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1. 发明申请

WO2011030196A1 PROCESS FOR THE PRODUCTION OF BIO-OIL FROM SOLID URBAN WASTE 审中-公开
标题翻译：从固体废物生产生物油的工艺
公开(公告)号：WO2011030196A1
公开(公告)日：2011-03-17
申请号：PCT/IB2010/002176
申请日：2010-09-01
申请人： ENI S.P.A. , BOSETTI, Aldo , BIANCHI, Daniele , FRANZOSI, Giuliana , RICCI, Marco
发明人： BOSETTI, Aldo , BIANCHI, Daniele , FRANZOSI, Giuliana , RICCI, Marco
IPC分类号： C10G1/00 , C10G1/04 , C02F3/28
CPC分类号： C10G1/04 , C10G1/002 , C10G1/02 , C10G2300/1003 , C10G2300/1011 , Y02P30/20 , Y02W10/37
摘要： A process for the production of bio-oil from solid urban waste, comprising the following steps: a) subjecting said solid urban waste to liquefaction, obtaining a mixture including an oily phase consisting of bio-oil, a solid phase and an aqueous phase; b) subjecting the aqueous phase obtained in the liquefaction step a) to fermentation, obtaining a fermented biomass; c) feeding the fermented biomass obtained in the fermentation step b) to the liquefaction step a). The bio-oil (or bio-crude) thus obtained can be advantageously used in the production of biofuels which can be used as such or mixed with other motor vehicle fuels. Alternatively, this bio-oil (or bio-crude) can be used as such (biocombustible) or mixed with fossil combustibles (combustible oil, coal, etc.) for the generation of electric energy or heat.
摘要翻译：一种从固体城市废物生产生物油的方法，包括以下步骤：a）使所述固体城市废物进行液化，得到包括由生物油，固相和水相组成的油相的混合物; b）使在液化步骤a）中获得的水相发酵，获得发酵生物质; c）将发酵步骤b）中获得的发酵生物质送入液化步骤a）。由此获得的生物油（或生物粗品）可有利地用于生产生物燃料，其可以原样使用或与其它机动车辆燃料混合。或者，该生物油（或生物粗品）可以原样使用（生物燃烧）或与化石可燃物（可燃油，煤等）混合以产生电能或热量。

2. 发明申请

WO2012117319A1 INTEGRATED PROCESS FOR THE PRODUCTION OF BIO-OIL FROM SLUDGE COMING FROM A WASTEWATER PURIFICATION PLANT 审中-公开
标题翻译：从废水净化厂的泥沙生产生物油的综合工艺
公开(公告)号：WO2012117319A1
公开(公告)日：2012-09-07
申请号：PCT/IB2012/050850
申请日：2012-02-24
申请人： ENI S.P.A. , BOSETTI, Aldo , BIANCHI, Daniele , FRANZOSI, Giuliana
发明人： BOSETTI, Aldo , BIANCHI, Daniele , FRANZOSI, Giuliana
IPC分类号： C02F11/10 , C10G3/00
CPC分类号： C02F11/10 , C10G3/40 , C10G2300/1003 , C10G2300/1014 , C10G2300/1018 , C10G2300/208 , Y02P30/20 , Y02W10/37 , Y02W10/40
摘要： Integrated process for the production of bio-oil from sludge coming from a wastewater purification plant comprising the following steps: (a) sending wastewater to said purification plant obtaining sludge; (b) subjecting the sludge obtained in said step (a) to liquefaction, obtaining a mixture Including an oily phase consisting of bio-oil, a solid phase and an aqueous phase; (c) sending the aqueous phase obtained in said step (b) to said purification plant. The bio-oil (or "bio-crude") thus obtained can be advantageously used in the production of bio-fuels which can be used as such, or in a mixture with other automotive fuels. Otherwise, said bio-oil (or "bio-crude") can be used as such (bio-fuel), or in a mixture with fossil fuels (combustible oil, coal, etc.), for the generation of electric energy or heat.
摘要翻译：用于从污水净化设备的污泥生产生物油的综合过程包括以下步骤：（a）将废水送至所述净化设备获得污泥; （b）使在所述步骤（a）中获得的污泥液化，获得混合物包括由生物油，固相和水相组成的油相; （c）将所述步骤（b）中获得的水相送至所述净化装置。由此获得的生物油（或“生物粗品”）可有利地用于生产可以直接使用或与其它汽车燃料混合使用的生物燃料。否则，所述生物油（或“生物原油”）可以如此使用（生物燃料）或与化石燃料（可燃油，煤等）的混合物用于产生电能或热量。

