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    • 1. 发明申请
    • GLYCOL AND GLYCOL ETHER LUBRICANTS AND SPOTTING FLUIDS
    • GLYCOL和GLYCOL润滑剂和喷头液体
    • WO1995028455A1
    • 1995-10-26
    • PCT/US1995004224
    • 1995-04-05
    • BAKER HUGHES INCORPORATED
    • BAKER HUGHES INCORPORATEDALONSO-DEBOLT, Maria, A.BLAND, Ronald, G.CHAI, Bong, JinEICHELBERGER, Peter, B.ELPHINGSTONE, Eugene, A.
    • C09K07/00
    • C09K8/22C09K8/02C09K2208/02C09K2208/34E21B31/03Y10S507/928
    • A non-polluting additive or spotting fluid which lubricates, releases and/or prevents differentially stuck drill strings and casings in the wellbore of a subterranean well is presented. This additive composition comprises a glycol or glycol ether derived from a long chain epoxide of greater than 3 carbon atoms (preferably greater than 10 carbon atoms); and preferably comprises the reaction product between 2-ethylhexanol and the epoxide of 1-hexadecene. The present invention enhances the lubricity of a drilling fluid to prevent drill string sticking and when utilized as a spotting agent reduces the time required to release a stuck pipe. This invention also helps reduce or prevent foaming. By eliminating the need for traditional oil-based components, the present invention is non-toxic to marine life, biodegradable, environmentally acceptable, easy to prepare, and capable of being disposed of at the drill site without costly disposal procedures.
    • 提出了一种在地下井的井眼中润滑,释放和/或防止差异卡钻钻柱和壳体的无污染添加剂或点样液。 该添加剂组合物包含衍生自大于3个碳原子(优选大于10个碳原子)的长链环氧化物的二醇或二醇醚; 并且优选包含2-乙基己醇与1-十六碳烯的环氧化物之间的反应产物。 本发明提高了钻井液的润滑性以防止钻柱粘附,并且当用作点样剂时,减少了释放卡住管所需的时间。 本发明还有助于减少或防止起泡。 通过不需要传统的油基成分,本发明对海洋生物无毒性,可生物降解,环境可接受,易于制备,并且能够在钻孔位置处理而无需昂贵的处理程序。
    • 2. 发明申请
    • DRAG REDUCING AGENTS FOR OIL - AND SYNTHETIC-BASED FLUIDS
    • 用于油和合成液体的DRAG还原剂
    • WO2014093483A1
    • 2014-06-19
    • PCT/US2013/074377
    • 2013-12-11
    • BAKER HUGHES INCORPORATED
    • HALLIDAY, William, S.CLAPPER, Dennis, K.BLAND, Ronald, G.
    • C09K8/32C09K8/035E21B43/22
    • C09K8/28C09K8/34
    • Minimizing circulating pressure loss and/or reducing friction in drilling fluid operations to minimize equivalent circulating density (ECD) and maximize flow for borehole cleaning, tool optimization and efficient drilling may be achieved by the addition of friction improvers or drag reducers while circulating drilling fluids. Suitable drag reducers may include, but not necessarily be limited to, poly(alpha-olefins); polyisobutylene; condensation polymers of dicarboxylic acids or anhydrides, or polyols and monocarboxylic acids, addition polymers of unsaturated esters; copolymers of alpha-olefins with unsaturated esters; poly¬ styrene acylated with long chain fatty acids; polyalkylene oxides; copolymers of alkyl acrylates with N-containing olefins; and combinations thereof.
    • 最小化钻井液操作中的循环压力损失和/或减少摩擦,以尽量减少等效循环密度(ECD),并最大限度地提高钻孔清洗的流量,优化工具并进行有效的钻井,同时循环钻井液可增加摩擦改进剂或减阻剂。 合适的减阻剂可以包括但不限于聚(α-烯烃); 聚异丁烯; 二羧酸或酸酐的缩聚物,或多元醇和一元羧酸,不饱和酯的加成聚合物; α-烯烃与不饱和酯的共聚物; 用长链脂肪酸酰化的聚苯乙烯; 聚环氧烷; 丙烯酸烷基酯与含N烯烃的共聚物; 及其组合。
    • 3. 发明申请
    • SPOTTING FLUID AND LUBRICANT
    • 喷油和润滑剂
    • WO1995030818A1
    • 1995-11-16
    • PCT/US1995005604
    • 1995-05-04
    • BAKER HUGHES INCORPORATED
    • BAKER HUGHES INCORPORATEDBLAND, Ronald, G.ADAMS, James, G.
