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1. 发明申请

WO2022056146A1 TRANSITION METAL-CATALYZED PRODUCTION OF ALCOHOL AND CARBONYL COMPOUNDS FROM HYDROCARBONS 审中-公开
公开(公告)号：WO2022056146A1
公开(公告)日：2022-03-17
申请号：PCT/US2021/049690
申请日：2021-09-09
申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP , MONWAR, Masud, M. , BARR, Jared, L. , CRUZ, Carlos, A. , CLEAR, Kathy, S. , MCDANIEL, Max, P.
发明人： ELLIS, William Chad
IPC分类号： B01J23/22 , B01J23/28 , B01J23/30 , C07C27/10 , C07C29/48 , C07C45/27 , C07C51/16 , B01J37/34 , B01J37/16 , B01J35/00
摘要： Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and a supported transition metal catalyst - containing molybdenum, tungsten, or vanadium - are irradiated with a light beam at a wavelength in the UV-visible spectrum, optionally in an oxidizing atmosphere, to form a reduced transition metal catalyst, followed by hydrolyzing the reduced transition metal catalyst to form a reaction product containing the alcohol compound and/or the carbonyl compound.

2. 发明申请

WO2014074622A1 LOW DENSITY POLYOLEFIN RESINS AD FILMS MADE THEREFROM 审中-公开
标题翻译：低密度聚烯烃树脂AD膜制成
公开(公告)号：WO2014074622A1
公开(公告)日：2014-05-15
申请号：PCT/US2013/068785
申请日：2013-11-06
申请人： MCDANIEL, Max, P. , SUKHADIA, Ashish, M. , DING, Errun , TSO, Chung, Ching , MASINO, Albert, P. , YANG, Qing , GUATNEY, Lloyd, W. , ST. JEAN, Guylaine , HERT, Daniel, G.
发明人： MCDANIEL, Max, P. , SUKHADIA, Ashish, M. , DING, Errun , TSO, Chung, Ching , MASINO, Albert, P. , YANG, Qing , GUATNEY, Lloyd, W. , ST. JEAN, Guylaine , HERT, Daniel, G.
IPC分类号： C08J5/18 , C08L23/08
CPC分类号： C08F210/16 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F210/14 , C08F2410/02 , C08F2500/05 , C08F2500/08 , C08F2500/09 , C08F2500/12 , C08J5/18 , C08J2323/08 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2314/06 , C08F4/65904 , C08F2500/04 , C08F2500/07 , C08F2500/26
摘要： Disclosed herein are broad molecular weight distribution olefin polymers having densities in the 0.895 to 0.930 g/cm 3 range, and with improved impact and tear resistance. These polymers can have a ratio of Mw/Mn in the 8 to 35 range, a high load melt index in the 4 to 50 range, less than about 0.008 LCB per 1000 total carbon atoms, and a reverse comonomer distribution.
摘要翻译：本文公开了具有在0.895至0.930g / cm 3范围内的密度并具有改善的耐冲击性和抗撕裂性的宽分子量分布烯烃聚合物。这些聚合物可以具有8至35范围内的Mw / Mn比，4至50范围内的高负荷熔体指数，每1000个总碳原子小于约0.008LCB，反向共聚单体分布。

3. 发明申请

WO2014035875A1 VAPOR PHASE PREPARATION OF FLUORIDED SOLID OXIDES 审中-公开
标题翻译：氟化固体氧化物的蒸气相制备
公开(公告)号：WO2014035875A1
公开(公告)日：2014-03-06
申请号：PCT/US2013/056606
申请日：2013-08-26
申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP , MCDANIEL, Max P , COLLINS, Kathy S , YANG, Qing , CRAIN, Tony R
发明人： MCDANIEL, Max P , COLLINS, Kathy S , YANG, Qing , CRAIN, Tony R
IPC分类号： B01J37/26 , B01J27/12 , C08F10/00
CPC分类号： B01J35/1023 , B01J21/12 , B01J35/02 , B01J35/1019 , B01J35/1047 , B01J37/26 , C08F4/65912 , C08F4/65927 , C08F110/02 , C08F4/65916
摘要： Methods for the vapor phase preparation of fluorided solid oxide activator-supports, using certain calcining temperatures and fluoriding temperatures, are disclosed.
摘要翻译：公开了使用某些煅烧温度和氟化温度来制备氟化固体氧化物活化剂 - 载体的方法。

