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1. 发明申请

WO2010077351A1 SOUR SERVICE HYDROPROCESSING FOR LUBRICANT BASE OIL PRODUCTION 审中-公开
标题翻译：用于润滑油基础油生产的服务水处理
公开(公告)号：WO2010077351A1
公开(公告)日：2010-07-08
申请号：PCT/US2009/006737
申请日：2009-12-30
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , PRENTICE, Krista, M. , SCHLEICHER, Gary, P. , ZHANG, Lei , HILBERT, Timothy, L. , DAAGE, Michel, A. , HANTZER, Sylvain , LAI, Wenyih, F. , MENTZER, David , HEANEY, William, F. , ELIA, Christine, N. , MCCARTHY, Stephen, J. , LUO, Shifang, L.
发明人： PRENTICE, Krista, M. , SCHLEICHER, Gary, P. , ZHANG, Lei , HILBERT, Timothy, L. , DAAGE, Michel, A. , HANTZER, Sylvain , LAI, Wenyih, F. , MENTZER, David , HEANEY, William, F. , ELIA, Christine, N. , MCCARTHY, Stephen, J. , LUO, Shifang, L.
IPC分类号： C10G65/04 , C10G67/00
CPC分类号： C10G45/62 , C10G2300/202 , C10G2300/207 , C10G2400/10
摘要： An integrated process for producing lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or a high pressure separation can be used to partially eliminate contaminants.
摘要翻译：提供了一种在酸性条件下从原料生产润滑剂基础油的综合方法。在较高硫条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。可以将酸性进料输送到催化脱蜡步骤，而不会分离硫和氮污染物，或者可以使用高压分离来部分地消除污染物。

2. 发明申请

WO2010074722A1 HIGH ACTIVITY MTT FRAMEWORK TYPE MOLECULAR SIEVES 审中-公开
标题翻译：高活性MTT框架类型分子筛
公开(公告)号：WO2010074722A1
公开(公告)日：2010-07-01
申请号：PCT/US2009/006558
申请日：2009-12-15
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , LAI, Wenyih, F. , ELIA, Christine, N.
发明人： LAI, Wenyih, F. , ELIA, Christine, N.
IPC分类号： B01J29/06
CPC分类号： C10G45/64 , B01J29/70 , B01J29/74 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C01B39/065 , C01B39/48
摘要： A process is described of producing an MTT framework type molecular sieve by crystallizing a mixture capable of forming said molecular sieve, wherein the mixture comprises sources of alkali or alkaline earth metal (M), an oxide of trivalent element (X), an oxide of tetravalent element (Y), water and a directing agent (R) of the formula (CH 3 ) 3 N + CH 2 CH 2 CH 2 N + (CH 3 ) 2 CH 2 CH 2 CH 2 N + (CH 3 ) 3 , and has a composition, in terms of mole ratios, within the following ranges: YO 2 /X 2 O 3 less than 45 H 2 O/YO 2 5 to 100 OH - /YO 2 0.05 to 0.5 M/YO 2 0.05 to 0.5 and R/YO 2 >0 to
摘要翻译：描述了通过使能够形成所述分子筛的混合物结晶来生产MTT框架型分子筛的方法，其中所述混合物包含碱金属或碱土金属（M）的源，三价元素（X）的氧化物，四价元素（Y），水和式（CH 3）3 N + CH 2 CH 2 CH 2 N +（CH 3）2 CH 2 CH 2 CH 2 N +（CH 3）3的定向剂（R），并且具有以摩尔比计在下列范围内的组成：YO 2 / X2O3小于45H 2 O / YO 2 5〜100 OH- / YO 2 0.05〜0.5 M / YO 2 0.05〜0.5，R / YO 2> 0〜0.5。

3. 发明申请

WO2010077308A1 DEWAXING CATALYSTS AND PROCESSES 审中-公开
标题翻译：脱蜡催化剂和工艺
公开(公告)号：WO2010077308A1
公开(公告)日：2010-07-08
申请号：PCT/US2009/006563
申请日：2009-12-15
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , ELIA, Christine, N. , LAI, Wenyih, F.
发明人： ELIA, Christine, N. , LAI, Wenyih, F.
IPC分类号： B01J21/00
CPC分类号： C10G45/62 , B01J29/70 , B01J29/74 , B01J29/76 , B01J29/78 , B01J29/80 , B01J2229/20 , B01J2229/42 , C10G45/12 , C10G45/64 , C10G47/18 , C10G2300/1062 , C10G2300/301 , C10G2400/02 , C10G2400/04 , C10G2400/10
摘要： A process for dewaxing a waxy component-containing hydrocarbon feedstock comprises contacting the feedstock under dewaxing conditions with a catalyst system comprising ZSM-48 and a molecular sieve of the MTT framework type.
摘要翻译：用于脱蜡含蜡组分的烃原料的方法包括在脱蜡条件下将原料与包含ZSM-48和MTT骨架类型的分子筛的催化剂体系接触。

