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1. 发明申请

WO2011102924A3 PROCESS FOR ACTIVATING CHROMIUM CATALYST BY TWO STEP THERMAL TREATMENT 审中-公开
标题翻译：通过两步热处理活化铬催化剂的方法
公开(公告)号：WO2011102924A3
公开(公告)日：2015-09-03
申请号：PCT/US2011021097
申请日：2011-01-13
申请人： CHEVRON PHILLIPS CHEMICAL CO , BENHAM ELIZABETH A , MCDANIEL MAX P
发明人： BENHAM ELIZABETH A , MCDANIEL MAX P
IPC分类号： C08F2/38 , B01J23/26
CPC分类号： B01J37/08 , B01J23/26 , B01J37/14 , C08F10/00 , C08F4/24
摘要： A system and method for activating chromium catalyst, including: increasing temperature of a chromium catalyst at a first rate for a first period of time to a first temperature; and increasing temperature of the chromium catalyst at a second rate for a second period of time from the first temperature to a second temperature, wherein the first rate is greater than the second rate, and wherein the first period precedes the second period.
摘要翻译：一种用于活化铬催化剂的体系和方法，包括：将第一时间段的铬催化剂的温度升至第一温度; 以及以第二速率将铬催化剂的温度从第一温度升至第二温度第二时间段，其中第一速率大于第二速率，并且其中第一时段在第二周期之前。

2. 发明申请

WO2015007828A1 CHROMIUM(III) SILICATE CATALYSTS SUITABLE FOR PE SYNTHESIS 审中-公开
标题翻译：（III）适合PE合成的硅酸盐催化剂
公开(公告)号：WO2015007828A1
公开(公告)日：2015-01-22
申请号：PCT/EP2014/065348
申请日：2014-07-17
申请人： ETH ZURICH
发明人： COPÉRET, Christophe , CONLEY, Matthew , DELLEY, Murielle
IPC分类号： C08F4/22 , C08F4/24 , C08F10/02 , C08F4/02
CPC分类号： C08F110/02 , C07F13/005 , C08F10/02 , C08F2410/03 , C08F4/22 , C08F4/24 , C08F4/025 , C08F2500/04
摘要： Molecular precursor chromium compounds and chromium on silica catalyst precursors suitable for use in producing chromium on silica catalysts are disclosed. The molecular precursor compounds can be chromium(II) and/or chromium(III) and/or chromium (IV) compounds wherein all ligands are easily removable, in particular ligands selected from the group consisting of anionic ligands of the type -O-CR 3 R 4 -CH-R 1 R 2 or -O-Si-(O- CR 3 R 4 -CH-R 1 R 2 ) 3 wherein R1, R2, R3 and R4 may be the same or different and may be any group that does not affect decomposition of the ligand via elimination of beta-hydrogen from -CR 3 R 4 -CH-R 1 R 2 , amide anionic ligands of the type -N-Si-R 5 R 6 R 7 and/or -N-C-R 5 R 6 R 7 , wherein R 5 , R 6 and R 7 can be the same or different and are preferably selected from hydrogen, methyl groups, ethyl groups, n-propyl groups, iso-propyl groups, tert-butyl groups or aromatic groups; as well as coordinating solvents. These molecular precursors can be grafted to silica and - if need be - either before or after heat treatment during which the ligands are removed, oxidized to Cr(III). The chromium on silica catalyst is characterized by the absence of any organic ligands.
摘要翻译：公开了分子前体铬化合物和适用于在二氧化硅催化剂上生产铬的二氧化硅催化剂前体上的铬。分子前体化合物可以是其中所有配体易于除去的铬（II）和/或铬（III）和/或铬（IV）化合物，特别是选自-O-CR 3 R 4型阴离子配体的配体 -CH-R 1 R 2或-O-Si-（O-CR 3 R 4 -CH-R 1 R 2）3，其中R 1，R 2，R 3和R 4可以相同或不同，并且可以是不影响配体通过消除来自-CR 3 R 4 -CH-R 1 R 2的β-氢，-N-Si-R 5 R 6 R 7和/或-NC-R 5 R 6 R 7的酰胺阴离子配位体，其中R 5，R 6和R 7可以相同或不同，优选选自氢，甲基，乙基，正丙基，异丙基，叔丁基或芳基; 以及配位溶剂。这些分子前体可以接枝到二氧化硅上，如果需要，在热处理之前或之后，将配体除去，氧化成Cr（III）。二氧化硅催化剂上的铬的特征在于不存在任何有机配体。

