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    • 2. 发明申请
    • POLYCARBAZOLYL(METH)ACRYLATE LIGHT EMISSIVE COMPOSITIONS
    • 聚甲基丙烯酸(甲基)丙烯酸酯光敏组合物
    • WO2008130806A1
    • 2008-10-30
    • PCT/US2008/059110
    • 2008-04-02
    • GENERAL ELECTRIC COMPANYYE, QingLIU, JieLITZ, Kyle, Erik
    • YE, QingLIU, JieLITZ, Kyle, Erik
    • C08F230/04H05B33/14
    • C08F230/04C07F15/0033C09K11/06C09K2211/1007C09K2211/1011C09K2211/1029C09K2211/1044C09K2211/1092C09K2211/185H01L51/004H01L51/0042H01L51/0043H01L51/0085H01L51/5016H05B33/14
    • The present invention provides polymer derived from a monomer of formula I and a polymerizable phosphorescent organometallic compound of formula L' 2 MZ', wherein R 1 is H or CH 3 ; R 2 is H or C 1 -C 5 alkyl; R 3 is H or CH 3 ; R 4 and R 5 are independently H, CH 3 , t-butyl, triarylsilyl, trialkylsilyl, diphenyl phosphine oxide, or diphenyl phosphine sulfide; m ranges from 1 to about 20; n ranges from 1 to about 20; L' and Z' are independently bidentate ligands; at least one of L' and Z' comprises at least one substituent selected from C 2-20 alkenyl, C 2-20 alkynyl, C 2-20 substituted alkenyl, C 2-20 substituted alkynyl, C 2-20 alkenyloxy, C 2-20 alkynyloxy, styryl, acryloyl, and methacryloyl; and M is Ga, Al, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Lr, Rf, Db, Sg, Bbh, Hs, Mt, Ds, Rg, Uub, Eu, Tb, La, Po, or a combination thereof. The polymers of the invention are useful as light emissive layers in light emitting devices. Thus, the present invention also provides an organic light emitting device comprising a light emissive layer comprising a polymer derived from a monomer of formula I, and a polymerizable phosphorescent organometallic compound of formula L' 2 MZ'.
    • 本发明提供衍生自式I单体的聚合物和式L'2 MZ'的可聚合磷光有机金属化合物,其中R 1是H或CH 2, 3 ; R 2是H或C 1 -C 5烷基; R 3是H或CH 3 N; R 4和R 5独立地为H,CH 3,叔丁基,三芳基甲硅烷基,三烷基甲硅烷基,二苯基氧化膦或二苯基硫化膦; m范围从1到大约20; n范围从1到约20; L'和Z'独立为二齿配体; L'和Z'中的至少一个包含至少一个选自C 2-20 - 烯基,C 2-20炔基,C 2-20环烷基, 取代的烯基,C 2-20取代的炔基,C 2-20链烯氧基,C 2-20炔氧基,苯乙烯基,丙烯酰基, 和甲基丙烯酰基; 并且M是Ga,Al,Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Y,Zr,Nb,Mo,Tc,Ru,Rh,Pd,Ag,Cd,Lu,Hf ,Ta,W,Re,Os,Ir,Pt,Au,Hg,Lr,Rf,Db,Sg,Bbh,Hs,Mt,Ds,Rg,Uub,Eu,Tb,La,Po或其组合。 本发明的聚合物可用作发光器件中的发光层。 因此,本发明还提供了一种有机发光器件,其包括包含衍生自式I单体的聚合物的光发射层和式L'2 MZ'的可聚合磷光有机金属化合物。
    • 6. 发明申请
    • PORPHYRIN COMPOSITIONS
    • 吡啶组合物
    • WO2006076247A2
    • 2006-07-20
    • PCT/US2006/000572
    • 2006-01-09
    • GENERAL ELECTRIC COMPANYLITZ, Kyle, ErikCELLA, James, AnthonyYE, Qing
    • LITZ, Kyle, ErikCELLA, James, AnthonyYE, Qing
    • C07D487/22C09K11/07
    • C07D487/22
    • Novel metal porphyrin compositions useful as organic phosphors are provided. The novel compositions are prepared from commercially available porphyrin-containing starting materials. In one instance a novel palladium-containing porphyrin composition having a number average molecular weight of greater than 12,000 grams per mole was prepared from 5,10,15,20-tetrakis(3',5'-di(hydroxy)phenyl)-21H-23H- porphyrin by reaction first with palladium(II) acetylacetonate, followed by reaction with 2-bromo-2-methylpropionyl bromide, and subsequent group transfer reaction of the alpha-bromo ester groups with 9,9-dioctyl-2-vinylfluorene in the presence of CuBr as a radical initiator. The product polymer exhibited a number average molecular weight of 12,884 grams per mole, a weight average molecular weight of 14,338 grams per mole, and a robust red phosphorescent emission. Porphyrin containing copoylmers comprising structural units derived from 9,9-dioctyl-2- vinylfluorene and 9-anthracenylmethyl methacrylate were prepared in a similar fashion.