3. 发明申请

WO2010069516A2 PROCESS FOR THE PRODUCTION OF BIO-OIL FROM BIOMASS 审中-公开
标题翻译：从生物量生产生物油的方法
公开(公告)号：WO2010069516A2
公开(公告)日：2010-06-24
申请号：PCT/EP2009/008862
申请日：2009-12-10
申请人： ENI S.P.A. , BIANCHI, Daniele , ROMANO, Anna Maria , FRANZOSI, Giuliana , BOSETTI, Aldo
发明人： BIANCHI, Daniele , ROMANO, Anna Maria , FRANZOSI, Giuliana , BOSETTI, Aldo
IPC分类号： C12P7/64
CPC分类号： C12P7/6463
摘要： Process for the production of bio-oil from biomass including at least one polysaccharide comprising: subjecting said biomass to acid hydrolysis in the presence of an aqueous solution of at least one organic acid selected from alkyl- or aryl-sulf onic acids having from C 7 to C 20 carbon atoms, preferably from C 9 to C 15 carbon atoms, or from halogenated carboxylic acids, at a temperature ranging from 80 °C to 160 °C, preferably from 100 °C to 150 °C, obtaining a first mixture comprising a first solid phase and a first aqueous phase; subjecting said first mixture to enzymatic hydrolysis, obtaining a second mixture comprising a second solid phase and a second aqueous phase; subjecting said second aqueous phase to fermentation in the presence of at least one oleaginous yeast, obtaining an aqueous suspension comprising cells of said oleaginous yeast; subjecting said aqueous suspension to thermal treatment obtaining an oily phase comprising bio-oil and a third aqueous phase. The bio-oil thus obtained can be advantageously used in the production of biofuels which can be used as such, or in a mixture with other fuels, for motor vehicles. Or, said bio-oil can be used as such (bio-combustible), or in a mixture with fossil combustibles (combustible oil, lignite, etc.), for the generation of electric energy or heat.
摘要翻译：用于从包括至少一种多糖的生物质生产生物油的方法，包括：在至少一种选自具有C7的烷基或芳基 - 磺酸的有机酸的水溶液存在下使所述生物质进行酸水解， C20碳原子，优选C9至C15碳原子，或卤代羧酸，在80℃至160℃，优选100℃至150℃的温度下，获得包含第一固相和第一水相; 使所述第一混合物进行酶水解，得到包含第二固相和第二水相的第二混合物; 在至少一种含油酵母的存在下对所述第二水相进行发酵，得到包含所述含油酵母的细胞的水性悬浮液; 使所述水性悬浮液经受热处理，得到包含生物油和第三水相的油相。由此获得的生物油可以有利地用于生产可以直接使用的生物燃料，或与其它燃料的混合物用于机动车辆。或者，所述生物油可以原样使用（生物可燃），也可以与化石可燃物（易燃油，褐煤等）混合使用，以产生电能或热量。