4. 发明申请

WO2009038740A2 SYNTHESIS OF HIGH ACTIVITY ZSM-48 审中-公开
标题翻译：高活性合成ZSM-48
公开(公告)号：WO2009038740A2
公开(公告)日：2009-03-26
申请号：PCT/US2008/010855
申请日：2008-09-18
申请人： EXXONMOBILE RESEARCH AND ENGINEERING COMPANY , LAI, Wenyih, F. , ROTH, Wieslaw, J. , KAY, Robert, E. , ELIA, Christine, N.
发明人： LAI, Wenyih, F. , ROTH, Wieslaw, J. , KAY, Robert, E. , ELIA, Christine, N.
IPC分类号： C01B33/26 , C07C7/00
CPC分类号： C01B39/48 , B01J29/703 , B01J29/7461 , B01J35/0066 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C10G45/64 , C10G2300/1022
摘要： A process for producing ZSM-48 comprises crystallizing an aqueous reaction mixture comprising at least one source of silica, at least one source of alumina, at least one source of hydroxyl ions, at least one source of diquaternary alkylammonium, R2+, ions having the formula: (CH 3 ) 3 N + (CH 2 ) 5 N + (CH 3 ) 3 and optionally ZSM-48 seed crystals, wherein said reaction mixture has a composition including the following molar ratios: R 2+ :SiO 2 less than 0.1 SiO 2 :Al 2 O 3 less than 100
摘要翻译：一种生产ZSM-48的方法包括使包含至少一种二氧化硅源，至少一种氧化铝源，至少一种羟基离子源，至少一种二季烷基铵R2 +的源，R2 +，具有式：（CH 3）3 N +（CH 2）5 N +（CH 3）3和任选的ZSM-48晶种，其中所述反应混合物具有包括以下摩尔比的组成：R2 +：SiO 2小于0.1SiO 2：Al 2 O 3小于100

5. 发明申请

WO2011133326A3 XYLENES ISOMERIZATION PROCESS AND CATALYST THEREFOR 审中-公开
公开(公告)号：WO2011133326A3
公开(公告)日：2011-10-27
申请号：PCT/US2011/031445
申请日：2011-04-06
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , OU, John, D., Y. , ROSS, April, D. , LEVIN, Doron , KALYANARAMAN, Mohan , LAI, Wenyih, F.
发明人： OU, John, D., Y. , ROSS, April, D. , LEVIN, Doron , KALYANARAMAN, Mohan , LAI, Wenyih, F.
IPC分类号： C07C5/27 , C07C15/08 , B01J29/40 , B01J29/70
摘要： The invention concerns a xylenes isomerization process for the production of equilibrium or near-equilibrium xylenes. The process utilizes a catalyst comprising HZSM-5 or MCM-49 and process conditions including a temperature of less than 295°C and a pressure sufficient to maintain the xylenes in liquid phase. In embodiments, the process can be operated in a continuous mode with ppm levels of dissolved H 2 in the feed and in other embodiments in a cyclic mode without the H2 in feed but with periodic regenerations using a feed having low ppm levels of H 2 .