    • 提供了可用作有机磷光体的新型金属卟啉组合物。 该新型组合物由市售的含卟啉原料制备。 在一种情况下,从5,10,15,20-四(3',5'-二(羟基)苯基)-21H(5')中制备数均分子量大于12,000克/摩尔的新颖的含钯卟啉组合物 -23H-卟啉通过首先与乙酰丙酮钯(II)反应,随后与2-溴-2-甲基丙酰溴反应,随后α-溴酯基与9,9-二辛基-2-乙烯基芴的组转移反应 存在CuBr作为自由基引发剂。 产物聚合物的数均分子量为12,884克/摩尔,重均分子量为14,338克/摩尔,并且具有坚固的红色磷光发射。 含有衍生自9,9-二辛基-2-乙烯基芴和9-蒽基甲基甲基丙烯酸酯的结构单元的含卟啉的共聚酰基酯以类似的方式制备。
    • 9. 发明申请
    • PHOSPHORESCENT IRIDIUM COMPLEXES
    • 磷酸盐复合物
    • WO2010051100A1
    • 2010-05-06
    • PCT/US2009/056160
    • 2009-09-08
    • GENERAL ELECTRIC COMPANYLITZ, Kyle, ErikCHICHAK, Kelly, ScottWHISENHUNT, Donald, Wayne, Jr.
    • LITZ, Kyle, ErikCHICHAK, Kelly, ScottWHISENHUNT, Donald, Wayne, Jr.
    • C07F15/00C07F15/06C09K11/06H01L51/00
    • C07F15/0046C07F15/0033C07F15/06Y10S428/917
    • Metal complexes of formula I and IA and polymers derived from the complexes are useful in optoelectronic devices (see I and IA) wherein M is Ir, Co or Rh; XX is a cyclometallated ligand (see XX); R 1 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, or substituted arylalkyl; R 2 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl; and at least one of R 1 and R 2 is other than hydrogen; R 1a is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, or substituted arylalkyl; R 2a is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl; and at least one of R 1a and R 2a is substituted alkyl, substituted aryl, substituted arylalkyl, and at least one substitutent of the substituted alkyl, substituted aryl, or substituted arylalkyl is a polymehzable group.
    • 式I和IA的金属络合物和衍生自络合物的聚合物可用于光电器件(见I和IA),其中M是Ir,Co或Rh; XX是环金属配体(参见XX); R 1是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基或取代的芳基烷基; R2是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基,取代的芳基烷基; 并且R 1和R 2中的至少一个不是氢; R 1a是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基或取代的芳基烷基; R2a是氢,烷基,取代的烷基,芳基,取代的芳基,芳基烷基,取代的芳基烷基; 并且R 1a和R 2a中的至少一个是取代的烷基,取代的芳基,取代的芳烷基,并且取代的烷基,取代的芳基或取代的芳烷基的至少一个取代基是可聚合的基团。