂肪族基团，C 5 SUB > - C _{20 脂环族基团或C _{<2> _{20 芳族基团; 和R 2是卤素原子，C 1 -C 20脂肪族基团，C 5 -C 5脂肪族基团 20脂环族基团，C 2 -C 50芳族基团或聚合物链。}}}

2. 发明申请

WO2008002889A3 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002889A3
公开(公告)日：2008-03-27
申请号：PCT/US2007072071
申请日：2007-06-26
申请人： GEN ELECTRIC , CHAN KWOK PONG , HAGBERG ERIK , MULLEN TARA J , ODLE ROY RAY , WHITE JAMES MITCHELL , YAMAGUCHI NORIMITSU
发明人： CHAN KWOK PONG , HAGBERG ERIK , MULLEN TARA J , ODLE ROY RAY , WHITE JAMES MITCHELL , YAMAGUCHI NORIMITSU
IPC分类号： C08K9/04 , C08J5/10 , C08J5/18 , C08K3/34 , C08K5/18 , C08K5/19 , C08K5/3432 , C08K5/50 , C08L71/00 , C08L79/08 , C08L81/04 , C08L81/06
CPC分类号： C08J3/201 , B82Y30/00 , C01B33/44 , C08J5/005 , C08K3/346 , C08K5/50 , C08K9/04
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a method of making a polymer-organoclay composite composition, said method comprising melt mixing a quaternary organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary organic cation with a polymeric resin comprising at least one polymer selected from the group consisting of polyamides, polyesters, polyarylene sulfides, polyarylene ethers, polyether sulfones, polyether ketones, polyether ether ketones, polyphenylenes, and polyphenylenes said polymeric resin being substantially free of polyetherimides; said melt mixing being carried out at a temperature in a range between about 300 °C and about 450 °C to provide a polymer-organoclay composite composition, said polymer-organoclay composite composition being characterized by a percent exfoliation of at least 10 percent.
摘要翻译：本发明涉及可用于制备有机粘土组合物，聚合物 - 有机粘土复合材料组合物和制备聚合物纳米复合材料的方法的有机盐组合物。在一个实施方案中，本发明提供了制备聚合物 - 有机粘土复合材料组合物的方法，所述方法包括熔融混合包含交替的无机硅酸盐层和有机层的季有机粘土组合物，所述有机层包含季铵有机阳离子与聚合树脂，选自聚酰胺，聚酯，聚亚芳基硫醚，聚亚芳基醚，聚醚砜，聚醚酮，聚醚醚酮，聚苯和聚苯的至少一种聚合物，所述聚合物树脂基本上不含聚醚酰亚胺; 所述熔体混合在约300℃至约450℃之间的温度下进行，以提供聚合物 - 有机粘土复合材料组合物，所述聚合物 - 有机粘土复合组合物的特征在于至少10％的剥离百分比。

3. 发明申请

WO2008002870A3 METHODS OF PREPARING POLYMER-ORGANOCLAY COMPOSITES AND ARTICLES DERIVED THEREFROM 审中-公开
标题翻译：制备聚合物 - 组织复合材料的方法及其衍生物
公开(公告)号：WO2008002870A3
公开(公告)日：2008-02-28
申请号：PCT/US2007072019
申请日：2007-06-25
申请人： GEN ELECTRIC , CHAN KWOK PONG , ODLE ROY RAY , HALL DAVID BRUCE , MAXAM JOHN LESTER , STELLA ALBERT SANTO , GENOVESE SARAH ELIZABETH , MULLEN TARA J , WHITE JAMES MITCHELL , HAGBERG ERIK
发明人： CHAN KWOK PONG , ODLE ROY RAY , HALL DAVID BRUCE , MAXAM JOHN LESTER , STELLA ALBERT SANTO , GENOVESE SARAH ELIZABETH , MULLEN TARA J , WHITE JAMES MITCHELL , HAGBERG ERIK
IPC分类号： C08F2/44 , C08K3/34 , C08K5/19 , C08K5/3432 , C08K5/50 , C08K9/04 , C08L79/08
CPC分类号： C08F2/44
摘要： A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.
摘要翻译：一种制备聚合物 - 有机粘土复合材料组合物的方法，包括将溶剂和未剥离的有机粘土组合以提供第一混合物，其中未剥离的有机粘土包含交替的无机硅酸盐层和有机层，并且在硅酸盐层之间具有初始间隔; 将第一混合物暴露于足够强度和持续时间的通电状态以增加无机硅酸盐层的初始间隔，以提供第二混合物; 使所述第二混合物与聚合物组合物接触，使得所述聚合物组合物填充位于至少一对硅酸盐层之间的至少一个区域，其中所述聚合物组合物至少部分地可溶于所述溶剂中; 以及从所述第二混合物中除去至少一部分所述溶剂，其中在去除所述溶剂之后，所述无机硅酸盐层保持被所述聚合物分离。