4. 发明申请

WO2011128741A1 PROCESS FOR THE PRODUCTION OF BIO-OIL FROM MUNICIPAL SOLID WASTE 审中-公开
标题翻译：生物油从城市固体废物生产的过程
公开(公告)号：WO2011128741A1
公开(公告)日：2011-10-20
申请号：PCT/IB2011/000693
申请日：2011-03-30
申请人： ENI S.P.A. , BOSETTI, Aldo , FRANZOSI, Giuliana
发明人： BOSETTI, Aldo , FRANZOSI, Giuliana
IPC分类号： C10G1/02 , C02F1/28 , C02F3/34
CPC分类号： C12P7/6409 , C02F1/281 , C02F1/42 , C02F3/28 , C02F3/341 , C02F3/347 , C02F11/18 , C02F2301/066 , C02F2303/10 , C10G1/02 , C10G2300/1011 , C10G2300/1014 , C10L3/08 , C10L5/46 , Y02E50/10 , Y02E50/30 , Y02E50/343 , Y02P30/20 , Y02W10/30 , Y02W10/37
摘要： A process for the production of bio-oil from municipal solid waste, comprising the following steps: a) subjecting said municipal solid waste to liquefaction obtaining a mixture including an oily- phase consisting of bio-oil, a solid phase and a first aqueous phase; b) subjecting the first aqueous phase obtained in the liquefaction step a) to a treatment with at least one adsorbing material obtaining a second aqueous phase; c) subjecting the second aqueous phase obtained in the treatment step b) with at least one adsorbing material to fermentation obtaining a biomass; d) subjecting the biomass obtained in the fermentation step c) to said liquefaction step a). The bio-oil (or bio-crude) thus obtained can be advantageously used in the production of biofuels which can be used as such or mixed with other fuels for motor vehicles. Alternatively, said bio-oil (or bio-crude) can be used as such (biocombustible) or mixed with fossil combustibles (combustible oil, coal, etc.) for the generation of electric energy or heat.
摘要翻译：一种从城市固体废物生产生物油的方法，包括以下步骤：a）对所述城市固体废物进行液化，得到包括由生物油，固相和第一水相组成的油相的混合物 ; b）使在液化步骤a）中获得的第一水相用至少一种获得第二水相的吸附材料进行处理; c）使处理步骤b）中获得的第二水相与至少一种吸附材料进行发酵获得生物质; d）使在发酵步骤c）中获得的生物质经历所述液化步骤a）。由此获得的生物油（或生物粗品）可以有利地用于生产生物燃料，其可以原样使用或与机动车辆的其它燃料混合。或者，所述生物油（或生物粗品）可以原样使用（生物燃烧）或与化石可燃物（可燃油，煤等）混合以产生电能或热量。

5. 发明申请

WO2010046115A2 INTEGRATED PROCESS FOR THE PRODUCTION OF BIO-OIL FROM MICRO-ORGANISMS 审中-公开
标题翻译：从微生物生产生物油的综合方法
公开(公告)号：WO2010046115A2
公开(公告)日：2010-04-29
申请号：PCT/EP2009/007582
申请日：2009-10-16
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , RISPOLI, Giacomo , BOSETTI, Aldo , BIANCHI, Daniele , GIOVENTU, Giuseppe
发明人： BELLUSSI, Giuseppe , RISPOLI, Giacomo , BOSETTI, Aldo , BIANCHI, Daniele , GIOVENTU, Giuseppe
IPC分类号： C12P7/64 , C11B1/14 , C12M1/04
CPC分类号： C12P7/6463 , C11B1/14 , C12M21/02 , C12M23/18 , C12M23/58 , C12M29/02 , C12M43/00 , Y02P20/125 , Y02P20/134
摘要： The cultivation of heterotrophic and phototrophic micro-organisms is integrated for the production of bio-oil for biofuels, wherein the overall algal suspension produced is first thickened, with recirculation of the excess water to cultivation containers, and then thermally treated at a high temperature. After cooling, a bio-oil phase is recovered together with a suspension rich in soluble carbohydrates and proteins which forms a nutritional/energy source for heterotrophic micro-organisms.
摘要翻译：整合了异养和光养微生物的培养以生产用于生物燃料的生物油，其中所产生的整个藻类悬浮液首先增稠，并将多余的水再循环到栽培容器中，并且然后在高温下热处理。冷却后，生物油相与富含可溶性碳水化合物和蛋白质的悬浮液一起回收，其形成异养微生物的营养/能量来源。

