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1. 发明申请

WO2012055957A3 PROCESS FOR THE REFINING OF CRUDE OIL 审中-公开
标题翻译：原油精炼工艺
公开(公告)号：WO2012055957A3
公开(公告)日：2012-08-23
申请号：PCT/EP2011068842
申请日：2011-10-27
申请人： ENI SPA , RISPOLI GIACOMO FERNANDO , BELLUSSI GIUSEPPE
发明人： RISPOLI GIACOMO FERNANDO , BELLUSSI GIUSEPPE
IPC分类号： C10G45/16 , C10G47/26 , C10G49/12 , C10G65/14 , C10G67/16 , C10G69/14
CPC分类号： C10G65/12 , B01J27/043 , B01J27/047 , B01J27/049 , B01J35/0013 , C10G7/00 , C10G45/16 , C10G47/26 , C10G49/12 , C10G65/14 , C10G67/16 , C10G69/14 , C10G2300/107 , C10G2300/206 , C10G2300/207 , C10G2300/301 , C10G2300/4081
摘要： A process for the refining of crude oil, comprising a separation unit of the crude oil, consisting of at least one atmospheric distillation unit for separating the various fractions, a unit for the conversion of the heavy fractions obtained, a unit for improving the quality of some of the fractions obtained by actions on the chemical composition of their constituents, and units for the removal of undesired components, characterized in that the heaviest fraction, the atmospheric distillation residue, is sent to the conversion unit comprising a hydroconversion reactor in slurry phase or of the ebullated bed type, into which hydrogen or a mixture of hydrogen and ¾S is introduced in the presence of a suitable nanodispersed hydrogenation catalyst.
摘要翻译：一种原油精炼方法，包括原油分离单元，其包括至少一个用于分离各馏分的常压蒸馏单元，用于转化所获得的重馏分的单元，用于提高原油品质的单元通过对其组分的化学组成作用而获得的一些馏分以及用于除去不需要的组分的单元，其特征在于最重馏分即常压蒸馏残余物被送至包含浆液相的加氢转化反应器的转化单元或的沸腾床类型，在合适的纳米分散氢化催化剂存在下将氢气或氢气和H 2 S的混合物引入其中。

2. 发明申请

WO2011039595A2 MIXED OXIDES OF TRANSITION METAL, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM, AND PREPARATION PROCESS COMPRISING SOL -GEL PROCESSES 审中-公开
标题翻译：过渡金属的混合氧化物，其获得的加氢催化剂以及包含溶解过程的制备方法
公开(公告)号：WO2011039595A2
公开(公告)日：2011-04-07
申请号：PCT/IB2010/002392
申请日：2010-09-23
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
发明人： BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
IPC分类号： B01J27/049 , B01J27/051 , B01J37/03 , B01J37/20 , B01J35/10
CPC分类号： B01J27/0515 , B01J23/002 , B01J23/883 , B01J23/8885 , B01J27/049 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/033 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/1044 , C10G2300/1062 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2400/04 , C10G2400/06 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/845 , B01J2523/847 , B01J2523/41
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) X a Y b Z c O d . pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, 0 is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) R I R II R III R IV NOH ( I ) wherein the groups R I -R IV , the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R 1 R 2 R 3 N (II) wherein R 1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R 2 and R 3 , the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R 1 , a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b) /c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d = (2a+6b+Hc)/2 wherein H = 4 when Z = Si H = 3 when Z = Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.
摘要翻译：描述了新的硫化金属催化剂，其含有选自Ni，Co及其混合物的金属X，选自Mo，W及其混合物的金属Y，选自Si，Al及其混合物的元素Z以及可能的有机残基，通过硫化混合氧化物前体获得，也是新的，具有通式（A）Xa Yb Zc Od。 pC（A）可以成形为没有粘合剂，或通过硫化具有式（A）的混合氧化物，成型为粘合剂，其中X选自Ni，Co及其混合物，Y选自Mo，W和混合物 Z选自Si，Al及其混合物，0为氧，C选自：氮化合物N，衍生自含氮化合物N的部分煅烧的有机残基，所述含氮化合物N当存在时为选自：a）具有式（I）RIRIIRIIIRIVNOH（I）的烷基氢氧化铵，其中基团RI-RIV相同或不同，是含有1至7个碳原子的脂族基团，b）具有式（II）的胺， R 1 R 2 R 3 N（II）其中R 1是含有4至12个碳原子的直链，支链或环状烷基，R 2和R 3相同或不同，选自H和直链，支链或环状的烷基，其含有4〜 12个碳原子，所述烷基等于或不同于R 1，a，b，c，d ar e分别是元素X，Y，Z，O的摩尔数，p是C相对于具有式（A）的前体的总重量的重量百分比，a，b，c，d高于（a + b）/ c高于或等于0.3且低于或等于10，优选从0.8至10d =（ 2a + 6b + Hc）/ 2，其中当Z = Al时，当Z = Si H = 3时，H = 4，p大于或等于0且小于或等于40％。所述催化剂可用作加氢处理催化剂。

