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    • 1. 发明申请
    • CHALCOGENIDE-BASED MATERIALS AND IMPROVED METHODS OF MAKING SUCH MATERIALS
    • 基于氯化铝的材料和改进的制造这种材料的方法
    • WO2011115894A1
    • 2011-09-22
    • PCT/US2011/028324
    • 2011-03-14
    • DOW GLOBAL TECHNOLOGIES LLCGERBI, Jennifer E.LANGLOIS, Marc G.NILSSON, Robert T.
    • GERBI, Jennifer E.LANGLOIS, Marc G.NILSSON, Robert T.
    • H01L21/02H01L21/36
    • H01L31/0749C23C14/0623C23C14/3464C23C14/5866H01L21/02568H01L21/02614H01L21/02631
    • The present invention provides strategies for making high quality CIGS photoabsorbing materials from precursor films that incorporate a sub-stoichiometric amount of chalcogen(s). Chalcogen(s) are incorporated into the CIGS precursor film via co-sputtering with one or more other constituents of the precursor. Optional annealing also may be practiced to convert precursor into more desirable chalcopyrite crystalline form in event all or a portion of the precursor has another constitution. The resultant precursors generally are sub-stoichiometric with respect to chalcogen and have very poor electronic characteristics. The conversion of these precursors into CIGS photoabsorbing material via chalcogenizing treatment occurs with dramatically reduced interfacial void content. The resultant CIGS material displays excellent adhesion to other layers in the resultant photovoltaic devices. Ga migration also is dramatically reduced, and the resultant films have optimized Ga profiles in the top or bottom portion of the film that improve the quality of photovoltaic devices made using the films.
    • 本发明提供了从含有亚化学计量量的硫族元素的前体膜制备高品质CIGS光吸收材料的策略。 通过与前体的一种或多种其它组分的共溅射将硫族化合物并入到CIGS前体膜中。 当前体的全部或一部分具有其它结构的情况下,还可以进行任选退火以将前体转化为更理想的黄铜矿结晶形式。 所得前体通常相对于硫属元素是亚化学计量的并且具有非常差的电子特性。 通过硫属化处理将这些前体转化成CIGS光吸收材料,其界面空隙率显着降低。 所得到的CIGS材料在所得到的光伏器件中显示出对其它层的优异粘合性。 Ga迁移也显着降低,并且所得膜在膜的顶部或底部具有优化的Ga分布,其改善了使用该膜制备的光电装置的质量。
    • 3. 发明申请
    • METHOD OF CONTROLLING INFILTRATION OF COMPLEX-SHAPED CERAMIC-METAL COMPOSITE ARTICLES AND THE PRODUCTS PRODUCED THEREBY
    • 复合成型陶瓷复合材料及其生产产品的控制方法
    • WO1998026102A1
    • 1998-06-18
    • PCT/US1997021588
    • 1997-11-21
    • THE DOW CHEMICAL COMPANYFOX, Richard, T.HAN, ChanPYZIK, Aleksander, J.NILSSON, Robert, T.
    • THE DOW CHEMICAL COMPANY
    • C22C01/10
    • G11B5/7315C04B41/5155C04B41/52C04B41/88C04B41/89C22C1/1036C22C2001/1021C22C2001/1057G11B5/8404
    • A process for preparing complex-shaped, ceramic-metal composite articles, comprising: (a) contacting a non-wettable powder that is non-wetting to a metal to be used for infiltration with a shaped ceramic body to form a layer of the non-wettable powder on one or more surfaces of the shaped ceramic body, wherein the shaped ceramic body has a region where there is no layer of the non-wettable powder, and (b) infiltration the shaped ceramic body with the metal through the region or regions where there is no layer of the non-wettable powder, such that a complex-shaped ceramic-metal composite comprising one or more metal phases and one or more ceramic phases is formed, wherein the article has substantially the net shape of the shaped ceramic body and undesirable regions of excess metal on the surface and undesirable phases within the complex-shaped ceramic-metal composite article near the surface are located only in the region or regions where there is no layer of the non-wettable powder. The process of the invention allows the preparation of complex-shaped ceramic-metal composite articles with undesirable regions of excess metal and undesirable phases on the surface(s), of, or within, the article only in the regions where there is, or was, no layer of non-wettable powder. The process of the invention allows the preparation of a complex-shaped ceramic-metal composite article which requires little or no machining of the surface(s) to achieve a finished article. A complex-shaped ceramic-metal composite article is prepared which contains few undesirable regions of excess metal and undesirable phases.
    • 一种制备复杂形状的陶瓷 - 金属复合制品的方法,包括:(a)将不湿润的非可润湿粉末与用于渗透的金属与成形陶瓷体接触以形成非 - 在成形陶瓷体的一个或多个表面上的可润湿粉末,其中成形陶瓷体具有不存在不可湿性粉末层的区域,(b)使成形陶瓷体与金属渗透穿过该区域或 其中不存在不可湿性粉末层的区域,使得形成包含一个或多个金属相和一个或多个陶瓷相的复合形状的陶瓷 - 金属复合材料,其中制品具有基本上成形陶瓷的净形状 表面上的多余金属的主体和不需要的区域以及表面附近的复合陶瓷 - 金属复合制品内的不期望的相位仅位于不具有不可湿性粉末层的区域或区域中。 本发明的方法允许制备复合形状的陶瓷 - 金属复合制品,其具有不需要的过量金属区域和不期望的相,仅在制品的表面上或内部存在, ,无层不可湿粉。 本发明的方法允许制备复杂形状的陶瓷 - 金属复合制品,其需要很少或不需要加工表面以实现最终制品。 制备复杂形状的陶瓷 - 金属复合制品,其包含少量不需要的过量金属和不期望的相的区域。