6. 发明申请

WO2009055215A1 METHOD OF MAKING M41S FAMILY MOLECULAR SIEVE 审中-公开
标题翻译：制备M41S家族分子筛的方法
公开(公告)号：WO2009055215A1
公开(公告)日：2009-04-30
申请号：PCT/US2008/078310
申请日：2008-09-30
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , LAI, Wenyih, F. , KAY, Robert, Ellis , MCCARTHY, Stephen, J.
发明人： LAI, Wenyih, F. , KAY, Robert, Ellis , MCCARTHY, Stephen, J.
IPC分类号： C01B39/00 , B01J29/04
CPC分类号： C01B37/02 , B01J29/0308 , B01J29/0333 , B01J29/041 , B01J29/044 , B01J29/70 , B01J29/76 , B01J29/82 , B01J29/83 , B01J29/84 , B01J29/85 , B01J2229/42 , C01B37/005 , C01B37/04 , C01B37/06 , C01B37/065 , C01B37/08 , C01B39/48 , C01B39/54
摘要： This disclosure relates to a novel method of making and recovering M41S family molecular sieve materials using synthesis mixtures having high solids-content and without a purification step. The solids-content, for example, is in a range from about 20 wt.% to 50 wt.%. The method also includes the step of mixing at least a portion of the M41S made with another material to form a composition, wherein the amount of said material to be mixed with said M41S product is such that said composition having less than 10 wt.% free fluid. The material mixed with the M41S made includes metal oxides, metal nitrides, metal carbides and mixtures thereof, as well as absorptive material capable of absorbing mother liquor and selected from the group consisting of carbon silica, alumina, titania, zirconia and mixtures thereof. The amount of the wastewater generated by this novel method is reduced by at least 50% to as much as 100% as comparing with conventional method of making M41S materials. By reducing and/or eliminating at least a portion of the wastewater generated in the synthesis product, the new method reduces cost of making of M41S materials and provides a more environmentally-friendly synthesis product.
摘要翻译：本公开涉及使用具有高固体含量并且没有纯化步骤的合成混合物制备和回收M41S家族分子筛材料的新方法。固体含量例如在约20重量％至50重量％的范围内。该方法还包括将至少一部分与另一种材料制成的M41S混合以形成组合物的步骤，其中与所述M41S产物混合的所述材料的量使得所述组合物的含量小于10重量％流体。与M41S混合的材料包括金属氧化物，金属氮化物，金属碳化物及其混合物，以及能够吸收母液并且选自碳二氧化硅，氧化铝，二氧化钛，氧化锆及其混合物的吸收材料。与传统的制备M41S材料的方法相比，这种新方法产生的废水量减少至少50％至多达100％。通过减少和/或消除在合成产物中产生的至少一部分废水，新方法降低了M41S材料的制造成本并提供了更环保的合成产品。

7. 发明申请

WO2012141834A1 SYNTHESIS AND USE OF M41S FAMILY MOLECULAR SIEVES 审中-公开
标题翻译：合成和使用M41S家族分子筛
公开(公告)号：WO2012141834A1
公开(公告)日：2012-10-18
申请号：PCT/US2012/028819
申请日：2012-03-12
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , LAI, Wenyih, F. , MCCARTHY, Stephen, J. , KAY, Robert, E.
发明人： LAI, Wenyih, F. , MCCARTHY, Stephen, J. , KAY, Robert, E.
IPC分类号： B01J29/04 , B01J29/03 , C01B37/00 , C01B37/02 , B01J37/02 , B01J37/00 , C10G45/64 , C10G45/62
CPC分类号： B01J29/74 , B01J29/0308 , B01J29/0325 , B01J29/041 , B01J29/043 , B01J29/70 , B01J35/1023 , B01J37/0009 , B01J37/0018 , B01J37/0045 , B01J37/0201 , B01J37/04 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C01B39/48 , C10G45/12 , C10G45/54 , C10G2300/1062 , C10G2400/10
摘要： A process is described for producing an M41 S family molecular sieve. The process comprises preparing a synthesis mixture capable of forming said molecular sieve in a reactor, which is equipped with a mixer having a Froude number of at least 1, said synthesis mixture having a solids content of at least 20 wt%. The synthesis mixture is heated in the reactor while agitating the mixture with said mixer to form a product mixture comprising water and crystals of said molecular sieve material. Thereafter at least part of the water is removed from the product mixture in the reactor so as to decrease the water content of the product mixture inside the reactor by at least 5 wt%.
摘要翻译：描述了用于生产M41S家族分子筛的方法。该方法包括制备能在反应器中形成所述分子筛的合成混合物，所述反应器装备有弗劳德数至少为1的混合器，所述合成混合物具有至少20重量％的固体含量。将合成混合物在反应器中加热，同时用所述混合器搅拌混合物，以形成包含水和所述分子筛材料晶体的产物混合物。此后，将至少部分水从反应器中的产物混合物中除去，以将反应器内的产物混合物的水含量降低至少5wt％。

8. 发明申请

WO2019236265A1 NAPHTAH HYDRODESULFURIZATION 审中-公开
公开(公告)号：WO2019236265A1
公开(公告)日：2019-12-12
申请号：PCT/US2019/032787
申请日：2019-05-17
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： BAI, Chuansheng , CUNNINGHAM, Majosefina , JOHNSON, Gregory, R. , LAI, Wenyih, F. , O'NEILL, Brandon, J.
IPC分类号： C10G45/08 , C10G45/12 , B01J23/882 , B01J29/072 , B01J29/46 , B01J37/20 , B01J35/10
摘要： Systems and methods are provided for performing selective hydrodesulfurization on a naphtha boiling range stream naphtha boiling range portion of a feed. It has been unexpectedly discovered that hydrodesulfurization with improved octane retention can be performed by using a catalyst that comprises CoMo supported on a catalyst support that includes a zeotype framework. By using a catalyst support including a zeotype framework, an unexpectedly high amount of octane in the naphtha boiling range portion of the hydrodesulfurized effluent is maintained.