3. 发明申请

WO2009149923A1 CATALYTIC SYSTEM AND PROCESS FOR THE HYDROCONVERSION OF HEAVY OIL PRODUCTS 审中-公开
标题翻译：催化体系和重油加氢工艺
公开(公告)号：WO2009149923A1
公开(公告)日：2009-12-17
申请号：PCT/EP2009/004193
申请日：2009-06-08
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , RISPOLI, Giacomo , CARATI, Angela
发明人： BELLUSSI, Giuseppe , RISPOLI, Giacomo , CARATI, Angela
IPC分类号： B01J23/28 , B01J23/883 , B01J29/70 , C10G45/04
CPC分类号： C10G45/04 , B01J23/882 , B01J23/883 , B01J27/051 , B01J29/041 , B01J29/061 , B01J29/072 , B01J29/166 , B01J29/7007 , B01J29/7615 , B01J35/0006 , B01J37/20 , C10G45/08 , C10G45/12 , C10G45/46 , C10G45/50 , C10G45/54 , C10G47/20 , C10G2300/1003 , C10G2300/1011 , C10G2300/1033 , C10G2300/1074 , Y02P30/20
摘要： Catalytic system which can be used in processes for the hydroconversion of heavy oils by means of hydrotreatment in slurry phase, characterized in that it comprises: a catalyst, having the function of hydrogenating agent, containing MoS 2 or WS 2 or mixtures thereof in lamellar form or an oil-soluble precursor thereof; a co-catalyst, having nanometric or micronic particle- sizes, selected from cracking and/or denitrogenation catalysts. The co-catalyst preferably consists of zeolites having small-sized crystals and with a low aggregation degree between the primary particles, and/or oxides or sulfides or precursors of sulfides of Ni and/or Co in a mixture with Mo and/or W.
摘要翻译：催化体系，其可用于通过浆料相中的加氢处理加氢转化重油的方法，其特征在于其包含：具有包含MoS 2或WS 2的氢化剂或其混合物的层状功能的催化剂或其油溶性前体; 具有选自裂化和/或脱氮催化剂的纳米或微米粒径的助催化剂。助催化剂优选由具有小尺寸晶体并且在初级粒子之间具有低聚集度的沸石和/或与Mo和/或W的混合物中的Ni和/或Co的硫化物的硫化物或硫化物的前体组成。

