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    • 2. 发明申请
    • METHOD FOR PRODUCING HALOGEN-FREE REACTIVE POLYISOBUTENE
    • 用于生产无卤素反应活性聚异丁烯
    • WO00008075A1
    • 2000-02-17
    • PCT/EP1999/005013
    • 1999-07-15
    • C08F4/06C08F4/10C08F4/12C08F4/18C08F4/24C08F4/26C08F110/10
    • C08F110/10C08F2/00C08F4/10C08F4/26C08F4/24C08F4/12C08F4/06C08F4/18C08F4/22
    • The invention relates to a method for producing reactive halogen-free polyisobutene containing more than 60 mole % terminal double bonds and having a mean molecular weight Mn of between 800 and 3,000 dalton, by cationic polymerization of isobutene in the liquid phase on an acid, substantially halogen-free heterogeneous catalyst. According to said method a) an isobutene-containing hydrocarbon mixture which consists essentially of C4 hydrocarbons and contains between 10 and 80 % by weight isobutene is used as educt; and b) continuous polymerization is carried out at between -30 and 0 DEG C and mean dwell times of the educt of no more than one hour, the temperature and dwell time being chosen such that isobutene conversion is less than 60 %. After separation of the resulting polyisobutene present in the fully reacted hydrocarbon mixture the isobutene is either enriched and returned to the polymerization stage or fed to another isobutene conversion stage which is coupled to the polymerization stage.
    • 一种用于产生具有大于60摩尔%的末端双键和平均分子量通过在液相中异丁烯的阳离子聚合在由酸性,基本不含卤素的非均相催化剂的Mn为800〜3000道尔顿的含量无卤素,反应活性聚异丁烯过程 具有10的异丁烯含量至80%(重量)作为起始材料基本上使用C4烃和一种烃混合物b)一种)在-30一个含异丁烯的连续聚合至0℃,并在一小时以上的原料的平均滞留时间 被进行,这是所选择的温度和停留时间,使得异丁烯的转化率小于60%,并且其中,从所得到的聚异丁烯中,未反应的烃混合物,所述异丁烯分离后或者累积并循环到聚合或聚合的单元,其耦合其他 异丁烯实施用品。