4. 发明申请

WO2008002880A3 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002880A3
公开(公告)日：2008-04-24
申请号：PCT/US2007072036
申请日：2007-06-25
申请人： GEN ELECTRIC , CHAN KWOK PONG , MAXAM JOHN LESTER , ODLE ROY RAY , MULLEN TARA J , WHITE JAMES MITCHELL , HAGBERG ERIK
发明人： CHAN KWOK PONG , MAXAM JOHN LESTER , ODLE ROY RAY , MULLEN TARA J , WHITE JAMES MITCHELL , HAGBERG ERIK
IPC分类号： C08K9/04 , C08K3/34 , C08K5/50 , C08L71/00 , C08L79/08 , C08L81/06
CPC分类号： C08F2/44 , C01P2002/72 , C01P2004/04 , C08K9/04 , C08L79/08 , C09C1/42
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a polymer-organoclay composite composition comprising (a) a polymeric resin; and (b) an organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary phosphonium cation having structure (XXXIII) wherein Ar 12 , Ar 13 , Ar 14 and Ar 15 are independently C 2 -C 50 aromatic radicals; and Ar 16 is a C 2 -C 200 aromatic radical, or a polymer chain comprising at least one aromatic group.
摘要翻译：本发明涉及可用于制备有机粘土组合物，聚合物 - 有机粘土复合材料组合物和制备聚合物纳米复合材料的方法的有机盐组合物。在一个实施方案中，本发明提供了一种聚合物 - 有机粘土复合材料组合物，其包含（a）聚合物树脂; 和（b）包含交替的无机硅酸盐层和有机层的有机粘土组合物，所述有机层包含具有结构（XXXIII）的季鏻阳离子，其中Ar 12，Ar 13， Ar 14和Ar 15独立地是C 2 -C 50芳族基团; 和Ar 16是C 2 -C 20芳族基团，或包含至少一个芳族基团的聚合物链。

5. 发明申请

WO2008002866A3 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002866A3
公开(公告)日：2008-02-28
申请号：PCT/US2007072013
申请日：2007-06-25
申请人： GEN ELECTRIC , CHAN KWOK PONG , ODLE ROY RAY , MULLEN TARA J , WHITE JAMES MITCHELL , HAGBERG ERIK
发明人： CHAN KWOK PONG , ODLE ROY RAY , MULLEN TARA J , WHITE JAMES MITCHELL , HAGBERG ERIK
IPC分类号： C08K9/04 , C08K3/34 , C08K5/50
CPC分类号： C08K9/04 , C08K5/50
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides an organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary phosphonium cation having structure (Formula XXXIII), wherein Ar 12 , Ar 13 , Ar 14 and Ar 15 are independently C 2 -C 50 aromatic radicals; and Ar 16 is a C 2 -C 200 aromatic radical, or a polymer chain comprising at least one aromatic group.
摘要翻译：本发明涉及可用于制备有机粘土组合物，聚合物 - 有机粘土复合材料组合物和制备聚合物纳米复合材料的方法的有机盐组合物。在一个实施方案中，本发明提供了一种有机粘土组合物，其包含交替的无机硅酸盐层和有机层，所述有机层包含具有结构（式XXXIII）的季鏻阳离子，其中Ar 12， 13，Ar 14和Ar 15独立地是C 2 -C 50芳族基团; 和Ar 16是C 2 -C 20芳族基团，或包含至少一个芳族基团的聚合物链。