4. 发明申请

WO2012170762A1 POLYMER COMPOSITIONS FOR BLOW MOLDING APPLICATIONS 审中-公开
标题翻译：用于吹塑成型应用的聚合物组合物
公开(公告)号：WO2012170762A1
公开(公告)日：2012-12-13
申请号：PCT/US2012/041466
申请日：2012-06-08
申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP , YANG, Qing , MCDANIEL, Max P. , BEAULIEU, William B. , YU, Youlu , CRAIN, Tony R.
发明人： YANG, Qing , MCDANIEL, Max P. , BEAULIEU, William B. , YU, Youlu , CRAIN, Tony R.
IPC分类号： C08F10/00 , C08F210/02
CPC分类号： C08F210/16 , C08F4/65904 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08L23/0815 , C08L2314/06 , C08F210/14 , C08F2500/07 , C08F2500/12 , C08F2500/13
摘要： A polymer having a density of from about 0.960 g/cc to about 0.965 g/cc and a melt index of from about 0.2 g/10 min. to about 0.6 g/10 min. wherein an article formed from the polymer has an environmental stress crack resistance of equal to or greater than about 150 hours when measured in accordance with ASTM D 1693 condition B, 100 % Igepal. A polymer having a density of from about 0.955 g/cc to about 0.960 g/cc and a melt index of from about 0.2 g/10 min. to about 0.6 g/10 min. wherein an article formed from the polymer has an environmental stress crack resistance of equal to or greater than about 500 hours when measured in accordance with ASTM D 1693 condition B, 100 % Igepal
摘要翻译：密度为约0.960g / cc至约0.965g / cc，熔体指数为约0.2g / 10min的聚合物。至约0.6g / 10min。其中根据ASTM D1693条件B，100％Igepal测量时，由聚合物形成的制品具有等于或大于约150小时的环境应力开裂性。密度为约0.955g / cc至约0.960g / cc，熔体指数为约0.2g / 10min的聚合物。至约0.6g / 10min。其中由所述聚合物形成的制品在根据ASTM D1693条件B测量时具有等于或大于约500小时的环境应力抗裂性，100％Igepal

5. 发明申请

WO2012033670A1 NOVEL CATALYST SYSTEMS AND METHODS OF MAKING AND USING SAME 审中-公开
标题翻译：新型催化剂体系及其制备和使用方法
公开(公告)号：WO2012033670A1
公开(公告)日：2012-03-15
申请号：PCT/US2011/049633
申请日：2011-08-30
申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP , YANG, Qing , MCDANIEL, Max, P. , MARTIN, Joel, L. , DING, Errun , ROHLFING, David, C. , CRAIN, Tony, R.
发明人： YANG, Qing , MCDANIEL, Max, P. , MARTIN, Joel, L. , DING, Errun , ROHLFING, David, C. , CRAIN, Tony, R.
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C08F4/64148 , C08F4/64151 , C08F4/653 , C08F4/65904 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/0815 , Y10S526/943 , C08F210/14 , C08F2500/12 , C08F2500/05 , C08F2500/17 , C08F4/63904 , C08F4/64144 , C08F4/64158
摘要： A catalyst composition comprising (a) a first metallocene complex represented by the general formula (MTE-A), where M 1 is Ti, Zr or Hf, X 1 and X 2 are each independently F, CI, Br, I, methyl, benzyl, phenyl, H, BH 4 , a hydrocarbyloxide group having up to 20 carbon atoms, a hydrocarbylamino group having up to 20 carbon atoms, a trihydrocarbylsilyl group having up to 20 carbon atoms, OBR' 2 wherein R' may be an alkyl group having up to 12 carbon atoms or an aryl group having up to 12 carbon atoms, and SO 3 R" wherein R" may be an alkyl group having up to 12 carbon atoms or an aryl group having up to 12 carbon atoms, and Cp 1 and Cp 2 are each independently a substituted or unsubstituted cyclopentadienyl group, or a substituted or unsubstituted indenyl group, where any substituent on Cp 1 and Cp 2 is H, a hydrocarbyl group having up to 18 carbon atoms or a hydrocarbylsilyl group having up to 18 carbon atoms, (b) a second metallocene complex, (c) a non-group 4 metallocene transition-metal complex, (d) an activator or activator-support, and (e) an optional cocatalyst.
摘要翻译：一种催化剂组合物，其包含（a）由通式（MTE-A）表示的第一茂金属络合物，其中M1是Ti，Zr或Hf，X1和X2各自独立地为F，Cl，Br，I，甲基，苄基，苯基，H，BH4，具有至多20个碳原子的烃氧基，具有至多20个碳原子的烃基氨基，具有至多20个碳原子的三烃基甲硅烷基，OBR 2，其中R'可以是具有至多12个碳原子或具有至多12个碳原子的芳基，SO 3 R“其中R”可以是具有至多12个碳原子的烷基或具有至多12个碳原子的芳基，而Cp1和Cp2各自独立地是取代的或未取代的环戊二烯基或取代或未取代的茚基，其中Cp1和Cp2上的任何取代基为H，具有至多18个碳原子的烃基或具有至多18个碳原子的烃基甲硅烷基，（b）第二茂金属络合物，（c）非基团4茂金属过渡金属络合物，（d）活化剂或活化剂 - 载体，和（e）任选的助催化剂。