    • E21B31/03
    • E21B31/03C09K8/02C09K8/32C09K2208/02
    • A non polluting additive or spotting fluid which releases and/or prevents differentially stuck drill strings and casings in the wellbore of a subterranean well is presented. This additive composition comprises an ester, preferably monohydric alcohol esters of fatty acids in combination with particulate asphalt. A preferred ester is 2-ethylhexanol ester of a tall oil fatty acid. A preferred asphalt is the asphalt described in Patent 5,120,708. Other preferred components in addition to the ester and asphalt include one or more suitable surfactants, suspension agents such as lime (Ca(OH)2), anticaking and grinding agent such as calcium silicate and antigellation agents such as sodium bicarbonate. The present invention enhances the lubricity of a drilling fluid to prevent drill string sticking and when utilized as a spotting agent reduces the time required to release a stuck pipe. By eliminating the need for oil-based components, the present invention is non-toxic to marine life, environmentally acceptable, easy to prepare, and capable of being disposed of at the drill site without costly disposal procedures.
    • 提出了一种在地下井的井筒中释放和/或防止差异卡钻钻柱和壳体的非污染添加剂或点样液。 该添加剂组合物包含酯,优选脂肪酸的一元醇酯与颗粒沥青的组合。 优选的酯是妥尔油脂肪酸的2-乙基己醇酯。 优选的沥青是专利5,120,708中描述的沥青。 酯和沥青之外的其它优选组分包括一种或多种合适的表面活性剂,悬浮剂如石灰(Ca(OH)2),防结块剂和研磨剂如硅酸钙和抗凝胶剂如碳酸氢钠。 本发明提高了钻井液的润滑性以防止钻柱粘附,并且当用作点样剂时,减少了释放卡住管所需的时间。 通过消除对油基成分的需要,本发明对海洋生物无毒,环境可接受,易于制备,并且能够在钻孔位置处理而无需昂贵的处理程序。
    • 4. 发明申请
    • PROCESS FOR DOWNHOLE HEATING
    • 井下加热的过程
    • WO2006039362A2
    • 2006-04-13
    • PCT/US2005/034910
    • 2005-09-29
    • BAKER HUGHES INCORPORATED
    • BLAND, Ronald, G.YOUNG, David, B.PLESS, Marvin, L.TRENERY, John, B.
    • E21B43/24E21B36/00
    • E21B36/008E21B43/24
    • Neutral electrolytes, relatively neutral electrolytes, metal oxides, metal hydroxides and/or organic exothermic hydration chemicals may be hydrated with water at a controlled location in a subterranean formation to generate sufficient exothermic heat to at least soften and possibly melt and flow bitumen at or near the location. This controlled and localized heating would be useful in drilling through relatively thick bitumen or "tar" beds. In one non­limiting embodiment the exothermic hydration reaction does not generate appreciable amounts of gas. Alternatively, the exothermic reaction may be used to liberate hydrocarbons from gas hydrates in an embodiment where the evolution of gas is acceptable.
    • 中性电解质,相对中性的电解质,金属氧化物,金属氢氧化物和/或有机放热水化化学品可以在地下地层的受控位置用水进行水合以产生足够的放热以至少软化并且 可能在位置或其附近熔化和流动沥青。 这种受控和局部加热对于钻穿较厚的沥青或“焦油”是有用的。 床。 在一个非限制性实施方案中,放热水合反应不产生可观量的气体。 或者,在气体逸出可接受的实施方案中,放热反应可用于从气体水合物中释放烃。
    • 7. 发明申请
    • METHOD OF PARTICLE CHARACTERIZATION BASED ON FLUORESCENCE IMAGING
    • 基于荧光成像的粒子表征方法
    • WO2003040701A1
    • 2003-05-15
    • PCT/US2002/034998
    • 2002-10-31
    • BAKER HUGHES INCORPORATED
    • BLAND, Ronald, G.JONES, Tom
    • G01N15/14
    • G01N15/0227G01N15/1459G01N15/1463G01N33/2823G01N2015/1486G01N2015/1497
    • The invention concerns a method for determining the particle size distribution (PSD) of bridging agents in fluids, particularly aqueous fluids used in hydrocarbon recovery such as drilling fluids, drill-in fluids, completion fluids, and the like. It was discovered that the PSD could be selectively determined for calcium carbonate as a bridging agent because it auto-fluoresces. The method is reproducible and is not bothered by the presence of other particles such as drill solids which interferes with conventional methods, for instance, light-scattering techniques. The light used to fluoresce the bridging agent may be filtered to a particular frequency if there are other components present that fluoresce. Flow cytometry is another technique that could be used to implement the invention.
    • 本发明涉及一种用于确定流体中桥连剂的颗粒尺寸分布PSD的方法,特别是用于烃回收的含水流体,例如钻井液,钻入流体,完井液等。 已经发现,由于自发荧光,PSD可以选择性地测定碳酸钙作为桥连剂。 该方法是可再现的,并且不受其它颗粒例如钻石固体的影响的困扰,这些颗粒干扰常规方法,例如光散射技术。 用于荧光桥接剂的光可以被过滤到特定的频率,如果存在荧光的其它成分。 流式细胞术是可用于实现本发明的另一种技术。