4. 发明申请

WO2007028540A1 PROCESS FOR THE REOXIDATION, WITHOUT THE FORMATION OF NITROGEN OXIDES, OF FERROUS SOLUTIONS COMING FROM THE REMOVAL PROCESS IN CONTINUOUS OF HYDROGEN SULFIDE FROM GASEOUS STREAMS BY MEANS OF THE REDOX METHOD 审中-公开
标题翻译：在氧化还原过程中，无法形成氮氧化物，通过REDOX方法从连续流出的硫酸氢盐中除去过程中的有害溶剂
公开(公告)号：WO2007028540A1
公开(公告)日：2007-03-15
申请号：PCT/EP2006/008524
申请日：2006-08-31
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , MILLI, Marcello
发明人： BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , MILLI, Marcello
IPC分类号： C10L3/10 , C01B17/05 , B01D53/14 , B01D53/52
CPC分类号： B01D53/1468 , B01D53/1418 , B01D53/1425 , B01D53/1493 , C01B17/05 , C10L3/10
摘要： Process for the reoxidation, without the formation of ni¬ trogen oxides, of ferrous solutions used in the removal process in continuous of hydrogen sulfide from gaseous streams containing them, comprising: a) putting a gas containing H∑S in contact with an oxidiz¬ ing acid aqueous solution of ferric nitrate and containing a heteropolyacid having rjedox properties; b) filtrating and separating the sulfur produced; c) reoxidizing the ferrous nitrate to ferric nitrate with air as such or enriched in oxygen at a pressure higher than atmospheric pressure; d) recycling the solution containing ferric nitrate and the heteropolyacid to the oxidation step (a); and e) discharging the air.
摘要翻译：包括：a）将含有H 2 S的气体与氧化物接触，用于在不含氧化物的情况下，再次氧化从含有它们的气流中连续除去硫化氢中的亚铁溶液，酸式硝酸铁水溶液，含有具有杂聚性质的杂多酸; b）过滤和分离产生的硫; c）将空气中的硝酸亚铁还原为硝酸铁，或在高于大气压的压力下富集氧气; d）将含有硝酸铁和杂多酸的溶液再循环到氧化步骤（a）中; 和e）排出空气。

5. 发明申请

WO2011045657A1 GAS OIL COMPOSITION COMPRISING DIALKYL CARBONATE FROM BIOALCOHOL 审中-公开
标题翻译：包含来自生物醇的碳酸二烷基酯的气体油组合物
公开(公告)号：WO2011045657A1
公开(公告)日：2011-04-21
申请号：PCT/IB2010/002611
申请日：2010-10-11
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , NOTARI, Marcello , REBESCO, Elena, Maria , SAVARESE, Maria, Cristina , SCORLETTI, Pietro , COLLIA, Despina , SERBOLISCA, Luca Paolo
发明人： BELLUSSI, Giuseppe , NOTARI, Marcello , REBESCO, Elena, Maria , SAVARESE, Maria, Cristina , SCORLETTI, Pietro , COLLIA, Despina , SERBOLISCA, Luca Paolo
IPC分类号： C10L1/19 , C10L1/18
CPC分类号： C10L1/1905 , C10L1/19
摘要： Gas oil composition comprising: - at least one gas oil; - at least one dialkyl carbonate; wherein said dialkyl carbonate is obtained from bio- alcohol. Said composition can be advantageously used as fuel, for example, as fuel for burners, or for heating boilers. In particular, said composition can be advantageously used as fuel for diesel engines.
摘要翻译：瓦斯油组合物，其包含： - 至少一种瓦斯油; - 至少一种碳酸二烷基酯; 其中所述碳酸二烷基酯是从生物醇获得的。所述组合物可以有利地用作燃料，例如用作燃烧器的燃料或用于加热锅炉。特别地，所述组合物可以有利地用作柴油机的燃料。

6. 发明申请

WO2009147496A3 CRACKING PROCESS AND ENHANCED CATALYSTS FOR SAID PROCESS 审中-公开
公开(公告)号：WO2009147496A3
公开(公告)日：2009-12-10
申请号：PCT/IB2009/005786
申请日：2009-05-28
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , MILLINI, Roberto , RIZZO, Caterina , COLOMBO, Daniele
发明人： BELLUSSI, Giuseppe , MILLINI, Roberto , RIZZO, Caterina , COLOMBO, Daniele
IPC分类号： B01J29/70 , B01J29/80 , C10G11/05
摘要： The present invention concerns a new cracking process, preferably a fluid catalytic process, characterized in that it is carried out in the presence of a catalyst containing ERS-10 zeolite. The invention also relates to a new catalytic composition containing said ERS-10 zeolite, which can be used as catalyst in catalytic cracking processes, in particular in fluid catalytic cracking processes (FCC).

