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    • 1. 发明申请
    • PHOSPHORESCENT IRIDIUM COMPLEXES
    • 磷酸盐复合物
    • WO2010051100A1
    • 2010-05-06
    • PCT/US2009/056160
    • 2009-09-08
    • GENERAL ELECTRIC COMPANYLITZ, Kyle, ErikCHICHAK, Kelly, ScottWHISENHUNT, Donald, Wayne, Jr.
    • LITZ, Kyle, ErikCHICHAK, Kelly, ScottWHISENHUNT, Donald, Wayne, Jr.
    • C07F15/00C07F15/06C09K11/06H01L51/00
    • C07F15/0046C07F15/0033C07F15/06Y10S428/917
    • Metal complexes of formula I and IA and polymers derived from the complexes are useful in optoelectronic devices (see I and IA) wherein M is Ir, Co or Rh; XX is a cyclometallated ligand (see XX); R 1 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, or substituted arylalkyl; R 2 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl; and at least one of R 1 and R 2 is other than hydrogen; R 1a is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, or substituted arylalkyl; R 2a is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl; and at least one of R 1a and R 2a is substituted alkyl, substituted aryl, substituted arylalkyl, and at least one substitutent of the substituted alkyl, substituted aryl, or substituted arylalkyl is a polymehzable group.
    • 式I和IA的金属络合物和衍生自络合物的聚合物可用于光电器件(见I和IA),其中M是Ir,Co或Rh; XX是环金属配体(参见XX); R 1是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基或取代的芳基烷基; R2是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基,取代的芳基烷基; 并且R 1和R 2中的至少一个不是氢; R 1a是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基或取代的芳基烷基; R2a是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基,取代的芳基烷基; 并且R 1a和R 2a中的至少一个是取代的烷基,取代的芳基,取代的芳烷基,并且取代的烷基,取代的芳基或取代的芳烷基的至少一个取代基是可聚合的基团。
    • 5. 发明申请
    • POLYCARBAZOLYL(METH)ACRYLATE LIGHT EMISSIVE COMPOSITIONS
    • 聚甲基丙烯酸(甲基)丙烯酸酯光敏组合物
    • WO2008130806A1
    • 2008-10-30
    • PCT/US2008/059110
    • 2008-04-02
    • GENERAL ELECTRIC COMPANYYE, QingLIU, JieLITZ, Kyle, Erik
    • YE, QingLIU, JieLITZ, Kyle, Erik
    • C08F230/04H05B33/14
    • C08F230/04C07F15/0033C09K11/06C09K2211/1007C09K2211/1011C09K2211/1029C09K2211/1044C09K2211/1092C09K2211/185H01L51/004H01L51/0042H01L51/0043H01L51/0085H01L51/5016H05B33/14
    • The present invention provides polymer derived from a monomer of formula I and a polymerizable phosphorescent organometallic compound of formula L' 2 MZ', wherein R 1 is H or CH 3 ; R 2 is H or C 1 -C 5 alkyl; R 3 is H or CH 3 ; R 4 and R 5 are independently H, CH 3 , t-butyl, triarylsilyl, trialkylsilyl, diphenyl phosphine oxide, or diphenyl phosphine sulfide; m ranges from 1 to about 20; n ranges from 1 to about 20; L' and Z' are independently bidentate ligands; at least one of L' and Z' comprises at least one substituent selected from C 2-20 alkenyl, C 2-20 alkynyl, C 2-20 substituted alkenyl, C 2-20 substituted alkynyl, C 2-20 alkenyloxy, C 2-20 alkynyloxy, styryl, acryloyl, and methacryloyl; and M is Ga, Al, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Lr, Rf, Db, Sg, Bbh, Hs, Mt, Ds, Rg, Uub, Eu, Tb, La, Po, or a combination thereof. The polymers of the invention are useful as light emissive layers in light emitting devices. Thus, the present invention also provides an organic light emitting device comprising a light emissive layer comprising a polymer derived from a monomer of formula I, and a polymerizable phosphorescent organometallic compound of formula L' 2 MZ'.
    • 本发明提供衍生自式I单体的聚合物和式L'2 MZ'的可聚合磷光有机金属化合物,其中R 1是H或CH 2, 3 ; R 2是H或C 1 -C 5烷基; R 3是H或CH 3 N; R 4和R 5独立地为H,CH 3,叔丁基,三芳基甲硅烷基,三烷基甲硅烷基,二苯基氧化膦或二苯基硫化膦; m范围从1到大约20; n范围从1到约20; L'和Z'独立为二齿配体; L'和Z'中的至少一个包含至少一个选自C 2-20 - 烯基,C 2-20炔基,C 2-20环烷基, 取代的烯基,C 2-20取代的炔基,C 2-20链烯氧基,C 2-20炔氧基,苯乙烯基,丙烯酰基, 和甲基丙烯酰基; 并且M是Ga,Al,Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Y,Zr,Nb,Mo,Tc,Ru,Rh,Pd,Ag,Cd,Lu,Hf ,Ta,W,Re,Os,Ir,Pt,Au,Hg,Lr,Rf,Db,Sg,Bbh,Hs,Mt,Ds,Rg,Uub,Eu,Tb,La,Po或其组合。 本发明的聚合物可用作发光器件中的发光层。 因此,本发明还提供了一种有机发光器件,其包括包含衍生自式I单体的聚合物的光发射层和式L'2 MZ'的可聚合磷光有机金属化合物。