3. 发明申请

WO2013092195A1 PROCESS FOR PREPARING OLEFIN POLYMER BY SLURRY LOOP POLYMERIZATION HAVING HIGH POWDER DENSITY 审中-公开
标题翻译：通过具有高浓度密度的浆料环聚合制备烯烃聚合物的方法
公开(公告)号：WO2013092195A1
公开(公告)日：2013-06-27
申请号：PCT/EP2012/074303
申请日：2012-12-04
申请人： BASELL POLYOLEFINE GMBH
发明人： KÖLLING, Lars , MIHAN, Shahram
IPC分类号： C08F10/02 , C08F4/22 , B01J19/18
CPC分类号： C08F110/02 , C08F2/14 , C08F10/02 , C08F210/16 , C08F210/14 , C08F2500/07 , C08F2500/12 , C08F2500/24 , C08F4/24
摘要： The instant invention pertains to a process for preparing an ethylene homo- or copolymer in the presence of a supported chromium catalyst by slurry loop polymerization or copolymerization, whereby the resulting polymer powder has an increased powder density, in which the supported chromium catalyst has a chromium content of from 0.01 to 5 wt.-%, based on the element in the finished catalyst, and shows a particle size distribution measured according to ISO 13320-2009 comprising two main fractions one of which having a d 50 of from 15 to 40 μm and the other having a d 50 of from 45 to 80 μm said catalyst being further characterized by the fact that less than 10% wt of its catalyst particles has diameter lower than 20 μm.
摘要翻译：本发明涉及在负载型铬催化剂存在下通过淤浆环聚合或共聚合制备乙烯均聚物或共聚物的方法，由此得到的聚合物粉末具有增加的粉末密度，其中负载的铬催化剂具有铬基于成品催化剂中的元素含量为0.01至5重量％，并且显示根据ISO 13320-2009测量的粒度分布，其包含两个主要部分，其中一个具有15至40μm的d 50，以及另一个具有45-80微米的d50，所述催化剂的特征还在于其小于10重量％的催化剂颗粒的直径小于20微米。

4. 发明申请

WO2011092306A1 INJECTION STRETCH BLOW MOULDING CONTAINERS PREPARED WITH POLYETHYLENE 审中-公开
标题翻译：注塑吹塑成型容器用聚乙烯制成
公开(公告)号：WO2011092306A1
公开(公告)日：2011-08-04
申请号：PCT/EP2011/051255
申请日：2011-01-28
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , BOISSIERE, Jean-Marie , VANTOMME, Aurélien , BELLOIR, Pierre , VAN SINOY, Alain
发明人： BOISSIERE, Jean-Marie , VANTOMME, Aurélien , BELLOIR, Pierre , VAN SINOY, Alain
IPC分类号： C08F10/02 , C08F2/34
CPC分类号： B65D1/0207 , B29C49/06 , B65B5/00 , C08F10/00 , C08F10/02 , Y10T428/1397 , C08F2/34 , C08F2500/12 , C08F2500/07 , C08F4/24
摘要： An injection stretch blow moulded container prepared essentially from polyethylene prepared in the presence of a chromium-based catalyst system, the polyethylene having a density of from 0.950 to 0.965 g/cm 3 , measured following the method of standard test ASTM 1505 at a temperature of 23 °C, a melt index Ml 2 of from 0.5 to 5 g/10min, measured following the method of standard test ASTM D 1238 at a temperature of 190 °C and under a load of 2.16 kg, and a high load melt index HLMI of from 40 to 150 g/10min, measured following the method of standard test ASTM D 1238 at a temperature of 190 °C and under a load of 21.6 kg, the container weighing from 10 to 150g per dm 3 of volume, when the container has a volume of less than 300 cm 3 , the container weighing from 10 to 80g per dm 3 of volume, when the container has a volume of at least 300 cm 3 .
摘要翻译：基于由在铬基催化剂体系存在下制备的聚乙烯制备的注射拉伸吹塑成型容器，密度为0.950-0.965g / cm 3的聚乙烯，按照标准测试ASTM 1505的方法，在23℃ ℃，根据标准试验ASTM D 1238的方法，在190℃的温度和2.16kg的负荷下测量的熔体指数M12为0.5至5g / 10min，高负荷熔体指数HLMI为在190℃的温度和21.6kg的负荷下，按照标准测试ASTM D 1238的方法测量的容积为10至150g / dm 3的容器的容积为40至150g / 10min，当容器具有体积小于300cm 3的容器，当容器具有至少300cm 3的体积时，容器的体积为10至80g / dm 3。