6. 发明申请

WO2008002890A3 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002890A3
公开(公告)日：2008-03-27
申请号：PCT/US2007072072
申请日：2007-06-26
申请人： GEN ELECTRIC , CHAN KWOK PONG , CROLL JOSHUA MCCLELLAN , HAGBERG ERIK , MAXAM JOHN LESTER , MULLEN TARA J , ODLE ROY RAY , SUFFIELD RACHEL MARIE , WHITE JAMES MITCHELL , YAMAGUCHI NORIMITSU
发明人： CHAN KWOK PONG , CROLL JOSHUA MCCLELLAN , HAGBERG ERIK , MAXAM JOHN LESTER , MULLEN TARA J , ODLE ROY RAY , SUFFIELD RACHEL MARIE , WHITE JAMES MITCHELL , YAMAGUCHI NORIMITSU
IPC分类号： C08J3/20 , C08J5/10 , C08J5/18 , C08K3/34 , C08K5/18 , C08K5/19 , C08K5/3432 , C08K5/50 , C08K9/04 , C08L79/08
CPC分类号： C08J5/18 , C08J3/201 , C08J5/10 , C08J2379/08 , C08K3/346 , C08K5/18 , C08K5/19 , C08K5/3432 , C08K5/50 , C08K9/04
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a method of making a polymer-organoclay composite composition, said method comprising melt mixing a quaternary organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary organic cation with a polyetherimide composition; said melt mixing being carried out at a temperature in a range between about 300°C and about 450°C to provide a polymer-organoclay composite composition, said polymer-organoclay composite composition being characterized by a percent exfoliation of at least 10 percent.
摘要翻译：本发明涉及可用于制备有机粘土组合物的有机盐组合物，聚合物 - 有机粘土复合组合物和用于制备聚合物纳米复合材料的方法。在一个实施方案中，本发明提供制备聚合物 - 有机粘土复合组合物的方法，所述方法包括熔融混合包含交替的无机硅酸盐层和有机层的季有机粘土组合物，所述有机层包含季聚有机阳离子和聚醚酰亚胺组合物; 所述熔融混合在约300℃至约450℃范围内的温度下进行以提供聚合物 - 有机粘土复合组合物，所述聚合物 - 有机粘土复合组合物的特征在于至少10％的百分比剥落。

7. 发明申请

WO2008002891A2 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002891A2
公开(公告)日：2008-01-03
申请号：PCT/US2007072073
申请日：2007-06-26
申请人： GEN ELECTRIC , CAO FENG , CHAN KWOK PONG , HAGBERG ERIK , KHOURI FARID FOUAD , MULLEN TARA J , ODLE ROY RAY , WHITE JAMES MITCHELL , YAMAGUCHI NORIMITSU
发明人： CAO FENG , CHAN KWOK PONG , HAGBERG ERIK , KHOURI FARID FOUAD , MULLEN TARA J , ODLE ROY RAY , WHITE JAMES MITCHELL , YAMAGUCHI NORIMITSU
IPC分类号： C08F2/44 , C08K3/34 , C08K5/17 , C08K5/50 , C08K9/04 , C08L79/08
CPC分类号： C08F2/44
摘要： In one embodiment, the present invention provides a method of making a polymer- organoclay composite composition comprising (a) contacting under condensation polymerization conditions a first monomer, a second monomer, a solvent, and an organoclay composition, said organoclay composition comprising alternating inorganic silicate layers and organic layers, to provide a first polymerization reaction mixture, wherein one of said first monomer and second monomers is a diamine and the the other is an dianhydride; (b) carrying out a stoichiometry verification step on the first polymerization reaction mixture; (c) optionally adding additional reactant (monomer 1, monomer 2, or chainstopper) to the first polymerization reaction mixture to provide a second polymerization reaction mixture; and (d) removing solvent from the first polymerization reaction mixture or the second polymerization reaction mixture to provide a first polymer-organoclay composite composition comprising a polymer component and an organoclay component wherein the organoclay component is at least 10% exfoliated.
摘要翻译：在一个实施方案中，本发明提供制备聚合物 - 有机粘土复合组合物的方法，其包括（a）在缩聚条件下使第一单体，第二单体，溶剂和有机粘土组合物接触，所述有机粘土组合物包含交替的无机硅酸盐层和有机层，以提供第一聚合反应混合物，其中所述第一单体和第二单体之一是二胺，另一个是二酐; （b）在第一聚合反应混合物上进行化学计量验证步骤; （c）任选地向第一聚合反应混合物中加入另外的反应物（单体1，单体2或链闭锁剂）以提供第二聚合反应混合物; （d）从第一聚合反应混合物或第二聚合反应混合物中除去溶剂，以提供包含聚合物组分和有机粘土组分的第一聚合物 - 有机粘土复合组合物，其中有机粘土组分至少10％剥离。

