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1. 发明申请

WO2011117705A2 PROCESS FOR THE CONVERSION OF LIGNIN TO LIQUID HYDROCARBONS 审中-公开
标题翻译：液化石油烯烃转化方法
公开(公告)号：WO2011117705A2
公开(公告)日：2011-09-29
申请号：PCT/IB2011/000591
申请日：2011-03-17
申请人： ENI S.P.A. , DELLEDONNE, Daniele , BUZZONI, Roberto , BIANCHI, Daniele
发明人： DELLEDONNE, Daniele , BUZZONI, Roberto , BIANCHI, Daniele
IPC分类号： C10G1/00 , C10G1/06 , C10G3/00 , C10L1/04 , C07C37/54
CPC分类号： C10G3/50 , C07C37/54 , C10G1/002 , C10G1/06 , C10G3/46 , C10G3/47 , C10G3/48 , C10G2300/1014 , C10G2300/4006 , C10G2300/4018 , C10G2300/44 , C10G2400/02 , C10G2400/06 , C10L1/04 , Y02P30/20 , C07C39/08 , C07C39/06
摘要： Process for the conversion of lignin to liquid hydro- carbons comprising: subjecting the lignin to hydrogenolysis in the presence of at least one hydrogenolysis catalyst, at a temperature ranging from 250°C to 350°C, preferably ranging from 290 °C to 320 °C, so as to obtain depolymerized lignin; subjecting said depolymerized lignin to hydrotreating so as to obtain a mixture of liquid hydrocarbons. Said liquid hydrocarbons can be used as such (biofuels) for the production of reformulated gasolines, or they can be used for the production of gasolines or of gas oils through conventional refining processes.
摘要翻译：将木质素转化为液态碳氢化合物的方法，包括：在至少一种氢解催化剂存在下，在250℃至350℃，优选290℃至320℃的温度下使木质素进行氢解 C，以获得解聚的木质素; 对所述解聚的木质素进行加氢处理，以获得液体烃的混合物。所述液体烃可以如此使用（生物燃料）用于生产重整汽油，或者它们可以用于通过常规精制方法生产汽油或瓦斯油。

2. 发明申请

WO2010015404A1 PROCESS FOR THE PRODUCTION OF SUGARS FROM BIOMASS 审中-公开
标题翻译：从生物量生产糖的过程
公开(公告)号：WO2010015404A1
公开(公告)日：2010-02-11
申请号：PCT/EP2009/005713
申请日：2009-08-03
申请人： ENI S.p.A. , BIANCHI, Daniele , ROMANO, Anna Maria
发明人： BIANCHI, Daniele , ROMANO, Anna Maria
IPC分类号： C13K1/02 , C12P7/10
CPC分类号： C12P7/10 , C13K1/02 , Y02E50/16
摘要： Process for the production of sugars from biomass including at least one polysaccharide which comprises putting a biomass in contact with an aqueous solution of at least one organic acid selected from alkyl- or aryl- sulfonic acids having from C 7 to C 20 carbon atoms, preferably from C 9 to C 15 carbon atoms, or from halogenated carboxylic acids, at a temperature ranging from 80°C to 140°C, preferably from 100°C to 125°C. The sugars thus obtained can be advantageously used as carbon sources in fermentation processes for the production of alcohols (e.g., ethanol, butanol). Said alcohols can be advantageously used as automotive biofuels, or as components which can be added to automotive fuels.
摘要翻译：用于从包括至少一种多糖的生物质生产糖的方法，其包括将生物质与至少一种选自具有C7至C20碳原子的烷基或芳基磺酸的有机酸的水溶液接触，优选C 9 至C15碳原子，或卤代羧酸，在80℃至140℃，优选100℃至125℃的温度下进行。由此获得的糖可有利地用作生产醇（例如乙醇，丁醇）的发酵方法中的碳源。所述醇可有利地用作汽车生物燃料，或作为可添加到汽车燃料中的成分。