5. 发明申请

WO2010057925A1 METHOD FOR OPTIMISING THE SUPPLY OF CATALYST SLURRY TO A POLYMERIZATION REACTOR 审中-公开
标题翻译：优化催化剂浆料供应给聚合反应器的方法
公开(公告)号：WO2010057925A1
公开(公告)日：2010-05-27
申请号：PCT/EP2009/065399
申请日：2009-11-18
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , TANGHE, Rudi
发明人： TANGHE, Rudi
IPC分类号： C08F10/00 , C08F2/14 , C08F2/01 , C08F4/24
CPC分类号： C08F10/00 , B01J8/002 , B01J8/0035 , B01J8/20 , B01J2208/00628 , B01J2208/00663 , B01J2208/00752 , B01J2208/00769 , C08F10/02 , C08F2400/02 , C08F2/00 , C08F4/24 , C08F2/01
摘要： The present invention relates to a method for optimizing the supply of a catalyst slurry during a polymerization process for preparing a polyolefin in a polymerization reactor (1), whereby said slurry consists of solid catalyst particles suspended in a hydrocarbon diluent and is characterised by a ratio of solid catalyst particles/diluent, whereby the catalyst slurry is fed to the reactor through at least two parallel catalyst feeding conduits (4, 104) which are intermittently operative in the polymerisation process, said method comprising the steps of : - determining an effective initial ratio solid catalyst particles/diluent for the polymerization process; - determining the actual ratio solid catalyst particles/diluent in a first operative feeding conduit (4); - calculating the difference between actual and initial ratio and in the event that said difference is more than a specified threshold, shutting down the first catalyst feeding conduit (4) and activating a second catalyst feeding conduit (104). The catalyst slurry is periodically supplied to the reactor. The invention also relates to polyolefin production processes and polyolefin producing units.
摘要翻译：本发明涉及在聚合反应器（1）中制备聚烯烃聚合过程中优化催化剂浆料供应的方法，其中所述浆料由悬浮在烃类稀释剂中的固体催化剂颗粒组成，其特征在于比例的固体催化剂颗粒/稀释剂，由此催化剂浆料通过在聚合过程中间歇地操作的至少两个平行的催化剂进料导管（4,104）进料到反应器中，所述方法包括以下步骤： - 确定有效的初始比固体催化剂颗粒/稀释剂用于聚合过程; - 确定第一操作进料管道（4）中固体催化剂颗粒/稀释剂的实际比例; - 计算实际和初始比率之间的差异，以及在所述差异大于指定阈值的情况下，关闭第一催化剂进料管道（4）并激活第二催化剂供给管道（104）。催化剂浆料周期性地供应到反应器中。本发明还涉及聚烯烃生产方法和聚烯烃生产单元。

6. 发明申请

WO2009085104A1 CONTINUOUS CATALYST ACTIVATOR 审中-公开
标题翻译：连续催化剂活化剂
公开(公告)号：WO2009085104A1
公开(公告)日：2009-07-09
申请号：PCT/US2008/013529
申请日：2008-12-09
申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP , NEWSOME, Charles K. , BENHAM, Elizabeth A. , CYMBALUK, Ted H. , MCDANIEL, Max P.
发明人： NEWSOME, Charles K. , BENHAM, Elizabeth A. , CYMBALUK, Ted H. , MCDANIEL, Max P.
IPC分类号： B01J8/26 , B01J8/36
CPC分类号： B01J19/0033 , B01J8/006 , B01J8/26 , B01J8/36 , B01J23/26 , B01J23/92 , B01J35/023 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J37/08 , B01J37/16 , B01J38/10 , B01J38/30 , B01J2208/0084 , C08F10/00 , C08F210/16 , Y02P20/584 , C08F210/14 , C08F2500/12 , C08F4/24
摘要： Methods and systems for preparing catalyst, such as chromium catalysts, are provided. The valence of at least a portion of the catalyst sent to an activator is changed from Cr(III) to Cr(VI). The catalyst is prepared or activated continuously using a fluidization bed catalyst activator.
摘要翻译：提供了制备催化剂如铬催化剂的方法和系统。送到活化剂的催化剂的至少一部分的化合价从Cr（III）变为Cr（VI）。使用流化床催化剂活化剂连续制备或活化催化剂。