8. 发明申请

WO2008002867A2 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002867A2
公开(公告)日：2008-01-03
申请号：PCT/US2007072015
申请日：2007-06-25
申请人： GEN ELECTRIC , CHAN KWOK PONG , ODLE ROY RAY , WHITE JAMES MITCHELL , HAGBERG ERIK
发明人： CHAN KWOK PONG , ODLE ROY RAY , WHITE JAMES MITCHELL , HAGBERG ERIK
IPC分类号： C08K9/04 , C08K3/34 , C08K5/3432
CPC分类号： C08K9/04 , C08K5/50
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a polymer-organoclay composite composition comprising (a) a polymeric resin; and (b) an organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a pyridinium cation having structure (Formula XXV), wherein Ar 6 , Ar 7, and Ar 8 are independently C 2 -C 50 aromatic radicals; "b" is a number from 0 to 2; R 3 is independently at each occurrence a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, or a C 2 -C 20 aromatic radical; and Ar 11 is a C 2 - C 200 aromatic radical, or a polymer chain comprising at least one aromatic group.
摘要翻译：本发明涉及可用于制备有机粘土组合物的有机盐组合物，聚合物 - 有机粘土复合组合物和用于制备聚合物纳米复合材料的方法。在一个实施方案中，本发明提供了一种聚合物 - 有机粘土复合组合物，其包含（a）聚合物树脂; 和（b）包含交替的无机硅酸盐层和有机层的有机粘土组合物，所述有机层包含具有结构（式XXV）的吡啶鎓阳离子，其中Ar 6，Ar 7，和Ar 8独立地为C 2 -C 50芳族基团; “b”是从0到2的数字; R 3在每次出现时独立地为卤素原子，C 1 -C 20脂肪族基团，C 5 SUB > - C _{20 脂环族基团或C _{<2> _{20 芳族基团; 并且Ar 11是C 2-20芳族基团或包含至少一个芳族基团的聚合物链。}}}