3. 发明申请

WO2009156842A1 PROCESS FOR THE PRODUCTION OF ESTERS OF LEVULINIC ACID FROM BIOMASSES 审中-公开
标题翻译：从生物量生产橄榄酸的方法
公开(公告)号：WO2009156842A1
公开(公告)日：2009-12-30
申请号：PCT/IB2009/006070
申请日：2009-06-19
申请人： ENI S.P.A. , BIANCHI, Daniele , ROMANO, Anna Maria
发明人： BIANCHI, Daniele , ROMANO, Anna Maria
IPC分类号： C07C67/42 , C07C69/716
CPC分类号： C07C67/00 , C07C69/716
摘要： A new process is described for the direct synthesis of esters of levulinic acid starting from biomasses contain ing one or more polysaccharides and from aliphatic alco hols, in the presence of a suitable organic acid cata lyst. In particular, the biomasses can be lignin- cellulose biomasses. The esters thus obtained can be used as oxygenated components in the formulation of fuels for motor vehicles, with the aim of reducing the particulate emissions.
摘要翻译：描述了一种新的方法，用于在合适的有机酸催化剂的存在下从含有一种或多种多糖和脂族醇的生物质直接合成乙酰丙酸的酯。特别地，生物质可以是木质纤维素生物质。由此获得的酯可用作汽车燃料配方中的氧化组分，目的是减少颗粒物排放。

4. 发明申请

WO2008052759A1 PROCESS FOR THE ENZYMATIC REMOVAL OF FILTER-CAKES PRODUCED BY WATER-BASED DRILLING AND COMPLETION FLUIDS 审中-公开
标题翻译：通过水基钻井和完井液生产的过滤器的酶除去过程
公开(公告)号：WO2008052759A1
公开(公告)日：2008-05-08
申请号：PCT/EP2007/009448
申请日：2007-10-29
申请人： ENI S.P.A. , BATTISTEL, Ezio , BIANCHI, Daniele , COBIANCO, Sandra , FORNAROLI, Marco
发明人： BATTISTEL, Ezio , BIANCHI, Daniele , COBIANCO, Sandra , FORNAROLI, Marco
IPC分类号： C09K8/524 , C09K8/582
CPC分类号： C09K8/52 , C09K8/524 , C09K8/582 , C12N9/2437 , C12N9/2445 , C12P19/26 , C12Y302/01021
摘要： The invention relates to a process for the solubilization of material containing scleroglucan and/or xanthan gum which comprises putting the above material in contact with an aqueous solution comprising an enzyme selected from a cellulase from Trichoderma reesei and/or a glucosidase from Aspergillus Niger.
摘要翻译：本发明涉及一种用于增溶含有硬葡聚糖和/或黄原胶的材料的方法，其包括将上述材料与包含选自里氏木霉纤维素酶和/或来自尼日尔曲霉的葡糖苷酶的酶的水溶液接触。

5. 发明申请

WO2006050827A1 CONTINUOUS PROCESS FOR THE PREPARATION OF PHENOL FROM BENZENE IN A FIXED BED REACTOR 审中-公开
标题翻译：在固定床反应器中从苯中制备苯酚的连续方法
公开(公告)号：WO2006050827A1
公开(公告)日：2006-05-18
申请号：PCT/EP2005/011575
申请日：2005-10-26
申请人： POLIMERI EUROPA S.P.A. , BIANCHI, Daniele , BORTOLO, Rossella , BUSTO, Chiara , LAZZARI, Carla
发明人： BIANCHI, Daniele , BORTOLO, Rossella , BUSTO, Chiara , LAZZARI, Carla
IPC分类号： C07C37/60 , C07C39/04 , B01J29/89
CPC分类号： B01J37/12 , B01J29/89 , B01J37/0009 , B01J2229/30 , B01J2229/42 , C07C37/60 , Y02P20/52 , C07C39/04
摘要： The invention relates to a continuous process for the preparation of phenol by means of the direct oxidation of benzene with hydrogen peroxide in the presence of a catalyst based on titanium silicalite TS-1 comprising: (a) running the process in a fixed bed reactor containing the catalyst based on TS-1 at a temperature ranging from 80-120°C and at a pressure ranging from 3-15 atm; (b) feeding to the reactor a stream containing H 2 0 2 , benzene, sulfolane and water in a single or double phase, wherein the quantities of the single components are within the range of 0.2-6, 15-60, 30-80, 0.5-30 parts by weight, respectively, for every 100 units fed and whose total flow rate is calculated so that the residence time in the reactor (defined as the ratio between the quantity of catalyst by weight and the feeding flow rate) ranges from 0.3 to 2 min; (c) recovery of the products, by-products and solvent from the liquid stream leaving the reactor.
摘要翻译：本发明涉及一种通过在基于钛硅沸石TS-1的催化剂存在下用过氧化氢直接氧化苯的连续方法，其包括：（a）在含有基于TS-1的催化剂在80-120℃的温度和3-15atm的压力范围内; （b）在单相或双相中向反应器中加入含有H 2 O 2 H 2，SO 2，苯，环丁砜和水的流，其中，对于每供给的100单位，单个组分分别在0.2-6,15-60,30-80,0.5-30重量份的范围内，并且计算其总流速使得在反应器中的停留时间（定义因为催化剂的量与进料流量的比例）为0.3-2分钟; （c）从离开反应器的液体物流中回收产物，副产物和溶剂。