6. 发明申请

WO2011057783A1 PROCESS FOR THE SEPARATION OF A MULTIPHASE STREAM WHICH FLOWS ALONG A PIPE BY MEANS OF A T-JUNCTION 审中-公开
标题翻译：通过T型接头分离管道流动的多相流的方法
公开(公告)号：WO2011057783A1
公开(公告)日：2011-05-19
申请号：PCT/EP2010/006864
申请日：2010-11-09
申请人： ENI S.P.A. , MONTINI, Alfredo , BOSETTI, Aldo , BARBAVARA, Mirko
发明人： MONTINI, Alfredo , BOSETTI, Aldo , BARBAVARA, Mirko
IPC分类号： B01D19/00 , F17D1/00
CPC分类号： F17D1/005 , B01D19/0063
摘要： The present invention relates to a separation process for j multiphase streams which flow into j pipes, with j varying from 1 to n, where n is an integer number, said multiphase streams comprising a gas or vapour phase, one or more liquid phases and a solid phase, said process characterized in that it comprises the following steps: • transporting j multiphase streams through j pipes towards j T junctions situated along said pipes, • separating, by means of said j T junctions, each of j streams into two fluxes so that one flux has a higher volumetric gas composition and the other has a higher volumetric liquid composition; • completing the phase separation in the 2j fluxes leaving the T junctions by means of j+1 traditional separators, of which at least j separators substantially separate fluxes which are characterized by a higher volumetric gas composition, and at least one separator separates fluxes characterized by a higher volumetric liquid composition; • controlling the velocity of the two fluxes leaving each j T junction by means of a control system, in order to regulate the volumetric ratio of the fluxes leaving each T junction and respect the critical entrainment condition of the gas phase in each flux having a higher volumetric gas composition; • storing the liquid phases separated by means of separators in an accumulation vessel and piping the gas phases separated by means of separators having a higher volumetric composition of gas, to an evacuating line.
摘要翻译：本发明涉及流入j管的j个多相流的分离过程，其中j为1至n，其中n为整数，所述多相流包含气相或气相，一个或多个液相和所述方法的特征在于其包括以下步骤：将j个多相流通过j个管道传送到沿着所述管道的jT接头，通过所述j个T接头将j个流中的每一个流分成两个通量，一个通量具有较高的体积气体组成，另一个具有较高的体积液体组成; °完成在通过j + 1传统分离器离开T结的2j通量中的相分离，其中至少j个分离器基本上分离以较高的体积气体组成为特征的通量，并且至少一个分离器分离由较高的体积液体组成; °控制通过控制系统离开每个jT接头的两个通量的速度，以便调节离开每个T接头的通量的体积比，并且对于具有较高的每个通量的每个通量中的气相的临界夹带状态体积气体组成; 将通过分离器分离的液相储存在积聚容器中，并将通过具有较高体积组成气体的分离器分离的气相管道送入排气管线。