7. 发明申请

WO2005075351A3 PROCESS FOR THE REMOVAL OF HYDROGEN SULFIDE, BY MEANS OF ITS OXIDATION IN THE PRESENCE OF HETERO POLYACIDS 审中-公开
标题翻译：通过在异戊二烯存在下氧化还原硫化氢的方法
公开(公告)号：WO2005075351A3
公开(公告)日：2006-09-28
申请号：PCT/EP2005000669
申请日：2005-01-20
申请人： ENI SPA , ENITECNOLOGIE SPA , DE ANGELIS ALBERTO , BELLUSSI GIUSEPPE , POLLESEL PAOLO , ROMANO UGO , PEREGO CARLO
发明人： DE ANGELIS ALBERTO , BELLUSSI GIUSEPPE , POLLESEL PAOLO , ROMANO UGO , PEREGO CARLO
IPC分类号： C01B17/05 , B01D53/14 , B01D53/52
CPC分类号： B01D53/52 , B01D2257/304 , C01B17/05
摘要： Hydrogen sulfide is oxidized to sulfur by means of treatment with an aqueous acid solution containing trivalent iron and a hetero polyacid having formula (I): H n X V y M (12-y) O 40 ; or a sole hetero polyacid having formula (II): H n Me M 12 O 40 ; wherein the symbols X, M Me n and y are specified in the text. At the end of the oxidation, the solution is treated with gas containing oxygen to re-oxidize the reduced metal.
摘要翻译：通过用含有三价铁的含水酸溶液和具有式（I）的杂多酸处理将硫化氢氧化成硫：H 1 H 1 H （12-y）O 40; 或具有式（II）的唯一的杂多酸：H n Me M 12 O 40; 其中符号X，M Me n和y在文中指定。在氧化结束时，用含氧的气体处理溶液以再还原还原的金属。

8. 发明申请

WO2005014192A1 PROCESS FOR THE DISPOSAL OF SULFUR IN THE FORM OF COMPOUNDS LIQUID AT ROOM TEMPERATURE 审中-公开
标题翻译：化合物液体在室温下处理硫磺的方法
公开(公告)号：WO2005014192A1
公开(公告)日：2005-02-17
申请号：PCT/EP2004/007565
申请日：2004-07-06
申请人： ENI S.p.A. , ENITECNOLOGIE S.p.A. , DE ANGELIS, Alberto , POLLESEL, Paolo , BELLUSSI, Giuseppe , LOCKHART, Thomas, Paul
发明人： DE ANGELIS, Alberto , POLLESEL, Paolo , BELLUSSI, Giuseppe , LOCKHART, Thomas, Paul
IPC分类号： B09B1/00
CPC分类号： E21B41/0057 , B09B1/008 , B65G5/00
摘要： Process for the disposal of sulfur in the liquid state which comprises: a) transforming elemental sulfur into sulfanes having the general formula H 2 S n+1 , wherein n is a number from 1 to 7; b) optionally mixing elemental sulfur in powder form with the liquid sulfanes, up to such a concentration as to guarantee the pumpability of the mixture; c) injecting the sulfanes liquid at room temperature into geological formations having a temperature lower than 150°C.
摘要翻译：用于处理液态硫的方法，其包括：a）将元素硫转化为具有通式H 2 Sn + 1的硫烷，其中n为1至7的数; b）任选地将粉末形式的元素硫与液体硫烷混合，直至其浓度保证混合物的可泵送性; c）将室温下的硫烷液体注入温度低于150℃的地质构造中。