7. 发明申请

WO2005111098A1 A PROCESS FOR THE PREPARATION OF AN ETHYLENE COPOLYMER 审中-公开
标题翻译：一种制备乙烯共聚物的方法
公开(公告)号：WO2005111098A1
公开(公告)日：2005-11-24
申请号：PCT/EP2005/004640
申请日：2005-04-28
申请人： SABIC POLYETHYLENES B.V. , NOOIJEN, Godefridus, Arnoldus, Henricus , MEIJERS, Ramon, Hubertus, Anna, Maria , MCCARTHY, Mary , VAN KESSEL, Matthijs
发明人： NOOIJEN, Godefridus, Arnoldus, Henricus , MEIJERS, Ramon, Hubertus, Anna, Maria , MCCARTHY, Mary , VAN KESSEL, Matthijs
IPC分类号： C08F210/00
CPC分类号： C08F10/00 , C08F210/16 , C08F4/69 , C08F2/001 , C08F4/24 , C08F2500/18 , C08F2500/24
摘要： The invention relates to a process for the preparation of an ethylene copolymer by polymerizing ethylene and at least one alpha-olefin in the presence of a chromium-containing catalyst and a diluent. In the first step of the polymerization ethylene and/or propylene and optionally at least one alpha-olefin comprising 3 to 12 carbon atoms are polymerized with a chromium containing catalyst in an inert diluent in the absence of an alkyl-containing promoter and in a second step, after 2-650 grams of polymer per gram of catalyst have been produced in the first step, the polymerization of ethylene and alpha-olefin takes place in the presence of an alkyl-containing promoter.
摘要翻译：本发明涉及通过在含铬催化剂和稀释剂存在下聚合乙烯和至少一种α-烯烃来制备乙烯共聚物的方法。在聚合的第一步中，在不存在含烷基促进剂的情况下，将乙烯和/或丙烯以及任选的至少一种含有碳原子数为3至12的α-烯烃与惰性稀释剂中的含铬催化剂聚合，步骤中，在第一步中已经生产了每克催化剂2-650克聚合物之后，乙烯和α-烯烃的聚合在含烷基促进剂的存在下进行。

8. 发明申请

WO2005075520A1 PREPARATION OF SUPPORTED CATALYSTS FOR POLYMERIZATION 审中-公开
标题翻译：支持的聚合催化剂的制备
公开(公告)号：WO2005075520A1
公开(公告)日：2005-08-18
申请号：PCT/EP2005/001031
申请日：2005-02-02
申请人： BASELL POLYOLEFINE GMBH , MIHAN, Shahram , WULFF-DÖRING, Joachim , KÖPPL, Alexander , ROHDE, Wolfgang
发明人： MIHAN, Shahram , WULFF-DÖRING, Joachim , KÖPPL, Alexander , ROHDE, Wolfgang
IPC分类号： C08F4/02
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F4/025 , C08F4/24 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F2500/18 , C08F2500/24 , C08F4/22 , C08F4/78
摘要： The invention relates to a process for preparing a supported catalyst, in particular for the polymerization and/or copolymerization of olefins, which comprises: 5 a) preparing a hydrogel; b) milling the hydrogel to give a finely particulate hydrogel; c) producing a slurry based on the finely particulate hydrogel; d) drying the slurry comprising the finely particulate hydrogel to give the support for catalysts; e) producing the supported catalyst by applying at least one transition metal and/or at least one transition metal compound to the support for catalysts and, if appropriate, activating the applied metal and/or compound, wherein a finely particulate hydrogel in which - at least 5% by volume of the particles, based on the total volume of the particles, have a particle size in the range from > 0 pm to 0 pm to 0 pm to
摘要翻译：本发明涉及一种制备负载型催化剂的方法，特别是用于烯烃的聚合和/或共聚合，其包括：a）制备水凝胶; b）研磨水凝胶以得到细颗粒水凝胶; c）基于细颗粒水凝胶生产浆料; d）干燥包含细颗粒状水凝胶的浆料，得到催化剂载体; e）通过将至少一种过渡金属和/或至少一种过渡金属化合物施加到催化剂的载体上，并且如果合适地活化所施加的金属和/或化合物，从而制备负载型催化剂，其中细颗粒状水凝胶中，基于颗粒的总体积，至少5体积％的颗粒具有在>0μm至<_3μm范围内的粒度; 和/或 - 至少40体积％的颗粒，基于颗粒的总体积，具有>0μm至< - 12μm范围内的粒度，和/或 - 至少75体积％颗粒基于颗粒的总体积具有>0μm至<-35μm范围内的粒度，在步骤b）中产生，并且可以如步骤a）至d所述制备的载体）用于在步骤e）中制备催化剂。