6. 发明申请

WO2010098827A1 POLYETHYLENE FILM HAVING IMPROVED BARRIER PROPERTIES AND METHODS OF MAKING SAME 审中-公开
标题翻译：具有改进障碍物的聚乙烯膜及其制造方法
公开(公告)号：WO2010098827A1
公开(公告)日：2010-09-02
申请号：PCT/US2010/000508
申请日：2010-02-23
申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP , SUKHADIA, Ashish, M. , MCDANIEL, Max, P. , CYMBALUK, Ted, H. , KRISHNASWAMY, Rajendra, K. , SZMUTO, Lawrence
发明人： SUKHADIA, Ashish, M. , MCDANIEL, Max, P. , CYMBALUK, Ted, H. , KRISHNASWAMY, Rajendra, K. , SZMUTO, Lawrence
IPC分类号： C08F10/02 , C08F4/24 , C08F4/02 , C08J5/18
CPC分类号： C08F110/02 , C08J5/18 , C08J2323/04 , C08F4/24 , C08F2500/07 , C08F2500/12 , C08F2500/17 , C08F2500/19 , C08F2500/26
摘要： A polymeric resin having a density of greater than 0.960 g/cc, a melt index of from 1.3 g/10 min. to 2.8 g/10 min., a zero shear viscosity of from Ix 10 4 Pa*s to 1 x 10 5 Pa*s, a recoverable shear parameter of from 220 to 370, and a CY-a parameter of from 0.155 to 0.200. A polymeric resin having an initial tension defined by the equation IT>-1.67*(MI)+b where b is 5.17 and a percent decrease in the extrusion pressure of the resin of 30% when compared to polymer resin of similar melt index prepared with a catalyst that has not undergone an activation comprising an oxidation, reduction, oxidation sequence wherein the resin when formed into a film has a moisture vapor transmission rate of from 0.21 g.mil/100 in 2 /day to 0.33 g.mil/100 in 2 /day.
摘要翻译：密度大于0.960g / cc，熔体指数为1.3g / 10min的聚合物树脂。至2.8g / 10分钟，零剪切粘度为1×10 4 Pa * s至1×10 5 Pa * s，可恢复剪切参数为220至370，CY-a参数为0.155至0.200。具有由等式IT> -1.67 *（MI）+ b定义的初始张力的聚合物树脂，其中b为5.17，并且与用相同熔体指数制备的类似熔体指数的聚合物树脂相比，树脂挤出压力的百分比降低30％没有经历活化的催化剂，其包含氧化还原氧化序列，其中当形成膜时树脂的水蒸气透过率为0.21g.mil / 100in2 / day至0.33g.mil / 100in2 / 天。