6. 发明申请

WO2012052368A1 PROCESS FOR THE PRODUCTION OF LIPIDS FROM BIOMASS 审中-公开
标题翻译：从生物量生产脂肪的方法
公开(公告)号：WO2012052368A1
公开(公告)日：2012-04-26
申请号：PCT/EP2011/068043
申请日：2011-10-14
申请人： Eni S.p.A. , FRANZOSI, Giuliana , PIZZA, Francesca , CUCCHETTI, Daniela , BIANCHI, Daniele , COMPAGNO, Concetta Maria , GALAFASSI, Silvia , UNIVERSITA'DEGLI STUDI DI MILANO
发明人： FRANZOSI, Giuliana , PIZZA, Francesca , CUCCHETTI, Daniela , BIANCHI, Daniele , COMPAGNO, Concetta Maria , GALAFASSI, Silvia
IPC分类号： C12P7/64
CPC分类号： C12P7/64 , C10L1/026 , C10L2290/26 , C10L2290/548 , C12P7/6463 , C12P2203/00 , Y02E50/13
摘要： Process for the production of lipids from biomass comprising polysaccharides. The biomass is subjected to acid hydrolysis to obtain a solid phase and an aqueous phase. The solid phase is subjected to acid or to enzymatic hydrolysis obtaining a further solid phase and a further aqueous phase. The aqueous phases obtained from both hydrolysis steps are subjected to fermentation with an oleaginous yeast. The obtained fermentation broth comprises oleaginous cellular biomass which is subjected to microfiltration for the isolation of lipids. Said lipids can be used in the production of biodiesel or green diesel.
摘要翻译：用于从包含多糖的生物质生产脂质的方法。将生物质进行酸水解，得到固相和水相。将固相进行酸或酶水解，得到另外的固相和另外的水相。从两个水解步骤获得的水相用含油酵母进行发酵。所获得的发酵液包含油细胞生物质，其经过微量过滤以分离脂质。所述脂质可用于生产生物柴油或绿色柴油。