9. 发明申请

WO1996029140A1 NITROGEN OXIDE-REDUCING CATALYST AND PROCESS FOR REDUCING NITROGEN OXIDES IN EXHAUST GAS 审中-公开
标题翻译：氮氧化物还原催化剂和减少排气中氮氧化物的方法
公开(公告)号：WO1996029140A1
公开(公告)日：1996-09-26
申请号：PCT/JP1996000637
申请日：1996-03-14
申请人： OSAKA GAS COMPANY LIMITED , ENIRICERCHE S.P.A. , TABATA, Takeshi , KOKITSU, Mikako , OKADA, Osamu , OHTSUKA, Hirofumi , BELLUSSI, Giuseppe , SABATINO, Luigina, Maria, Flora
发明人： OSAKA GAS COMPANY LIMITED , ENIRICERCHE S.P.A.
IPC分类号： B01D53/86
CPC分类号： B01J29/04 , B01D53/9418 , B01D2251/208 , B01D2255/20746 , B01D2255/20761
摘要： The present invention relates to a catalyst for reducing nitrogen oxides (NOx) in exhaust gas, comprising crystalline metallosilicate ion-exchanged with Co, and channels of particular structure formed in the crystalline metallosilicate, and to a NOx reduction process using said catalyst; said catalyst having a high selectivity for NOx reduction and a high NOx reduction activity even at low temperatures.
摘要翻译：本发明涉及一种用于还原废气中的氮氧化物（NOx）的催化剂，其包括与Co离子交换的结晶金属硅酸盐和在所述结晶金属硅酸盐中形成的特定结构的通道，以及使用所述催化剂的NOx还原方法。所述催化剂对于NOx还原具有高选择性，即使在低温下也具有高NOx还原活性。

10. 发明申请

WO2011039595A3 MIXED OXIDES OF TRANSITION METALS, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM, AND PREPARATION PROCESS COMPRISING SOL -GEL PROCESSES 审中-公开
标题翻译：过渡金属的混合氧化物，其获得的加氢催化剂以及包含溶解过程的制备方法
公开(公告)号：WO2011039595A3
公开(公告)日：2011-10-13
申请号：PCT/IB2010002392
申请日：2010-09-23
申请人： ENI SPA , BELLUSSI GIUSEPPE , CARATI ANGELA , GAGLIARDI MARIA FEDERICA , ZANARDI STEFANO , MARELLA MARCELLO , SCATTOLIN ROBERTO , TOMASELLI MICHELE
发明人： BELLUSSI GIUSEPPE , CARATI ANGELA , GAGLIARDI MARIA FEDERICA , ZANARDI STEFANO , MARELLA MARCELLO , SCATTOLIN ROBERTO , TOMASELLI MICHELE
IPC分类号： B01J27/049 , B01J27/051 , B01J35/10 , B01J37/03 , B01J37/20
CPC分类号： B01J27/0515 , B01J23/002 , B01J23/883 , B01J23/8885 , B01J27/049 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/033 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/1044 , C10G2300/1062 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2400/04 , C10G2400/06 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/845 , B01J2523/847 , B01J2523/41
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) Xa Yb Zc Od. pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, 0 is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH ( I ) wherein the groups RI-RIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b) /c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d = (2a+6b+Hc)/2 wherein H = 4 when Z = Si H = 3 when Z = Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.
摘要翻译：描述了新的硫化金属催化剂，其含有选自Ni，Co及其混合物的金属X，选自Mo，W及其混合物的金属Y，选自Si，Al及其混合物的元素Z以及可能的有机残基，通过硫化混合氧化物前体获得，也是新的，具有通式（A）Xa Yb Zc Od。 pC（A）可以成形为没有粘合剂，或通过硫化具有式（A）的混合氧化物，成型为粘合剂，其中X选自Ni，Co及其混合物，Y选自Mo，W和混合物 Z选自Si，Al及其混合物，0为氧，C选自：氮化合物N，衍生自含氮化合物N的部分煅烧的有机残基，所述含氮化合物N当存在时为选自：a）具有式（I）RIRIIRIIIRIVNOH（I）的烷基氢氧化铵，其中基团RI-RIV相同或不同，是含有1至7个碳原子的脂族基团，b）具有式（II）的胺， R 1 R 2 R 3 N（II）其中R 1是含有4至12个碳原子的直链，支链或环状烷基，R 2和R 3相同或不同，选自H和直链，支链或环状的烷基，其含有4〜 12个碳原子，所述烷基等于或不同于R 1，a，b，c，d ar e分别是元素X，Y，Z，O的摩尔数，p是C相对于具有式（A）的前体的总重量的重量百分比，a，b，c，d高于（a + b）/ c高于或等于0.3且低于或等于10，优选为0.8至10d =（ 2a + 6b + Hc）/ 2，其中当Z = Al时，当Z = Si H = 3时，H = 4，p大于或等于0且小于或等于40％。所述催化剂可用作加氢处理催化剂。

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