7. 发明申请

WO2009134361A1 METHODS OF PREPARING A POLYMERIZATION CATALYST 审中-公开
标题翻译：制备聚合催化剂的方法
公开(公告)号：WO2009134361A1
公开(公告)日：2009-11-05
申请号：PCT/US2009/002594
申请日：2009-04-29
申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP , MCDANIEL, Max, P. , COLLINS, Kathy, S.
发明人： MCDANIEL, Max, P. , COLLINS, Kathy, S.
IPC分类号： C08F10/00 , C08F4/24 , C08F4/18
CPC分类号： C08F110/02 , C08F4/18 , C08F4/24 , C08F2500/12 , C08F2500/04
摘要： A method comprising contacting a support with a chromium-containing compound and a tin-containing compound to produce a catalyst precursor, and activating the catalyst precursor in a temperature range of from about 400 〬C to about 700 〬C to produce a polymerization catalyst. A method comprising contacting a support with a chromium-containing compound and a tin-containing compound to produce a catalyst precursor, activating the catalyst precursor in a temperature range of from about 400 〬C to about 700 〬C to produce a polymerization catalyst, and contacting the polymerization catalyst with ethylene in a reaction zone under suitable reaction conditions to form polyethylene wherein the molecular weight distribution of the polyethylene is broadened. 〫〫
摘要翻译：一种方法，包括使载体与含铬化合物和含锡化合物接触以产生催化剂前体，并在约400℃至约700℃的温度范围内活化催化剂前体以产生聚合催化剂。一种方法，包括使载体与含铬化合物和含锡化合物接触以制备催化剂前体，在约400℃至约700℃的温度范围内活化催化剂前体以产生聚合催化剂，以及在合适的反应条件下在反应区中使聚合催化剂与乙烯接触以形成聚乙烯，其中聚乙烯的分子量分布变宽。 ??

8. 发明申请

WO2009117128A1 ALUMINA-SILICA ACTIVATOR-SUPPORTS FOR METALLOCENE CATALYST COMPOSITIONS 审中-公开
标题翻译：用于金属催化剂组合物的氧化铝 - 二氧化硅活化剂 - 支持物
公开(公告)号：WO2009117128A1
公开(公告)日：2009-09-24
申请号：PCT/US2009/001741
申请日：2009-03-18
申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP , MCDANIEL, Max, P. , YANG, Qing , MUNINGER, Randall, S. , BENHAM, Elizabeth, A. , COLLINS, Kathy, S.
发明人： MCDANIEL, Max, P. , YANG, Qing , MUNINGER, Randall, S. , BENHAM, Elizabeth, A. , COLLINS, Kathy, S.
IPC分类号： C08F4/02 , C08F4/6592 , C08F10/02 , B01J31/22
CPC分类号： C08F10/02 , B01J31/143 , B01J31/1608 , B01J31/1616 , B01J31/1805 , B01J31/2226 , B01J31/2295 , B01J2531/0225 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F110/02 , C08F210/16 , C08F4/65916 , C08F4/025 , C08F210/14
摘要： The present invention provides activator-supports containing alumina-silica compounds with high levels of alumina, and polymerization catalyst compositions employing these activator-supports together with a metallocene compound. Methods for making these activator-supports based on alumina-silica and for using such compounds in catalyst compositions for the polymerization and copolymerization of olefins are also provided.
摘要翻译：本发明提供含有氧化铝含量高的氧化铝 - 二氧化硅化合物的活化剂 - 载体，以及使用这些活化剂 - 载体和茂金属化合物的聚合催化剂组合物。还提供了用于制备基于氧化铝 - 二氧化硅的这些活化剂 - 载体和在催化剂组合物中用于烯烃的聚合和共聚的方法。