7. 发明申请

WO2011070432A1 PROCESS FOR THE PRODUCTION OF BIO-OIL FROM PHOTOTROPHIC AND HETEROTROPHIC ALGAE 审中-公开
标题翻译：生物油生产过程从光热和异位酸生产
公开(公告)号：WO2011070432A1
公开(公告)日：2011-06-16
申请号：PCT/IB2010/003179
申请日：2010-12-07
申请人： ENI S.P.A. , D'ADDARIO, Ezio, Nicola , DE FERRA, Francesca , CAPUANO, Federico , MIGLIO, Roberta , BOSETTI, Aldo , CARNELLI, Lino
发明人： D'ADDARIO, Ezio, Nicola , DE FERRA, Francesca , CAPUANO, Federico , MIGLIO, Roberta , BOSETTI, Aldo , CARNELLI, Lino
IPC分类号： C12P7/64
CPC分类号： C12P7/649 , Y02E50/13
摘要： A process for the production of bio -oil from phototrophic and heterotrophic algae comprising: cultivating at least one phototrophic alga, under photoautotrophic conditions, in order to obtain a first aqueous suspension of algal biomass; - cultivating at least one heterotrophic alga, under heterotrophic conditions, in order to obtain a second aqueous suspension of algal biomass; - subjecting said first aqueous suspension of algal biomass to concentration in order to obtain a first concentrated aqueous suspension of algal biomass; - combining said first concentrated aqueous suspension of algal biomass with said second aqueous suspension of algal biomass obtaining a third aqueous suspension of algal biomass; - subjecting said third aqueous suspension of algal biomass to concentration in order to obtain a second concentrated aqueous suspension of algal biomass; - subjecting said second concentrated aqueous suspension of algal biomass to thermal treatment in order to obtain an oily phase comprising bio-oil and an aqueous phase comprising organic compounds.
摘要翻译：一种从光养和异养藻类生产生物油的方法，包括：在光自养条件下培养至少一种光营养藻，以获得藻类生物质的第一含水悬浮液; - 在异养条件下培养至少一种异养藻，以获得藻类生物质的第二水性悬浮液; - 对藻类生物质的所述第一水性悬浮液进行浓缩，以获得藻类生物质的第一浓缩水悬浮液; 将藻类生物质的所述第一浓缩水性悬浮液与藻类生物质的所述第二水性悬浮液相组合，得到藻类生物质的第三水性悬浮液; - 使藻类生物质的所述第三水性悬浮液浓缩，以获得藻类生物质的第二浓缩水悬浮液; - 将藻类生物质的所述第二浓缩水悬浮液经受热处理，以获得包含生物油和含有机化合物的水相的油相。

8. 发明申请

WO2002088067A1 PROCESS FOR THE SYNTHESIS OF MIXTURES OF METHANE DIPHENYL DIAMINE AND ITS HIGHER HOMOLOGUES WITH A CONTROLLED ISOMER DISTRIBUTION 审中-公开
标题翻译：甲基二苯基二胺混合物的合成方法及其与异构体异构体分布的较高等位基因
公开(公告)号：WO2002088067A1
公开(公告)日：2002-11-07
申请号：PCT/EP2002/004714
申请日：2002-04-29
申请人： ENI S.P.A. , ENICHEM S.P.A. , ENITECNOLOGIE S.P.A. , DE ANGELIS, Alberto , PEREGO, Carlo , FARIAS, Otello , BOSETTI, Aldo
发明人： DE ANGELIS, Alberto , PEREGO, Carlo , FARIAS, Otello , BOSETTI, Aldo
IPC分类号： C07C209/54
CPC分类号： C07C209/54 , C07C209/78 , C07C211/49 , C07C211/50
摘要： A process for preparing methane diphenyl diamine (MDA) or a mixture of methane diphenyl diamine (MDA) and its higher homologues with a controlled isomer distribution using a modified zeolite having "shape selectivity". The mixture contains compounds having the following general formula (I): where R represents a hydrogen atom or a C1 to C8 (iso)alkyl group, a C4 to C10 cycloalkyl group or a C6 to C12 aromatic group and n is a whole number greater than or equal to one so as to give a functionality of 2 to 6.
摘要翻译：使用具有“形状选择性”的改性沸石制备具有受控异构体分布的甲烷二苯基二胺（MDA）或甲烷二苯基二胺（MDA）及其高级同系物的混合物的方法。该混合物包含具有以下通式（I）的化合物：其中R表示氢原子或C1至C8（iso）烷基，C4至C10环烷基或C6至C12芳族基团，n为整数较大以上，以赋予2〜6的功能。