7. 发明申请

WO2011128742A1 PROCESS FOR THE PRODUCTION OF LIQUID HYDROCARBONS WITH A LOW CONTENT OF AROMATIC COMPOUNDS 审中-公开
标题翻译：生产低浓度芳香族化合物的液体碳氢化合物的方法
公开(公告)号：WO2011128742A1
公开(公告)日：2011-10-20
申请号：PCT/IB2011/000694
申请日：2011-03-30
申请人： ENI S.P.A. , PAPARATTO, Giuseppe , RAMELLO, Stefano , BUZZONI, Roberto , BIANCHI, Daniele
发明人： PAPARATTO, Giuseppe , RAMELLO, Stefano , BUZZONI, Roberto , BIANCHI, Daniele
IPC分类号： C07C1/24 , C07C9/14 , B01J21/12
CPC分类号： B01J29/06 , B01J29/40 , B01J2229/42 , C07C1/20 , C10G3/49 , C10G3/54 , C10G2300/1014 , C10G2300/4018 , C10G2400/02 , C10G2400/06 , C10G2400/08 , C10L1/04 , C10L1/06 , C10L1/08 , C07C11/02
摘要： Process for the production of liquid hydrocarbons with a low content of aromatic compounds which comprises putting an aqueous mixture including at least one alcohol having from 2 to 4 carbon atoms in contact with at least one catalyst selected from zeolites having a silica/alumina molar ratio (SAR) ranging from 100 to 500, preferably ranging from 200 to 300. The liquid hydrocarbon thus obtained can be subsequently subjected to hydrogenation for the production of gasolines, of kerosene (jet fuel), or of gas oils.
摘要翻译：用于生产具有低含量芳族化合物的液体烃的方法，其包括将包含至少一种具有2至4个碳原子的醇的含水混合物与至少一种选自具有二氧化硅/氧化铝摩尔比的沸石的催化剂接触 SAR）为100至500，优选为200至300.然后可以将如此得到的液态烃进行氢化，生产汽油，煤油（喷气燃料）或瓦斯油。

8. 发明申请

WO2011077242A1 PROCESS FOR THE PRODUCTION OF FUEL COMPONENTS FOR MOTOR VEHICLES 审中-公开
标题翻译：制造汽车燃料部件的过程
公开(公告)号：WO2011077242A1
公开(公告)日：2011-06-30
申请号：PCT/IB2010/003379
申请日：2010-12-23
申请人： ENI S.P.A. , RIVETTI, Franco , MANTEGAZZA, Maria, Angela , BIANCHI, Daniele
发明人： RIVETTI, Franco , MANTEGAZZA, Maria, Angela , BIANCHI, Daniele
IPC分类号： C07C2/66 , C07C15/02 , C10G69/12 , C07C2/86 , C07C15/085
CPC分类号： C07C2/864 , C07C2529/70 , C10G29/22 , C07C15/085
摘要： A process is described for the production of fuel components for motor vehicles by the alkylation, with one or more alcohols, of a mixture containing benzene, and the separation of a product which boils within the gasoline boiling range, wherein the alkylation and separation take place in two different steps. The process is carried out in the presence of a zeolite belonging to the BEA family. At the end of the process, a substantial amount of benzene is no longer present in the final mixture, due to the alkylation of said substrate with the alcohol or alcohols used. The process also allows a product which boils within the diesel boiling range to be obtained. A particularly preferred aspect is to use alcohols deriving from raw materials of an agricultural or vegetable origin.
摘要翻译：描述了一种用于通过烷基化生产汽车燃料组分的方法，其中一种或多种醇含有苯的混合物，以及在汽油沸程范围内沸腾的产物的分离，其中烷基化和分离发生在两个不同的步骤。该方法在属于BEA族的沸石存在下进行。在该方法结束时，由于所用底物与所用的醇或醇的烷基化，最终混合物中不再存在大量的苯。该方法还允许获得在柴油沸程范围内沸腾的产物。特别优选的方面是使用衍生自农业或植物来源的原料的醇。