9. 发明申请

WO2009085100A2 FAST ACTIVATING CATALYST 审中-公开
标题翻译：快速活化催化剂
公开(公告)号：WO2009085100A2
公开(公告)日：2009-07-09
申请号：PCT/US2008013497
申请日：2008-12-09
申请人： CHEVRON PHILLIPS CHEMICAL CO , NEIL GEORGE , BENHAM ELIZABETH A , CYMBALUK TED H , MCDANIEL MAX P
发明人： NEIL GEORGE , BENHAM ELIZABETH A , CYMBALUK TED H , MCDANIEL MAX P
IPC分类号： C08F10/00 , C08F4/02 , C08F4/69
CPC分类号： C08F10/00 , B01J21/08 , B01J23/26 , B01J35/1019 , B01J35/1047 , B01J35/1061 , B01J37/0207 , B01J37/036 , B01J37/06 , C08F110/02 , C08F4/025 , C08F4/78 , C08F2500/09 , C08F2500/12 , C08F2500/17 , C08F2500/07
摘要： A method of preparing a catalyst comprising aging a silica support in an alkaline solution to produce an alkaline aged silica support, removing at least a portion of the alkaline solution from the alkaline aged silica support to produce a dried silica support, and activating the silica support to produce a catalyst composition, wherein alkaline aging lowers the surface area of the silica support to less than about 50% of the original value and wherein activation of the silica support is carried out in batches of equal to or greater than about 500 lbs for a time period of less than about 8 hours. A method of preparing a polymer comprising alkaline aging a silica support material, adding chromium to the silica support material prior to the alkaline aging, after the alkaline aging, or both to form a chromium-silica support, rapidly activating the chromium-silica support produce an activated olefin polymerization catalyst, contacting the activated olefin polymerization catalyst with at least one monomer in a reaction zone under conditions suitable to produce a polymer, and recovering the polymer
摘要翻译：一种制备催化剂的方法，包括在碱性溶液中老化二氧化硅载体以产生碱性老化二氧化硅载体，从碱性老化二氧化硅载体除去至少一部分碱性溶液以产生干燥二氧化硅载体，并活化二氧化硅载体以产生催化剂组合物，其中碱性老化将二氧化硅载体的表面积降低到小于原始值的约50％，并且其中二氧化硅载体的活化以等于或大于约500lb的批次进行，用于时间段少于约8小时。一种制备聚合物的方法，其包括使二氧化硅载体材料碱性老化，在碱性老化之前，碱性老化之后向二氧化硅载体材料中加入铬，或两者形成铬二氧化硅载体，快速活化铬 - 二氧化硅载体产物活化烯烃聚合催化剂，在适合于生产聚合物的条件下，在反应区中使活化烯烃聚合催化剂与至少一种单体接触，并回收聚合物

10. 发明申请

WO2009042149A2 METHODS OF PREPARING A POLYMERIZATION CATALYST 审中-公开
标题翻译：制备聚合催化剂的方法
公开(公告)号：WO2009042149A2
公开(公告)日：2009-04-02
申请号：PCT/US2008011068
申请日：2008-09-24
申请人： CHEVRON PHILLIPS CHEMICAL CO , COLLINS KATHY S , MCDANIEL MAX P
发明人： COLLINS KATHY S , MCDANIEL MAX P
IPC分类号： C08F4/60 , B01J21/06 , B01J23/26 , B01J35/10 , B01J37/02 , B01J37/08 , C08F4/18 , C08F4/24 , C08F10/00
CPC分类号： B01J31/2239 , B01J23/86 , B01J31/223 , B01J31/2234 , B01J2231/122 , B01J2531/46 , B01J2531/62 , C08F10/00 , C08F210/16 , C08F2410/04 , C08F4/24 , C08F4/16 , C08F4/22 , C08F4/025 , C08F210/14
摘要： A method of preparing a catalyst comprising contacting a support with a trivalent titanium compound and a chromium-containing compound. A catalyst composition comprising a support, chromium, and titanium, wherein the titanium is derived from Ti3Cl3, Ti2(SO4)3,,Ti(OAc)3, Ti(+3) oxylate, Ti(NO3)3, Ti(+3) lactate or combinations thereof.
摘要翻译：一种制备催化剂的方法，包括使载体与三价钛化合物和含铬化合物接触。包含载体，铬和钛的催化剂组合物，其中钛衍生自Ti3Cl3，Ti2（SO4）3，Ti（OAc）3，Ti（+3）氧化物，Ti（NO3）3，Ti（+3））乳酸盐或其组合。

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