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    • 7. 发明申请
    • STRUCTURED ZIRCONIUM SOLUTIONS
    • 结构化的ZIRCONIUM解决方案
    • WO2017072507A1
    • 2017-05-04
    • PCT/GB2016/053332
    • 2016-10-27
    • MAGNESIUM ELEKTRON LIMITED
    • SCAPENS, David Alastair
    • C01G25/00C01G25/06B01J13/00
    • C01G25/02B01J21/066B01J23/10B01J35/1014B01J35/1038B01J37/031B01J37/04B01J37/06B01J37/08B01J2523/00C01F17/00C01F17/0018C01P2002/60C01P2006/12C01P2006/13C01P2006/14C01P2006/16C01P2006/17B01J2523/3706B01J2523/3712B01J2523/3718B01J2523/48B01J2523/36B01J2523/3725
    • This invention relates to azirconium solution or sol comprising:(a) zirconium,(b) nitrate, acetate and/or chloride ions, and(c) one or more complexing agents being an organic compound comprising at least one of the following functional groups: an amine, an organosulphate, a sulphonate, a hydroxyl, an etheror a carboxylic acid group,wherein the molar ratio of components (a):(b) is 1:0.7to 1:4.0,the molar ratio of components (a):(c) is 1:0.0005 to 1:0.1, and thepH of the zirconium solution or sol is less than 5. The invention also relates to a process for preparing a zirconium solution or sol, the process comprising the steps of:(a)dissolving a zirconium salt in nitric, acetic and/or hydrochloric acid, and(b)adding one or more complexing agents to the resulting solution, the one or more complexing agents being an organic compound comprising at least one of the following functional groups: an amine, an organosulphate, a sulphonate, a hydroxyl, an etheror a carboxylic acid group, and (c)heating the solutionor solto a temperature of at least 75°C. In addition, the invention relates to products formed from the zirconium solution or solor obtainable by the process.
    • 本发明涉及锆溶液或溶胶,其包含:(a)锆,(b)硝酸盐,乙酸盐和/或氯离子,和(c)一种或多种络合剂,其为包含以下的有机化合物: 至少一种以下官能团:胺,有机硫酸酯,磺酸酯,羟基,醚或羧酸基团,其中组分(a):(b)的摩尔比为1:0.7至1:4.0, 组分(a):( c)的摩尔比为1:0.0005至1:0.1,并且锆溶液或溶胶的pH小于5.本发明还涉及制备锆溶液或溶胶的方法,该方法 包括以下步骤:(a)将锆盐溶解在硝酸,乙酸和/或盐酸中,和(b)将一种或多种络合剂加入到所得溶液中,所述一种或多种络合剂是包含至少一种 以下官能团之一:胺,有机硫酸酯,磺酸酯,羟基,醚或羧酸gr 和(c)将溶液加热到至少75℃的温度。 此外,本发明涉及由该方法可获得的锆溶液或solor形成的产物。