9. 发明申请

WO2017222765A1 ISOPARAFFIN-OLEFIN ALKYLATION 审中-公开
标题翻译：异链烷烃 - 烯烃烷基化
公开(公告)号：WO2017222765A1
公开(公告)日：2017-12-28
申请号：PCT/US2017/035349
申请日：2017-06-01
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： METTLER, Matthew, S. , DAKKA, Jihad, M. , JOHNSON, Ivy, D. , PRIGOZHINA, Stefani , SMITH, Charles, M. , LONERGAN, William, W. , LOVELESS, Brett , ELIA, Christine, N. , LAI, Wenyih, F.
IPC分类号： C07C2/62 , C07C9/16 , C07C9/21
CPC分类号： B01J29/7038 , B01J29/035 , B01J29/18 , B01J35/026 , B01J37/0018 , B01J37/06 , B01J37/08 , B01J2229/42 , C07C2/58 , C07C2/62 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2529/035 , C07C2529/18 , C07C2529/70 , C07C9/16
摘要： In a process for the catalytic alkylation of an olefin with an isoparaffi, an olefin- containing feed is contacted with an isoparaffin-containing feed under alkylation conditions in the presence of a solid acid catalyst comprising a crystalline microporous material of at least one of the MWW and MOR framework types, wherein the solid acid catalyst is substantially free of amorphous alumina.
摘要翻译：在用异链烷烃催化烷基化烯烃的方法中，在包含结晶微孔的固体酸催化剂的存在下，使含烯烃的进料与烷基化条件下的含异链烷烃进料接触至少一种MWW和MOR骨架类型的材料，其中固体酸催化剂基本上不含无定形氧化铝。

10. 发明申请

WO2017112377A1 BASE METAL DEWAXING CATALYST 审中-公开
标题翻译：碱金属脱蜡催化剂
公开(公告)号：WO2017112377A1
公开(公告)日：2017-06-29
申请号：PCT/US2016/064144
申请日：2016-11-30
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： MCCARTHY, Stephen, J. , BAI, Chuansheng , LAI, Wenyih, F. , PODSIADLO, Paul , LONERGAN, William, W.
IPC分类号： C10G45/62 , C10G45/64 , C10G45/10 , C10G45/12 , B01J29/44 , B01J29/46 , B01J29/48 , B01J29/70 , B01J37/00 , B01J37/02 , B01J37/20 , C10G65/04
CPC分类号： C10G45/64 , B01J29/48 , B01J29/7861 , B01J2229/186 , B01J2229/42 , C10G45/10 , C10G45/12 , C10G45/62 , C10G65/043 , C10G2400/04 , C10G2400/10
摘要： Methods are provided for making base metal catalysts with improved activity. After forming catalyst particles based on a support comprising a zeolitic molecular sieve, the catalyst particles can be impregnated with a solution comprising a) metal salts (or other precursors) for a plurality of base metals and b) an organic dispersion agent comprising 2 to 10 carbons. The impregnated support particles can be dried to form a base metal catalyst, and then optionally sulfided to form a sulfided base metal catalyst. The resulting (sulfided) base metal catalyst can have improved activity for cloud point reduction and/or for improved activity for heteroatom removal, relative to a base metal dewaxing catalyst prepared without the use of a dispersion agent.
摘要翻译：提供了用于制备具有改善的活性的贱金属催化剂的方法。在形成基于包含沸石分子筛的载体的催化剂颗粒之后，可以用包含a）用于多种贱金属的金属盐（或其他前体）和b）包含2至10 碳。浸渍的载体颗粒可以被干燥以形成贱金属催化剂，然后任选地被硫化以形成硫化的贱金属催化剂。与不使用分散剂制备的贱金属脱蜡催化剂相比，所得（硫化）贱金属催化剂可降低浊点降低活性和/或提高杂原子去除活性。

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