9. 发明申请

WO2010069516A3 PROCESS FOR THE PRODUCTION OF BIO-OIL FROM BIOMASS 审中-公开
标题翻译：从生物量生产生物油的工艺
公开(公告)号：WO2010069516A3
公开(公告)日：2011-06-30
申请号：PCT/EP2009008862
申请日：2009-12-10
申请人： ENI SPA , BIANCHI DANIELE , ROMANO ANNA MARIA , FRANZOSI GIULIANA , BOSETTI ALDO
发明人： BIANCHI DANIELE , ROMANO ANNA MARIA , FRANZOSI GIULIANA , BOSETTI ALDO
IPC分类号： C12P7/64
CPC分类号： C12P7/6463
摘要： Process for the production of bio-oil from biomass comprising: - subjecting said biomass to acid hydrolysis in the presence of an aqueous solution of at least one organic acid selected from alkyl- or aryl-sulfonic acids having from C7 to C20 carbon atoms, or from halogenated carboxylic acids, at a temperature ranging from 80 °C to 160 °C, obtaining a first mixture comprising a first solid phase and a first aqueous phase; - subjecting said first mixture to enzymatic hydrolysis, obtaining a second mixture comprising a second solid phase and a second aqueous phase; - subjecting said second aqueous phase to fermentation in the presence of at least one oleaginous yeast, obtaining an aqueous suspension comprising cells of said oleaginous yeast; - subjecting said aqueous suspension to thermal treatment obtaining an oily phase comprising bio-oil and a third aqueous phase. The bio-oil thus obtained can be advantageously used in the production of biofuels.
摘要翻译：用于从生物质生产生物油的方法，包括： - 在至少一种选自具有C7至C20碳原子的烷基 - 或芳基 - 磺酸的有机酸的水溶液存在下使所述生物质进行酸水解，或从卤代羧酸，在80℃至160℃的温度范围内，获得包含第一固相和第一水相的第一混合物; - 对所述第一混合物进行酶水解，得到包含第二固相和第二水相的第二混合物; - 在至少一种含油酵母的存在下对所述第二水相进行发酵，得到包含所述含油酵母细胞的含水悬浮液; - 对所述水性悬浮液进行热处理，获得包含生物油和第三水相的油相。由此获得的生物油可有利地用于生物燃料的生产。

10. 发明申请

WO2010046051A3 PROCESS FOR THE PRODUCTION OF LIPIDS FROM BIOMASS 审中-公开
标题翻译：从生物质生产脂质的方法
公开(公告)号：WO2010046051A3
公开(公告)日：2010-08-26
申请号：PCT/EP2009007388
申请日：2009-10-14
申请人： ENI SPA , BIANCHI DANIELE , FRANZOSI GIULIANA , ROMANO ANNA MARIA
发明人： BIANCHI DANIELE , FRANZOSI GIULIANA , ROMANO ANNA MARIA
IPC分类号： C12P7/64 , C11B1/02 , C11B1/06 , C12P19/02 , C12P19/14 , C13K1/02 , D21C3/04
CPC分类号： C12P7/649 , C10L1/026 , C11B1/025 , C11B1/06 , C11C3/003 , C12P7/6463 , C12P19/02 , C12P19/14 , C12P2201/00 , C13K1/02 , D21C3/04 , D21C11/0007 , Y02E50/13
摘要： A process for the production of lipids from biomass including at least one polysaccharide comprising: subjecting said biomass to acid hydrolysis in the presence of an aqueous solution of at least one organic acid selected from alkyl- or aryl-sulfonic acids having from C7 to C20 carbon atoms, preferably from C9 to C15 carbon atoms, or from halogenated carboxylic acids, at a temperature ranging from 80°C to 160°C, preferably from 100°C to 150°C, obtaining a first mixture comprising a first solid phase and a first aqueous phase; - subjecting said first mixture to enzymatic hydrolysis obtaining a second mixture comprising a second solid phase and a second aqueous phase; subjecting said second aqueous phase to fermentation in the presence of at least one oleaginous yeast obtaining an oleaginous cellular biomass comprising lipids. The lipids thus obtained can be advantageously used in the production of biodiesel or green diesel which can be used as such, or in a mixture with other fuels for motor vehicles.
摘要翻译：由生物质生产脂质的方法，所述生物质包括至少一种多糖，所述方法包括：使所述生物质在选自具有C7至C20碳的烷基 - 或芳基 - 磺酸的至少一种有机酸的水溶液存在下进行酸水解原子，优选C9-C15的碳原子或由卤代羧酸在80℃至160℃，优选100℃至150℃的温度下反应，获得包含第一固相和第一固相的第一混合物第一水相; - 使所述第一混合物进行酶水解，获得包含第二固相和第二水相的第二混合物; 使所述第二水相在至少一种含油酵母存在下进行发酵，获得包含脂质的含油细胞生物质。由此获得的脂质可以有利地用于生产生物柴油或绿色柴油，所述生物柴油或绿色柴油可以原样使用，或与其他汽车燃料混合使用。

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