9. 发明申请

WO2005105286A2 RHENIUM CATALYST SUPPORTED ON MODIFIED ALUMINA AND USE THEREOF IN THE METATHESIS REACTION OF OLEFINS 审中-公开
标题翻译：改性氧化铝支持的铑催化剂及其在烯烃反应中的应用
公开(公告)号：WO2005105286A2
公开(公告)日：2005-11-10
申请号：PCT/EP2005/002478
申请日：2005-03-08
申请人： POLIMERI EUROPA S.P.A. , QUERCI, Cecilia , BOSETTI, Aldo , GENNARO, Antonio , GUERRINI, Rinaldo , RUSSO, Matteo
发明人： QUERCI, Cecilia , BOSETTI, Aldo , GENNARO, Antonio , GUERRINI, Rinaldo , RUSSO, Matteo
IPC分类号： B01J
CPC分类号： B01J23/36 , B01J21/04 , B01J23/8896 , B01J37/0207 , B01J37/0209 , C07C6/04 , C07C6/06 , C07C2521/04 , C07C2523/16 , C07C2527/10 , C07C11/02
摘要： A heterogeneous catalyst is described, active in the metathesis reaction of olefins comprising alumina as inert carrier and a rhenium compound as active component, characterized in that rhenium is present in an amount of less than 5% by weight with respect to the total preferably from 1 to 4% by weight, and the inert carrier is impregnated with at least one inorganic halide selected from FeC1 3 , CuCl 2, TiC1 4 , RuC1 3 , ZnC1 2 and NH 4 C1, and/or the corresponding bromides or iodides and, subsequently, treated at a high temperature.
摘要翻译：描述了非均相催化剂，其在包含氧化铝作为惰性载体的烯烃和作为活性组分的铼化合物的复分解反应中有活性，其特征在于铼的存在量相对于总计优选为1重量份小于5重量％至4重量％，惰性载体用至少一种选自FeCl 3，CuCl 2，TiC 14，RuC 13，ZnCl 2和NH 4 Cl的无机卤化物，和/或相应的溴化物或碘化物浸渍，随后在高温下进行处理。

10. 发明申请

WO2005051534A1 RHENIUM CATALYST ON A SILANIZED ALUMINA CARRIER AND ITS USE IN THE METATHESIS REACTION OF OLEFINS 审中-公开
标题翻译：硅烷载体上的堇青石催化剂及其在烯烃反应中的应用
公开(公告)号：WO2005051534A1
公开(公告)日：2005-06-09
申请号：PCT/EP2004/012098
申请日：2004-10-26
申请人： POLIMERI EUROPA S.P.A. , QUERCI, Cecilia , BOSETTI, Aldo , GUERRINI, Rinaldo , PANELLA, Francesco , RUSSO, Matteo
发明人： QUERCI, Cecilia , BOSETTI, Aldo , GUERRINI, Rinaldo , PANELLA, Francesco , RUSSO, Matteo
IPC分类号： B01J23/36
CPC分类号： B01J37/0209 , B01J21/04 , B01J23/36 , B01J31/0231 , B01J31/0274 , B01J31/0275 , B01J31/122 , B01J31/2265 , B01J37/0203 , B01J2231/543 , B01J2531/74 , C07C6/04 , C07C6/06 , C07C2521/04 , C07C2523/36
摘要： A process is described for the preparation of a heterogeneous catalyst containing rhenium as active component and an inert carrier medium. characterized in that said inert carrier is previously treated with a silanizing compound containing chlorine, before the laying of the active component on the carrier, and the activation of the heterogeneous catalyst takes place by means of thermal treatment followed by a rapid final cooling. The catalyst is particularly active in metathesis reactions of olefins.
摘要翻译：描述了制备含有铼作为活性组分和惰性载体介质的非均相催化剂的方法。其特征在于，在将活性组分铺设在载体上之前，预先用含氯的硅烷化化合物处理所述惰性载体，并通过热处理进行快速最终冷却来进行非均相催化剂的活化。催化剂在烯烃的复分解反应中特别有活性。

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