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    • 4. 发明申请
    • SYNTHESIS AND USE OF ZSM-12
    • ZSM-12的合成及应用
    • WO2011017506A2
    • 2011-02-10
    • PCT/US2010/044527
    • 2010-08-05
    • EXXONMOBIL RESEARCH AND ENGINEERING COMPANYLAI, Frank, W.ELKS, Jeffrey, T.KAY, Robert, E.
    • LAI, Frank, W.ELKS, Jeffrey, T.KAY, Robert, E.
    • B01J29/70
    • B01J29/7034C01B39/42C07C6/126C07C2529/70C10G45/64C10G2300/1096C10G2400/30Y02P20/52C07C15/08
    • A process is described for synthesizing a porous, crystalline material having the framework structure of ZSM- 12 of the formula: (n)YO 2 : X 2 O 3 wherein X is a trivalent element, Y is a tetravalent element and n is between about 80 and about 250. In the process, a mixture capable of forming said material is prepared comprising sources of alkali or alkaline earth metal (M), an oxide of trivalent element (X), an oxide of tetravalent element (Y), hydroxyl ions (OH'), water and tetraethylammonium cations (R), wherein said mixture has a composition, in terms of mole ratios, within the following ranges: YO 2 /X 2 O 3 = 100 to 300; H 2 O/YO 2 = 5 to 15; OH - /YO 2 = 0.10 to 0.30; M/Y0 2 = 0.05 to 0.30; and R/YO 2 = 0.10 to 0.20. The mixture is reacted at a temperature of at least about 300° F (149° C) for a time of less than about 50 hours to form crystals of the crystalline material and the crystalline material is then recovered.
    • 描述了用于合成具有下式的ZSM-12骨架结构的多孔晶体材料的方法:(n)YO 2:X 2: 其中X是三价元素,Y是四价元素且n在约80和约250之间。在该方法中,制备能够形成所述材料的混合物,其包含 碱金属或碱土金属(M),三价元素(X)的氧化物,四价元素(Y)的氧化物,羟基离子(OH'),水和四乙基铵阳离子(R),其中所述混合物具有 在以下范围内:摩尔比的项:YO 2 / X 2 O 3 = 100至300; H 2 O / YO 2 = 5至15; OH - / - YO 2 = 0.10至0.30; M / Y0 2 = 0.05至0.30; 和R / YO 2 = 0.10至0.20。 该混合物在至少约300℃的温度下反应。 F(149℃)的时间小于约50小时以形成晶体材料的晶体,然后回收晶体材料。