9. 发明申请

WO2008002868A3 PYRIDINIUM SALTS FOR POLYMER COMPOSITES AND METHODS FOR THEIR PREPARATION 审中-公开
标题翻译：聚合物复合材料的PYRIDINIUM SALTS及其制备方法
公开(公告)号：WO2008002868A3
公开(公告)日：2008-02-28
申请号：PCT/US2007072017
申请日：2007-06-25
申请人： GEN ELECTRIC , CHAN KWOK PONG , WHITE JAMES MITCHELL
发明人： CHAN KWOK PONG , WHITE JAMES MITCHELL
IPC分类号： C08K9/04 , C07D213/06 , C07D213/20 , C07D401/14 , C07D411/12 , C08K3/34 , C08K5/50 , C08L71/00 , C08L79/08 , C08L81/06
CPC分类号： C07D411/12 , C07D213/06 , C07D213/20 , C07D401/14 , C08K5/50
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a pyridinium salt having structure XV; wherein Ar 6 , Ar 7 , and Ar 8 are independently C 2 -C 50 aromatic radicals; "b" is a number from 0 to 2; "d" is a number from 0 to 4; R 3 and R 4 are independently at each occurrence a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, or a C 2 -C 20 aromatic radical; Z is a bond, a divalent C 1 -C 20 aliphatic radical, a divalent C 5 -C 20 cycloaliphatic radical, a divalent C 2 -C 20 aromatic radical, an oxygen linking group, a sulfur linking group, a SO 2 linking group, or a Se linking group; Ar 9 is a C 10 - C 200 aromatic radical, or a polymer chain comprising at least one aromatic group; and X - is a charge balancing counterion.
摘要翻译：本发明涉及可用于制备有机粘土组合物，聚合物 - 有机粘土复合材料组合物和制备聚合物纳米复合材料的方法的有机盐组合物。在一个实施方案中，本发明提供具有结构XV的吡啶鎓盐; 其中Ar 6，Ar 7和Ar 8独立地是C 2 -C 50，芳基; “b”是从0到2的数字; “d”是从0到4的数字; R 3和R 4在每次出现时独立地为卤原子，C 1 -C 20脂族基团，C 5 -C 20脂环族基团或C 2 -C 20 -C 20芳族基团; Z是键，二价C 1 -C 20脂肪族基团，二价C 5 -C 20脂族基团，脂环族基团，二价C 2 -C 20芳族基团，氧连接基团，硫连接基团，SO 2连接基团，或Se连接组; 芳族基团是包含至少一个芳族基团的聚合物链; 而X - SUP是电荷平衡抗衡离子。

10. 发明申请

WO2008002887A2 COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES 审中-公开
标题翻译：聚合物复合材料的组合物和方法
公开(公告)号：WO2008002887A2
公开(公告)日：2008-01-03
申请号：PCT/US2007072069
申请日：2007-06-26
申请人： GEN ELECTRIC , CROLL JOSHUA , WHITE JAMES MITCHELL , WANG WENHUI , KHOURI FARID FOUAD , HARRIGAN MARCUS , CHAN KWOK PONG , SUFFIELD RACHEL MARIE
发明人： CROLL JOSHUA , WHITE JAMES MITCHELL , WANG WENHUI , KHOURI FARID FOUAD , HARRIGAN MARCUS , CHAN KWOK PONG , SUFFIELD RACHEL MARIE
CPC分类号： C08K5/50
摘要： This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides an organoclay composition comprising alternating inorganic silicate layers and organic layers, said organic layers comprising a quaternary phosphonium cation having structure (X) wherein Ar 1, Ar 2 , and Ar 3 are independently C 2 -C 50 aromatic radicals; Ar 4 is a bond or a C 2 -C 50 aromatic radical; "a" is a number from 1 to about 200; "c" is a number from 0 to 3; R 1 is independently at each occurrence a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, or a C 2 -C 20 aromatic radical; and R 2 is a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, a C 2 -C 50 aromatic radical, or a polymer chain.
摘要翻译：本发明涉及可用于制备有机粘土组合物，聚合物 - 有机粘土复合材料组合物和制备聚合物纳米复合材料的方法的有机盐组合物。在一个实施方案中，本发明提供了一种有机粘土组合物，其包含交替的无机硅酸盐层和有机层，所述有机层包含具有结构（X）的季鏻阳离子，其中Ar 1， / SUP>和Ar 3独立地为C 2 -C 50芳族基团; Ar 4是一个键或一个C 2 -C 50芳族基团; “a”是从1到大约200的数字; “c”是从0到3的数字; R 1在每次出现时独立地为卤素原子，C 1 -C 20脂族基团，C 5 H 12 -C 20脂环族基团或C 2 -C 20芳族基团; 和R 2是卤素原子，C 1 -C 20脂族基团，C 5 -C 20个脂环族基团，C 2 -C 20 - 50芳族基团或聚合物链。

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