9. 发明申请

WO2004052948A8 SUPPORTED CHROMIUM CATALYST AND ITS USE FOR PREPARING HOMOPOLYMERS AND COPOLYMERS OF ETHYLENE 审中-公开
标题翻译：支持的铬催化剂及其用于制备乙烯的共聚物和共聚物的用途
公开(公告)号：WO2004052948A8
公开(公告)日：2005-06-16
申请号：PCT/EP0313914
申请日：2003-12-09
申请人： BASELL POLYOLEFINE GMBH , ROHDE WOLFGANG , FUNK GUIDO , HAUFE ANDREAS , BOLD ANKE , NADALIN NEIL
发明人： ROHDE WOLFGANG , FUNK GUIDO , HAUFE ANDREAS , BOLD ANKE , NADALIN NEIL
IPC分类号： B01J21/06 , B01J23/26 , B01J37/02 , C08F10/00 , C08F210/16
CPC分类号： C08F210/16 , C08F4/24 , C08F210/14 , C08F2500/18 , C08F2500/12 , C08F2500/07 , C08F2500/04 , C08F2500/13
摘要： Process for preparing supported, titanized chromium catalysts, which comprises the following steps: A) bringing a support material into contact with a protic medium comprising a titanium compound and a chromium compound, B) optionally removing the solvent, C) optionally calcining the precatalyst obtained after step B) and D) optionally activating the precatalyst obtained after step B) or C) in an oxygen-containing atmosphere at from 400°C to 1100°C.
摘要翻译：制备负载的钛化铬催化剂的方法，其包括以下步骤：A）使载体材料与包含钛化合物和铬化合物的质子介质接触，B）任选地除去溶剂，C）任选地煅烧所得到的预催化剂步骤B）和D）任选地在步骤B）或C）中在400℃至1100℃的含氧气氛中活化预催化剂。

10. 发明申请

WO2004076494A2 PRODUCTION OF BROAD MOLECULAR WEIGHT POLYETHYLENE 审中-公开
标题翻译：生产广泛分子量聚乙烯
公开(公告)号：WO2004076494A2
公开(公告)日：2004-09-10
申请号：PCT/US2004001706
申请日：2004-01-23
申请人： UNIVATION TECH LLC , CANN KEVIN J , ZHANG MINGHUI , MOORHOUSE JOHN H , APECETCHE MARIA A
发明人： CANN KEVIN J , ZHANG MINGHUI , MOORHOUSE JOHN H , APECETCHE MARIA A
IPC分类号： B01J21/08 , B01J23/26 , B01J31/12 , C08F4/02 , C08F4/24 , C08F4/44 , C08F4/60 , C08F10/00 , C08F10/02 , C08F210/16 , C08F
CPC分类号： B01J31/122 , B01J21/08 , B01J23/26 , C08F10/00 , C08F10/02 , C08F210/16 , C08F2410/01 , C08F2410/04 , C08F4/025 , C08F4/24 , C08F4/69 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/18 , C08F2500/07
摘要： Broad molecular weight polyethylene and polyethylene having a bimodal molecular weight profile can be produced with chromium oxide based catalyst systems employing alkyl silanols. The systems may also comprise various organoaluminum compounds. Catalyst activity and molecular weight of the resulting polyethylene may also be tuned using the present invention.
摘要翻译：具有双峰分子量分布的宽分子量聚乙烯和聚乙烯可以用采用烷基硅烷醇的氧化铬基催化剂体系制备。该系统还可以包含各种有机铝化合物。所得聚乙烯的催化剂活性和分子量也可使用本发明进行调节。

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